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At least 1,153 records · Page 64

Summary Report for the Analysis of the Sludge Batch 7b (Macrobatch 9) DWPF Pour Stream Glass Sample for Canister S04023

In order to comply with the Defense Waste Processing Facility (DWPF) Waste Form Compliance Plan for Sludge Batch 7b, Savannah River National Laboratory (SRNL) personnel characterized the Defense Waste Processing Facility (DWPF) pour stream (PS) glass sample collected while filling canister S04023. This report summarizes the results of the compositional analysis for reportable oxides and radionuclides and the normalized Product Consistency Test (PCT) results. The PCT responses indicate that the DWPF produced glass that is significantly more durable than the Environmental Assessment glass. Results and further details are documented in SRNL-STI-2013-00462, Revision 1 “Analysis of the DWPF Sludge Batch 7b (Macrobatch 9) Pour Stream Glass Sample.”

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Selection of Glasses to Confirm the 0.65 Weight Percent Sulfate Solubility Limit for Sludge Batch 10

In preparation for Sludge Batch 10 (SB10) processing, projections of sulfate (SO 4 2- ) in glass at 36% waste loading (WL) were calculated in May 2020 for Tank 40 blend projections representing 0.7M and 0.85M Na wash endpoints. The projected SO 4 2- ) concentrations for either sludge-only (SO) or coupled processing with the Salt Waste Processing Facility (SWPF) were either near or exceeded the current Sludge Batch 9 (SB9) limit of 0.65 weight percent (wt.%). Four nominal glass compositions were selected based on SO and coupled processing for the 0.85M Na wash endpoint Tank 40 blend projection to conduct an initial evaluation of the SB10 sulfate solubility behavior. A sulfate salt phase was absent from each of the prepared glasses, which provided preliminary results that supported the 0.65 wt.% SO 4 2- ) limit for SB10.

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GSA Aquifer Cutouts for E-Area PA Revision Transport Simulations

The 2018 General Separations Area (GSA) aquifer model is dissected into four refined cutouts for aquifer transport in preparation for the next E-Area Low-Level Waste Facility (LLWF) Performance Assessment (PA) revision. The recommended refined horizontal and vertical grid sizes are 20 ft and 3 ft, respectively. The horizontal resolution appropriately represents longitudinal dispersion with dispersivity of 15.4 ft. Four cutouts (i.e., West, Center, East 1, and East 2) are selected to adequately contain tracer plumes emanating from disposal units expected in the E-Area LLWF. For feasible computation, each cutout is refined to mesh sizes much less than the PORFLOW limit of 1,024,000 nodes.

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Physical Properties of the Salt Waste Processing Next Generation Solvent Formulation

In 2020, a review team examined the risks associated with the implementation of a new solvent formulation, similar to what was used in Modular Caustic-Side Solvent Extraction Unit (MCU). The team identified a number of risks associated with the change and pathways to mitigate some of the risks. SRNL has been tasked with examination and testing of a Salt Waste Processing Facility (SWPF) formulation for a Next Generation Solvent (NGS) intended for use at that facility. This formulation is known as the “$NGS\tiny{OPTIMUM}$”. This formulation consists of: 50 mM MAXCalix; 3 mM TiDG•HCl; 0.65 M Modifier; Remainder Isopar-L™. SRNL examined several physical aspects of this solvent in order to confirm its suitability for use at SWPF, such as viscosity, dispersion, surface tension, and third phase formation. Results indicate no unusual properties of this solvent when compared to the current “BOBCalix” solvent in use at SWPF.

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Results for the October 2025 Semiannual Salt Waste Processing Facility Decontaminated Salt Solution Sample

In this Technical Report, the chemical and radionuclide contaminant results from the October 2025 Semiannual sample of the Salt Waste Processing Facility (SWPF) Decontaminated Salt Solution (DSS) salt solution are presented in tabulated form. The information from this characterization will be used by Savannah River Mission Completion (SRMC) for the transfer of aqueous waste from SWPF to the Saltstone Production Facility (SPF) where the waste will be treated and disposed in the Saltstone Disposal Facility. This Technical Report compares results, where applicable, to SPF Waste Acceptance Criteria (WAC) LIMITS and TAR GETS that were established at the time the SWPF DSS sample was obtained. 1 The October 2025 Semiannual sample of the SWPF DSS is a composite from one month of SWPF processing during the Third Quarter Fiscal Year 2025 (3QFY2025) and two months of SWPF processing during the Fourth Quarter Fiscal Year 2025 (4QFY2025).

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Acceptable Knowledge Summary Report for REMOTE-HANDLED DEPLETED URANIUM INGOTS FROM MATERIALS AND FUELS COMPLEX

This Acceptable Knowledge (AK) Summary Report has been prepared for the Central Characterization Program (CCP) for remote-handled (RH) transuranic (TRU) waste generated and managed by the Materials and Fuels Complex (MFC), formerly Argonne National Laboratory-West (ANL-W) and part of the Idaho National Laboratory (INL). The waste described in this report, depleted uranium ingots (waste stream ID-MFC-DU-INGOT), was historically generated in Building 765, the Fuel Conditioning Facility (FCF), formerly, Hot Fuel Examination Facility (HFEF)-South. This AK Summary Report, along with the referenced supporting documents, provides a defensible and auditable record of AK for the designated waste stream, depleted uranium ingots, produced from the FCF electrorefining process. The references and AK source documents used to prepare this report are listed in Sections 8.0 and 9.0 respectively. The source documents cited throughout this report are identified by alphanumeric designations corresponding to a unique Source Document Tracking Number (e.g., AKA01, C001, CCE01, DR001, M001, P001, and U001).

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Fiscal Year 2020 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada

U.S. Department of Energy Standard DOE-STD-5002-2017, “Disposal Authorization Statement and Tank Closure Documentation,” requires preparation of an Annual Summary Report comparing low-level radioactive waste disposal facilities operations with the Disposal Authorization Statement (DAS) and its supporting technical documents including the performance assessment (PA) and the composite analysis (CA). The fiscal year (FY) 2020 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) was prepared by reviewing planned and discovered changes, waste receipts, monitoring results, research and development (R&D) results, and the status of DAS conditions and issues to assess the validity of the DASs, PAs, and CAs.

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CSM, 50 Years Anniversary: Retrospective - 20118

The Centre de Stockage de la Manche (CSM), in La Hague (France) was in 1969 the first radioactive waste disposal facility built and operated in France for Low and Intermediate level waste (LILW). Each chapter of the paper exposes the main achievements of a decade of the CSM history, from the decision to dispose radioactive waste on surface to the preservation of the memory of the site. Through the history of the CSM, it is the evolution of waste management that unfolds over 50 years, shedding light on the choices we make today and the issues of tomorrow. (authors)

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Annual Summary Report (FY 2025) Performance Assessment for the Environmental Restoration Disposal Facility

Beginning in 1996, the Environmental Restoration Disposal Facility (ERDF) started accepting low-level radioactive, hazardous, and mixed wastes that were generated during cleanup activities at the Hanford Site. ERDF is composed of a series of cells or disposal areas and can accommodate future design expansions as needed. Currently, there are eight cells and two supercells in ERDF. Each supercell is the equivalent of two cells. During this reporting period, fiscal year (FY) 2025, extending from October 1, 2024, through September 30, 2025, approximately 50,653 metric tons (55,835 U.S. tons) of waste was disposed at ERDF. From ERDF inception through September 30, 2025, approximately 17.3 million metric tons (19.1 million U.S. tons) of waste has been disposed at ERDF, which equates to consumption of approximately 91.0% of the currently constructed disposal volume. According to the design of ERDF, the facility has the ability to be expanded as needed. In 2023, the Department of Energy approved the construction of supercell 11 to provide additional disposal capacity to meet the cleanup mission at the Hanford Site. The construction of supercell 11 began in FY 2025, and it is expected to take up to two years. Construction of the new cell will not affect ongoing waste disposal activities at ERDF.

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Use of Unmanned Aerial Systems for Post-closure Waste Site Maintenance and Surveillance - 20143

The P- and R-Area Reactor buildings, located at SRS near Aiken, SC, were in-situ decommissioned by grouting below-grade portions of the buildings and demolishing some above-grade structures to grade level. Other reactor building structures were left above-grade and sealed to prevent human or animal access. Because the above grade-structures are expected to continue in their present state for hundreds of years, the condition of the building roofs is critical to mitigate rainwater intrusion. For this reason, building roof areas were strengthened with high strength concrete to ensure the long-term integrity of the roof structure. Periodic inspections of the roof structures are required to ensure that the roofs are functioning properly and to identify damage areas. The traditional method of inspecting closed reactor buildings requires the use of a helicopter and photographer to generate photographs and videos for review. This method proved sufficient but lacked the resolution and clarity that is required for a thorough inspection of the building structure. Fortunately, the Savannah River National Laboratory (SRNL) has established a Small Unmanned Aircraft System (sUAS) program using commercially available and custom-built remote-controlled aircraft. EC and ACP contacted the SRNL program to evaluate whether the sUAS technology could be employed for periodic reactor building inspections. The sUAS can fly within a few meters of the reactor buildings and hover, allowing for a more thorough aerial inspection. The initial sUAS inspection of the P-Area Reactor building was completed in February 2018 and at the R-Area Reactor building in August 2018 and were successful in providing higher resolution photos and videos. The sUAS inspections also revealed that vegetation had begun to grow on the roofs that could potentially damage the structure integrity. SRNL partnered with Virginia Polytechnic Institute and State University to build a custom heavy lift sUAS that could be equipped with herbicides to remotely treat the vegetative growth. Herbicides were successfully applied to the R-Area Reactor building roof using the custom sUAS in September 2018. The use of unmanned aircraft systems at SRS to perform aerial inspections and herbicide treatment in otherwise inaccessible areas has proven to be an efficient and cost-effective technology that provides high value, increases knowledge of facility conditions, and provides for early detection of damage. Periodic inspections of the reactor building roofs using sUAS technology are performed safely, efficiently, and at a significant cost and schedule savings while reducing emissions, noise, and fossil fuel use. The use of sUAS equipment for building inspections and herbicide application at SRS is unique within the DOE complex. The goal of SRS is to apply this remote technology to other waste unit operations and maintenance activities in the future. (authors)

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LAW Simulant Recipes for Evaluation of Real-Time, In-Line Monitoring Instruments

Statistically designed recipes were generated for evaluation of in-line instrumentation for the Real-Time In-Line Monitoring (RTIM) program in support of the Hanford Direct-Feed Low Activity Waste (DFLAW) program. The composition matrices were prepared based on Low Activity Waste (LAW) feed vector, melter feed, and Effluent Management Facility (EMF) feed information provided by the flowsheet integration modelling for the DFLAW portion of the Waste Treatment Plant (WTP) mission. These composition matrices were converted to recipes for the LAW feed using the approaches for LAW simulant recipes developed by Savannah River National Laboratory (SRNL). Recipes for the glass forming chemicals (GFCs) were developed based on expected mineral forms to be used to for each element to be added to the recipe. The recipe matrices are shown in the Appendix.

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Sludge Batch 10 Flowsheet Testing with Non-radioactive Simulants

Fourteen Chemical Processing Cell (CPC) simulations were performed with nonradioactive sludge simulants at the Aiken County Technology Laboratory in Aiken, SC. Four of these experiments were performed with Tank 51 sludge simulant. The remaining ten were performed with Tank 40 sludge simulant. The purpose of these experiments was to elucidate the chemistry and characteristics of Sludge Batch (SB) 10 as anticipated in the Defense Waste Processing Facility (DWPF). Experiments were performed at acid stoichiometries between 76% and 138% of the Koopman Minimum Acid requirement (85% - 144% of the Hsu acid requirement) and at REDuction/OXidation (REDOX) targets between 0.1 and 0.3. Testing examined the impact of coupled operations and sludge-only operations during Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) processing at both design basis and nominal boilup rates. This report shares conclusions made as a result of this testing.

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Nuclear Systems Kilopower Overview

The Nuclear Systems Kilopower Project was initiated by NASAs Space Technology Mission Directorate Game Changing Development Program in fiscal year 2015 to demonstrate subsystem-level technology readiness of small space fission power in a relevant environment (Technology Readiness Level 5) for space science and human exploration power needs. The Nuclear Systems Kilopower Project consists of two elements. The primary element is the Kilopower Prototype Test, also called the Kilopower Reactor Using Stirling Technology(KRUSTY) Test. This element consists of the development and testing of a fission ground technology demonstrator of a 1 kWe fission power system. A 1 kWe system matches requirements for some robotic precursor exploration systems and future potential deep space science missions, and also allows a nuclear ground technology demonstration in existing nuclear test facilities at low cost. The second element, the Mars Kilopower Scalability Study, consists of the analysis and design of a scaled-up version of the 1 kWe reference concept to 10 kWe for Mars surface power projected requirements, and validation of the applicability of the KRUSTY experiment to key technology challenges for a 10 kWe system. If successful, these two elements will lead to initiation of planning for a technology demonstration of a 10 kWe fission power capability for Mars surface outpost power.

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Evaluation of Ammonium and Iodine Decontamination Factors for Hanford's Waste Treatment and Immobilization Plant Feed in the Effluent Treatment Facility

Savannah River National Laboratory (SRNL) reviewed the unit operations in the Effluent Treatment Facility (FTP) at the Hanford site to estimate the partitioning of iodine and ammonia when processing Waste Treatments and Immobilization Plant (WTP) feed. The evaluation consisted of literature and vendor data reviews and no experiments were performed. A list of the unit operations reviewed, along with estimated decontamination factors (DFs) for both iodine and ammonium are shown in the table below. With the exception of the Peroxide Decomposer, reasonable estimations of the decontamination factors for all operations are provided.

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Characterization of Salt Waste Processing Facility August 2022 Tank 201 sample

Two Salt Waste Processing Facility (SWPF) Tank 201 samples were collected from the replacement of the decontaminated salt solution (DSS) coalescer at different times; one in December of 2021 and the other in August 2022. The December 2021 sample was collected after nitric and water flushing of the DSS Coalescer. The Aug 2022 sample was collected after water flushing only. The December 2021 Tank 201 solids were previously characterized and documented. SWPF requested the characterization of the August 2022 Tank 201 sample, and the comparison of the characterization results for these two Tank 201 solids collected at different dates.

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Characterization of Infrequent Samples from the Concentration, Storage, and Transfer Facility: H-Area Diversion Box 7 (HDB-7) Sump Sample: December 2021 Sample

In December 2021, SRR-E sent an ~250 mL sample identified as HDB-7 from an H-Area diversion box sump to SRNL for analysis. The sample was clear and colorless and free from any solids. SRNL analysis indicated that the sample contained 2.97E+05 dpm/mL Cs-137, 3.74E+05 dpm/mL total beta activity, 1.04E+03 dpm/mL beta activity following cesium removal, and below detectable levels of alpha activity and alpha activity following cesium removal. In addition, the pH of the sample was 7.32, free hydroxide concentration was 2.09E-07 M, and the density was 0.991 g/mL.

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West Valley Demonstration Project (WVDP) (Annual Site Environmental Report (ASER), Calendar Year 2022)

The report, prepared for the U.S. Department of Energy West Valley Demonstration Project office (DOE-WVDP), summarizes the environmental protection program at the WVDP for calendar year (CY) 2022. Monitoring and surveillance of the facilities used by the DOE are conducted to verify protection of public health and safety and the environment. The report is a key component of DOE’s effort to keep the public informed of environmental conditions at the WVDP. The quality assurance protocols applied to the environmental monitoring program ensure the validity and accuracy of the monitoring data. In addition to demonstrating compliance with environmental laws, regulations, and directives, evaluation of data collected in 2022 continued to indicate that WVDP activities pose no threat to public health or safety, or to the environment.

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Characterization of infrequent samples from the concentration, storage and transfer facility: leak detection box (LDB) drain cell sample LIMS# 20195

Savannah River Remediation Engineering (SRR-E) requested that the Savannah River National Laboratory (SRNL) analyze the Concentration, Storage, and Transfer Facility (CSTF) samples from the following Tank Farm areas: the sump encasement, catch tank, drain cell and waste tank annulus. In general, these CSTF samples will be analyzed on an infrequent basis and analyses will include detection for total beta/gamma, total alpha activities and pH measurements. This report presents characterization results for the Leak Detection Box Drain Cell (LDB-DC) sample. The results are measurements for total gamma, total alpha, total beta, pH, density, anions, elementals and total mercury for the LDB-DC sample.

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