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DOE OSTI2020

Modeling Molecules under Pressure with Gaussian Potentials

The computational modeling of molecules under high pressure is a growing research area that augments experimental high-pressure chemistry. Here, a new electronic structure method for modeling atoms and molecules under pressure, Gaussians On Surface Tesserae Simulate HYdrostatic Pressure (GOSTSHYP) approach, is introduced. In this method, a set of Gaussian potentials is distributed evenly on the van der Waals surface of the investigated chemical system, leading to a compression of the electron density and the atomic scaffold. Since no parameters other than pressure need to be specified, GOSTSHYP allows straightforward geometry optimizations and ab initio molecular dynamics simulations of chemical systems under pressure for nonexpert users. In this work, calculated energies, bond lengths, and dipole moments under pressure fall within the range of established computational methods for high-pressure chemistry. A Diels-Alder reaction and the cyclotrimerization of acetylene showcase the ability of GOSTSHYP to model pressure-induced chemical reactions. The connection to mechanochemistry is pointed out.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1982

Mars - The regolith-atmosphere-cap system and climate change

A model is derived for the prediction of the Martian regolith-atmosphere-cap CO2 regime's behavior, as well as for the description of the roly of the regime in climate change, through descriptions of the time-temperature histories of 90 regolith 'chunks' on a latitude-depth grid. The influence of differences in regolith adsorption laws for basalt and clay, and the influence of variations in regolith depth with (1) latitude, (2) regolith thermal diffusivity, and (3) total exchangeable CO2 inventory on predicted variations in atmospheric pressure and cap mass, are examined. It is found that the atmosphere acts as a low capacity conduit between two reservoirs through which 10-100 times the current atmospheric mass of CO2 flows. The exchange between the reservoirs is driven by obliquity variations, with the polar cap the dominant CO2 sink at low obliquity and the regolith dominating at high obliquity.

Fanale, F. P.↗

NASA NTRS2009

Adapting Radio Control [RC) Models for Research Roles (158308)

Small Unmanned Aircraft Systems (UAS) have show to be useful for numerous observations that can be helpful in Earth science research and related applications. The potential benefits of small instrumented platforms operated within line-of-sight include high spatial resolution, quick response, minimum environmental impact, and affordability, Results to date suggest there is a strong future for small UASs operated for research and environmental monitoring purposes. For example, there is clearly significant potential for observations suitable for agricultural research and production activities. Local scale atmospheric measurements can be helpful in our understanding of water and carbon cycle processes, as well as provide monitoring of key environmental factors such as carbon dioxide and ozone. Recent work has included an emphasis on remote sensing coastal observations, w3h an eye towards related measurements in the polar regions. Specific elements associated with successfully utilizing these small airborne systems include mission definition, sensors and data systems, platform subsystems, airspace access and training.

Bland, Geoffrey L.↗

DOE OSTI2023

Critical fluctuations in liquid–liquid extraction organic phases controlled by extractant and diluent molecular structure

Extractant aggregation in liquid–liquid extraction organic phases impacts extraction energetics and is related to the deleterious efficiency-limiting liquid–liquid phase transition known as third phase formation. Using small angle X-ray scattering, we find that structural heterogeneities across a wide range of compositions in binary mixtures of malonamide extractants and alkane diluents are well described by Ornstein–Zernike scattering. This suggests that structure in these simplified organic phases originates from the critical point associated with the liquid–liquid phase transition. To confirm this, we measure the temperature dependence of the organic phase structure, finding critical exponents consistent with the 3D Ising model. Molecular dynamics simulations were also consistent with this mechanism for extractant aggregation. Due to the absence of water or any other polar solutes required to form reverse-micellar-like nanostructures, these fluctuations are inherent to the binary extractant/diluent mixture. Further, we also show how the molecular structure of the extractant and diluent modulate these critical concentration fluctuations by shifting the critical temperature: critical fluctuations are suppressed by increasing extractant alkyl tail lengths or decreasing diluent alkyl chain lengths. This is consistent with how extractant and diluent molecular structure are known to impact metal and acid loading capacity in many-component LLE organic phases, suggesting phase behavior of practical systems may be effectively studied in simplified organic phases. Overall, the explicit connection between molecular structure, aggregation and phase behavior demonstrated here will enable the design of more efficient separations processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1977

Radar detectability of asteroids - A survey of opportunities for 1977 through 1987

The study of asteroids by earth-based radar during the period 1977 to 1987 is discussed. Detection modeling, including backscattering laws, limits of detectability, and in particular, measurement of center frequency, center-to-limb bandwidth, and areal spectral density, is reviewed. The number of detectable objects and detectable events falling into various 5-decibel radar target loss slots is estimated; a total of 60 different asteroids should be observable on about 130 occasions by either the Goldstone or Arecibo radar systems during the decade considered. Furthermore, the detectability margins for many objects should be large enough to permit more refined analysis of the radar spectrograms. Data acquired during the ten-year period may be used to find the radius, average surface roughness, rotation rate, direction of polar axis, and estimates of the Doppler frequency offsets for many of the asteroids. Also, information about radar albedos and orbital parameters may be obtainable in a number of cases.

Jurgens, R. F.↗

NASA NTRS2000

The Sensitivity of Model Ozone to Advective and Photochemical Processes in the High Latitude Winter Lower Stratosphere

Three dimensional chemistry and transport models (CTMs) contain a set of coupled continuity equations which describe the evolution of constituents such as ozone and other minor species which affect ozone. Both advection and photochemical processes contribute to constituent evolution, and a CTM provides a means to evaluate these contributions separately. Such evaluation is particularly useful when both terms are important to the modeled tendency. An example is the ozone tendency in the high latitude winter lower stratosphere, where advection tends to increase ozone, and catalytic processes involving chlorine radicals tend to decrease ozone. The Goddard three dimensional chemistry and transport model uses meteorological fields from the Goddard Earth Observing System Data Assimilation System, thus the modeled ozone evolution may reproduce the observed evolution and provide a test of the model representation of photochemical processes if the transport is shown to be modeled appropriately. We have investigated the model advection further using diabatic trajectory calculations. For long lived constituents such as N2O, the model field for a particular time on a potential temperature surface is compared with a field produced by calculating 15 day back trajectories for a fixed latitude longitude grid, and mapping model N2O at the terminus of the back trajectories onto the initial grid. This provides a quantitative means to evaluate two aspects of the CTM transport: one, the model horizontal gradient between middle latitudes and the polar vortex is compared with the gradient produced using the non-diffusive trajectory calculation; two, the model vertical advection, which is produced by the divergence of the horizontal winds, is compared with the vertical transport expected from diabatic cooling.

Douglass, A.↗

NASA NTRS2001

Microwave Polarized Signatures Generated within Cloud Systems: SSM/I Observations Interpreted with Radiative Transfer Simulations

Special Sensor Microwave /Imager (SSM/I) observations in cloud systems are studied over the tropics. Over optically thick cloud systems, presence of polarized signatures at 37 and 85 GHz is evidenced and analyzed with the help of cloud top temperature and optical thickness extracted from visible and IR satellite observations. Scattering signatures at 85 GHz (TbV(85) less than or = 250 K) are associated with polarization differences greater than or = 6 K, approx. 50%, of the time over ocean and approx. 40% over land. In addition. over thick clouds the polarization difference at 37 GHz is rarely negligible. The polarization differences at 37 and 85 GHz do not stem from the surface but are generated in regions of relatively homogeneous clouds having high liquid water content. To interpret the observations, a radiative transfer model that includes the scattering by non-spherical particles is developed. based on the T-matrix approach and using the doubling and adding method. In addition to handling randomly and perfectly oriented particles, this model can also simulate the effect of partial orientation of the hydrometeors. Microwave brightness temperatures are simulated at SSM/I frequencies and are compared with the observations. Polarization differences of approx. 2 K can be simulated at 37 GHz over a rain layer, even using spherical drops. The polarization difference is larger for oriented non-spherical particles. The 85 GHz simulations are very sensitive to the ice phase of the cloud. Simulations with spherical particles or with randomly oriented non-spherical ice particles cannot replicate the observed polarization differences. However, with partially oriented non-spherical particles, the observed polarized signatures at 85 GHz are explained, and the sensitivity of the scattering characteristics to the particle size, asphericity, and orientation is analyzed. Implications on rain and ice retrievals are discussed.

Prigent, Catherine↗

NASA NTRS2004

Global Aerosol Profiling by Orbital Lidar, GLAS Results and Validation

The Geoscience Laser Altimeter System (GLAS) launched in 2003 is the first polar orbiting satellite lidar. The instrument was designed for high performance observations of the distribution and optical scattering cross sections of clouds and aerosol. GLAS is approaching six months of on orbit data operation. These data from thousands of orbits illustrate the ability of space lidar to accurately and dramatically measure the height distribution of global aerosol to an unprecedented degree. There were many intended science applications of the GLAS data and significant results have already been realized. profiling is a fundamentally new measurement from space with multiple applications. A most important aerosol application is providing input to global aerosol generation and transport models. Another is improved measurement of aerosol optical depth. A main approach to verify the aerosol optical depth retrieval is comparison to surface measurements by Aeronet. A special feature of the GLAS satellite bus is to rapidly point the lidar instrument at off nadir targets with less than 100 m accuracy. About a dozen selected Aeronet sites were pointed at whenever the G U S lidar came within 5 degrees of zenith. These plus a more general comparison to nearby sites support the G U S data product values. In addition the GUS data can be used to add vertical distribution information to Aeronet aerosol measurements.. As an EOS project instrument, GLAS data products are openly available to the science community. First year results from G U S are summarized.

Spinhirne, J. D.↗

NASA NTRS2008

NASA Remote Sensing Applications for Archaeology and Cultural Resources Management

NASA's Earth Science Mission Directorate recently completed the deployment of the Earth Observation System (EOS) which is a coordinated series of polar-orbiting and low inclination satellites for long-term global observations of the land surface, biosphere, solid Earth, atmosphere, and oceans. One of the many applications derived from EOS is the advancement of archaeological research and applications. Using satellites, manned and unmanned airborne platform, NASA scientists and their partners have conducted archaeological research using both active and passive sensors. The NASA Stennis Space Center (SSC) located in south Mississippi, near New Orleans, has been a leader in space archaeology since the mid-1970s. Remote sensing is useful in a wide range of archaeological research applications from landscape classification and predictive modeling to site discovery and mapping. Remote sensing technology and image analysis are currently undergoing a profound shift in emphasis from broad classification to detection, identification and condition of specific materials, both organic and inorganic. In the last few years, remote sensing platforms have grown increasingly capable and sophisticated. Sensors currently in use, including commercial instruments, offer significantly improved spatial and spectral resolutions. Paired with new techniques of image analysis, this technology provides for the direct detection of archaeological sites. As in all archaeological research, the application of remote sensing to archaeology requires a priori development of specific research designs and objectives. Initially targeted at broad archaeological issues, NASA space archaeology has progressed toward developing practical applications for cultural resources management (CRM). These efforts culminated with the Biloxi Workshop held by NASA and the University of Mississippi in 2002. The workshop and resulting publication specifically address the requirements of cultural resource managers through the use of remote sensing. In 2007, NASA awarded six competitively chosen projects in Space Archaeology through an open solicitation whose purpose, among several, was to addresses the potential benefits to modern society that can be derived through a better understanding of how past cultures succeeded or failed to adapt to local, regional, and global change. A further objective of NASA's space archaeology is the protection and preservation of cultural heritage sites while planning for the sustainable development of cultural resources. NASA s archaeological approach through remote sensing builds on traditional methods of aerial archaeology (i.e. crop marks) and utilizes advanced technologies for collecting and analyzing archaeological data from digital imagery. NASA s archaeological research and application projects using remote sensing have been conducted throughout the world. In North America, NASA has imaged prehistoric mound sites in Mississippi; prehistoric shell middens in Louisiana, Puebloan sites in New Mexico and more recently the sites associated with the Lewis and Clark Corps of Discovery Expedition (1804-1806). In Central America, NASA archaeologists have researched Mayan sites throughout the region, including the Yucatan and Costa Rica, as well as Olmec localities in Veracruz. Other data has been collected over Angkor, Cambodia, Giza in Egypt, the lost city of Ubar on the Arabian Peninsula.

Giardino, Marco J.↗

NASA NTRS2011

Geomagnetic Secular Variation Prediction with Thermal Heterogeneous Boundary Conditions

It has long been conjectured that thermal heterogeneity at the core-mantle boundary (CMB) affects the geodynamo substantially. The observed two pairs of steady and strong magnetic flux lobes near the Polar Regions and the low secular variation in the Pacific over the past 400 years (and perhaps longer) are likely the consequences of this CMB thermal heterogeneity. There are several studies on the impact of the thermal heterogeneity with numerical geodynamo simulations. However, direct correlation between the numerical results and the observations is found very difficult, except qualitative comparisons of certain features in the radial component of the magnetic field at the CMB. This makes it difficult to assess accurately the impact of thermal heterogeneity on the geodynamo and the geomagnetic secular variation. We revisit this problem with our MoSST_DAS system in which geomagnetic data are assimilated with our geodynamo model to predict geomagnetic secular variations. In this study, we implement a heterogeneous heat flux across the CMB that is chosen based on the seismic tomography of the lowermost mantle. The amplitude of the heat flux (relative to the mean heat flux across the CMB) varies in the simulation. With these assimilation studies, we will examine the influences of the heterogeneity on the forecast accuracies, e.g. the accuracies as functions of the heterogeneity amplitude. With these, we could be able to assess the model errors to the true core state, and thus the thermal heterogeneity in geodynamo modeling.

Kuang, Weijia↗

NASA NTRS2015

NASA Propulsion Concept Studies and Risk Reduction Activities for Resource Prospector Lander

The Resource Prospector mission is to investigate the Moon's polar regions in search of volatiles. The government-version lander concept for the mission is composed of a braking stage and a liquid-propulsion lander stage. A propulsion trade study concluded with a solid rocket motor for the braking stage while using the 4th-stage Peacekeeper (PK) propulsion components for the lander stage. The mechanical design of the liquid propulsion system was conducted in concert with the lander structure design. A propulsion cold-flow test article was fabricated and integrated into a lander development structure, and a series of cold flow tests were conducted to characterize the fluid transient behavior and to collect data for validating analytical models. In parallel, RS-34 PK thrusters to be used on the lander stage were hot-fire tested in vacuum conditions as part of risk reduction activities.

Trinh, Huu P.↗

DOE OSTI2025

Thermodynamics of continuous spin photons

Special relativity allows massless particles to have states of different integer (or half-integer) helicities that mix under boosts, much like the spin states of a massive particle. Such massless particles are known as “continuous spin” particles (CSPs), a term coined by Wigner, and they are notable for their infinite tower of spin polarizations. The mixing under boosts is controlled by a spin scale 𝜌 with units of momentum. Normally, we assume 𝜌 = 0. The interactions of CSPs are known to satisfy certain simple properties, one of which is that the 𝜌 → 0 limit generically recovers familiar interactions of massless scalars, photons, or gravitons, with all other polarizations decoupling in this limit. Thus, one can ask if the photon of the Standard Model is a CSP at small but nonzero 𝜌. One concern about this possibility—originally raised by Wigner—is that the infinite tower of polarizations could pose problems for thermodynamics. To address this question, we study the thermal evolution of a CSP photon gas coupled to isothermal matter, across CSP helicity modes and phase space. We find that the structure of the interactions dictated by Lorentz symmetry implies well-behaved thermodynamics. When the CSP photon’s interactions with charged matter are turned on, the primary ℎ =±1 helicity modes thermalize quickly, while the other modes require increasingly long time scales to thermalize, set by powers of 𝑇/𝜌. In familiar thermal systems, the CSP photon behaves like the QED photon with small 𝜌- and time-dependent corrections to its effective relativistic degrees of freedom. Sizable departures from familiar thermal behavior arise at energy scales comparable to 𝜌 and could have testable experimental consequences.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1993

Magellan vertical polarization radar observations

The Magellan high-gain radar antenna system was designed to transmit and receive signals in a pure linear polarization state. The nominal mapping configuration placed this linear polarization direction parallel to the surface of Venus, providing SAR image data in the HH polarization (horizontal transmit and receive) and radiothermal emission data in the H (horizontal - receive only) polarization. During Magellan's extended mission (cycles 2 and 3), two brief experiments were conducted in which the spacecraft was rotated 90 degrees along the axis of the antenna boresight, producing SAR data in the VV polarization and emission data in the V polarization. This study focuses on the SAR results from the first experiment, which included portions of the highly reflective Beta Regio highlands. Theoretical models of polarimetric backscatter, along with experimental data from terrestrial surfaces, predict VV backscatter cross section values to be higher than HH values for most natural surfaces. Randomly polarized ('depolarized') backscatter from rough surfaces is expected in equal amounts for either incident polarization. Roughness differences will therefore be more pronounced in HH measurements than in VV, because the depolarized random component makes up a proportionately larger fraction of the HH backscatter. In addition, HH cross section values are observed to fall off more rapidly than VV values with increasing incidence angle. Slope-related backscatter differences will, therefore, be more pronounced in HH images. The small perturbation polarimetric scattering model also predicts higher VV to HH ratios for surfaces of high dielectric constant.

Plaut, Jeffrey J.↗

NASA NTRS1999

High-Resolution Mapping of Lunar Crustal Magnetic Fields: Correlations with Albedo Markings of the Reiner Gamma Class

During the last eight months of the Lunar Prospector mission (December 1999-July 1999), the spacecraft was placed in a relatively low-altitude (15-30-km perapsis), near-polar orbit that allowed high-resolution mapping of crustal magnetic fields. We report here initial studies of the correlation of locally strong magnetic anomalies with unusual, swirl-like albedo markings of the Reiner Gamma class. Based on this correlation, which is known from earlier studies of Apollo subsatellite magnetometer data, it has been proposed that the swirls represent regions whose higher albedos have been preserved via deflection of the solar-wind ion bombardment by strong crustal fields. This model in turn depends on the hypothesis that solar-wind implanted H is at least one component of the process that optically matures exposed silicate surfaces in the inner solar system . Specifically, it is hypothesized that implanted H acts as an effective reducing agent to enhance the rate of production of nanophase metallic Fe particles from preexisting silicates during micrometeoroid impacts. According to the model, the curvilinear shapes of these albedo markings are caused, at least in part, by the geometry of ion deflections in a magnetic field. The improved resolution and coverage of the Prospector data allow more detailed mapping of the fields, especially on the lunar farside. This permits a more quantitative test of whether all albedo markings of this class are associated with strong local magnetic fields.Only if the latter condition is met can the solar-wind deflection hypothesis he valid. The basic procedure for mapping crustal magnetic fields using Lunar Prospector magnetometer data follows that developed for analysis of Apollo subsatellite magnetometer data. The specific mapping steps are (1) selection of mission time intervals suitable for mapping crustal fields; these are limited essentially either to times when the Moon is in a lobe of the geomagnetic tail or to times when the Moon is in the solar wind but the spacecraft is in the lunar wake; the data are transformed to a radial, east, and north coordinate system with measurements given as a function of spacecraft latitude, longitude, and altitude; (2) visual editing of individual orbit segments selected for minimal external field disturbances; (3) minimization of remaining low-frequency external fields for individual orbit data segments by quadratic detrending; and (4) two-dimensional filtering of individual orbit segments to produce a vector field map along the slightly curved surface defined by the spacecraft altitude; maps of the three field components (radial, east, and north), the field magnitude, and the spacecraft altitude are constructed. For data obtained at low to middle latitudes, the horizontal resolution of the field maps is limited by the orbit-track separation (about 30 km at the equator). Maps of the field magnitude have been constructed within limited selenographic regions based mainly on data acquired in March, April, and May of 1999. This was a time period when the orbit plane was nearly aligned with the Sun-Moon line so that field mapping was possible at times when the Moon was in the solar wind as well as when the Moon was in the geomagnetic tail. Most of the coverage is across the lunar farside. However, a shows an example of a field map produced from solar-wind wake data for a region including Reiner Gamm on western Oceanus Procellarum (location: 58.5W, 7.5N). The contour interval is 3 nT and the mean spacecraft altitude is 18 km to within the accuracy allowed by the resolution of the map (30 km or about 1 deg.); strong magnetic anomalies correlate closely with swirl locations. Individual orbit profiles (whose resolution along the orbit track is comparable to the spacecraft altitude of 18 km) also demonstrate a good correlation of field magnitude with surface albedo. In order to investigate the correlation of magnetic fields with the location of swirl features, we have reexamined available lunar imagery (Lunar Orbiter, Apollo, and Clementine) to identify and map swirl locations within regions where swirls have previously been mapped. In these images, swirls were distinguished from other high-albedo features such as crater rays by their curvilinear shapes and increased visibility in forward-scattered light. Digital maps of swirls identified by all available imagery were then superposed on maps of the field magnitude at the spacecraft altitude. Based upon analysis of these composite magnetic/geologic maps, we draw the preliminary conclusion that swirl features are associated with magnetic anomalies revealed by Lunar Prospector. Detailed maps of these swirl features are currently being constructed for the magnetically strong regions antipodal to the Imbrium, Serenitatis, and Crisium Basins. Additional information contained in the original,

Hood, L. L.↗

NASA NTRS2003

Atmospheric Soundings from AIRS/AMSU/HSB

AIRS was launched on EOS Aqua on May 5, 2002, together with AMSU A and HSB, to form a next generation polar orbiting infrared and microwave atmospheric sounding system. The primary products of AIRS/AMSU/HSB are twice daily global fields of atmospheric temperature-humidity profiles, ozone profiles, sea/land surface skin temperature, and cloud related parameters including OLR. The sounding goals of AIRS are to produce 1 km tropospheric layer mean temperatures with an RMS error of 1K, and 1 km layer precipitable water with an rms error of 1K, and 1 km layer precipitable water with an rms error of 20 percent, in cases with up to 80 percent cloud cover. The AIRS data products are significant for studying climate variability and change, as well as for use in initialization of General Circulation Models with the objective of improving analysis fields and subsequent forecast skill. Data assimilation experiments to evaluate the impact of AIRS retrievals on analysis and forecast skill are being conducted. Sample fields of parameters retrieved from AIRS/AMSU/HSB data will be presented and validated as a function of retrieved fractional cloud cover. Select fields will also be compared to those contained in the ECMWF analysis, done without the benefit of AIRS data, on both an instantaneous and monthly mean basis, to demonstrate information that AIRS can add to that already contained in the ECMWF analysis.

Susskind, Joel↗

NASA NTRS2016

Hemispheric Differences in Tropical Lower Stratospheric Transport and Tracers Annual Cycle

Transport of long-lived tracers (such as O, CO, and N O) in the lower stratosphere largely determines the composition of the entire stratosphere. Stratospheric transport includes the mean residual circulation (with air rising in the tropics and sinking in the polar and middle latitudes), plus two-way isentropic (quasi-horizontal) mixing by eddies. However, the relative importance of two transport components remains uncertain. Previous studies quantified the relative role of these processes based on tropics-wide average characteristics under common assumption of well-mixed tropics. However, multiple instruments provide us with evidence that show significant differences in the seasonal cycle of ozone between the Northern (0-20N) and Southern (0-20S) tropical (NT and ST respectively) lower stratosphere. In this study we investigate these differences in tracer seasonality and quantify transport processes affecting tracers annual cycle amplitude using simulations from Goddard Earth Observing System Chemistry Climate Model (GEOSCCM) and Whole Atmosphere Community Climate Model (WACCM) and compare them to observations from the Microwave Limb Sounder (MLS) on the Aura satellite. We detect the observed contrast between the ST and NT in GEOSCCM and WACCM: annual cycle in ozone and other chemical tracers is larger in the NT than in the ST but opposite is true for the annual cycle in vertical advection. Ozone budgets in the models, analyzed based on the Transformed Eulerian Mean (TEM) framework, demonstrate a major role of quasi-horizontal mixing vertical advection in determining the NTST ozone distribution and behavior. Analysis of zonal variations in the NT and ST ozone annual cycles further suggests important role of North American and Asian Summer Monsoons (associated with strong isentropic mixing) on the lower stratospheric ozone in the NT. Furthermore, multi model comparison shows that most CCMs reproduce the observed characteristic of ozone annual cycle quite well. Thus, latitudinal variations within the tropics have to be considered in order to understand the balance between upwelling and quasi- horizontal mixing in the tropical lower stratosphere and the paradigm of well mixed tropics has to be reconsidered.

Chemistry-Climate Models↗

NASA NTRS2021

A Model for the Coupled Eruption of a Pseudostreamer and Helmet Streamer

A highly important aspect of solar activity is the coupling between eruptions and the surrounding coronal magnetic-field topology, which determines the trajectory and morphology of the event and can even lead to sympathetic eruptions from multiple sources. In this paper, we report on a numerica lsimulation of a new type of coupled eruption, in which a coronal jet initiated by a large pseudostreamer filament eruption triggers a streamer-blowout coronal mass ejection (CME) from the neighboring helmet streamer. Our configuration has a large opposite-polarity region positioned between the polarcoronal hole and a small equatorial coronal hole, forming a pseudostreamer flanked by the coronalholes and the helmet streamer. Further out, the pseudostreamer stalk takes the shape of an extendedarc in the heliosphere. We energize the system by applying photospheric shear along a section of the polarity inversion line within the pseudostreamer. The resulting sheared-arcade filament channel develops a flux rope that eventually erupts as a classic coronal-hole-type jet. However, the enhanced breakout reconnection above the channel as the jet is launched progresses into the neighboring helmet streamer, partially launching the jet along closed helmet streamer field lines and blowing out thestreamer top to produce a classic bubble-like CME. This CME is strongly deflected from the jet’s initial trajectory and contains a mixture of open and closed magnetic field lines. We present the detailed dynamics of this new type of coupled eruption, its underlying mechanisms and the implications of thiswork for the interpretation of in-situ and remote-sensing observations.

P F Wyper↗

DOE OSTI2025

Holistic Microstructure Control Strategies in Photopolymerization‐Induced Phase Separation of Acrylate Systems

Open porous materials, known for their large surface area and interconnected structures, are essential in various applications, including batteries, ion exchange, catalysis, filtration, and electronic waste recycling. A critical aspect of the functionality of porous membranes is the precise control of pore size and morphology. Photopolymerization-induced phase separation (photo-PIPS) offers a convenient and versatile methods for creating porous structures. However, controlling the porous morphology remains challenging due to the complex interplay between thermodynamics, polymerization kinetics, and monomer structures, which makes it difficult to establish the relationship between processing conditions and resulting morphology in photo-PIPS. Herein, a physics-based phase-field model capable of generating and characterizing the microstructures of porous materials based on both average and localized features is developed. Using the phase-field simulations as test bed, the effects of polarity, light intensity, and curing temperature, as well as the previously unexplored roles of chain transfer agents and substrates, on the morphology of the resulting porous microstructure are investigated. Experiments are performed to verify the results predicted by the simulations. This work lays out a comprehensive guide for designing PIPS-derived porous microstructures and offers practical engineering strategies for tailoring microstructure-level topology and size of pores for application-specific needs.

36 MATERIALS SCIENCE↗