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At least 1,153 records · Page 64

Innovations Driven by Advanced Characterization to Strategize Critical Mineral Production and Beneficial Reuse from Fossil Energy Waste

Critical minerals (CM), such as rare earth elements (REE), cobalt, nickel, and lithium, have important uses in modern electronics and advanced manufacturing, yet are vulnerable to potential supply chain disruptions. Relatively abundant and readily available fossil energy (FE) wastes, such as coal combustion ash, acid mine drainage (AMD) and treatment solids (AMD solids), and Oil and Gas (O&G) drilling wastes (drill cuttings and produced waters) are under consideration as CM feedstocks. The National Energy Technology Laboratory (NETL) has studied CM resources for various FE wastes as part of the U.S. Department of Energy’s mission of bolstering the domestic CM supply, and makes the data available to the public on EDX at sites such as the NEWTS group. Advanced characterization utilizing synchrotron x-ray techniques coupled with laboratory extractions has been performed to identify CM hosting phases in these FE wastes to inform CM recoverability mechanisms. Novel methods to selectively recover CMs while co-producing other valuable byproducts have been developed. Successful examples discussed here include: (1) The identification of REE/Co/Ni/Sc binding and hosting phases in select FE waste (coal combustion ash and AMD solids), resulting in the development of a patented CM step-extraction process, (2) coupled production of functional sorbents from these extraction wastes and for CM recovery. A pilot-scale testing to evaluate the patent’s technical feasibility for extracting REE from coal ash on a barrel scale has been successfully performed. Additionally, (3) evaluation and measurements of brine geochemistry from U.S. O&G produced waters has informed a high Li recovery potential from Marcellus Shale produced water. NETL researchers have been developing tailored pre-treatment processes, an innovative and highly durable lithium sorbent, and geochemical model guided precipitation to accelerate Li production from the Marcellus Shale produced waters. These innovations driven by characterization are integral for maximizing and advancing the potential for CM recovery while offsetting the cost and environmental footprint for FE waste management.

critical mineral processing↗

Land-Atmosphere Interactions: Successes, Problems and Prospects

After two decades of active research, a much better understanding of the broader role of biospheric processes on the local climate has emerged. A surface-albedo increase, particularly in desert border regions of the subtropics (as well as the deforested tropical regions), leads to a net surface energy deficit, which in turn leads to a relative sinking and reduced rainfall. On the other hand, studies of the influence of altered ratios of evapotranspiration and sensible fluxes, in situations where the net solar income is unchanged, show that evapotranspiration is a more desirable flux for increased precipitation and vitality of the biosphere. Besides providing water vapor and convective available potential energy (CAPE) to the lower troposphere, evapotranspiration helps in building larger CAPE before "turning on" the moist-convection. Larger CAPE in the lower troposphere enables convection to reach into the deeper atmosphere thereby heating the upper troposphere; indeed, moist-convection is also accompanied by the evaporation of falling precipitation that cools and moistens the lower atmosphere. While convective, as opposed to stratiform, precipitation reduces the fractional cloud cover; it also allows more solar radiation to reach the surface thereby invigorating surface fluxes. These, together with moist convection and associated downdrafts help to maintain the characteristic upper temperature limit(s) of the moist-land as well as oceanic regions. Regardless of the above understanding, several important problems continue to hinder the accurate simulation of a realistic land atmosphere interaction in a numerical model (both GCM and/or Meso-scale models). Among the unsolved problems are parameterization of sub-grid scale land processes that include small-scale variability of soil moisture, snow-cover and snow-physics, the biodiversity of the biosphere, orography, local drainage characteristics under natural conditions, and surface flow over the natural terrain. A well-known non-linear response of surface fluxes to these variations makes the problem of parameterizing land-atmosphere interaction processes hard-to-address and simulate, particularly in a GCM. In our presentation, we will discuss how orographic, snow-cover, and water table interactions can be included into a Simple Biosphere Model such as SiB/SSiB. Figure I shows how, in the Russian region, spring snowmelt affects the soil moisture profile. Corresponding figure 2 shows how interaction with the water table decreases the natural evapotranspiration in the Sahel region simulation. While these simulations need better validation with data, the simulations reveal that surface processes are sensitive to these parameterizations. With these developments, we continue to advance our understanding of the interaction of land with the atmosphere aloft, but the intrinsic variability of the newer parameters, e. g., hydraulic properties of the soil, diminish the positive influences of these advances on the improved climate simulation with GCMs.

Sud, Y. C.↗

Modern Era Retrospective-analysis for Research and Applications (MERRA) Global Water and Energy Budgets

In the Summer of 2009, NASA's Modern Era Retrospective-analysis for Research and Applications (MERRA) will have completed 28 years of global satellite data analyses. Here, we characterize the global water and energy budgets of MERRA, compared with available observations and the latest reanalyses. In this analysis, the climatology of the global average components are studied as well as the separate land and ocean averages. In addition, the time series of the global averages are evaluated. For example, the global difference of precipitation and evaporation generally shows the influence of water vapor observations on the system. Since the observing systems change in time, especially remotely sensed observations of water, significant temporal variations can occur across the 28 year record. These then are also closely connected to changes in the atmospheric energy and water budgets. The net imbalance of the energy budget at the surface can be large and different signs for different reanalyses. In MERRA, the imbalance of energy at the surface tends to improve with time being the smallest during the most recent and abundant satellite observations.

Bosilovich, Michael G.↗

Diurnal cycle of precipitation over the tropics and central United States: intercomparison of general circulation models

Diurnal precipitation is a fundamental mode of variability that climate models have difficulty in accurately simulating. Here, in this work, the diurnal cycle of precipitation (DCP) in participating climate models from the Global Energy and Water Exchanges' DCP project is evaluated over the tropics and central United States. Common model biases such as excessive precipitation over the tropics, too frequent light-to-moderate rain, and the failure to capture propagating convection in the central United States still exist. Over the central United States, the issues of too weak rainfall intensity in climate runs is well improved in their hindcast runs with initial conditions from numerical weather prediction analyses. But the improvement is minimal over the central Amazon. Incorporating the role of the large-scale environment in convective triggering processes helps resolve the phase-locking issue in many models where precipitation often incorrectly peaks near noon due to maximum insolation over land. Allowing air parcels to be lifted above the boundary layer improves the simulation of nocturnal precipitation which is often associated with the propagation of mesoscale systems. Including convective memory in cumulus parameterizations acts to suppress light-to-moderate rain and promote intense rainfall; however, it also weakens the diurnal variability. Simply increasing model resolution (with cumulus parameterizations still used) cannot fully resolve the biases of low-resolution climate models in DCP. The hierarchy modeling framework from this study is useful for identifying the missing physics in models and testing new development of model convective processes over different convective regimes.

58 GEOSCIENCES↗

UNCERTAINTY-AWARE DEEP LEARNING FRAMEWORK FOR FORECASTING COASTAL WATER LEVEL IN VIRGINIA BEACH

Coastal areas like Virginia Beach, USA, are increasingly vulnerable to flooding. To mitigate the impact of flooding, it is crucial for the City of Virginia Beach to have reliable 72-hour-ahead (3 days) forecasts of water levels at key gauge locations. To support this effort, several sensors have been installed throughout the city to monitor water levels and other environmental parameters such as wind speed, precipitation, and atmospheric pressure. Leveraging sensor data from one of these locations, we developed an uncertainty-aware deep learning model to forecast water levels. We employed deep quantile regression (DQR) to quantify variability in the predictions and examined the performance of three different model architectures. In addition to exclusively including historical data, we investigated the improvement wind forecasts provide to the accuracy of 72-hour-ahead water level predictions. The results show a twelvefold improvement in the flood forecast for a real flooding event.

Hasan, Mahmud [Thomas Jefferson National Accelerat↗

Characterization of Mesoscale Convective Systems by Means of Composite Radar Reflectivity Data

A mesoscale convective system (MCS) is broadly defined as a cloud and precipitation system of mesoscale dimensions (often too large for most aircraft to circumnavigate) with deep-convective activity concentrated in at least part of the MCS, or present during part of its evolution. A large areal fraction of MCSs is stratiform in nature, yet estimates from MCSs over the Great Plains, the Southeast, and tropical waters indicate that at least half of the precipitation is of convective origin. The presence of localized convection is important, because within convective towers cloud particles and hydrometeors are carried upward towards the cloud top. Ice crystals then move over more stratiform regions, either laterally, or through in situ settling over decaying and spreading convection. These ice crystals then grow to precipitation-size particles in mid- to upper tropospheric mesoscale updrafts. The convective portion of a MCS is often a more or less continuous line of thunderstorms, and may be either short-lived or long-lived. Geerts (1997) presents a preliminary climatology of MCSs in the southeastern USA, using just one year of composite digital radar reflectivity data. In this study MCSs are identified and characterized by means of visual inspection of animated images. A total of 398 MCSs were identified. In the warm season MCSs were found to be about twice as frequent as in the cold season. The average lifetime and maximum length of MCSs are 9 hours, and 350 km, respectively, but some MCSs are much larger and more persistent. In the summer months small and short-lived MCSs are relatively more common, whereas in winter larger and longer-lived systems occur more frequently. MCSs occur more commonly in the afternoon, in phase with thunderstorm activity, but the amplitude of the diurnal cycle is small compared to that of observed thunderstorms. It is estimated that in the Southeast more than half of all precipitation and severe weather results from MCSs.

Geerts, Bart↗

NiAl–MoO 2 S 2 Nanoparticles: Structural Evolution and Mechanistic Insights into High-Performance Selenium Oxyanion Removal across Diverse pH Conditions

Advancing sorbent materials for the selective removal of toxic oxyanions from water requires synthetic control, tunable chemistry, and an atomic-level understanding of structure–function relationships. Here, we report the synthesis and detailed characterization of NiAl–MoO 2 S 2 , a novel layered double hydroxide (LDH) nanomaterial designed for the efficient sequestration of selenium oxoanions (SeO 3 2– and SeO 4 2– ) from complex aqueous environments. The material is synthesized through a room-temperature ion-exchange process, wherein interlayer NO 3 – anions in NiAl–LDH are replaced with MoO 2 S 2 2– clusters, forming high-surface-area, flower-like nanoparticles. Comprehensive structural analysis using the synchrotron X-ray pair distribution function, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy reveals a distinct chemical transformation of intercalated [MoO 2 S 2 ] 2– into [Mo 2 O 2 S 6 ] 2– -like clusters, generating redox-active interlayers that drive selenium capture. This tailored interfacial chemistry underpins the material’s exceptional sorption performance, achieving distribution coefficients (K d ) ≥ 10 6 mL/g and maximum capacities of 343 mg/g for SeO 4 2– and 514 mg/g for SeO 3 2– , outperforming state-of-the-art inorganic sorbents. Importantly, NiAl–MoO 2 S 2 maintains high selectivity and capacity across acidic, neutral, and alkaline pH, efficiently removing selenium from ppm to sub-10 ppb trace levels, even in the presence of competing ions typical of natural and industrial waters. The selenium uptake proceeds via reductive precipitation coupled with the oxidation of molybdenum and sulfide within the LDH framework. This study highlights the power of strategic synthetic modification and interlayer functionalization in LDHs to unlock new structural motifs and redox chemistries, offering a scalable route to advanced materials for environmental remediation.

Adsorption↗

Metastable precipitation and ion–extractant transport in liquid–liquid separations of trivalent elements

The extractant-assisted transport of metal ions from aqueous to organic environments by liquid–liquid extraction has been widely used to separate and recover critical elements on an industrial scale. While current efforts focus on designing better extractants and optimizing process conditions, the mechanism that underlies ionic transport remains poorly understood. Here, we report a nonequilibrium process in the bulk aqueous phase that influences interfacial ion transport: the formation of metastable ion–extractant precipitates away from the liquid–liquid interface, separated from it by a depletion region without precipitates. Although the precipitate is soluble in the organic phase, the depletion region separates the two and ions are sequestered in a long-lived metastable state. Since precipitation removes extractants from the aqueous phase, even extractants that are sparingly soluble in water will continue to be withdrawn from the organic phase to feed the aqueous precipitation process. Solute concentrations in both phases and the aqueous pH influence the temporal evolution of the process and ionic partitioning between the precipitate and organic phase. Aqueous ion–extractant precipitation during liquid–liquid extraction provides a reaction path that can influence the extraction kinetics, which plays an important role in designing advanced processes to separate rare earths and other minerals.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Subseasonal Representation and Predictability of North American Weather Regimes Using Cluster Analysis

Abstract This study focuses on assessing the representation and predictability of North American weather regimes, which are persistent large-scale atmospheric patterns, in a set of initialized subseasonal reforecasts created using the Community Earth System Model, version 2 (CESM2). The k -means clustering was used to extract four key North American (10°–70°N, 150°–40°W) weather regimes within ERA5 reanalysis, which were used to interpret CESM2 subseasonal forecast performance. Results show that CESM2 can recreate the climatology of the four main North American weather regimes with skill but exhibits biases during later lead times with overoccurrence of the West Coast high regime and underoccurrence of the Greenland high and Alaskan ridge regimes. Overall, the West Coast high and Pacific trough regimes exhibited higher predictability within CESM2, partly related to El Niño. Despite biases, several reforecasts were skillful and exhibited high predictability during later lead times, which could be partly attributed to skillful representation of the atmosphere from the tropics to extratropics upstream of North America. The high predictability at the subseasonal time scale of these case-study examples was manifested as an “ensemble realignment,” in which most ensemble members agreed on a prediction despite ensemble trajectory dispersion during earlier lead times. Weather regimes were also shown to project distinct temperature and precipitation anomalies across North America that largely agree with observational products. This study further demonstrates that unsupervised learning methods can be used to uncover sources and limits of subseasonal predictability, along with systematic biases present in numerical prediction systems. Significance Statement North American weather regimes are large-scale atmospheric patterns that can persist for several days. Their skillful subseasonal (2 weeks or greater) prediction can provide valuable lead time to prepare for temperature and precipitation anomalies that can stress energy and water resources. The purpose of this study was to assess the climatological representation and subseasonal predictability of four key North American weather regimes using a research subseasonal prediction system and clustering analysis. We found that the Pacific trough and West Coast high regimes exhibited higher predictability than other regimes and that skillful representation of conditions across the tropics and extratropics can increase predictability during later lead times. Future work will quantify causal pathways associated with high predictability.

58 GEOSCIENCES↗

Investigating the Evolution of Ice Particle Distributions in Mixed-Phase Clouds

The goal of this project is to conduct modeling studies that focus on the processes that control the macrophysical and microphysical properties of mixed phase clouds, such as the partitioning of water phase and the processes that promote precipitation and govern cloud evolution. The process specific to this project is the collection of vapor-grown non-spherical ice crystals and snow hydrometeors through aggregation, as uncertainty remains in the evolution of particle properties as they aggregate. To aid in the understanding of ice particle evolution from pristine monomers to aggregates, the aggregation process is depicted using an offline simulator for ice crystal collection, namely the Ice Particle and Aggregate Simulator (IPAS). Of particular interest in the context of this work is the influence of monomer habit on aggregation and subsequently on cloud microphysical structure. This overarching goal has been completed by conducting modeling studies using the Adaptive Habit Model (AHM) in mixed-phase cloud systems, which predicts and evolves ice shape. While the AHM is designed with physical detail in mind, those details may be lost on larger spatial or temporal scales. Hence, how the contributions of particle growth and collection control the evolution of ice particle size distributions (PSDs) and redistribute mass within the cloud and at the surface has been investigated. Analyses include microphysical sensitivity investigations that inform on future improvement capabilities of microphysical parameterizations in larger scale models. Further, improvements of processes within ice clouds have resulted from this work as the environmental processes controlling ice crystal growth, microphysical processes, and precipitation are inherently integrated within this investigation.

54 ENVIRONMENTAL SCIENCES↗

FY24 Task 5: Leachate Disposition

Directly feeding sludge solids to the high-level waste (HLW) Waste Treatment Plant represents an alternative flowsheet seeking to initiate sludge processing as soon as possible. Key processing functions previously captured during baseline pretreatment operations include leaching and washing prior to solids concentration. These operations should be considered in the potential direct feed flowsheets to maximize waste feed loading, minimize HLW volume, and mitigate corrosion challenges associated with vitrification of high phosphate and fluoride concentrations. Additionally, single-shell tank (SST) retrievals and waste transfers to double-shell tanks (DSTs) in a direct feed flowsheet would likely also benefit from some level of leaching, washing, and solids concentration in order to reduce DST space and mission duration. These operations could occur in a new facility or potentially in available DSTs. If washing and leaching are utilized, an effective disposition pathway for the wash water and leachate solutions are needed. Three target species that benefit significantly from leaching and washing are phosphate, fluoride and aluminum. Phosphate (PO 4 3- ) and fluoride (F - ) can contribute substantially to the amount of carrier fluid needed for dissolution, and the resulting volume of liquid generated. Disposition of this retrieval solution should be evaluated in order to prevent crystallization of these anions throughout system processing. Since there is a high probability that any retrieval solutions will be at or near their PO 4 3- and F - solubility limits, evaporation or blending with a high Na supernate (>3.5 M) is not recommended for the wash water streams without a method to remove precipitants prior to solution disposal. Additionally, aluminum present in the southeast quadrant of the Hanford site represents roughly 60% of the waste solids in the initial processing tanks. These aluminum solids are in the form of gibbsite (Al(OH) 3 ) and can pose significant challenges for processing due to the fast-settling times and high solids loading associated with these materials. Easily remediated by caustic addition to the solids, these wash solutions could be processed through crystalline silicotitanate (CST) ion exchange columns to prepare the supernate solutions for disposition. The current target for feed conditions to the Low Activity Waste (LAW) melter are waste streams that contain nominally 5-6 M Na. Fractions within the tanks contain upwards of 0.2 M phosphate and fluoride in solution at 3.5 M Na. Concentrating these solutions above 5 M Na would result in an exceedance of the solubility limits, and potential for uncontrolled precipitation of the phosphate and fluoride crystal material. The resulting crystalline salt material is typically sodium fluoride phosphate, also referred to as natrophosphate (Na 7 FPO 4 ·19H 2 O). Salt phases are of importance in tank waste due to their chemical reactivity, which can result in precipitation, dissolution, or transformation, impacting any downstream processes (Bolling et al. 2020, Russell, Snow, and Peterson 2010). Salt generation and precipitation could pose challenges by causing system plugging and melter corrosion if left in the supernate stream, or limit sodium molarity of the supernate that would be accepted without incident in waste operations. To understand the impact of this salt generation, the crystallization of natrophosphate in multiple simulant feed matrices was studied to understand the implications of various tank waste supernate chemistries. Three matrices were examined: high PO 4 3- /low F - , low PO 4 3- /high F - , and an average matrix. Subsequent testing was performed with the average matrix with the inclusion of CsNO 3 , and a final run with the average matrix including CsNO 3 and a 137 Cs spike for tracer purposes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Precipitation Recycling in the NASA GEOS Data Assimilation System

Analysis of precipitation recycling can improve the understanding of regional hydrologic anomalies, especially their evolution and maintenance. Diagnostic models of the recycling of precipitation and are applied to 15 years of the NASA Goddard Earth Observing System (GEOS) Data Assimilation System (DAS). Recycled precipitation is defined as the fraction of precipitation within a given region that originated as surface evaporation from the same region. The focus of the present work is on the interannual variability of the central United States hydrologic cycle and precipitation recycling. The extreme years of 1988 (drought) and 1993 (flood) are compared with the 15 year base period mean annual cycle. The results indicate that recycling ratio (the amount of precipitation with a local source relative to the total precipitation) is greater in 1988 than both the base period mean and the 1993 season (with 1993 recycling ratio less than the mean). On the other hand, both the summers of 1988 and 1993 show less total recycled precipitation than the mean. The results also show that precipitation recycling may have been more important in the spring of 1993, when the region was primed for flooding, than the summer, when the sever flooding occurred. The diagnostic approaches to precipitation recycling suffer from some weaknesses. Numerical simulations and assimilation using passive tracers have the potential to provide more accurate calculations of precipitation recycling and the remote sources of water. This ability is being incorporated into the latest GEOS data assimilation system, and some preliminary results will be presented.

Bosilovich, Michael G.↗

The Curious Shorelines of Gorgonum Chaos

Level, bench-like platforms in the interior of the Gorgonum Chaos basin appear to be shorelines associated with an ancient lake. These shorelines, however, seem to lack the typical features of shorelines associated with wave and current transport and erosion, such as crescentic embayments, spits, barrier islands, and wave-cut cliffs. Rather, the lakefacing platform edges are commonly rounded and cumulate in planform, often evenly encircling presumed islands. We interpret these shorelines to have been formed by outward growth in a quiescent environment, possibly in ice-covered bodies of water and possibly, in part, as chemical precipitates.

A D Howard↗

NASA's East and Southeast Asia Initiatives: BASE-ASIA and EAST-AIRE

Airborne dust from northern China influences air quality and regional climate in Asia during springtime. However, with the economic growth in China, increased emission of particulate air pollutants from industrial and vehicular sources will not only impact the earth's radiation balance, but also adversely affect human health year round. In addition, both of dust and aerosol pollutants can be transported swiftly across the Pacific affecting North America within a few days. Asian dust and pollutant aerosols can be detected by their colored appearance using current Earth observing satellites (e.g., MODIS, SeaWiFS, TOMS, etc.) and by sunphotometers deployed on the surface of the earth. Biomass burning has been a regular practice for land clearing and conversion in many countries, especially those in Africa, South America, and Southeast Asia. However, the climatology of Southeast Asia is very different than that of Africa and South America, such that large-scale biomass burning causes smoke to interact extensively with clouds during the peak-burning season of March to April. Globally significant sources of greenhouse gases (eg., CO2, CH4), chemically active gases (e.g., NO, CO, HC, CH3Br), and atmospheric aerosols are produced by biomass burning. These gases influence the Earth-atmosphere system, impacting both global climate and tropospheric chemistry. Some aerosols can serve as cloud condensation nuclei, which play a role in determining cloud lifetime and precipitation, altering the earth's radiation and water budgets. Biomass burning also affects the biogeochemical cycling of nitrogen and carbon compounds; the hydrological cycle; land surface reflectivity and emissivity; and ecosystem biodiversity and stability. Two NASA initiatives, EAST-AIRE (East Asian Study of Tropospheric Aerosols: an International Regional Experiment) and BASE-ASIA (Biomass-burning Aerosols in South East-Asia: Smoke Impact Assessment) will be presented. The objectives of these initiatives is to develop a better understanding of the impacts of aerosols on regional-to-global climate, hydrological and carbon cycles, and tropospheric chemistry.

Tsay, S.↗

Precipitation processes developed during TOGA COARE (1992), GATE (1974), SCSMEX (1998), and KWAJEX (1999): 3D Cloud Resolving Model Simulation

Real clouds and cloud systems are inherently three-dimensional (3D). Because of the limitations in computer resources, however, most cloud-resolving models (CRMs) today are still two-dimensional (2D). A few 3D CRMs have been used to study the response of clouds to large-scale forcing. In these 3D simulations, the model domain was small, and the integration time was 6 hours. Only recently have 3D experiments been performed for multi-day periods for tropical cloud systems with large horizontal domains at the National Center for Atmospheric Research (NCAR), NOAA GFDL, the U.K. Met. Office, Colorado State University and NASA Goddard Space Flight Center. An improved 3D Goddard Cumulus Ensemble (GCE) model was recently used to simulate periods during TOGA COARE (December 19-27, 1992), GATE (september 1-7, 1974), SCSMEX (May 18-26, June 2-11, 1998) and KWAJEX (August 7-13, August 18-21, and August 29-September 12, 1999) using a 512 by 512 km domain and 41 vertical layers. The major objectives of this paper are: (1) to identify the differences and similarities in the simulated precipitation processes and their associated surface and water energy budgets in TOGA COARE, GATE, KWAJEX, and SCSMEX, and (2) to asses the impact of microphysics, radiation budget and surface fluxes on the organization of convection in tropics.

Tao, W.-K.↗

Moisture Advection and Fresh Water Flux over Oceans

Moisture transport in the atmosphere is one of the most significant components in the hydrological cycle. Under stationary condition, ocean surface fresh water flux, which is the difference between precipitation (P) and evaporation (E), is balanced by the divergence of column-integrated moisture transport (IMT) in the atmosphere. Characterizing accurately a global picture of IMT from observation is a difficult task. It requires measurements of vertical profiles for wind vector and humidity. More specifically, IMT can be defined as the integration in pressure coordinates the product of specific humidity q and wind vector u, where g is the gravitational acceleration, and p, is the atmospheric pressure at ocean surface.In this study, a statistical relationship is derived between u, and u(sub)s using data from numerical weather prediction model. The relationship is then validated using surface and vertical profile from radiosonde data, before applied to spacebased measurements.

scatterometers↗

Large-Scale Circulation and Climate Variability

The causes of regional climate trends cannot be understood without considering the impact of variations in large-scale atmospheric circulation and an assessment of the role of internally generated climate variability. There are contributions to regional climate trends from changes in large-scale latitudinal circulation, which is generally organized into three cells in each hemisphere-Hadley cell, Ferrell cell and Polar cell-and which determines the location of subtropical dry zones and midlatitude jet streams. These circulation cells are expected to shift poleward during warmer periods, which could result in poleward shifts in precipitation patterns, affecting natural ecosystems, agriculture, and water resources. In addition, regional climate can be strongly affected by non-local responses to recurring patterns (or modes) of variability of the atmospheric circulation or the coupled atmosphere-ocean system. These modes of variability represent preferred spatial patterns and their temporal variation. They account for gross features in variance and for teleconnections which describe climate links between geographically separated regions. Modes of variability are often described as a product of a spatial climate pattern and an associated climate index time series that are identified based on statistical methods like Principal Component Analysis (PC analysis), which is also called Empirical Orthogonal Function Analysis (EOF analysis), and cluster analysis.

Perlwitz, J.↗

Southern Rockies Western Slope Agriculture: Identifying Drivers of Rangeland Production for Drought Planning on the Western Slope of the Southern Rockies

Over the last decade, the southern Rocky Mountains of the United States have experienced increasingly severe and variable drought. Local ranchers and landowners have reported strain on their operations, citing decreasing forage production for their cattle and a need to adjust their business models, even considering abandoning their businesses altogether. The study identified Major Land Resource Area-48 (MLRA-48) and northwestern Colorado as the key region for analysis. NASA DEVELOP partnered with the BLM Colorado River Field Office, Colorado State University Extension, USDA Forest Service, and the National Drought Mitigation Center to address stakeholder concerns of the efficacy of existing remotely sensed rangeland production estimation platforms and explore possible early warning climatic indicators of drought. The study identified two key rangeland platforms, the Rangeland Production Monitoring Service (RPMS) and Rangeland Analysis Platform (RAP) and used in-situ data to statistically validate their efficacy. RAP outperformed RPMS in estimating in-situ biomass and was therefore used in our climate modeling. Our study performed a random forest analysis, sampling 1500 points across the study area, comparing monthly RAP biomass estimates to a variety of climatic variables, including mean precipitation, temperature, palmer drought severity index, snow water equivalent, wind speed and direction, and vapor pressure deficit. After analysis, our study determined that vapor pressure deficit is a key indicator in predicting forage production in MLRA-48. Our study recommends the use of RAP in estimating potential forage, with caution for its tendency to overestimate. Our climate analysis provided our partners with greater understanding of the influence of various climatic factors in determining forage production and allows them to assist landowners in planning for future drought.

Addie Gonzalez↗