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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Integration Tests of the 4 kW-class High Voltage Hall Accelerator Power Processing Unit with the HiVHAc and the SPT-140 Hall Effect Thrusters

NASAs Science Mission Directorate is sponsoring the development of a 4 kW-class Hall propulsion system for implementation in NASA science and exploration missions. The main components of the system include the High Voltage Hall Accelerator (HiVHAc), an engineering model power processing unit (PPU) developed by Colorado Power Electronics, and a xenon flow control module (XFCM) developed by VACCO Industries. NASA Glenn Research Center is performing integrated tests of the Hall thruster propulsion system. This presentation presents results from integrated tests of the PPU and XFCM with the HiVHAc engineering development thruster and a SPT-140 thruster provided by Space System Loral. The results presented in this paper demonstrate thruster discharge initiation, open-loop and closed-loop control of the discharge current with anode flow for both the HiVHAc and the SPT-140 thrusters. Integrated tests with the SPT-140 thruster indicated that the PPU was able to repeatedly initiate the thrusters discharge, achieve steady state operation, and successfully throttle the thruster between 1.5 and 4.5 kW. The measured SPT-140 performance was identical to levels reported by Space Systems Loral.

Hall Thrusters↗
DOE OSTI2024

Analysis of strain in ion implanted 4H-SiC by fringes observed in synchrotron X-ray topography

A novel high energy implantation system has been successfully developed to fabricate 4H-SiC superjunction devices for medium and high voltage via implantation of dopant atoms with multi-energies ranging from 13 to 66 MeV. The significantly higher levels of energy used compared to conventional implantation processes, necessitates detailed characterization of the lattice damage caused by implantation. To achieve this by employing the novel high energy system, 4H-SiC wafer with 12 μm epilayers were blanket implanted by 13.8–65.7 MeV Al atoms. The lattice damages induced by the implantation were primarily characterized by Synchrotron X-ray Plane Wave Topography (SXPWT) and Reciprocal Space Mapping (RSM). Topographs reveal fringe contrast akin to multiple asymmetric diffraction peaks with an angular separation of only 2″ (arcseconds) observed on rocking curves, indicating inhomogeneous strain distribution across the implanted layer. The strain profile of the implanted layer was extracted from the fringe contrast by applying Rocking-curve Analysis by Dynamical Simulation (RADS). In conclusion, the maximum strain value is similar to that measured on the RSM.

A1. Characterization↗
NASA NTRSDate not supplied

Evaluation of Coatings for the Electrodynamic Dust Shield Application on Thermal Radiators

Dust acts as a blackbody, becoming hot if left in direct sunlight. This is a problem for thermal radiators where the main function is to radiate heat away from an object. If dust lands on the thermal radiator, the unit will less effectively reject heat, and it will overheat. This can lead to electrical or system failure. The current state-of-the-art in active dust mitigation is the Electrodynamic Dust Shield (EDS) which uses an electric field generated by alternating high positive and negative voltages (low current) to eject the charged dust off surfaces. An EDS made from copper coated Kapton is an ideal candidate to be bonded to a thermal radiator and coated with a low solar absorptance, high heat-emitter coating. This work compares the dust removal of copper-Kapton EDSs covered with different thermal radiator coatings in air and vacuum environments. The coatings include AZ-93 paint, Thermal Bright, and Solar White, a coating developed by the Applied Physics Lab (APL) at NASA Kennedy Space Center (KSC). The resistance and the thickness of the various coatings impact how well it works as an insulative layer for the EDS. Preliminary results indicate that Solar White may have better properties for dust removal and thermal rejection than the other coatings.

Krystal L Acosta↗
NASA NTRSDate not supplied

Evaluation of Coatings for the Electrodynamic Dust Shield Application on Thermal Radiators

Space dust acts as a blackbody, becoming hot if left in direct sunlight. This is a problem for thermal radiators used in space missions, where the main function is to radiate heat away from an object. If dust lands on the thermal radiator, the unit will less effectively reject heat, and it will overheat, leading to electrical or system failure. The current state-of-the-art in active dust mitigation is the Electrodynamic Dust Shield (EDS) which uses an electric field generated by alternating high positive and negative voltages (low current) to eject the charged dust off surfaces. An EDS made from copper coated Kapton is an ideal candidate to be bonded to a thermal radiator and coated with a low solar absorptance, high heat-emitter coating. This work compares the dust removal of copper-Kapton EDSs covered with different thermal radiator coatings in air and vacuum environments. The coatings include AZ-93 paint, Thermal Bright, and Solar White, a coating developed by the Applied Physics Lab (APL) at NASA Kennedy Space Center (KSC). The resistance and the thickness of the various coatings impact how well it works as an insulative layer for the EDS. Preliminary results indicate that Solar White may have better properties for dust removal and thermal rejection than the other coatings.

Krystal L. Acosta↗
DOE OSTI2021

Dual active site tandem catalysis of metal hydroxyl oxides and single atoms for boosting oxygen evolution reaction

We report the high voltage in oxygen evolution reaction (OER) often causes structural change in electrocatalysts and forms multiple active sites. Therefore, exploring the synergy of various active sites is extremely significant to develop catalysts for OER with multiple elementary steps. Herein, we adopt the physically adsorbed metal ions method to successfully synthesize a highly-efficient electrocatalyst containing the dual active sites of Fe-NiOOH and NiC4 single atoms (marked as Ni SAs/Fe-NiOOH). The Ni SAs/Fe-NiOOH displays outstanding OER performance with an overpotential of 269 mV to deliver current density of 10 mA/cm 2 that shows 55 mV superior to commercial IrO 2 /CB at the same condition. Experiments and density functional theory calculations indicate that the excellent OER activity of Ni SAs/Fe-NiOOH catalyst is attributed to the synergy of dual active sites of NiC 4 SAs and Fe-NiOOH. A tandem catalysis mechanism is also proposed to reveal the synergism of two active centers, which makes the potential-determining step more facile and accordingly decreases the OER overpotential. This work offers a new concept of tandem catalysis to develop the electrocatalysts with many elemental steps, like OER and oxygen reduction reaction catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Stochastic Microgrid Scheduling With Chance‐Constrained Resilience Consideration

Traditionally, it is assumed that microgrids transition seamlessly from grid‐connected operation to islanded mode in the event of sudden main grid outages. In reality, the islanding process, especially unintentional islanding, is rarely seamless. Instead, it is subject to voltage and frequency fluctuations caused by the instantaneous disconnection of the point of common coupling (PCC) switch, variations in loads and renewable generation output and even the protection tripping of distributed energy resources (DERs). To mitigate these fluctuations and facilitate a smooth islanding process, we propose a stochastic microgrid scheduling model that incorporates chance‐constrained resilience measures. Specifically, the resilience measure is defined as the probability of successful islanding (PSI), that is, the probability that a microgrid can mitigate the generation‐demand imbalance caused by the disconnection of the PCC switch, variations in load and renewable generation and DER tripping. This measure is modelled using chance constraints. Unlike existing reliability and resilience indices, which typically neglect the possibility of microgrid/DER failure under extreme events and assume their survival while primarily focussing on reducing impact duration or magnitude, the proposed PSI‐based framework explicitly addresses microgrid and DER survival during the islanding transition. The formulated nonlinear chance constraints are approximated using a multiinterval approach and equivalently represented as a mixed‐integer linear programming (MILP) formulation. Case study results validate the proposed method, showing that the PSI estimation error is reduced to less than 8%, compared to approximately 28% with existing methods. Various sensitivity analyses on the DER tripping rate and PSI settings were performed to validate the robustness of the proposed method. In particular, the necessity of accounting for DER tripping in the PSI calculation was demonstrated.

chance constrained optimization↗
NASA NTRS2016

Integration Tests of the 4 kW-Class High Voltage Hall Accelerator Power Processing Unit with the HiVHAc and the SPT-140 Hall Effect Thrusters

NASA's Science Mission Directorate is sponsoring the development of a 4 kW-class Hall propulsion system for implementation in NASA science and exploration missions. The main components of the system include the High Voltage Hall Accelerator (HiVHAc), an engineering model power processing unit (PPU) developed by Colorado Power Electronics, and a xenon flow control module (XFCM) developed by VACCO Industries. NASA Glenn Research Center is performing integrated tests of the Hall thruster propulsion system. This paper presents results from integrated tests of the PPU and XFCM with the HiVHAc engineering development thruster and a SPT-140 thruster provided by Space System Loral. The results presented in this paper demonstrate thruster discharge initiation along with open-loop and closed-loop control of the discharge current with anode flow for both the HiVHAc and the SPT-140 thrusters. Integrated tests with the SPT-140 thruster indicated that the PPU was able to repeatedly initiate the thruster's discharge, achieve steady state operation, and successfully throttle the thruster between 1.5 and 4.5 kW. The measured SPT-140 performance was identical to levels reported by Space Systems Loral.

Power Processing Unit↗
DOE OSTI2021

Data-Driven Global Sensitivity Analysis of Three-Phase Distribution System with PVs

Global sensitivity analysis (GSA) of distribution system with respect to stochastic PV variations plays an important role in designing optimal voltage control schemes. This paper proposes a Kriging, i.e., Gaussian process modeling enabled data-driven GSA method. The key idea is to develop a surrogate model that captures the hidden global relationship between voltage and real and reactive power injections from the historical data. With the surrogate model, the Sobol index can be conveniently calculated to assess the global sensitivity of voltage to various power injection variations. Comparison results with other model-based GSA methods on the IEEE 37-bus feeder, such as the polynomial chaos expansion and the Monte Carlo approaches demonstrate that the proposed method can achieve accurate GSA outcomes while maintaining high computational efficiency.

distribution system analysis↗
DOE OSTI2022

Predicting Solar Cell Performance from Terahertz and Microwave Spectroscopy

Abstract Mobilities and lifetimes of photogenerated charge carriers are core properties of photovoltaic materials and can both be characterized by contactless terahertz or microwave measurements. Here, the expertise from fifteen laboratories is combined to quantitatively model the current‐voltage characteristics of a solar cell from such measurements. To this end, the impact of measurement conditions, alternate interpretations, and experimental inter‐laboratory variations are discussed using a (Cs,FA,MA)Pb(I,Br) 3 halide perovskite thin‐film as a case study. At 1 sun equivalent excitation, neither transport nor recombination is significantly affected by exciton formation or trapping. Terahertz, microwave, and photoluminescence transients for the neat material yield consistent effective lifetimes implying a resistance‐free JV‐curve with a potential power conversion efficiency of 24.6 %. For grainsizes above ≈20 nm, intra‐grain charge transport is characterized by terahertz sum mobilities of ≈32 cm 2 V −1 s −1 . Drift‐diffusion simulations indicate that these intra‐grain mobilities can slightly reduce the fill factor of perovskite solar cells to 0.82, in accordance with the best‐realized devices in the literature. Beyond perovskites, this work can guide a highly predictive characterization of any emerging semiconductor for photovoltaic or photoelectrochemical energy conversion. A best practice for the interpretation of terahertz and microwave measurements on photovoltaic materials is presented.

14 SOLAR ENERGY↗
DOE OSTI2020

Determination of background doping polarity of unintentionally doped semiconductor layers

Here, we present a method of determining the background doping type in semiconductors using capacitance–voltage measurements on overetched double mesa p–i–n or n–i–p structures. Unlike Hall measurements, this method is not limited by the conductivity of the substrate. By measuring the capacitance of devices with varying top and bottom mesa sizes, we were able to conclusively determine which mesa contained the p–n junction, revealing the polarity of the intrinsic layer. This method, when demonstrated on GaSb p–i–n and n–i–p structures, concluded that the material is residually doped p-type, which is well established by other sources. The method was then applied to a 10 monolayer InAs/10 monolayer AlSb superlattice, for which the doping polarity was unknown, and indicated that this material is also p-type.

42 ENGINEERING↗
DOE OSTI2025

Analysis of the HAE activity in the TJ-II stellarator using a Landau closure model

The aim of this study is to analyze the stability of helical Alfvén eigenmodes (HAEs) in TJ-II discharges and the stabilizing effect of the energetic particles generated by the neutral beam injector (NBI) on pressure gradient-driven modes (PGDMs). HAE and PGDM stability is studied using the linear version of the gyro-fluid code FAR3d and the continuous structure by the STELLGAP code. First, Alfvén eigenmode (AE) and PGDM activity observed in the experiments is reproduced by the simulations, identifying unstable m/n = 4/7 − 2/3 and 7/12 − 5/8 HAEs triggered around ρ = 0.66 showing a frequency of 209 and 204 kHz, respectively, as well as 5/3 PGDM. Next, a parametric study is performed with respect to the thermal ion density and iota profile in the middle-outer plasma region to verify the robustness of the simulation results with respect to the uncertainty of experimental profiles. The analysis confirms that experimental uncertainty does not cause large deviations in the simulation results, showing the destabilization of the same HAEs for all the configurations tested. The simulations also indicate the decay of the 5/3 PGDM growth rate as the energetic particle (EP) population in the plasma increases, consistent with the experiment. Stability analysis of the n = 3, 7, 11, n = 5, 9, 13, n = 6, 10, 14, and n = 8, 12 helical families is performed with respect to the NBI operational regime for different EP energies, β as well as deposition profiles. The most unstable configuration is the radially localized on-axis NBI operation (stiff EP density profile gradients nearby the magnetic axis). Using the simulation model that reproduces the observed Alfvén activity, we extend the study to analyze NBI performance within a theoretical framework. It shows that increasing NBI voltage (which raises EP energy) leads to a degradation in NBI performance for a given power (related to EP β and their density). To achieve better NBI operation, higher voltage must be balanced with lower injection power, ensuring stable AEs while keeping the same EP β.

Plasma confinement↗
NASA NTRS1990

Ensemble Monte Carlo characterization of graded Al(x)Ga(1-x)As heterojunction barriers

The current-voltage characteristics of graded Al(x)Ga(1-x)As heterojunction barriers were investigated using a self-consistent ensemble Monte Carlo method. Results are presented for barriers with two doping levels (10 to the 15th/cu cm and 10 to the 17th/cu cm) and two barrier heights (100 and 265 meV). It was found that the lower barrier structure exhibited little rectification at room temperature at both doping levels, while the higher barrier exhibited considerable rectification. The structures with the lower doping value exhibited a smaller current in both forward and reverse regions, due to space-charge effect. The results of studies of the energy and momentum distribution functions along the barrier indicate that the assumption of drifted Maxwellian distribution used in energy-momentum models is not justified for Gamma valley electrons.

Kamoua, R.↗
DOE OSTI2024

Increased Static Charge–Induced Threshold Voltage Shifts and Memristor Activity in Pentacene OFETs Comprising Polystyrene–Based Gate Dielectrics Containing Electroactive Small Molecule Crystallites

Top-contact bottom-gate pentacene OFETs are fabricated with single layer dielectrics comprised of either polystyrene (PS), poly(4-methylstyrene) (P4MS), or poly(4-tert-butylstyrene) (P4TBS). The polystyrenes are blended with varying concentrations of two different small molecules, dibenzotetrathiafulvalene (DBTTF) and 2,8-difluoro-5,11-bis(triethylsilylethynyl)anthradithiophene (diF-TES-ADT), to form small, separated crystallites contained throughout the polymer dielectric layer. The OFET characteristics of these devices are investigated and their threshold voltage shifts are measured after –70 V static charging for 5 min. Two-terminal measurements are conducted using multiple different gate biases in the range of –50 to +50 V to investigate memristor behavior in the devices. OFETs containing DBTTF exhibited ΔVth increases as large as 330% relative to control OFETs containing no DBTTF, while OFETs containing at least 7.5 wt.% DBTTF exhibited memristor activity, with currents ranging from 20 nA to 44 µA depending on the applied bias. Furthermore, this work demonstrates that including small, separated crystallites in polymer dielectrics enhances their charge storage ability and can be promising for creating nonbinary memory devices for data processing. Additionally, the observed memristor activity indicates the OFETs in this work can be used in development of neuromorphic systems that aim to mimic the synaptic behavior of the human nervous system.

25 ENERGY STORAGE↗
DOE OSTI2025

Relationship between Sodium Content and Copper Activity for High Voltage Stability in O3-Type Layered Oxide Cathodes

Layered oxides with an O3 framework have attracted attention as cathode materials for sodium-ion batteries due to their high discharge capacity. Yet they are hampered for commercialization by poor cyclability due to structural instability during the sodium (de)intercalation process. The introduction of Cu in small fractions to the transition metal layers has been empirically observed to improve reversible specific capacity and cycling stability. Understanding the redox activity of Cu in O3-type Na x TMO 2 materials is crucial, as it could directly influence the charge compensation mechanism, voltage profile, and structural stability. However, the precise role of Cu in O3-type sodium cathodes under high-voltage cycling conditions (>4.1 V) remains insufficiently understood. To close this gap of knowledge, we studied the effect of Cu in two representative layered oxides with the same O3 stacking but different sodium stoichiometry, Na 0.9 Mn 1/2 Fe 1/3 Cu 1/6 O 2 and NaMn 1/2 Fe 1/3 Cu 1/6 O 2 . X-ray spectroscopy reveals that in Na 0.9 Mn 1/2 Fe 1/3 Cu 1/6 O 2 , Cu exhibits dual redox activity, Cu + /Cu 2+ in the pristine state and Cu 2+ /Cu 3+ upon charging in the sodium-deficient material, whereas only the Cu + /Cu 2+ redox couple is observed in the fully stoichiometric layered oxide. Furthermore, the results indicate that even a slight deficiency in sodium can significantly impact the electrochemical performance and material stability and alter the elemental redox activity of Cu.

Batteries↗
DOE OSTI2023

Selecting the Optimal Fluorinated Ether Co-Solvent for Lithium Metal Batteries

To guide the selection of a suitable fluorinated ether (FE) co -solvent for lithium metal batteries, it is crucial to understand the relationship between the organic structures of the FEs and the electrochemical performance of an FE-containing electrolyte. In this work, 1,1,2,2-tetrafluoro-1-(2,2,2-trifluoroethoxy)ethane (FEE), 1,1,2,2-tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)-propane (TTE), and 1,2-bis(1,1,2,2-tetrafluoroethoxy)ethane (OFDEE) were chosen as representative FE co-solvents because of their distinct structural properties. The structure-activity relationship between the FEs and the electrochemical performance of Li||LiNi 0.6 Mn 0.2 Co 0.2 O 2 (Li||NMC622) cells was correlated and quantified by Fourier-transform infrared and multi-dimensional nuclear magnetic resonance techniques. Sand's model was also employed to assess the extent of lithium dendrite formation in the cells using various FE electrolytes. The cycling performance of Li||NMC622 cells using different FE co-solvents follows the order FEE > TTE > OFDEE. Further, since the direct measurement of Sand's time is difficult, we introduced relative Sand's time to probe the diffusion behavior of each electrolyte, and the results showed that the best performance was obtained in the electrolyte with the longest relative Sand's time. Moreover, the lithium metal cell using the electrolyte with FEE co-solvent showed similar capacity retention compared with the baseline electrolyte at room temperature, but it demonstrated significantly improved low-temperature performance. The results indicate that FEE is a promising co-solvent candidate for improving the low-temperature performance of lithium metal batteries because it possesses not only non-solvating behavior but also very low viscosity and non-flammability. The advanced electrolyte LiPF 6 -FEC-DMC-FEE enables very stable cycling of lithium metal batteries at various temperatures.

25 ENERGY STORAGE↗
DOE OSTI2023

Spread Spectrum Time Domain Reflectometry (SSTDR) and Frequency Domain Reflectometry (FDR) for Detection of Cable Anomalies Using Machine Learning

Cables are initially qualified for nuclear power plant use for 40 years. As plants extend their operating license to 60 and 80 years, continued use of these cables must shift to a performance-based approach since it is cost prohibitive to completely replace cables that are likely still capable of performing their design function. A variety of cable tests are available and are commonly applied during outages when the cables can be taken out of service. Frequency domain reflectometry (FDR) is one of these test methods that is being more broadly accepted and used because it not only detects anomalies along the cable with a low-voltage signal that does not stress the cable insulation, but the technique also locates the anomalies. This supports follow-up local inspection and local repair or partial replacement of a damaged cable segment. Currently, FDR testing is only applied to cables that are taken out of service since the test instrument would be damaged by operational voltages. A related technology that has found some acceptance in the aircraft and rail industry is spread spectrum time domain reflectometry (SSTDR). This technology has been implemented with a custom commercial instrument by LiveWire Innovation Inc. that is designed to operate on live cables up to 1000 volts. One of the main conclusions of a previous effort was that cable reflectometry plots can be difficult for humans to analyze due to baseline noise, low or noisy anomaly response peaks, or large responses from cable ends. Detection of cable anomalies for many of these frequencies and test conditions was challenging for manual analysis. This presented an ideal opportunity for ML analysis to distinguish undamaged cable indications from anomalous cable indications. This research discusses application of machine learning (ML) to reflectometry cable test methods. The goal was to assess feasibility to distinguish undamaged cable reflectometry responses from damaged or anomalous cable reflectometry responses. The assessment considered the 3 instruments, multiple frequency bandwidths from each instrument, multiple cable anomalies and test conditions, and both supervised and unsupervised ML approaches. Although approaches and analysis methods were not identical or directly comparable, both outputs were encouraging. The unsupervised prediction weighted accuracy was assessed by instrument and by frequency. It performed better at high frequencies with the highest prediction accuracy of 0.84 for the higher frequency FDR, 0.79 for the 48-MHz LiveWire SSTDR, and 0.77 for 300-MHz PNNL SSTDR. The initial weighted accuracy average across all frequencies for using supervised ML was 0.56 to 0.68. The supervised analysis was repeated with noisier training data removed resulting in weighted accuracies of 0.69 to 0.87. These weighted accuracies are not directly comparable due to differences in the supervised and unsupervised analysis details but do indicate an encouraging trend. Even with limited and unbalanced data, strong prediction accuracies seem encouraging for further work including more data under a wider range of conditions.

42 ENGINEERING↗
NASA NTRS1986

Performance characteristics of ring-cusp thrusters with xenon propellant

The performance characteristics and operating envelope of several 30-cm ring-cusp ion thrusters with xenon propellant were investigated. Results indicate a strong performance dependence on the discharge chamber boundary magnetic fields and resultant distribution of electron currents. Significant improvements in discharge performance over J-series divergent-field thrusters were achieved for large throttling ranges, which translate into reduced cathode emission currents and reduced power dissipation which should be of significant benefit for operation at thruster power levels in excess of 10 kW. Mass spectrometry of the ion beam was documented for both the ring-cusp and J-series thrusters with xenon propellant for determination of overall thruster efficiency, and lifetime. Based on the lower centerline values of doubly charged ions in the ion beam and the lower operating discharge voltage, the screen grid erosion rate of the ring-cusp thruster is expected to be lower than the divergent-field J-series thruster by a factor of 2.

Patterson, M. J.↗
NASA NTRS1986

Performance characteristics of ring-cusp thrusters with xenon propellant

The performance characteristics and operating envelope of several 30-cm ring-cusp ion thrusters with xenon propellant were investigated. Results indicate a strong performance dependence on the discharge chamber boundary magnetic fields and resultant distribution of electron currents. Significant improvements in discharge performance over J-series divergent-field thrusters were achieved for large throttling ranges, which translate into reduced cathode emission currents and reduced power dissipation which should be of significant benefit for operation at thruster power levels in excess of 10 kW. Mass spectrometer of the ion beam was documented for both the ring-cusp and J-series thrusters with xenon propellant for determination of overall thruster efficiency, and lifetime. Based on the lower centerline values of doubly charged ions in the ion beam and the lower operating discharge voltage, the screen grid erosion rate of the ring-cusp thruster is expected to be lower than the divergent-field J-series thruster by a factor of 2.

Patterson, M. J.↗