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All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Fuel quality processing study, volume 1

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

Ohara, J. B.↗
DOE OSTI2024

Solid State Solar Thermochemical Fuel (SoFuel) for Long Duration Storage

Efficient thermal storage systems, when coupled with renewable energy, enable the decarbonization of numerous industrial processes requiring high temperature steam or air, and provide a path for seasonal building heating, especially for colder climates. Existing thermal storage systems face a significant challenge due to losses inherent to all high temperature systems. A viable route to long-term storage is to use thermochemical reactions to convert concentrated solar energy to a fuel that is shelf-stable and can be stored at room temperature, thus eliminating losses associated with high temperature storage. The Solid-State Solar Thermochemical Fuel (SoFuel) technology developed by Michigan State University, Oregon State University, and Mississippi State University provides reactors and processes with minimal sensible heat losses and allows storing solar energy as a solid-state fuel at room temperature for long duration. The production of SoFuel occurs within a cylindrical cavity reduction chemical reactor that captures concentrated solar radiation from a solar field. Reactive magnesium manganese oxide (Mg-Mn-O) resides within the cylindrical cavity chemical reactor and undergoes thermal reduction as the temperature exceeds 1350°C. The thermally reduced Mg-Mn-O pellets (the SoFuel) are cooled down through a recuperative process and stored within a bin until used. The SoFuel can directly supply up to 1100°C heat to an adjacent power plant for electricity generation or industrial heating. Oxidation of SoFuel pellets occurs in a counter flow reactor and supplies heat to the user for electricity generation or industrial processing, after which the fuel is returned to the concentrating solar field where it is regenerated for re-use. Both reactors can be controlled well using a variety of strategies. With the low cost of the material, its cyclability, and the possibility of using the pelletized with on-sun reactors, or with electricity that would be curtailed, this project offers a viable option of medium- and long-term thermal energy storage.

14 SOLAR ENERGY↗
DOE OSTI2025

Solid State Solar Thermochemical Fuel (SoFuel) for Long Duration Storage

Efficient thermal storage systems, when coupled with renewable energy, enable the decarbonization of numerous industrial processes requiring high temperature steam or air, and provide a path for seasonal building heating, especially for colder climates. Existing thermal storage systems face a significant challenge due to losses inherent to all high temperature systems. A viable route to long-term storage is to use thermochemical reactions to convert concentrated solar energy to a fuel that is shelf-stable and can be stored at room temperature, thus eliminating losses associated with high temperature storage. The Solid-State Solar Thermochemical Fuel (SoFuel) technology developed by Michigan State University, Oregon State University, and Mississippi State University provides reactors and processes with minimal sensible heat losses and allows storing solar energy as a solid-state fuel at room temperature for long duration. The production of SoFuel occurs within a cylindrical cavity reduction chemical reactor that captures concentrated solar radiation from a solar field. Reactive magnesium manganese oxide (Mg-Mn-O) resides within the cylindrical cavity chemical reactor and undergoes thermal reduction as the temperature exceeds 1350°C. The thermally reduced Mg-Mn-O pellets (the SoFuel) are cooled down through a recuperative process and stored within a bin until used. The SoFuel can directly supply up to 1100C heat to an adjacent power plant for electricity generation or industrial heating. Oxidation of SoFuel pellets occurs in a counter flow reactor and supplies heat to the user for electricity generation or industrial processing, after which the fuel is returned to the concentrating solar field where it is regenerated for re-use. Both reactors can be controlled well using a variety of strategies. With the low cost of the material, its cyclability, and the possibility of using the pelletized with on-sun reactors, or with electricity that would be curtailed, this project offers a viable option of medium- and long-term thermal energy storage.

25 ENERGY STORAGE↗
DOE OSTI2025

Cybersecurity Considerations for Hydrogen Infrastructure in Airport Environments

This report explores key cybersecurity concerns and best practices within environments that serve as reference points for the development of hydrogen fueling infrastructure for aviation. This cybersecurity analysis leverages prior NREL studies: 1) hydrogen fueling station component validation to identify vulnerabilities and failure events documented in physical equipment, and 2) electric aircraft charging infrastructure analysis to explore primary cybersecurity vulnerabilities. It reviews the criticality of digitized technologies in sustaining hydrogen fuel production, storage, and fueling systems, noting cybersecurity concerns that are universal to power systems and industrial control systems in general. In considering cybersecurity vulnerabilities within a future landscape of hydrogen energy for aviation applications, a reference architecture was intended to reveal the points of connection between assets and the potential sensors that are vulnerable to manipulation in the event of compromised access or communication within a SCADA system. A generalized reference architecture can help stakeholders, engineers, or strategists understand connections, criticalities, and standard practices when it comes to designing and planning for new systems. There are several gaps to account for in assessing the future of hydrogen production, storage, and fueling for aviation. Engaging stakeholders, including aircraft manufacturers, electric utilities, site property owners, and local communities, will inform decision-making around site structure, operations, and resources for future hydrogen fueling infrastructure to understand operational needs and cybersecurity awareness. Cybersecurity mitigation strategy must consider physical attack vectors that emerge with the integration of hydrogen systems into existing airport security requirements. The cybersecurity risk assessment contained in this report is an entry point into potential future granular-level analyses to be conducted as part of hazard and risk assessments for safe aviation hydrogen infrastructure, determining how the scale of hydrogen fuel infrastructure for aviation impacts the volume of cyber attack vectors, and what, if any, are the vulnerabilities associated with different types of on-board hydrogen systems. In this nascent development phase, assessing how best to integrate cybersecurity practices into an evolving U.S. aviation landscape provides critical insights into building increased awareness and stakeholder engagement to support a cyber-resilient infrastructure.

08 HYDROGEN↗
DOE OSTI2018

Inventory and Waste Characterization Status Report and OWL Update.

This report represents completion of milestone deliverable M2SF-18SNO10309013 "Inventory and Waste Characterization Status Report and OWL Update that reports on FY2018 activities for the work package (WP) SF-18SNO1030901. This report provides the detailed final information for completed FY2018 work activities for WP SF-18SN01030901, and a summary of priorities for FY2019. This status report on FY2018 activities includes evaluations of waste form characteristics and waste form performance models, updates to the OWL development, and descriptions of the two planned management processes for the OWL. Updates to the OWL include an updated user's guide, additions to the OWL database content for wastes and waste forms, results of the Beta testing and changes implemented from it. There are two processes being planned in FY2018, which will be implemented in FY2019. One process covers methods for interfacing with the DOE SNF DB (DOE 2007) at INL on the numerous entries for DOE managed SNF, and the other process covers the management of updates to, and version control/archiving of, the OWL database. In FY2018, we have pursued three studies to evaluate/redefine waste form characteristics and/or performance models. First characteristic isotopic ratios for various waste forms included in postclosure performance studies are being evaluated to delineate isotope ratio tags that quantitatively identify each particular waste form. This evaluation arose due to questions regarding the relative contributions of radionuclides from disparate waste forms in GDSA results, particularly, radionuclide contributions of DOE-managed SNF vs HLW glass. In our second study we are evaluating the bases of glass waste degradation rate models to the HIP calcine waste form. The HIP calcine may likely be a ceramic matrix material, with multiple ceramic phases with/without a glass phase. The ceramic phases are likely to have different degradation performance from the glass portion. The distribution of radionuclides among those various phases may also be a factor in the radionuclide release rates. Additionally, we have an ongoing investigation of the performance behavior of TRISO particle fuels and are developing a stochastic model for the degradation of those fuels that accounts for simultaneous corrosion of the silicon carbide (SiC) layer and radionuclide diffusion through it. The detailed model of the TRISO particles themselves, will be merged with models of the degradation behavior(s) of the graphite matrix (either prismatic compacts or spherical "pebbles") containing the particles and the hexagonal graphite elements holding the compacts.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Effect of Socio-Political Factors in Nuclear Power Development in Multi-National Framework

Nuclear fuel cycle is a complex process with numerous steps influenced by both engineering and socio-economic factors. A number of studies have been done in this area providing a comprehensive view of nuclear fuel cycle in term of the energy scenarios, material flows, or pricing mechanism. However, the effect of other socio-economic aspects like public acceptance, proliferation risks, or the trans-boundary nature of the nuclear fuel cycle have not been investigated thoroughly. This research is an attempt to develop such a hybrid model of multinational nuclear fuel cycle using system dynamics and the quantifiable effects of political and social impacts on the development of nuclear fuel cycle through multi-attribute analysis of historical data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2017

Advanced Ultrafast Spectroscopy for Chemical Detection of Nuclear Fuel Cycle Materials

The development of new signatures and observables from processes related to proliferation activities are often related to the development of technologies. In our physical world, the intensity of observables is linearly related to the input drivers (light, current, voltage, etc.). Ultrafast lasers with high peak energies, opens the door to a new regime where the intensity of the observables is not necessarily linear with the laser energy. Potential nonlinear spectroscopic applications include chemical detection via remote sensing through filament generation, material characterization and processing, chemical reaction specificity, surface phenomena modifications, X-ray production, nuclear fusion, etc. The National Security Directorate laser laboratory is currently working to develop new tools for nonproliferation research with femtosecond and picosecond lasers. Prior to this project, we could only achieve laser energies in the 5 nano-Joule range, preventing the study of nonlinear phenomena. To advance our nonproliferation research into the nonlinear regime we require laser pulses in the milli-Joule (mJ) energy range. We have procured and installed a 35 fs-7 mJ laser, operating at one-kilohertz repetition rate, to investigate elemental and molecular detection of materials in the laboratory with potential applications in remote sensing. Advanced, nonlinear Raman techniques will be used to study materials of interest that are in a matrix of many materials and currently with these nonlinear techniques we can achieve greater than three orders of magnitude signal enhancement. This work studying nuclear fuel cycle materials with nonlinear spectroscopies will advance SRNL research capabilities and grow a core capability within the DOE complex.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2021

Computational Risk Analysis of Propane Releases in Maintenance Facilities

Liquefied petroleum gas (LPG) is a viable, cleaner alternative to traditional diesel fuel used in busses and other heavy-duty vehicles and could play a role in helping the US meet its lower emission goals. While the LPG industry has focused efforts on developing vehicles and fueling infrastructure, we must also establish safe parameters for maintenance facilities which are servicing LPG fueled vehicles. Current safety standards aid in the design of maintenance facilities, but additional quantitative analysis is needed to prove safeguards are adequate and suggest improvements where needed. In this report we aim to quantify the amount of flammable mass associated with propane releases from vehicle mounted fuel vessels within enclosed garages. Furthermore, we seek to qualify harm mitigation with variable ventilations and facility layout. To accomplish this we leverage validated computational resources at Sandia National Laboratories to simulate various release scenarios representative of real world vehicles and maintenance facilities. Flow solvers are used to predict the dynamics of fuel systems as well as the evolution of propane during release events. From our simulated results we observe that both inflow and outflow ventilation locations play a critical role in reducing flammable cloud size and potential overpressure values during a possible combustion event.

03 NATURAL GAS↗
DOE OSTI2018

Engineering Anaerobic Gut Fungi for Lignocellulose Breakdown

Biofuels derived from plant biomass (lignocellulose) are attractive alternatives to petroleum-based products, as they avoid many of the economic and environmental problems that plague traditional energy sources. Breakdown of plant waste into simple sugars would translate into the production of renewable fuels via microbial fermentation. However, existing technologies are insufficient to allow for industrial-scale production of these products due to difficulties associated with the recalcitrance of crude lignin-rich biomass, and the high cost/poor performance of known cellulolytic enzymes (cellulases). Therefore, there is a critical need to develop new technologies to break down lignocellulosic biomass into fermentable sugars for downstream fuel development. Towards this goal, much can be learned by studying how anaerobic microbes depolymerize lignocellulose in biomass-rich environments, such as the digestive tract of large herbivores. Anaerobic gut fungi are native to the gut and rumen of these animals, where they have evolved unique abilities to break down lignocellulosic biomass through invasive growth and the secretion of powerful enzymes. The goal of this project was to engineer anaerobic gut fungi as novel platform organisms for biofuel production from plant material. To accomplish this goal, a panel of anaerobic fungi was isolated form different herbivores and screened for their ability to degrade lignocellulose. Four novel strains were isolated and genetically sequenced, including Piromyces finnis, Neocallimastix californiae, Anaeromyces robustus, and Caecomyces churrovis. Transcriptomic and genomic characterization of these anaerobic fungi revealed that they harbor the largest collection of biomass-degrading enzymes of any sequenced fungus, and delineated the basic metabolic networks that govern lignocellulose hydrolysis within anaerobic fungi, RNA sequencing enabled the dynamics and mechanism associated with carbon catabolite repression to be delineated, which revealed how important enzyme groups are coordinated during breakdown. Through cluster analysis, a set of putative novel enzymes associated with lignocellulose breakdown was discovered, which also revealed a set of proteins critical to the formation of fungal cellulosomes (multi-enzyme complexes). Using this information, genetic transformation strategies to manipulate gut fungi were developed, which would endow them with enhanced functionality against a range of industrially relevant substrates. Collectively, this information will establish the molecular framework for anaerobic fungal hydrolysis, and will guide in the development of lignocellulosic biofuels.

09 BIOMASS FUELS↗
DOE OSTI2018

VTO Annual Progress Report. I. Modeling and Simulation

ParaChoice supports the VTO mission using early-stage research to help in the development of technology that will improve affordability of transportation, while encouraging innovation and reducing dependence on petroleum. Analysis with the ParaChoice model enables exploration of key factors that influence consumer choice, and technology, fuel, and infrastructure development for the vehicle mix. Because of the distinct differences between requirements, needs, and use patterns for light duty vehicles (LDVs) relative to heavy duty vehicles (HDVs), this project models the dynamics of each of these segments to characterize the factors that influence technology adoption.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1980

Performance deterioration of commercial high-bypass ratio turbofan engines

NASA programs for improving aircraft engine fuel efficiency include the Engine Component Improvement Project of which the Engine Diagnostics section is to identify performance deterioration factors for the JT9D and CF6 high-bypass ratio turbofan engines and to develop technology for fuel consumption reduction. The program tests and inspects engines, examines deteriorated elements, formulates deterioration trends and models, identifies specific causative events or modules and determines mechanisms. Results show that short-term performance deterioration is less than 1% of cruise specific fuel consumption and is caused by flight loads or thermal damage due to rubbing of turbine blade tips against shrouds. Long-term deterioration is 2.5-3% of cruise specific fuel consumption after 2500-3000 flights and mechanisms are thermal damage to blade tips with rubbing and damaged airfoils and parts.

Mehalic, C. M.↗
DOE OSTI2024

Development of New Reactor Core Configuration for Power Uprate - Fuel Reload & Heat Processing Analyses, Core Design, System Safety Assessments, and Fuel Performance Analyses

With the passage of the Infrastructure Investment and Jobs Act in 2021 and the Inflation Reduction Act (IRA) in 2022, the United States stands at a critical juncture for the future of nuclear power. These landmark policies provide significant support for clean energy initiatives, positioning nuclear power as a key component of the nation’s strategy to reduce carbon emissions and achieve energy security. This growing emphasis on nuclear energy is driven by the need for reliable, low-carbon power sources as the country transitions away from fossil fuels. Federal policy, along with increasing state-level support, is encouraging investment in nuclear technology advancements to meet these demands. Building new nuclear power plants (NPPs), however, presents significant challenges due to high costs and long construction timelines. As a result, increasing the power output of existing NPPs through power uprates has emerged as a more feasible and cost-effective strategy. One key area of advancement is the development of accident-tolerant fuel (ATF), such as chromium-coated zirconium alloy cladding, which offers enhanced material performance, enabling power uprates in light water reactors (LWRs). Given the growing demand for nuclear energy fueled by federal policies and state initiatives, it is essential to evaluate the feasibility and benefits of significant power uprates in existing pressurized water reactors (PWRs) using advanced fuel technologies. The introduction of ATF concepts opens new opportunities for safely and economically achieving these power increases. Assessing whether these innovations can support substantial power uprates while maintaining operational safety is crucial to maximizing the potential of the nation’s existing nuclear infrastructure. This project aims to explore how power uprates can be achieved by boosting reactor thermal power output and optimizing reactor core design, while ensuring the safety and economic viability of NPPs. Specifically, it will focus on demonstrating the technical and economic feasibility of power uprates in a PWR using low 5-10% enrichment uranium (LEU+) high burnup (HBU) fuel combined with ATF concepts. In fiscal year 2024 (FY24), the research and development focus on building foundational models and conducting multi-physics performance and safety analyses to support the power uprate. The findings of the study would be shared through LWRS Seasonal Meetings, conferences and workshops with utility companies and researchers. These also serve as a basis for further study of fuel reloading optimization with ATF claddings.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1973

Design of a miniature hydrogen fueled gas turbine engine

The design, development, and delivery of a miniature hydrogen-fueled gas turbine engine are discussed. The engine was to be sized to approximate a scaled-down lift engine such as the teledyne CAE model 376. As a result, the engine design emerged as a 445N(100 lb.)-thrust engine flowing 0.86 kg (1.9 lbs.) air/sec. A 4-stage compressor was designed at a 4.0 to 1 pressure ratio for the above conditions. The compressor tip diameter was 9.14 cm (3.60 in.). To improve overall engine performance, another compressor with a 4.75 to 1 pressure ratio at the same tip diameter was designed. A matching turbine for each compressor was also designed. The turbine tip diameter was 10.16 cm (4.0 in.). A combustion chamber was designed, built, and tested for this engine. A preliminary design of the mechanical rotating parts also was completed and is discussed. Three exhaust nozzle designs are presented.

Burnett, M.↗
DOE OSTI2023

Extraction of Neptunium, Plutonium, Americium, Zirconium, and Technetium by Di-(2-Ethylhexyl)- Iso -Butyramide (DEH i BA) at High Metal Loadings

Increased focus on carbon neutral energy has generated a resurgence of interest in nuclear power, and in particular advanced reactors which are likely to utilize high assay low enriched uranium (HALEU). This in turn could increase the economic attractiveness of recovering still partially enriched uranium from used nuclear fuel. Concomitant to development of advanced reactors, advanced reprocessing schemes should be developed which address the disadvantages to well established reprocessing schemes. The present study focuses on using di-(2-ethylhexyl)-iso-butyramide (DEHiBA) under high metal loading conditions for the reprocessing of used nuclear fuel. The elements examined in the study include the dominant transuranic actinides (Np, Pu, Am) as well as the often-problematic Tc and Zr. Further, by increasing the concentration of the extractant from the more commonly reported 1.0 M – 1.5 M, the extraction of hexavalent actinides is substantially increased, while maintaining effective rejection of tri, tetra, and pentavalent actinides, particularly in the presence of high loadings of uranium. In conclusion, the extraction of Zr by 1.5 M DEHiBA is noted to be negligible by comparison to tributyl phosphate (TBP), however the coextraction of Tc with U is observed to be nominally twice the quantity that is extracted by TBP indicating a need for effective Tc management.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Demonstrate Viability of Accelerated Fuel Qualification Approaches

This presentation summarizes the research under LDRD grogram, Demonstrate Viability of Accelerated Fuel Qualification Approaches. It is demonstrated that the fabrication process of uranium carbide fuel has been developed and neutronic, thermal and hydraulic analysis have been conducted for the Fission Accelerated Steady-state Testing (FAST). This program provides basis of expansion of FAST as an efficient platform to broad nuclear fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2015

The NASA Advanced Space Power Systems Project

The goal of the NASA Advanced Space Power Systems Project is to develop advanced, game changing technologies that will provide future NASA space exploration missions with safe, reliable, light weight and compact power generation and energy storage systems. The development effort is focused on maturing the technologies from a technology readiness level of approximately 23 to approximately 56 as defined in the NASA Procedural Requirement 7123.1B. Currently, the project is working on two critical technology areas: High specific energy batteries, and regenerative fuel cell systems with passive fluid management. Examples of target applications for these technologies are: extending the duration of extravehicular activities (EVA) with high specific energy and energy density batteries; providing reliable, long-life power for rovers with passive fuel cell and regenerative fuel cell systems that enable reduced system complexity. Recent results from the high energy battery and regenerative fuel cell technology development efforts will be presented. The technical approach, the key performance parameters and the technical results achieved to date in each of these new elements will be included. The Advanced Space Power Systems Project is part of the Game Changing Development Program under NASAs Space Technology Mission Directorate.

batteries↗
DOE OSTI2017

Final Report - Stationary and Emerging Market Fuel Cell System Cost Assessment

The U.S. Department of Energy (DOE) is focused on providing a portfolio of technology solutions to meet energy security challenges of the future. Fuel cells are a part of this portfolio of technology offerings. To help meet these challenges and supplement the understanding of the current research, Battelle has executed a five-year program that evaluated the total system costs and total ownership costs of two technologies: (1) an ~80 °C polymer electrolyte membrane fuel cell (PEMFC) technology and (2) a solid oxide fuel cell (SOFC) technology, operating with hydrogen or reformate for different applications. Previous research conducted by Battelle, and more recently by other research institutes, suggests that fuel cells can offer customers significant fuel and emission savings along with other benefits compared to incumbent alternatives. For this project, Battelle has applied a proven cost assessment approach to assist the DOE Fuel Cell Technologies Program in making decisions regarding research and development, scale-up, and deployment of fuel cell technology. The cost studies and subsequent reports provide accurate projections of current system costs and the cost impact of state-of-the-art technologies in manufacturing, increases in production volume, and changes to system design on system cost and life cycle cost for several near-term and emerging fuel cell markets. The studies also provide information on types of manufacturing processes that must be developed to commercialize fuel cells and also provide insights into the optimization needed for use of off-the-shelf components in fuel cell systems. Battelle’s analysis is intended to help DOE prioritize investments in research and development of components to reduce the costs of fuel cell systems while considering systems optimization.

08 HYDROGEN↗
DOE OSTI2021

Comparison of mechanical properties measured on multiple scales

FeCrAl alloys are being developed for accident tolerant fuels for current light water reactors. Specifically as fuel claddings with enhanced safety. These alloys are being developed to have excellent corrosion resistance in light water reactor coolant environments and structural integrity for longer durations in the case of a loss of coolant scenario where time is critical for safety. Tensile, shear punch, and Vickers hardness testing was performed on neutron irradiated FeCrAl alloys with three variations in composition. Testing was done at room temperature for comparison of the three techniques. FeCrAl alloys in this report were irradiated at Oak Ridge National Laboratory (ORNL) in the High Flux Isotope Reactor (HFIR) to 7 dpa and at 320 °C.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗