Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Interstellar”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Laboratory optical spectroscopy of the thiophenoxy radical and its profile simulation as a diffuse interstellar band based on rotational distribution by radiation and collisions

The gas-phase optical absorption spectrum of the thiophenoxy radical (C{sub 6}H{sub 5}S), a diffuse interstellar band (DIB) candidate molecule, was observed in the discharge of thiophenol using a cavity ringdown spectrometer. The ground-state rotational constants of the thiophenoxy radical were theoretically calculated, and the excited-state rotational constants were determined from the observed rotational profile. The rotational profile of a near prolate molecule having C {sub 2v} symmetry was simulated on the basis of a rotational distribution model by radiation and collisions. Although the simulated profile did not agree with the observed DIBs, the upper limit of the column density for the thiophenoxy radical in the diffuse clouds toward HD 204827 was evaluated to be 2 × 10{sup 13} cm{sup –2}. The profile simulation indicates that rotational distribution by radiation and collisions is important to reproduce a rotational profile for a DIB candidate and that the near prolate C {sub 2v} molecule is a possible candidate for DIB with a band width variation dependent on the line of sight.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

DIRECT DETERMINATION OF THE HF/H{sub 2} ABUNDANCE RATIO IN INTERSTELLAR GAS

We report the first detection of the v = 1-0, R(0) ro-vibrational transition of HF at 2.499385 {mu}m arising from interstellar gas. The line is seen in absorption toward three background sources-HD 154368, Elias 29, and AFGL 2136 IRS 1-all of which have reported H{sub 2} column densities determined from observations of H{sub 2}. This allows for the first direct determination of the HF/H{sub 2} abundance ratio. We find values of N(HF)/N(H{sub 2}) = 1.15 Multiplication-Sign 10{sup -8} and 0.69 Multiplication-Sign 10{sup -8} for HD 154368 and Elias 29, respectively. The sight line toward AFGL 2136 IRS 1 also shows absorption from the v = 1-0, R(1) transition of HF, indicating warm, dense (n {sub H} {approx}> 10{sup 9} cm{sup -3}) gas, likely very close to the central protostar. Ascribing portions of the HF absorption to warm and cold gas, we find N(HF)/N(H{sub 2}) = (1.7-2.9) Multiplication-Sign 10{sup -8} and (0.33-0.58) Multiplication-Sign 10{sup -8} for the two components, respectively. Except for the warm component toward AFGL 2136 IRS 1, all observed HF/H{sub 2} ratios are well below N(HF)/N(H{sub 2}) = 3.6 Multiplication-Sign 10{sup -8}, the value predicted if nearly all gas phase fluorine is in the form of HF. Models of fluorine chemistry that account for depletion onto grains are able to reproduce the results toward HD 154368, but not in the cold, dense gas toward AFGL 2136 IRS 1 and Elias 29. Most likely, some combinations of simplifying assumptions made in the chemical models are responsible for these discrepancies.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2013

INTERPRETATION OF INFRARED VIBRATION-ROTATION SPECTRA OF INTERSTELLAR AND CIRCUMSTELLAR MOLECULES

Infrared vibration-rotation lines can be valuable probes of interstellar and circumstellar molecules, especially symmetric molecules, which have no pure rotational transitions. But most such observations have been interpreted with an isothermal absorbing slab model, which leaves out important radiative transfer and molecular excitation effects. A more realistic non-LTE and non-isothermal radiative transfer model has been constructed. The results of this model are in much better agreement with the observations, including cases where lines in one branch of a vibration-rotation band are in absorption and another in emission. In general, conclusions based on the isothermal absorbing slab model can be very misleading, but the assumption of LTE may not lead to such large errors, particularly if the radiation field temperature is close to the gas temperature.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2013

THE NEUTRAL INTERSTELLAR GAS TOWARD SNR W44: CANDIDATES FOR TARGET PROTONS IN HADRONIC {gamma}-RAY PRODUCTION IN A MIDDLE-AGED SUPERNOVA REMNANT

We present an analysis of the interstellar medium (ISM) toward the {gamma}-ray supernova remnant (SNR) W44. We used NANTEN2 {sup 12}CO(J = 2-1) and {sup 12}CO(J = 1-0) data and Arecibo H I data in order to identify the molecular and atomic gas in the SNR. We confirmed that the molecular gas is located in the SNR shell with a primary peak toward the eastern edge of the shell. We newly identified high-excitation molecular gas along the eastern shell of the SNR in addition to the high-excitation broad gas previously observed inside the shell; the line intensity ratio between the {sup 12}CO(J = 2-1) and {sup 12}CO(J = 1-0) transitions in these regions is greater than {approx}1.0, suggesting a kinetic temperature of 30 K or higher, which is most likely due to heating by shock interaction. By comparing the ISM with {gamma}-rays, we find that target protons of hadronic origin are dominated by molecular protons of average density around 200 cm{sup -3}, where the possible contribution of atomic protons is 10% or less. This average density is consistent with the recent discovery of the low-energy {gamma}-rays suppressed in 50 MeV-10 GeV as observed with AGILE and Fermi. The {gamma}-ray spectrum differs from place to place in the SNR, suggesting that the cosmic-ray (CR) proton spectrum significantly changes within the middle-aged SNR perhaps due to the energy-dependent escape of CR protons from the acceleration site. We finally derive a total CR proton energy of {approx}10{sup 49} erg, consistent with the SN origin of the majority of the CRs in the Galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

THE TURBULENCE POWER SPECTRUM IN OPTICALLY THICK INTERSTELLAR CLOUDS

The Fourier power spectrum is one of the most widely used statistical tools to analyze the nature of magnetohydrodynamic (MHD) turbulence in the interstellar medium. Lazarian and Pogosyan predicted that the spectral slope should saturate to -3 for an optically thick medium and many observations exist in support of their prediction. However, there have not been any numerical studies to date for testing these results. We analyze the spatial power spectrum of MHD simulations with a wide range of sonic and Alfvenic Mach numbers, which include radiative transfer effects of the {sup 13}CO transition. We numerically confirm the predictions of Lazarian and Pogosyan that the spectral slope of line intensity maps of an optically thick medium saturates to -3. Furthermore, for very optically thin supersonic CO gas, where the density or CO abundance values are too low to excite emission in all but the densest shock compressed gas, we find that the spectral slope is shallower than expected from the column density. Finally, we find that mixed optically thin/thick CO gas, which has average optical depths on the order of unity, shows mixed behavior: for super-Alfvenic turbulence, the integrated intensity power spectral slopes generally follow the same trend with sonic Mach number as the true column density power spectrum slopes. However, for sub-Alfvenic turbulence the spectral slopes are steeper with values near -3 which are similar to the very optically thick regime.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

TIMESCALES ON WHICH STAR FORMATION AFFECTS THE NEUTRAL INTERSTELLAR MEDIUM

Turbulent neutral hydrogen (H I) line widths are often thought to be driven primarily by star formation (SF), but the timescale for converting SF energy to H I kinetic energy is unclear. As a complication, studies on the connection between H I line widths and SF in external galaxies often use broadband tracers for the SF rate, which must implicitly assume that SF histories (SFHs) have been constant over the timescale of the tracer. In this paper, we compare measures of H I energy to time-resolved SFHs in a number of nearby dwarf galaxies. We find that H I energy surface density is strongly correlated only with SF that occurred 30-40 Myr ago. This timescale corresponds to the approximate lifetime of the lowest mass supernova progenitors ({approx}8 M{sub Sun }). This analysis suggests that the coupling between SF and the neutral interstellar medium is strongest on this timescale, due either to an intrinsic delay between the release of the peak energy from SF or to the coherent effects of many supernova explosions during this interval. At {Sigma}{sub SFR} > 10{sup -3} M{sub Sun} yr{sup -1} kpc{sup -2}, we find a mean coupling efficiency between SF energy and H I energy of {epsilon} = 0.11 {+-} 0.04 using the 30-40 Myr timescale. However, unphysical efficiencies are required in lower {Sigma}{sub SFR} systems, implying that SF is not the primary driver of H I kinematics at {Sigma}{sub SFR} < 10{sup -3} M{sub Sun} yr{sup -1} kpc{sup -2}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

PROBING THE INTERSTELLAR MEDIUM OF z {approx} 1 ULTRALUMINOUS INFRARED GALAXIES THROUGH INTERFEROMETRIC OBSERVATIONS OF CO AND SPITZER MID-INFRARED SPECTROSCOPY

We explore the relationship between gas, dust, and star formation in a sample of 12 ultraluminous infrared galaxies (ULIRGs) at high-redshift compared to a similar sample of local galaxies. We present new CO observations and/or Spitzer mid-IR spectroscopy for six 70 {mu}m selected galaxies at z {approx} 1 in order to quantify the properties of the molecular gas reservoir, the contribution of an active galactic nucleus (AGN) to the mid-IR luminosity, and the star formation efficiency (SFE = L{sub IR}/L{sup '}{sub CO}). The mid-IR spectra show strong polycyclic aromatic hydrocarbon (PAH) emission, and our spectral decomposition suggests that the AGN makes a minimal contribution (<25%) to the mid-IR luminosity. The 70 {mu}m selected ULIRGs, which we find to be spectroscopic close pairs, are observed to have high SFE, similar to local ULIRGs and high-redshift submillimeter galaxies, consistent with enhanced IR luminosity due to an ongoing major merger. Combined with existing observations of local and high-redshift ULIRGs, we further compare the PAH, IR, and CO luminosities. We show that the ratio L{sub PAH,6.2}/L{sub IR} decreases with increasing IR luminosity for both local and high-redshift galaxies, but the trend for high-redshift galaxies is shifted to higher IR luminosities; the average L{sub PAH,6.2}/L{sub IR} ratio at a given L{sub IR} is {approx}3 times higher at high-redshift. When we normalize by the molecular gas, we find this trend to be uniform for galaxies at all redshifts and that the molecular gas is correlated with the PAH dust emission. The similar trends seen in the [C II] to molecular gas ratios in other studies suggests that PAH emission, like [C II], continues to be a good tracer of photodissociation regions even at high-redshift. Together the CO, PAH, and far-IR fine structure lines should be useful for constraining the interstellar medium conditions in high-redshift galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

KETENE FORMATION IN INTERSTELLAR ICES: A LABORATORY STUDY

The formation of ketene (H{sub 2}CCO, ethenone) in polar and apolar ices was studied with in situ 0.8 MeV proton irradiation, far-UV photolysis, and infrared spectroscopic analyses at 10-20 K. Using isotopically enriched reagents, unequivocal evidence was obtained for ketene synthesis in H{sub 2}O-rich and CO{sub 2}-rich ices, and several reaction products were identified. Results from scavenging experiments suggested that ketene was formed by free-radical pathways, as opposed to acid-base processes or redox reactions. Finally, we use our results to draw conclusions about the formation and stability of ketene in the interstellar medium.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2013

INTERSTELLAR DUST PROPERTIES OF M51 FROM AKARI MID-INFRARED IMAGES

Using mid-infrared (MIR) images of four photometric bands of the Infrared Camera on board the AKARI satellite, S7 (7 μm), S11 (11 μm), L15 (15 μm), and L24 (24 μm), we investigate the interstellar dust properties of the nearby pair of galaxies M51 with respect to their spiral arm structure. The arm and interarm regions are defined based on a spatially filtered stellar component model image and we measure the arm/interarm contrast for each band. The contrast is lowest in the S11 image, which we interpret as meaning that among the four AKARI MIR bands, the S11 image best correlates with the spatial distribution of dust grains including colder components. On the other hand, the L24 image, with the highest contrast, traces warmer dust heated by star forming activity. The surface brightness ratio between the bands, i.e., color, is measured over the disk of the main galaxy, M51a, at 300 pc resolution. We find that the distribution of S7/S11 is smooth and traces the global spiral arm pattern well while L15/S11 and L24/S11 peak at individual H II regions. This result indicates that the ionization state of polycyclic aromatic hydrocarbons (PAHs) is related to the spiral structure. Comparison with observational data and dust models also supports the importance of the variation in the PAH ionization state within the M51a disk. However, the mechanism driving this variation is not yet clear from the currently available datasets. Another suggestion from the comparison with the models is that the PAH fraction in the total dust mass is higher than previously estimated.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Toward detection of AlCH{sub 2} and AlCH{sub 2}{sup +} in the interstellar medium

Highly reliable molecular properties have been computed for AlCH{sub 2} and AlCH{sub 2}{sup +} at the CCSD(T)/cc-pwCVQZ level of theory. These simple aluminum species are relevant to the chemistry of the interstellar medium (ISM) and circumstellar medium, and are proposed to form in regions where aluminum and methylene exist in appreciable concentrations because AlCH{sub 2} and AlCH{sub 2}{sup +} are thermodynamically stable with respect to dissociation. Herein, dissociation energies were computed for both species through extrapolation to the complete basis set limit using focal point analysis. For the neutral species, 86 kcal mol{sup –1} is required to heterolytically cleave the Al-C single bond, while the cationic species requires 38 kcal mol{sup –1}. To aid in identification within the ISM, the anharmonic (fundamental) frequencies, spectroscopic constants, and vibrationally averaged properties for AlCH{sub 2} and the corresponding cation are also reported.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Cosmic ray sampling of a clumpy interstellar medium

How cosmic rays sample the multi-phase interstellar medium (ISM) in starburst galaxies has important implications for many science goals, including evaluating the cosmic ray calorimeter model for these systems, predicting their neutrino fluxes, and modeling their winds. Here, we use Monte Carlo simulations to study cosmic ray sampling of a simple, two-phase ISM under conditions similar to those of the prototypical starburst galaxy M82. The assumption that cosmic rays sample the mean density of the ISM in the starburst region is assessed over a multi-dimensional parameter space where we vary the number of molecular clouds, the galactic wind speed, the extent to which the magnetic field is tangled, and the cosmic ray injection mechanism. We evaluate the ratio of the emissivity from pion production in molecular clouds to the emissivity that would be observed if the cosmic rays sampled the mean density, and seek areas of parameter space where this ratio differs significantly from unity. The assumption that cosmic rays sample the mean density holds over much of parameter space; however, this assumption begins to break down for high cloud density, injection close to the clouds, and a very tangled magnetic field. We conclude by evaluating the extent to which our simulated starburst region behaves as a proton calorimeter and constructing the time-dependent spectrum of a burst of cosmic rays.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Instability of evaporation fronts in the interstellar medium

The neutral component of the interstellar medium is segregated into the cold neutral medium (CNM) and warm neutral medium (WNM) as a result of thermal instability. It was found that a plane-parallel CNM-WNM evaporation interface, across which the CNM undergoes thermal expansion, is linearly unstable to corrugational disturbances, in complete analogy with the Darrieus-Landau instability (DLI) of terrestrial flames. We perform a full linear stability analysis as well as nonlinear hydrodynamic simulations of the DLI of such evaporation fronts in the presence of thermal conduction. We find that the DLI is suppressed at short length scales by conduction. The length and time scales of the fastest growing mode are inversely proportional to the evaporation flow speed of the CNM and its square, respectively. In the nonlinear stage, the DLI saturates to a steady state where the front deforms to a finger-like shape protruding toward the WNM, without generating turbulence. The evaporation rate at nonlinear saturation is larger than the initial plane-parallel value by a factor of ∼2.4 when the equilibrium thermal pressure is 1800 k {sub B} cm{sup –3} K. The degrees of front deformation and evaporation-rate enhancement at nonlinear saturation are determined primarily by the density ratio between the CNM and WNM. We demonstrate that the Field length in the thermally unstable medium should be resolved by at least four grid points to obtain reliable numerical outcomes involving thermal instability.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Some insights into formamide formation through gas-phase reactions in the interstellar medium

We study the viability of different gas-phase ion-molecule reactions that could produce precursors of formamide in the interstellar medium. We analyze different reactions between cations containing a nitrogen atom (NH{sub 3}{sup +}, NH{sub 4}{sup +}, NH{sub 3}OH{sup +}, and NH{sub 2}OH{sup +}) and neutral molecules having one carbonyl group (H{sub 2}CO and HCOOH). First, we report a theoretical estimation of the reaction enthalpies for the proposed processes. Second, for more favorable reactions, from a thermodynamic point of view, we perform a theoretical study of the potential energy surface. In particular, the more exothermic processes correspond to the reactions of ionized and protonated hydroxylamine with formaldehyde. In addition, a neutral-neutral reaction has also been considered. The analysis of the potential energy surfaces corresponding to these reactions shows that these processes present a net activation barrier and that they cannot be considered as a source of formamide in space.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Formation of different isotopomers of chloronium in the interstellar medium

The main focus of this paper is to explore the possibility of finding two deuterated isotopomers of H{sub 2}Cl{sup +} (chloronium) in and around the interstellar medium. The presence of a chloronium ion has recently been confirmed by the Herschel Space Observatory's Heterodyne Instrument for the far-infrared. It observed para-chloronium toward six sources in the Galaxy. To date the existence of its deuterated isotopomers (HDCl{sup +} and D{sub 2}Cl{sup +}) have not been discussed in the literature. We find that these deuterated gas phase ions could be destroyed by various ion-molecular reactions, dissociative recombination (DR), and cosmic rays (CRs). We compute all of the ion-molecular (polar) reaction rates by using the parameterized trajectory theory and the ion-molecular (non-polar) reaction rates by using the Langevin theory. For DR- and CR-induced reactions, we adopt two well-behaved rate formulas. We also include these rate coefficients in our large gas-grain chemical network to study the chemical evolution of these species around the outer edge of the cold, dense cloud. In order to study spectral properties of the chloronium ion and its two deuterated isotopomers, we have carried out quantum chemical simulations. We calculated ground-state properties of these species by employing second-order Moller-Plesset perturbation theory (MP2) along with quadruple-zeta correlation consistent (aug-cc-pVQZ) basis set. Infrared and electronic absorption spectra of these species are calculated by using the same level of theory. The MP2/aug-cc-pVQZ level of theory is used to report the different spectroscopic constants of these gas phase species. These spectroscopic constants are essential to predict the rotational transitions of these species. Our predicted column densities of D{sub 2}Cl{sup +}, HDCl{sup +}, along with spectral information may enable their future identification around outer edges of cold, dark clouds.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Self-sustained turbulence without dynamical forcing: A two-dimensional study of a bistable interstellar medium

In this paper, the nonlinear evolution of a bistable interstellar medium is investigated using two-dimensional simulations with a realistic cooling rate, thermal conduction, and physical viscosity. The calculations are performed using periodic boundary conditions without any external dynamical forcing. As the initial condition, a spatially uniform unstable gas under thermal equilibrium is considered. At the initial stage, the unstable gas quickly segregates into two phases: cold neutral medium (CNM) and warm neutral medium (WNM). Then, self-sustained turbulence with velocity dispersion of 0.1-0.2 km s{sup –1} is observed in which the CNM moves around in the WNM. We find that the interfacial medium (IFM) between the CNM and WNM plays an important role in sustaining the turbulence. The self-sustaining mechanism can be divided into two steps. First, thermal conduction drives fast flows streaming into concave CNM surfaces toward the WNM. The kinetic energy of the fast flows in the IFM is incorporated into that of the CNM through the phase transition. Second, turbulence inside the CNM deforms interfaces and forms other concave CNM surfaces, leading to fast flows in the IFM. This drives the first step again and a cycle is established by which turbulent motions are self-sustained.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Computational prediction of the spectroscopic parameters of methanediol, an elusive molecule for interstellar detection

The molecular structure of methanediol has been investigated by means of quantum chemical calculations. Two conformers, corresponding to C{sub 2} and C {sub s} symmetries, respectively, were considered. The C{sub 2} conformer is found to lie about 1.7 (at 298 K) or 2.3 (at 0 K) kcal mol{sup –1} below the C {sub s} conformer. Predictions for their rotational constants, vibrational frequencies, IR intensities, and dipole moments have been provided. The lowest-lying isomer has a very low dipole moment, around 0.03 D, whereas the C {sub s} conformer has a relatively high dipole moment, namely, 2.7 D. The barrier for the C {sub s} →C{sub 2} process is predicted to be around 0.7-1 kcal mol{sup –1}. Based on the energetic results the proportion of the C{sub s} conformer is likely to be negligible under low temperature conditions, such as in the interstellar medium. Therefore, it is predicted that detection by radioastronomy of methanediol would be rather unlikely.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2014

Nucleation and stabilization of carbon-rich structures in interstellar media

We study the conditions under which carbon clusters of different sizes form and stabilize. We describe the approach to equilibrium by simulating tenuous carbon gas dynamics to long times. First, we use reactive molecular dynamics simulations to describe the nucleation of long chains, large clusters, and complex cage structures in carbon- and hydrogen-rich interstellar gas phases. We study how temperature, particle density, the presence of hydrogen, and carbon inflow affect the nucleation of molecular moieties with different characteristics, in accordance with astrophysical conditions. We extend the simulations to densities that are orders of magnitude lower than current laboratory densities, to temperatures that are relevant to circumstellar environments of planetary nebulae, and microsecond formation times. We correlate cluster size distributions from the simulations with thermodynamic equilibrium at low temperatures and gas densities, where entropy plays a significant role.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Widespread rotationally hot hydronium ion in the galactic interstellar medium

We present new Herschel observations of the (6,6) and (9,9) inversion transitions of the hydronium ion toward Sagittarius B2(N) and W31C. Sensitive observations toward Sagittarius B2(N) show that the high, ∼500 K, rotational temperatures characterizing the population of the highly excited metastable H{sub 3}O{sup +} rotational levels are present over a wide range of velocities corresponding to the Sagittarius B2 envelope, as well as the foreground gas clouds between the Sun and the source. Observations of the same lines toward W31C, a line of sight that does not intersect the Central Molecular Zone but instead traces quiescent gas in the Galactic disk, also imply a high rotational temperature of ∼380 K, well in excess of the kinetic temperature of the diffuse Galactic interstellar medium. While it is plausible that some fraction of the molecular gas may be heated to such high temperatures in the active environment of the Galactic center, characterized by high X-ray and cosmic-ray fluxes, shocks, and high degree of turbulence, this is unlikely in the largely quiescent environment of the Galactic disk clouds. We suggest instead that the highly excited states of the hydronium ion are populated mainly by exoergic chemical formation processes and the temperature describing the rotational level population does not represent the physical temperature of the medium. The same arguments may be applicable to other symmetric top rotors, such as ammonia. This offers a simple explanation of the long-standing puzzle of the presence of a pervasive, hot molecular gas component in the central region of the Milky Way. Moreover, our observations suggest that this is a universal process not limited to the active environments associated with galactic nuclei.

79 ASTRONOMY AND ASTROPHYSICS↗