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At least 1,153 records · Page 64

All sources NASA NTRS DOE OSTI

DOE OSTI2016

On the problem of internal optical loss and current leakage in laser heterostructures based on AlGaInAs/InP solid solutions

Semiconductor lasers based on MOCVD-grown AlGaInAs/InP separate-confinement heterostructures are studied. It is shown that raising only the energy-gap width of AlGaInAs-waveguides without the introduction of additional barriers results in more pronounced current leakage into the cladding layers. It is found that the introduction of additional barrier layers at the waveguide–cladding-layer interface blocks current leakage into the cladding layers, but results in an increase in the internal optical loss with increasing pump current. It is experimentally demonstrated that the introduction of blocking layers makes it possible to obtain maximum values of the internal quantum efficiency of stimulated emission (92%) and continuouswave output optical power (3.2 W) in semiconductor lasers in the eye-safe wavelength range (1400–1600 nm).

36 MATERIALS SCIENCE↗

DOE OSTI2018

Local Symmetry of a Channel for the Transport of Atoms and Molecules and Its Internal Dimensions

The effect of a channel’s symmetry type on its internal dimensions, which would allow the movement of atoms (ions, molecules), has been discussed. Based on the symmetry properties of the Lagrange function for the channel and the properties of the channel itself, its internal dimensions are determined. The particular example of the crystallographic channel of quartz and its dislocations is considered.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2018

Direct detection of MeV-scale dark matter utilizing germanium internal amplification for the charge created by the ionization of impurities

Light, MeV-scale dark matter (DM) is an exciting DM candidate that is undetectable by current experiments. A germanium (Ge) detector utilizing internal charge amplification for the charge carriers created by the ionization of impurities is a promising new technology with experimental sensitivity for detecting MeV-scale DM. We analyze the physics mechanisms of the signal formation, charge creation, charge internal amplification, and the projected sensitivity for directly detecting MeV-scale DM particles. We present a design for a novel Ge detector at helium temperature (~4 K) enabling ionization of impurities from DM impacts. With large localized E-fields, the ionized excitations can be accelerated to kinetic energies larger than the Ge bandgap at which point they can create additional electron–hole pairs, producing intrinsic amplification to achieve an ultra-low energy threshold of ~0.1 eV for detecting low-mass DM particles in the MeV scale. Correspondingly, such a Ge detector with 1 kg-year exposure will have high sensitivity to a DM-nucleon cross section of ~5 × 10 -45 cm 2 at a DM mass of ~10 MeV/c 2 and a DM-electron cross section of ~ 5 × 10 -46 cm 2 at a DM mass of 1 MeV/c 2 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2016

Development and Properties of Advanced Internal Magnesium Infiltration (AIMI) Processed MgB2 Wires

The development, processing, properties, and formation mechanisms of Advanced Internal Magnesium Infiltration (AIMI) MgB2 wires are discussed against a background of the related and original processes, Internal-Magnesium-Diffusion (IMD) and Magnesium-Reactive-Liquid-Infiltration (Mg-RLI). First reviewed are the formation, properties and applications of Mg-RLI bulks as basis for discussions of Mg-RLI-processed and IMD-processed wires. The transition from Mg-RLI- and IMD- to AIMI wires is explained, and the relative performances of powder-in-tube (PIT), IMD and AIMI wires are summarized in the form of an iso-Je diagram of Jc,nb versus Anb/ATOT in which ATOT, Anb, Jc,nb, and Je are, respectively, the wire s cross-sectional area, the area inside the chemical barrier, the critical current (Ic) normalized to Anb, and Ic normalized to ATOT. After the details of AIMI wire fabrication selection of starting powders, dopants, and reaction heat treatments are introduced the report goes on to describe in detail the development of high performance AIMI wires: layer Jcs, fill factors, Jes, and the effects of wire size, multifilamentarization, doping with C, and co-doping with C and Dy2O3. The two-stage mechanism of layer formation in AIMI wires is discussed: first the reactive infiltration of liquid Mg into a porous B pack, a process that terminates with the formation of a dense MgB2 layer; second the slow diffusion of Mg into any remaining B through that MgB2 layer. The report concludes with a brief general discussion of anisotropy, current percolation, and the Jc field dependence of MgB2 wires.

Collings, Prof Edward William↗

DOE OSTI2021

In Situ Measurement of Temperature Distributions in a Li-ion Cell during Internal Short Circuit and Thermal Runaway

Here we report in situ measurement of temperature distributions in a 2.5-Ah pouch format Li-ion cell during internal short circuit (ISC) and thermal runaway. The ISC and thermal runaway were triggered by nail penetration. The local temperatures were measured by embedded K type micro thermocouples in the middle layer of the experimental Li-ion cell. Highly non-uniform temperature distributions were observed during ISC and thermal runaway as compared with those during constant current discharging and external short circuit. The in situ measurement also captured details of how thermal runaway started from the ISC location and spread to the entire cell in a few seconds. Moreover, the comparison between ISC without thermal runaway and ISC with thermal runaway suggests that internal short circuit resistance plays a critical role in the risk of thermal runaway.

Huang, Shan↗

DOE OSTI2022

Using Membranes with Internal Microchannels to Prevent Drying-out during CO 2 Electrolysis

Scaling up CO 2 electrolysis is a vital aspect in the transition to manufacturing sustainable fuels and chemical compounds, satisfying the demand for chemicals and demand for storing renewable electricity. Depending on the employed catalyst, different products can be produced, such as carbon monoxide and ethylene, by applying a voltage on a CO 2 and H 2 O fed electrolyzer. CO is a desirable product according to techno-economic analysis, because it can be produced selectively using a silver catalyst and is a precursor for hydrocarbons in the Fischer–Tropsch process. In a state-of-the-art CO 2 electrolyzer, two electrodes are directly pressed against an ion-exchange membrane – this is called a zero-gap configuration. Therefore, the membrane is a crucial component for the system, since it has the role of providing a conductive medium between the electrodes. One of the challenges in CO 2 electrolysis is that water is consumed in the reaction. At high current density, this may cause the membrane's surface near the cathode to dry out, lowering efficiency or perhaps stopping the process entirely, since there is no longer a conductive medium. As a result, water management is critical for this process. In this work, we approach the drying-out challenge by studying the novel concept of a membrane with internal microchannels. These channels allow the circulation of water or an electrolyte inside the membrane, which reduces the water diffusion path and affects the membrane’s conductivity. The effects of channel geometry, location, and concentrations of electrolyte inside on water content, conductivity and overall performance are studied in a 2D COMSOL model. In addition, the effect of internal concentration of electrolyte on the membrane’s resistance, on the process performance and the K + cross-over to cathode side were investigated experimentally. Our modeling results prove that the presence of the channels can keep the membrane hydrated. The highest current densities are observed when the channel is closest to the cathode, and with smaller pores. Smaller pores are advantageous due to the trade-off between enhanced membrane conductivity and the lower conductivity of the liquid itself. If water is circulated in a large channel, it increases the membrane’s ionomer conductivity due to hydration but the overall conductivity is decreased since water is not highly conductive. Nonetheless, the results also show that a higher concentration of electrolyte inside the microchannels can significantly increase the total conductivity of the membrane, and therefore the energy efficiency of the process. These effects are most significant at higher current densities. In the experimental results, we’ve observed similar effects in terms of membrane conductivity and current density of the process – the higher the electrolyte concentration the higher the current density. Furthermore, a low concentration decreases the amount of potassium which crosses over to the cathode side, inhibiting salt deposition. We’ve concluded that a small channel, up to 90 µm wide, close to the pore with an electrolyte with a concentration of up to 10 mM could be very beneficial for the water management and energy efficiency of the process. This helps to keep the membrane hydrated at higher current densities, improves the conductivity of the membrane, and it doesn’t have significant impacts on the salt deposition.

Petrov, Kostadin Veselinov↗

DOE OSTI2018

How Well Can We Represent the Spectrum of Convective Clouds in a Climate Model? Comparisons between Internal Parameterization Variables and Radar Observations

Current climate models cannot resolve individual convective clouds, and hence parameterizations are needed. The primary goal of convective parameterization is to represent the bulk impact of convection on the gridbox-scale variables. Spectral convective parameterizations also aim to represent the key features of the subgrid-scale convective cloud field such as cloud-top-height distribution and in-cloud vertical velocities in addition to precipitation rates. Ground-based radar retrievals of these quantities have been made available at Darwin, Australia, permitting direct comparisons of internal parameterization variables and providing new observational references for further model development. A spectral convective parameterization [the convective cloud field model (CCFM)] is discussed, and its internal equation of motion is improved. Results from the ECHAM–HAM model in single-column mode using the CCFM and the bulk mass flux Tiedtke–Nordeng scheme are compared with the radar retrievals at Darwin. The CCFM is found to outperform the Tiedtke–Nordeng scheme for cloud-top-height and precipitation-rate distributions. Radar observations are further used to propose a modified CCFM configuration with an aerodynamic drag and reduced entrainment parameter, further improving both the convective cloud-top-height distribution (important for large-scale impact of convection) and the in-cloud vertical velocities (important for aerosol activation). This study provides a new development in the CCFM, improving the representation of convective cloud spectrum characteristics observed in Darwin. This is a step toward an improved representation of convection and ultimately of aerosol effects on convection. It also shows how long-term radar observations of convective cloud properties can help constrain parameters of convective parameterization schemes.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2019

IJER editorial: The future of the internal combustion engine

Internal combustion (IC) engines operating on fossil fuel oil provide about 25% of the world’s power (about 3000 out of 13,000 million tons oil equivalent per year—see Figure 1), and in doing so, they produce about 10% of the world’s greenhouse gas (GHG) emissions (Figure 2). Reducing fuel consumption and emissions has been the goal of engine researchers and manufacturers for years, as can be seen in the two decades of ground-breaking peer-reviewed articles published in this International Journal of Engine Research (IJER). Indeed, major advances have been made, making today’s IC engine a technological marvel. However, recently, the reputation of IC engines has been dealt a severe blow by emission scandals that threaten the ability of this technology to make significant and further contributions to the reduction of transportation sector emissions. In response, there have been proposals to replace vehicle IC engines with electric-drives with the intended goals of further reducing fuel consumption and emissions, and to decrease vehicle GHG emissions.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2020

Collaborative investigation of the internal flow and near-nozzle flow of an eight-hole gasoline injector (Engine Combustion Network Spray G)

The internal details of fuel injectors have a profound impact on the emissions from gasoline direct injection engines. However, the impact of injector design features is not currently understood, due to the difficulty in observing and modeling internal injector flows. Gasoline direct injection flows involve moving geometry, flash boiling, and high levels of turbulent two-phase mixing. In order to better simulate these injectors, five different modeling approaches have been employed to study the engine combustion network Spray G injector. Here these simulation results have been compared to experimental measurements obtained, among other techniques, with X-ray diagnostics, allowing the predictions to be evaluated and critiqued. The ability of the models to predict mass flow rate through the injector is confirmed, but other features of the predictions vary in their accuracy. The prediction of plume width and fuel mass distribution varies widely, with volume-of-fluid tending to overly concentrate the fuel. All the simulations, however, seem to struggle with predicting fuel dispersion and by inference, jet velocity. This shortcoming of the predictions suggests a need to improve Eulerian modeling of dense fuel jets.

ECN↗

DOE OSTI2019

Internal Mammary Chain Sentinel Nodes in Early-Stage Breast Cancer Patients: Toward Selective Removal

Background: Removal of internal mammary chain sentinel nodes (IMCSNs) affects prognosis and treatment of breast cancer, and internal mammary chain radiotherapy (IMCRT) can improve survival for selected patients. This study aimed to determine the effect of IMCSN biopsy on recurrence-free survival (RFS) and overall survival (OS) and to identify predictive factors for IMCSN and distant metastasis. Methods: Patients with IMCSNs were selected from a prospective database for the period 1999–2007. Lymphoscintigraphy was performed after intratumoral technetium-99 m injection, and all sentinel nodes were removed. Both RFS and OS were calculated for subgroups with tumor-positive, tumor-negative, or non-removed IMCSNs. Predictive factors were identified for tumor-positive IMCSNs and distant metastasis by regression analysis. Results: For 287 (85%) of 336 patients, IMCSN biopsy was performed, and metastasis was detected in 38 patients (13%). The patients with tumor-positive IMCSNs had poorer OS than the patients with no IMCSN metastasis or non-removed IMCSNs (p = 0.002). These patients also had worse RFS due to distant metastasis (p = 0.002). Axillary metastasis was predictive for tumor-positive IMCSNs (positive predictive value, 38.5%). The predictive factors for distant metastasis were tumor-positive IMCSNs (hazard ratio [HR], 2.5), non-removed IMCSNs (HR, 2.3), tumor diameter greater than 1.5 cm (HR, 3.5), and age older than 65 years (HR, 3.1; reference, < 50 years). Conclusions: Patients with IMCSNs have worse survival due to distant metastasis. The clinically relevant predictive factor for distant metastasis is tumor larger than 1.5 cm. According to the authors’ current protocol, IMCSN biopsy is performed for patients younger than 70 years who have a tumor larger than 1.5 cm, with the cardiotoxicity of the adjuvant IMCRT weighed against the survival benefit.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

DOE OSTI2022

A Procedure to Correct the Historical Atmospheric Longwave Irradiance Data When the World Reference Is Established with Respect to the International System of Units

Historical atmospheric longwave irradiance data sets with traceability to the International System of Units (SI) are essential for renewable energy and atmospheric science research and applications. To date, all pyrgeometers used to measure the irradiance are traceable to the interim World Infrared Standard Group (WISG), not to SI units. In 2013, the Absolute Cavity Pyrgeometer (ACP) (Reda et al. 2012) was developed at the National Renewable Energy Laboratory (NREL) to measure the atmospheric longwave irradiance. The ACP has been compared against the InfraRed Integrating Sphere (IRIS), developed by the Physikalisch-Meteorologisches Observatorium Davos/World Radiation Center (PMOD/WRC) (Grobner 2012). The ACP and the IRIS are absolute instruments traceable to SI units through the International Temperature Scale of 1990. Results of six comparisons between the ACP and the IRIS at different locations have shown that the irradiance measured by WISG pyrgeometers underestimates clear-sky atmospheric longwave irradiance by 2 W/m 2 to 6 W/m 2 (Grobner et al. 2014); therefore, once the world reference is established with traceability to SI units, the WISG would be corrected, then used to calibrate field pyrgeometers with traceability to SI units. The following described method is used to correct the historical atmospheric longwave irradiance data sets in anticipation of the WISG scale change.

47 OTHER INSTRUMENTATION↗

DOE OSTI2016

International land Model Benchmarking (ILAMB) Package v001.00

As a contribution to International Land Model Benchmarking (ILAMB) Project, we are providing new analysis approaches, benchmarking tools, and science leadership. The goal of ILAMB is to assess and improve the performance of land models through international cooperation and to inform the design of new measurement campaigns and field studies to reduce uncertainties associated with key biogeochemical processes and feedbacks. ILAMB is expected to be a primary analysis tool for CMIP6 and future model-data intercomparison experiments. This team has developed initial prototype benchmarking systems for ILAMB, which will be improved and extended to include ocean model metrics and diagnostics.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2016

International land Model Benchmarking (ILAMB) Package v002.00

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2017

Thin Internal Target Studies in a Compact FFAG

The production of radioisotopes using a thin internal target and recycled beam within a compact FFAG design has been studied. Radioisotopes have a wide range of uses in medicine, and recent disruption to the supply chain has seen a renewed effort to find alternative isotopes and production methods. The FFAG design features separate sector magnets with non-scaling, non-linear field gradients which are optimized with magnet geometry to achieve isochronisity at the level of 0.3%, sufficient for Continuous Wave (CW) operation. Simulations have demonstrated that beam currents of up to 10mA can comfortably be achieved with this design. To further improve production efficiency a thin internal target, where the beam passes through the target and is recirculated, may be used. This setup ensures that production takes place within a narrow energy range, potentially increasing production rates and reducing impurities.

43 PARTICLE ACCELERATORS↗

DOE OSTI2014

Feasibility Study of Implementing a Mobile Collaborative Information Platform for International Safeguards Inspections

In response to the growing pervasiveness of mobile technologies such as tablets and smartphones, the International Atomic Energy Agency and the U.S. Department of Energy National Laboratories have been exploring the potential use of these platforms for international safeguards activities. Specifically of interest are information systems (software, and accompanying servers and architecture) deployed on mobile devices to increase the situational awareness and productivity of an IAEA safeguards inspector in the field, while simultaneously reducing paperwork and pack weight of safeguards equipment. Exploratory development in this area has been met with skepticism regarding the ability to overcome technology deployment challenges for IAEA safeguards equipment. This report documents research conducted to identify potential challenges for the deployment of a mobile collaborative information system to the IAEA, and proposes strategies to mitigate those challenges.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2016

Internal (Annular) and Compressible External (Flat Plate) Turbulent Flow Heat Transfer Correlations.

Here we provide a discussion regarding the applicability of a family of traditional heat transfer correlation based models for several (unit level) heat transfer problems associated with flight heat transfer estimates and internal flow heat transfer associated with an experimental simulation design (Dobranich 2014). Variability between semi-empirical free-flight models suggests relative differences for heat transfer coefficients on the order of 10%, while the internal annular flow behavior is larger with differences on the order of 20%. We emphasize that these expressions are strictly valid only for the geometries they have been derived for e.g. the fully developed annular flow or simple external flow problems. Though, the application of flat plate skin friction estimate to cylindrical bodies is a traditional procedure to estimate skin friction and heat transfer, an over-prediction bias is often observed using these approximations for missile type bodies. As a correction for this over-estimate trend, we discuss a simple scaling reduction factor for flat plate turbulent skin friction and heat transfer solutions (correlations) applied to blunt bodies of revolution at zero angle of attack. The method estimates the ratio between axisymmetric and 2-d stagnation point heat transfer skin friction and Stanton number solution expressions for sub-turbulent Reynolds numbers %3C1x10 4 . This factor is assumed to also directly influence the flat plate results applied to the cylindrical portion of the flow and the flat plate correlations are modified by

42 ENGINEERING↗

DOE OSTI2016

Study of the internal structure, instabilities, and magnetic fields in the dense Z-pinch

Z-pinches are sources of hot dense plasma which generates powerful x-ray bursts and can been applied to various areas of high-energy-density physics (HEDP). The 26-MA Z machine is at the forefront of many of these applications, but important aspects of HEDP have been studied on generators at the 1 MA current level. Recent development of laser diagnostics and upgrade of the Leopard laser at Nevada Terawatt Facility (NTF) give new opportunities for the dense Z-pinch study. The goal of this project is the investigation of the internal structure of the stagnated Z pinch including sub-mm and micron-scale instabilities, plasma dynamics, magnetic fields, and hot spots formation and initiation. New plasma diagnostics will be developed for this project. A 3D structure and instabilities of the pinch will be compared with 3D MHD and spectroscopic modeling and theoretical analysis. The structure and dynamics of stagnated Z pinches has been studied with x-ray self-radiation diagnostics which derive a temperature map of the pinch with a spatial resolution of 70-150 µm. The regular laser diagnostics at 532 nm does not penetrate in the dense pinch due to strong absorption and refraction in trailing plasma. Recent experiments at NTF showed that shadowgraphy at the UV wavelength of 266 nm unfolds a fine structure of the stagnated Z-pinch with unprecedented detail. We propose to develop laser UV diagnostics for Z pinches with a spatial resolution <5 μm to study the small-scale plasma structures, implement two-frame shadowgraphy/interferometry, and develop methods for investigation of strong magnetic fields. New diagnostics will help to understand better basic physical processes in Z pinches. A 3D internal structure of the pinch and characteristic instabilities will be studied in wire arrays with different configurations and compared with 3D MHD simulations and analytical models. Mechanisms of “enhanced heating” of Z-pinch plasma will be studied. Fast dynamics of stagnated plasma will be studied to estimate its contribution to the Doppler broadening of x-ray lines. Development of “necks” and “hot spots” will be studied with high-resolution UV diagnostics, an x-ray streak camera, and x-ray spectroscopy. Laser initiation of hot spots in Z pinches will be tested. A Faraday rotation diagnostic at 266 nm will be applied to 1-10 MG magnetic fields. For magnetic fields B>20 MG, suggested in micropinches, Cotton-Mouton and cutoff diagnostics will be applied. A picosecond optical Kerr shutter will be tested to increase a sensitivity of UV methods for application at multi-MA Z pinches. The proposal is based on the experimental capability of NTF. The Zebra generator produces 1-1.7 MA Z-pinches with electron plasma density of 10 20 -10 21 cm -3 , electron temperature of 0.5-1 keV, and magnetic fields >10 MG. The Leopard laser was upgraded to energy of 90-J at 0.8 ns. This regime will be used for laser initiation of hot spots. A further upgrade to energy of 250-J is suggested for laser-Z-pinch interaction. A picosecond regime will be used for optical gating. A 10-TW Tomcat laser at NTF is available for the high energy UV laser probing of the Z-pinch. Two graduate students will develop new optical and x-ray diagnostics, carry out experiments, and process experimental data. Other students will be involved in the design and fabrication of loads, supporting regular optical and x-ray diagnostics, and data processing. The new plasma diagnostics may be applied to HEDP experiments at NTF and other multi-MA generators. The feasibility of the research plan is based on the experience of the scientific team in Z-pinch plasma physics, laser physics, development of new plasma diagnostics, and the experimental capability of NTF. The experimental group of Dr. V. V. Ivanov (UNR) collaborates with a group for Z pinch MHD modeling of Dr. J. P. Chittenden (Imperial College, London), and theoretical group of Dr. D. D. Ryutov (LLNL). The suggested research ideas are supported by preliminary experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2016

32nd International Conference on the Physics of Semiconductors

The International Conference on the Physics of Semiconductors (ICPS) continues a series of biennial conferences that began in the 1950's. ICPS is the premier meeting for reporting all aspects of semiconductor physics including electronic, structural, optical, magnetic and transport properties with an emphasis on new materials and their applications. The meeting will reflect the state of art in the semiconductor physics field and will serve as a forum where scholars, researchers, and specialists can interact to discuss future research directions and technological advancements. The conference typically draws 1,000 international physicists, scientists, and students. This is one of the largest science meetings on semiconductors and related materials to be held in the United States.

36 MATERIALS SCIENCE↗