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IUE (International Ultraviolet Explorer) has observed both high and low mass x ray binaries throughout its life. The UV spectra of high mass systems reveal the nature of the massive companion star and the effects of the x ray illumination of the stellar wind. In loss mass systems, the x ray illuminated disk or companion star dominates the UV light. System parameters and the characteristics of the accretion disk can be inferred.
We present a laboratory-constructed mass spectrometer optimized for recording infrared multiple photon dissociation (IRMPD) spectra of mass-selected ions using a benchtop tunable infrared optical parametric oscillator/amplifier (OPO/A). The instrument is equipped with two ionization sources, an electrospray ionization source, as well as an electron ionization source for troubleshooting. This hybrid mass spectrometer is composed of a quadrupole mass filter for mass selection, a reduced pressure ({approx}10{sup -5} Torr) quadrupole ion trap (QIT) for OPO irradiation, and a reflectron time-of-flight drift tube for detecting the remaining precursor and photofragment ions. A helium gas pulse is introduced into the QIT to temporarily increase the pressure and hence enhance the trapping efficiency of axially injected ions. After a brief pump-down delay, the compact ion cloud is subjected to the focused output from the continuous wave OPO. In a recent study, we implemented this setup in the study of protonated tryptophan, TrpH{sup +}, as well as collision-induced dissociation products of this protonated amino acid [W. K. Mino, Jr., K. Gulyuz, D. Wang, C. N. Stedwell, and N. C. Polfer, J. Phys. Chem. Lett. 2, 299 (2011)]. Here, we give a more detailed account on the figures of merit of such IRMPD experiments. The appreciable photodissociation yields in these measurements demonstrate that IRMPD spectroscopy of covalently bound ions can be routinely carried out using benchtop OPO setups.
We present a new determination of the intergalactic C IV mass density at 4.3 < z < 6.3. Our constraints are derived from high signal-to-noise spectra of seven quasars at z > 5.8 obtained with the newly commissioned Folded-Port Infrared Echellette (FIRE) spectrograph on the Magellan Baade telescope, coupled with six observations of northern objects taken from the literature. We confirm the presence of a downturn in the C IV abundance at (z) = 5.66 by a factor of 4.1 relative to its value at (z) = 4.96, as measured in the same sight lines. In the FIRE sample, a strong system previously reported in the literature as C IV at z = 5.82 is re-identified as Mg II at z = 2.78, leading to a substantial downward revision in {Omega}{sub Civ} for these prior studies. Additionally, we confirm the presence of at least two systems with low-ionization C II, Si II, and O I absorption but relatively weak signal from C IV. The latter systems may be of interest if the downward trend in {Omega}{sub Civ} at high redshift is driven in part by ionization effects.
We present results from a study to determine whether relations-established in the local universe-between the mass of supermassive black holes (SMBHs) and their host galaxies are in place at higher redshifts. We identify a well-constructed sample of 18 X-ray-selected, broad-line active galactic nuclei (AGNs) in the Extended Chandra Deep Field-South Survey with 0.5 < z < 1.2. This redshift range is chosen to ensure that Hubble Space Telescope (HST) imaging is available with at least two filters that bracket the 4000 A break, thus providing reliable stellar mass estimates of the host galaxy by accounting for both young and old stellar populations. We compute single-epoch, virial black hole (BH) masses from optical spectra using the broad Mg II emission line. For essentially all galaxies in our sample, their total stellar mass content agrees remarkably well, given their BH masses, with local relations of inactive galaxies and active SMBHs. We further decompose the total stellar mass into bulge and disk components separately with full knowledge of the HST point-spread function. We find that {approx}80% of the sample is consistent with the local M{sub BH}-M{sub *,{sub Bulge}} relation even with 72% of the host galaxies showing the presence of a disk. In particular, bulge-dominated hosts are more aligned with the local relation than those with prominent disks. We further discuss the possible physical mechanisms that are capable of building up the stellar mass of the bulge from an extended disk of stars over the subsequent 8 Gyr.
We present a new empirical model to predict solar energetic particle (SEP) event integrated and peak intensity spectra between 10 and 130 MeV at 1 AU, based on multi-point spacecraft measurements from the Solar TErrestrial RElations Observatory (STEREO), the Geostationary Operational Environmental Satellites (GOES), and the Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics (PAMELA) satellite experiment. The analyzed data sample includes 32 SEP events occurring between 2010 and 2014, with a statistically significant proton signal at energies in excess of a few tens of MeV, unambiguously recorded at three spacecraft locations. The spatial distributions of SEP intensities are reconstructed by assuming an energy-dependent 2D Gaussian functional form, and accounting for the correlation between the intensity and the speed of the parent coronal mass ejection (CME), and the magnetic-field-line connection angle. The CME measurements used are from the Space Weather Database Of Notifications, Knowledge, Information (DONKI). The model performance, including its extrapolations to lower/higher energies, is tested by comparing with the spectra of 20 SEP events not used to derive the model parameters. Despite the simplicity of the model, the observed and predicted event-integrated and peak intensities at Earth and at the STEREO spacecraft for these events show remarkable agreement, both in the spectral shapes and their absolute values.
Three-body AAB model for the $NN\bar K$(s NN = 0) kaonic cluster is considered based on the configuration space Faddeev equations. Within a single channel approach, the difference between masses of nucleons and kaons and the charge independence breaking of nucleon-nucleon interaction are taken into consideration. We definite the particle configurations in the system according to the particle masses and pair potentials. There are two sets of the particle configurations, ppK¯, npK¯ 0 and nnK¯ 0 , npK¯, charged and neutral. The three-body calculations are performed by applying NN and NK¯ phenomenological isospin-dependent potentials. The mass and energy spectra related to the particle configurations are presented. We evaluate the mass and energy uncertainties for the NNK¯ model. As a result, an analogy to NNN model for the 3 H and 3 He nuclei is proposed.
The pyrolyses of phenol and d{sub 5}-phenol (C{sub 6}H{sub 5}OH and C{sub 6}D{sub 5}OH) have been studied using a high temperature, microtubular ({mu}tubular) SiC reactor. Product detection is via both photon ionization (10.487 eV) time-of-flight mass spectrometry and matrix isolation infrared spectroscopy. Gas exiting the heated reactor (375 K-1575 K) is subject to a free expansion after a residence time in the {mu}tubular reactor of approximately 50-100 {micro}s. The expansion from the reactor into vacuum rapidly cools the gas mixture and allows the detection of radicals and other highly reactive intermediates. We find that the initial decomposition steps at the onset of phenol pyrolysis are enol/keto tautomerization to form cyclohexadienone followed by decarbonylation to produce cyclopentadiene; C{sub 6}H{sub 5}OH {yields} c-C{sub 6}H{sub 6} = O {yields} c-C{sub 5}H{sub 6} + CO. The cyclopentadiene loses a H atom to generate the cyclopentadienyl radical which further decomposes to acetylene and propargyl radical; c-C{sub 5}H{sub 6} {yields} c-C{sub 5}H{sub 5} + H {yields} HC {triple_bond} CH + HCCCH{sub 2}. At higher temperatures, hydrogen loss from the PhO-H group to form phenoxy radical followed by CO ejection to generate the cyclopentadienyl radical likely contributes to the product distribution; C{sub 6}H{sub 5}O-H {yields} C{sub 6}H{sub 5}O + H {yields} c-C{sub 5}H{sub 5} + CO. The direct decarbonylation reaction remains an important channel in the thermal decomposition mechanisms of the dihydroxybenzenes. Both catechol (o-HO-C{sub 6}H{sub 4}-OH) and hydroquinone (p-HO-C{sub 6}H{sub 4}-OH) are shown to undergo decarbonylation at the onset of pyrolysis to form hydroxycyclopentadiene. In the case of catechol, we observe that water loss is also an important decomposition channel at the onset of pyrolysis.
Ion mobility spectrometry-mass spectrometry and Fourier transform infrared spectroscopy (FTIR) techniques were combined with quantum chemical calculations to examine the origin of icosahedral clusters of the amino acid proline. When enantiopure proline solutions are electrosprayed (using nanospray) from 100 mM ammonium acetate, only three peaks are observed in the mass spectrum across a concentration range of five orders of magnitude: a monomer [Pro+H]{sup +} species, favored from 0.001 to 0.01 mM proline concentrations; a dimer [2Pro+H]{sup +} species, the most abundant species for proline concentrations above 0.01 mM; and, the dimer and dodecamer [12Pro+2H]{sup 2+} for 1.0 mM and more concentrated proline solutions. Electrospraying racemic D/L-proline solutions from 100 mM ammonium acetate leads to a monomer at low proline concentrations (0.001 to 0.1 mM), and a dimer at higher concentrations (>0.09 mM), as well as a very small population of 8 to 15 Pro clusters that comprise <0.1% of the total ion signals even at the highest proline concentration. Solution FTIR studies show unique features that increase in intensity in the enantiopure proline solutions, consistent with clustering, presumably from the icosahedral geometry in bulk solution. When normalized for the total proline, these results are indicative of a cooperative formation of the enantiopure 12Pro species from 2Pro. .
We present observational constraints on the initial-final mass relation (IFMR) using wide double white dwarfs (DWDs). We identify 65 new candidate wide DWDs within the Sloan Digital Sky Survey, bringing the number of candidate wide DWDs to 142. We then engage in a spectroscopic follow-up campaign and collect existing spectra for these objects; using these spectra, we derive masses and cooling ages for 54 hydrogen (DA) WDs in DWDs. We also identify one new DA/DB pair, four candidate DA/DC pairs, four candidate DA/DAH pairs, and one new candidate triple degenerate system. Because wide DWDs are co-eval and evolve independently, the difference in the pre-WD lifetimes should equal the difference in the WD cooling ages. We use this to develop a Bayesian hierarchical framework and construct a likelihood function to determine the probability that any particular IFMR fits a sample of wide DWDs. We then define a parametric model for the IFMR and find the best parameters indicated by our sample of DWDs. We place robust constraints on the IFMR for initial masses of 2–4 M{sub ⊙}. The WD masses produced by our model for stars within this mass range differ from those predicted by semi-empirical fits to open cluster WDs. Within this mass range, where there are few constraining open cluster WDs and disagreements in the cluster ages, wide DWDs may provide more reliable constraints on the IFMR. Expanding this method to the many wide DWDs expected to be discovered by Gaia may transform our understanding of the IFMR.
Using the Auger mass-composition analysis of ultra high energy cosmic rays, based on the shape-fitting of X{sub max} distributions [1], we demonstrate that mass composition and energy spectra measured by Auger, Telescope Array and HiRes can be brought into good agreement. The shape-fitting analysis of X{sub max} distributions shows that the measured sum of proton and Helium fractions, for some hadronic-interaction models, can saturate the total flux. Such p + He model, with small admixture of other light nuclei, naturally follows from cosmology with recombination and reheating phases. The most radical assumption of the presented model is the assumed unreliability of the experimental separation of Helium and protons, which allows to consider He/p ratio as a free parameter. The results presented here show that the models with dominant p + He composition explain well the energy spectrum of the dip in the latest (2015–2017) data of Auger and Telescope Array, but have some tension at the highest energies with the expected Greisen–Zatsepin–Kuzmin cutoff. The Auger-Prime upgrade experiment has a great potential to reject or confirm this model.
We analyze the emission line profiles detected in deep optical spectra of quasars to derive the mass of their super-massive black holes (SMBH) following the single-epoch virial method. Our sample consists in six radio-loud (RL) quasars and four radio-quiet (RQ) quasars. We carefully fit a broad and narrow Gaussian component for each emission line in both the Hβ (10 objects) and Hα regions (5 objects). A very good agreement of the derived SMBH masses, M{sub SMBH}, is found using the fitted broad Hβ and Hα emission lines. We compare our M{sub SMBH} results with those found by previous studies. We study the relationship between the M{sub SMBH} of the quasar and the stellar velocity dispersion, σ{sub ∗}, of the host galaxy. We use the measured M{sub SMBH} and σ{sub ∗} to investigate the M{sub SMBH}–σ{sub ∗} relation for both the RL and radio-quiet subsamples. Besides the scatter, we find a good agreement between radio-quiet quasars and AGN+quiescent galaxies and between RL quasars and AGN. Our analysis does not support the hypothesis of using σ([O iii] λ5007) as a surrogate for stellar velocity dispersions in high-mass, high-luminosity quasars. We also investigate the relationship between the 5 GHz radio-continuum luminosity, L{sub 5GHz}, of the quasar host galaxy with both M{sub SMBH} and σ{sub ∗}. We do not find any correlation between L{sub 5GHz} and M{sub SMBH}, although we observe a trend that galaxies with larger stellar velocity dispersions have larger L{sub 5GHz}. Using the results of our fitting for the narrow emission lines of [O iii] λ5007 and [N ii] λ6583 we estimate the gas-phase oxygen abundance of six quasars, being sub-solar in all cases.
Composition and mass data analysis of meteoroids in 1 milligram to 1 gram range using NASA LRC Faint Meteor Spectra Patrol data
We construct high signal-to-noise 'template' spectra by co-adding hundreds of spectra of nearby dwarfs spanning K7 to M4, taken with Keck/HIRES as part of the California Planet Search. We identify several spectral regions in the visible (370-800 nm) that are sensitive to the stellar luminosity and metallicity. We use these regions to develop a spectral calibration method to measure the mass, metallicity, and distance of low-mass stars, without the requirement of geometric parallaxes. Testing our method on a sample of nearby M dwarfs, we show that we can reproduce stellar masses to about 8%-10%, metallicity to {approx}0.15 dex, and distance to 11%. We were able to make use of HIRES spectra obtained as part of the radial velocity monitoring of the star KOI-314 to derive a new mass estimate of 0.57 {+-} 0.05 M{sub Sun }, a radius of 0.54 {+-} 0.05 R{sub Sun }, a metallicity, [Fe/H], of -0.28 {+-} 0.10, and a distance of 66.5 {+-} 7.3 pc. Using HARPS archival data and combining our spectral method with constraints from transit observations, we are also able to derive the stellar properties of GJ 3470, a transiting planet hosting M dwarf. We estimate a mass of 0.53 {+-} 0.05 M{sub Sun }, a radius of 0.50 {+-} 0.05 R{sub Sun }, a metallicity, [Fe/H], of 0.12 {+-} 0.12, and a distance of 29.9{+-}{sub 3.4}{sup 3.7} pc.
Recently, the general electromagnetic fluctuation theory for magnetized plasmas has been used to study the steady-state fluctuation spectra and the total intensity of low-frequency collective weakly damped modes for parallel wave vectors in Maxwellian plasmas. Now, we address the same question with respect to an arbitrary direction of the wave-vector. Here, we analyze this problem for equal mass plasmas. These plasmas are a very good tool to study various plasma phenomena, as they considerably facilitate the theoretical consideration and at the same time provide with their clear physical picture. Finally, we compare our results in the limiting case of parallel wave vectors with the previous study.
We propose one a variant of calculation of the energy spectrum of bound state systems with relativistic corrections. In the framework of quantum field theory, an expression that takes into account relativistic corrections to the mass of the bound state with a known nonrelativistic pair interaction potential is proposed on the basis of calculating the asymptotic behavior of correlation functions of the corresponding field currents with the necessary quantum numbers. Excluding the time variables allows one to determine nonperturbative corrections to the interaction potential. The following results have been obtained in the framework of this approach. The nonperturbative corrections arising due to the relativistic nature of a system to the interaction Hamiltonian are determined. The dependence of the constituent mass of bound-state forming particles on the free state mass and on the orbital and radial quantum numbers is analytically derived. The energy level shift of muonic hydrogen taking into account relativistic corrections is calculated. The energy spectrum of a wide class of potentials that describe the Coulomb bound state is analytically derived with relativistic corrections. The mass spectrum of the glueballs and the constituent masses of the gluons are analytically calculated taking into account spin-orbit, spin—spin, and tensor interactions. Our numerical results have shown very good agreement with the lattice data. Taking into account nonperturbative and nonlocality characters of interactions, the mass spectrum of the mesons consisting of light-light and light-heavy quarks with orbital and radial excitations is determined. Our results show that good agreement with the experimental data for the slope and the intercept of the Regge trajectory can be obtained only taking into account the nonperturbative and the nonlocal characters of interactions. The dependences of the constituent masses of constituent particles on the masses of a free state are certain. When quarks are light, then the difference between current and valent masses of quarks is greater than valent masses of quarks, and when quarks are heavy, then the difference between these masses is insignificant. One of the alternative variants of taking nonlocality into account has been suggested for the definition of properties of hadrons at large distances. The dependence of the constituent masses of constituent particles on the radius of confinement is determined.
We present the first robust measurement of the high redshift mass-metallicity (MZ) relation at 10(exp 8) < M/Stellar Mass < or approx. 10(exp 10), obtained by stacking spectra of 83 emission-line galaxies with secure redshifts between 1.3 < or approx. z < or approx. 2.3. For these redshifts, infrared grism spectroscopy with the Hubble Space Telescope Wide Field Camera 3 is sensitive to the R23 metallicity diagnostic: ([O II] (lambda)(lambda)3726, 3729 + [OIII] (lambda)(lambda)4959, 5007)/H(beta). Using spectra stacked in four mass quartiles, we find a MZ relation that declines significantly with decreasing mass, extending from 12+log(O/H) = 8.8 at M = 10(exp 9.8) Stellar Mass to 12+log(O/H)= 8.2 at M = 10(exp 8.2) Stellar Mass. After correcting for systematic offsets between metallicity indicators, we compare our MZ relation to measurements from the stacked spectra of galaxies with M > or approx. 10(exp 9.5) Stellar Mass and z approx. 2.3. Within the statistical uncertainties, our MZ relation agrees with the z approx. 2.3 result, particularly since our somewhat higher metallicities (by around 0.1 dex) are qualitatively consistent with the lower mean redshift (z = 1.76) of our sample. For the masses probed by our data, the MZ relation shows a steep slope which is suggestive of feedback from energy-driven winds, and a cosmological downsizing evolution where high mass galaxies reach the local MZ relation at earlier times. In addition, we show that our sample falls on an extrapolation of the star-forming main sequence (the SFR-M∗ relation) at this redshift. This result indicates that grism emission-line selected samples do not have preferentially high star formation rates (SFRs). Finally, we report no evidence for evolution of the mass-metallicity-SFR plane; our stack-averaged measurements show excellent agreement with the local relation.
This paper introduces a concept for global tilted irradiance (GTI) subordinate standard spectra to supplement the current standard spectra used in solar photovoltaic applications as defined in ASTM G173 and IEC60904. The proposed subordinate standard spectra correspond to atmospheric conditions and tilt angles that depart significantly from the main standard spectrum, and they can be used to more accurately represent various local conditions. For the definition of subordinate standard spectra cases with an elevation 1.5 km above sea level, the question arises whether the air mass should be calculated including a pressure correction or not. This study focuses on the impact of air mass used in standard spectra, and it uses data from 29 locations to examine which air mass is most appropriate for GTI and direct normal irradiance (DNI) spectra. Overall, it is found that the pressure-corrected air mass of 1.5 is most appropriate for DNI spectra. For GTI, a non-pressure-corrected air mass of 1.5 was found to be more appropriate.
We demonstrate a method to determine the structures of the primary photodissociation products from a cryogenically cooled parent ion. In this approach, a target ion is cooled by a pulse of buffer gas and tagged in a 20 K Paul trap. The cold ion is then photodissociated by pulsed (~5 ns) UV laser excitation, and the ionic products are trapped, cooled, and tagged by introduction of a second buffer gas pulse in the same trap. The tagged fragments are then ejected into a triple focusing, UV/vis/IR time-of-flight photofragmentation mass spectrometer which yields vibrational and electronic spectra of the mass-selected photofragments. Furthermore, these methods are demonstrated by application to the 266 nm photodissociation of the Rhodamine 6G cation to yield the R575 fragment ion based on loss of ethene as well as to a weaker secondary fragment arising from loss of m/z 43.