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At least 1,153 records · Page 64

All sources NASA NTRS DOE OSTI

DOE OSTI2021

Techno‐economic feasibility analysis of engineered energycane‐based biorefinery co‐producing biodiesel and ethanol

Abstract High feedstock cost and low oil yields per unit of land from temperate oilseed crops limit the growth of commercial‐scale biodiesel production. Recently, highly productive crops, such as sugarcane and energycane, have been engineered to accumulate triacylglycerides (TAGs) that allow the production of far more industrial vegetable oil than previously possible. A proof‐of‐concept suggests that biodiesel production from engineered energycane will be possible. However, before making efforts for scale‐up, it is critical to understand the commercial feasibility and economic competitiveness of this process. This study performs techno‐economic analysis of a unique biorefinery processing energycane to co‐produce biodiesel and ethanol. Comprehensive process simulation models were developed for two scenarios: (i) biodiesel from TAGs and ethanol from fermentation of sugars in juice and (ii) biodiesel from TAGs and ethanol from fermentation of sugars in juice and hydrolysis of carbohydrates in bagasse. Based on the target levels, the analysis was performed for energycane containing 0%, 5%, and 7.7% TAGs (d.b.). The biodiesel from engineered energycane was found economically viable and competitive to soybean biodiesel. Although the capital investment is higher compared to the soybean biodiesel plant, the biodiesel production costs ($0.66–$0.9/L) were lower than soybean biodiesel ($0.91/L). Biorefinery‐scenario‐1 processing energycane containing 7.7% TAG produces biodiesel with profitability (IRR 7.84) slightly lower than soybean biodiesel (IRR 8.3), but yields five times of biodiesel per unit land and is self‐sustainable for energy requirements. The surplus electricity can displace fossil electricity and provide environmental benefits. Monte Carlo simulation indicated that biorefinery is profitable with a 29%–65% probability (NPV > 0) which is largely controlled by feedstock composition and biodiesel market price. It is important to note that energycane can be grown on the marginal rainfed lands in S.E. USA, where soybean would not be viable. Biodiesel from engineered energycane would therefore be complementary to soydiesel in the United States.

09 BIOMASS FUELS↗

DOE OSTI2018

Heat transfer from glass melt to cold cap: Melting rate correlation equation

Increasing the efficiency of all-electric melters is a hot topic not only in the waste glass melting industry, where the melting rate directly influences the life cycle of the cleanup process, but also in the commercial glass industry, where increasingly stringent environmental regulations and rapid development of renewable energy sources ask for transformation of traditional fossil fuel technology. Batch-to-glass conversion in an all-electric melter proceeds in the cold cap—a layer of reacting and melting material floating on molten glass. The heat transfer into the cold cap is controlled by convection and conduction in the thermal boundary layer on the melt side, and by the properties of the foam layer at the cold cap/melt boundary. An overview of factors affecting heat transfer is presented and assessed using data from laboratory and pilot-scale experiments. The heat flux can be improved by (i) decreasing glass melt viscosity, (ii) decreasing the temperature at which the foam starts to collapse at the cold cap bottom, and (iii) increasing melt convection by bubbling gas into the glass melt under the cold cap. Detailed understanding of the conversion process can guide the formulation of feeds that melt easily and quickly.

Hrma, Pavel↗

DOE OSTI2023

Hydroformylation of pyrolysis oils to aldehydes and alcohols from polyolefin waste

Waste plastics are an abundant feedstock for the production of renewable chemicals. Pyrolysis of waste plastics produces pyrolysis oils with high concentrations of olefins (>50 weight %). The traditional petrochemical industry uses several energy-intensive steps to produce olefins from fossil feedstocks such as naphtha, natural gas, and crude oil. In this work, we demonstrate that pyrolysis oil can be used to produce aldehydes through hydroformylation, taking advantage of the olefin functionality. These aldehydes can then be reduced to mono- and dialcohols, oxidized to mono- and dicarboxylic acids, or aminated to mono- and diamines by using homogeneous and heterogeneous catalysis. This route produces high-value oxygenated chemicals from low-value postconsumer recycled polyethylene. Here, we project that the chemicals produced by this route could lower greenhouse gas emissions ~60% compared with their production through petroleum feedstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2012

Development of Green Fuels From Algae - The University of Tulsa

The general public has become increasingly aware of the pitfalls encountered with the continued reliance on fossil fuels in the industrialized world. In response, the scientific community is in the process of developing non-fossil fuel technologies that can supply adequate energy while also being environmentally friendly. In this project, we concentrate on green fuels which we define as those capable of being produced from renewable and sustainable resources in a way that is compatible with the current transportation fuel infrastructure. One route to green fuels that has received relatively little attention begins with algae as a feedstock. Algae are a diverse group of aquatic, photosynthetic organisms, generally categorized as either macroalgae (i.e. seaweed) or microalgae. Microalgae constitute a spectacularly diverse group of prokaryotic and eukaryotic unicellular organisms and account for approximately 50% of global organic carbon fixation. The PI's have subdivided the proposed research program into three main research areas, all of which are essential to the development of commercially viable algae fuels compatible with current energy infrastructure. In the fuel development focus, catalytic cracking reactions of algae oils is optimized. In the species development project, genetic engineering is used to create microalgae strains that are capable of high-level hydrocarbon production. For the modeling effort, the construction of multi-scaled models of algae production was prioritized, including integrating small-scale hydrodynamic models of algae production and reactor design and large-scale design optimization models.

09 BIOMASS FUELS↗

DOE OSTI2012

Compact X-ray Light Source Workshop Report

This report is the result of a workshop held in September 2011 that examined the utility of a compact x-ray light source (CXLS) in addressing many scientific challenges critical to advancing energy science and technology. The U.S. Department of Energy (DOE) and National Academy of Sciences (NAS) have repeatedly described the need for advanced instruments that “predict, control, and design the components of energetic processes and environmental balance,” most notably in biological, chemical, environmental, and materials science. In numerous DOE and NAS reports, direct molecular-scale imaging and timedependent studies are seen as a powerful means to develop an atomistic-level understanding of scientific issues associated with current and future energy and environmental needs, including energy production and storage from both fossil-based and fossil-free sources and cleanup of government and industrial sites worldwide.

chemical imaging↗

DOE OSTI2013

Technical Support to SBIR Phase II Project: Improved Conversion of Cellulose Waste to Ethanol Using a Dual Bioreactor System: Cooperative Research and Development (Final Report)

Over-dependence on fossil fuel has spurred research on alternative energy. Inedible plant materials such as grass and corn stover represent abundant renewable natural resources that can be transformed into biofuel. Problems in enzymatic conversion of biomass to sugars include the use of incomplete synergistic enzymes, end-product inhibition, and adsorption and loss of enzymes necessitating their use in large quantities. Technova Corporation will develop a defined consortium of natural microorganisms that will efficiently break down biomass to energy-rich soluble sugars, and convert them to cleaner-burning ethanol fuel. The project will also develop a novel biocatalytic hybrid reactor system dedicated to this bioprocess, which embodies recent advances in nanotechnology. NREL will participate to develop a continuous fermentation process.

09 BIOMASS FUELS↗

DOE OSTI2019

Extreme Weather and Climate Vulnerabilities of the Electric Grid: A Summary of Environmental Sensitivity Quantification Methods

Climate hazards and extreme weather affect all components of the electric grid system, from generation to end use. Increasing temperatures, decreasing water availability, more intense storm events, and sea level rise affect the ability of the electric grid to produce and transmit electricity from fossil, nuclear, and existing and emerging renewable energy sources. Most electricity infrastructure is built for past or current climate conditions. Due to long lifetimes, electricity systems are likely to be exposed more frequently to more extreme climate conditions than those for which they were designed, and may not operate as intended under changing climate conditions. Utilities, regulators, state energy offices, and other electricity system planners are beginning to conduct environmental risk assessments, develop climate resilience plans, and incorporate changing climate conditions into long-term planning processes. Here, we highlight the analytical resources available for sensitivity assessment of electrical grid components under extreme weather and climate, and identify gaps in the literature on quantitative methods available for assessment of component vulnerability.

Dumas, Melissa↗

DOE OSTI2022

LDRD External Report Summary

In order to lessen societies dependance on fossil fuels to fight climate change, new energy storage and electrification technology is needed. This work highlights the development of non-conventional electrolytes for lithium-ion and redox flow batteries for electric vehicle and grid storage applications.

25 ENERGY STORAGE↗

DOE OSTI2025

Hourly Load Profile Dataset for Electric Port Cargo Handling Equipment in the United States

Historically, ports have relied on fossil fuels, particularly diesel, as their primary energy source. Transitioning to electric cargo handling equipment (eCHE) offers a promising solution, as this relatively mature technology eliminates tailpipe emissions, reduces harmful airborne particulates, lowers noise pollution, and supports decarbonization. This study develops an initial estimation of hourly electricity demand for eCHE at the top 25 container ports (by tonnage) in the United States. These datasets, accessible at data.nrel.gov/submissions/281, provide valuable insights into the electricity demand patterns and potential grid impacts associated with widespread eCHE adoption, forming a foundation for future refinement based on stakeholder feedback.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2013

Biomass for thermochemical conversion: targets and challenges

Bioenergy will be one component of a suite of alternatives to fossil fuels. Effective conversion of biomass to energy will require the careful pairing of advanced conversion technologies with biomass feedstocks optimized for the purpose. Lignocellulosic biomass can be converted to useful energy products via two distinct pathways: enzymatic or thermochemical conversion. The thermochemical pathways are reviewed and potential biotechnology or breeding targets to improve feedstocks for pyrolysis, gasification, and combustion are identified. Biomass traits influencing the effectiveness of the thermochemical process (cell wall composition, mineral and moisture content) differ from those important for enzymatic conversion and so properties are discussed in the language of biologists (biochemical analysis) as well as that of engineers (proximate and ultimate analysis). We discuss the genetic control, potential environmental influence, and consequences of modification of these traits. Improving feedstocks for thermochemical conversion can be accomplished by the optimization of lignin levels, and the reduction of ash and moisture content. We suggest that ultimate analysis and associated properties such as H:C, O:C, and heating value might be more amenable than traditional biochemical analysis to the high-throughput necessary for the phenotyping of large plant populations. Expanding our knowledge of these biomass traits will play a critical role in the utilization of biomass for energy production globally, and add to our understanding of how plants tailor their composition with their environment.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1978

Thermal storage for industrial process and reject heat

Industrial production uses about 40 percent of the total energy consumed in the United States. The major share of this is derived from fossil fuel. Potential savings of scarce fuel is possible through the use of thermal energy storage (TES) of reject or process heat for subsequent use. Three especially significant industries where high temperature TES appears attractive - paper and pulp, iron and steel, and cement are discussed. Potential annual fuel savings, with large scale implementation of near-term TES systems for these three industries, is nearly 9,000,000 bbl of oil.

Duscha, R. A.↗

NASA NTRS1978

Thermal storage for industrial process and reject heat

Industrial production uses about 40% of the total energy consumed in the United States. The major share of this is derived from fossil fuel. Potential savings of scarce fuel is possible through the use of thermal energy storage (TES) of reject or process heat for subsequent use. Results of study contracts awarded by the Department of Energy (DOE) and managed by the NASA Lewis Research Center have identified three especially significant industries where high temperature TES appears attractive - paper and pulp, iron and steel, and cement. Potential annual fuel savings with large scale implementation of near-term TES systems for these three industries is nearly 9 million bbl of oil.

Duscha, R. A.↗

DOE OSTI2018

Functional Plasma-Sprayed Ceramic Coatings for Use in Fusion Energy Systems

There is growing demand for new, cleaner ways to supply the rapidly growing global energy demand, as concerns grow over climate change and declining supplies of fossil fuels. Nuclear fusion, the phenomenon in which atomic nuclei collide together and release massive quantities of energy, is one of the most promising options for generating large amounts of carbon-free energy in the future.1 To initiate a common nuclear fusion reaction of hydrogen isotopes – deuterium and tritium, a hot plasma state is needed at incredibly high temperatures approaching 100 million degrees centigrade. One practical way to achieve these conditions is to use magnetic confinement of the plasma in a toroidal nuclear reactor known as a tokamak (Figure 1). A commercial fusion power station will then harvest the energy by converting the heat provided by the fusion chain reaction into steam to power gas turbines, and generate electricity on to the grid, while the excess neutrons also produced in the process is captured by a blanket made of dense material surrounding the tokomak.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2024

Communities LEAP (Local Energy Action Program) Cohort 2

The U.S. Department of Energy's (DOE) Communities LEAP (Local Energy Action Program) partners with low income, energy-burdened communities that are disadvantaged and/or experience direct economic impacts from reducing their historical reliance on fossil fuels to build community-driven action plans for clean energy-related economic development.

C-LEAP↗

DOE OSTI2022

Dynamic optimization with flexible heat integration of a solar parabolic trough collector plant with thermal energy storage used for industrial process heat

There is an increasing need to reduce fossil fuel consumption used for industrial process heat to slow the effects of climate change. Using solar thermal heat is a viable way to replace fossil fuel use, but solar industrial process heat plants have limited implementation due to large upfront costs and inefficiencies from the inherent variability from solar energy. Having more flexible and optimized control over these plants can enable them to be more efficient. Here in this work, a solar industrial process heat plant with thermal energy storage that can flexibly collect and deliver heat to two industrial processes (flexible heat integration) is dynamically modeled with control setpoints found by a dynamic optimization method. The optimized case can increase the solar efficiency of the plant by 7.5% on average relative to a base case. The results show that it is best to collect heat at lower temperatures for all but ideal solar conditions, only medium to high quality heat should be stored in large quantities, and exchanging heat with a lower temperature heat sink is generally more efficient. The optimized case is able to reduce the levelized cost of heat of the plant to $31.83/MWh th compared to a base case value of $34.10/MWh th . The optimized case can reduce emissions by 22.2% compared to a plant which uses only natural gas. This work shows that dynamic optimization with flexible heat integration can be a cost-effective way to increase efficiency so that more of these types of plants can be implemented.

14 SOLAR ENERGY↗

DOE OSTI2015

Ethyl 3-ethoxybutyrate, a new component of the transportation renewable fuel portfolio

The vast majority of energy that powers our global economy is from combustion of fossil fuels with the unintended consequence of increased deposition of carbon dioxide in the atmosphere and oceans. The scientific and technical challenges for the energy sector are to develop renewable energy sources that are sufficient to meet human energy consumption, are economically viable, and are ecologically sustainable. We investigated ethyl 3-ethoxybutyrate (EEB) as a fuel oxygenate in ultra low sulfur diesel (ULSD) with a bench-scale research engine and determined its economic potential as a renewable fuel with technoeconomic modeling using wastewater treatment plant biosolids as the feedstock for poly-3-hydroxyalkanoates (PHB), a bacterial storage polymer from which EEB can be synthesized. EEB blended well with ULSD, and cetane values of 10% and 20% v/v EEB-ULSD blends exceeded 40. A diesel internal combustion engine fueled with 5%, 10%, and 20% EEB-ULSD blends met or exceeded all tested transportation diesel fuel emissions criteria. Inedible organic feedstocks may be used to produce PHB; and thus, EEB might contribute to carbon reductions without compromising performance or air pollutant emissions. However, further research is needed to determine its role in the overall fuel portfolio. (C) 2015 Elsevier Ltd. All rights reserved.

09 BIOMASS FUELS↗

DOE OSTI2013

Annual Report: Innovative Process Technologies (30 September 2013)

Innovative Process Technologies is concerned with the development of innovative cost-effective technologies that promote efficiency, environmental performance, availability of advanced energy systems, and the development of computational tools that shorten development timelines of advanced energy systems. The project is focused on five distinct research tasks: (1) Sensors and Controls, (2) Power Electronics and Energetic Materials, (3) Innovative Energy Concepts (IEC), (4) Computational Materials, and (5) Multiphase Flow.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2019

Vacuum Sanitation Energy Efficiency Retrofits Project

The Alaska Native Tribal Health Consortium (ANTHC) is a non-profit Tribal health organization designed to meet the unique health needs of Alaska Native and American Indian people living in Alaska. In partnership with communities and health organizations across the state, ANTHC provides health services to over 175,000 Alaska Native and American Indian people. Part of ANTHC’s mission includes ensuring that Native Alaskan communities have access to clean and safe water and sewer services. ANTHC works with communities to provide safe drinking water and healthy wastewater services that directly supports the health of Alaska Native people. To ensure water and sewer facilities operate sustainably, ANTHC Alaska Rural Utility Collaborative (ARUC) and Tribal Utility Support (TUS) programs provide operations and maintenance services on rural sanitation facilities. A key component of many water and sanitation systems in rural Alaskan villages is the vacuum sewer system, which is typically installed in places where the topography is primarily flat, and the elevation differential is not enough for a gravity powered sewer system to function without freezing during the winter. The vacuum sewer system is also the most costly and energy intensive form of sewer system, due to many factors including: large horsepower vacuum pumps needed for operation, potential for frequent vacuum leaks which increase the pump’s run-times, manpower needed to maintain pipe grade throughout the system, and the amount of heat needed to be added to the above ground pipes to keep them from freezing. The Vacuum Sanitation Energy Efficiency Retrofits Project implemented strategies to reduce the operating costs for vacuum sewer systems located in the remote Alaskan communities of Alakanuk, Kotlik, and Noorvik. A variety of deep energy efficiency retrofits were installed to reduce the amount of diesel fuel and electricity required to operate these systems which use large amounts of energy to pump, heat, and collect sewage from the community.

20 FOSSIL-FUELED POWER PLANTS↗