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At least 1,135 records · Page 63

Turbulent entrainment in finite-length wind farms

In this article, we present an entrainment-based model for predicting the flow and power output of finite-length wind farms. The model is an extension of the three-layer approach of Luzzatto-Fegiz & Caulfield ( Phys. Rev. Fluids , vol. 3, 2018, 093802) for wind farms of infinite length, and assumes dependence of key flow quantities, such as the wind farm bulk velocity, on the streamwise distance from the farm entrance. To assist our analysis and validate the proposed model, we undertake a series of large-eddy simulations with different turbine spacing arrangements and layouts. Comparisons are also made with the top-down model with entrance effects of Meneveau ( J. Turbul. , vol. 13, 2012, N7) and data from the literature. The finite-length entrainment model is shown to be capable of capturing the power drop between contiguous rows of turbines as well as describing the advection and turbulent transport of kinetic energy in both the entrance and fully developed regions. The fully developed regime is approximated only deep in the wind farm, after approximately 15 rows of turbines. Our data suggest that for the cases considered in this study, the empirical coefficients that can be used to describe turbulent entrainment and transfers above the wind farm exhibit little dependence on the farm layout and may be considered constant for modelling purposes. However, the flow field within the wind farm layer can be strongly modulated by the turbine density (spacing) as well as the array layout, and to that extent it can be argued that they are both primary factors determining the wind farm power output.

17 WIND ENERGY↗

Physical properties and electronic structure of single-crystal KCo 2 As 2

We present a method for producing high quality KCo 2 As 2 crystals, stable in air and suitable for a variety of measurements. X-ray diffraction, magnetic susceptibility, electrical transport and heat capacity measurements confirm the high quality and an absence of long range magnetic order down to at least 2 K. Residual resistivity values approaching 0.25 µΩ cm are representative of the high quality and low impurity scattering, and a Sommerfeld coefficient γ = 7.3 mJ/mol K 2 signifies weaker correlations than the Fe-based counterparts. Together with Hall effect measurements, angle-resolved photoemission experiments reveal a Fermi surface consisting of electron pockets at the center and corner of the Brillouin zone, in line with theoretical predictions and in contrast to the mixed carrier types of other pnictides with the ThCr 2 Si 2 structure. A large, linear magnetoresistance of 200% at 14 T, together with an observed linear and hyperbolic, rather than parabolic, band dispersions are unusual characteristics of this compound.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Radionuclide-specific Parameters Dataset

The radionuclide-specific parameters dataset is searchable for radiological information for multiple isotopes simultaneously. After selecting radionuclides of interest and the desired parameters, the RAIS will generate a table containing the values, chosen according to an established hierarchy. Results can be downloaded in Excel format. 50 parameters are available, including atomic number, soil to animal transfer coefficients, plant uptake coefficients, half-life, specific activity, and water solubility. Seven primary sources are used to populate the dataset of radiological-specific parameters. These values should be used in cancer risk assessments for the calculation of preliminary remediation goals (PRGs), hazard characterization, and transport modeling. Users can select up to 1000 radionuclides per query. The dataset supports environmental risk assessments, regulatory decision-making, and environmental planning with tools for benchmarking against risk-based standards. This structured approach ensures a robust evaluation of environmental risks tailored to regulatory needs.

Manning, Karessa [Oak Ridge National Laboratory (O↗

Hypersonic research engine project. Phase 2: Aerothermodynamic Integration Model (AIM) data reduction computer program, data item no. 54.16

The data reduction program used to analyze the performance of the Aerothermodynamic Integration Model is described. Routines to acquire, calibrate, and interpolate the test data, to calculate the axial components of the pressure area integrals and the skin function coefficients, and to report the raw data in engineering units are included along with routines to calculate flow conditions in the wind tunnel, inlet, combustor, and nozzle, and the overall engine performance. Various subroutines were modified and used to obtain species concentrations and transport properties in chemical equilibrium at each of the internal and external engine stations. It is recommended that future test plans include the configuration, calibration, and channel assignment data on a magnetic tape generated at the test site immediately before or after a test, and that the data reduction program be designed to operate in a batch environment.

Gaede, A. E.↗

Longitudinal aerodynamic characteristics of a deflected-thrust propulsive-lift transport model

A wind-tunnel investigation was conducted to determine the effect of deflecting the engine exit of a four-engine double-slotted flap transport to provide STOL performance. Longitudinal aerodynamic data were obtained at various engine exit positions and deflections. The data were obtained at three flap deflections representing cruise, take-off, and landing conditions for a range of angles of attack and various thrust coefficients. Downwash angles at the location of the horizontal tail were measured. The data are presented without analysis or discussion. Photographs of the test configurations are shown.

Hoad, D. R.↗

Stratospheric distributions of odd nitrogen and odd hydrogen in a two-dimensional model

A two-dimensional pole-to-pole chemical model of the stratosphere is developed which extends from 8 to 38 km in altitude. Atmospheric motions are simulated by mean vertical and meridional winds and eddy diffusion coefficients. Seasonally averaged distributions of important odd nitrogen (NO, NO2, and HNO3) and odd hydrogen (H, OH, HO2, H2O2) compounds are computed. Photodissociation of N2O leads to production of odd nitrogen in the stratosphere, and the odd nitrogen is ultimately removed by downward transport into the troposphere and by rain-out (modeled by a rain-out lifetime of 30 days below 8-km altitude). Results are presented for a quasi-steady state in which seasonal cycles repeat themselves. These results show significant latitudinal as well as vertical variations in the predicted species which emphasize the need for at least two dimensions in accurate stratospheric modeling. Computed concentrations are compared with observations when they exist.

Prinn, R. G.↗

Transport properties in the Jovian atmosphere

Transport properties in a Jupiter-like atmosphere (89 mol % hydrogen and 11 mol % helium) are obtained by using the method of the kinetic theory of gases. The transport collision integrals are calculated by fitting various two-body semiempirical interaction potentials for which the collision integrals are tabulated to ab initio quantum mechanical calculations of the two-body interactions. The collision integrals are used to calculate the binary diffusion coefficients, viscosity, and 'total' thermal conductivity of the pure gases and the gas mixtures at 1-atm pressure from 1000 K to 25,000 K.

Biolsi, L.↗

Magnesium doping of efficient GaAs and Ga(0.75)In(0.25)As solar cells grown by metalorganic chemical vapor deposition

Magnesium has been substituted for zinc in GaAs and Ga(0.75)In(0.25)As solar cells grown by metalorganic chemical vapor deposition (MOCVD). Bis(cyclopentadienyl)magnesium (Cp2Mg) is used as the MOCVD transport agent for Mg. Full retention of excellent material quality and efficient cell performance results. The substitution of Mg for Zn would enhance the abruptness and reproducibility of doping profiles, and facilitate high temperature processing and operation, due to the much lower diffusion coefficient of Mg, relative to Zn, in these materials.

Lewis, C. R.↗

Potential benefits of magnetic suspension and balance systems

The potential of Magnetic Suspension and Balance Systems (MSBS) to improve conventional wind tunnel testing techniques is discussed. Topics include: elimination of model geometry distortion and support interference to improve the measurement accuracy of aerodynamic coefficients; removal of testing restrictions due to supports; improved dynamic stability data; and stores separation testing. Substantial increases in wind tunnel productivity are anticipated due to the coalescence of these improvements. Specific improvements in testing methods for missiles, helicopters, fighter aircraft, twin fuselage transports and bombers, state separation, water tunnels, and automobiles are also forecast. In a more speculative vein, new wind tunnel test techniques are envisioned as a result of applying MSBS, including free-flight computer trajectories in the test section, pilot-in-the-loop and designer-in-the-loop testing, shipboard missile launch simulation, and optimization of hybrid hypersonic configurations. Also addressed are potential applications of MSBS to such diverse technologies as medical research and practice, industrial robotics, space weaponry, and ore processing in space.

Lawing, Pierce L.↗

Oxygen-18 tracer study of the passive thermal oxidation of silicon

This work focuses on the thermal oxidation of silicon near 1273 K using the double-tracer oxidation method. The results confirm that oxidation occurs by the transport of electrically neutral nonnetwork oxygen through the interstitial space of the vitreous silica (v-SiO2) scale. Simultaneously, self- (or isotopic-) diffusion occurs in the network, resulting in characteristic isotopic fraction distributions near the gas-scale interface. The self-diffusion coefficients calculated from these profiles agree with those reported for tracer diffusion in v-SiO2, and the diffusion coefficient calculated from the scale growth is consistent with reported O2 permeation data. An important parameter that describes the double-oxidation behavior is a ratio relating the scale thickness grown during the second oxidation, the network self-diffusion coefficient for oxygen, and the time of the second oxidation.

Cawley, J. D.↗

Aerodynamic Characteristics of a Refined Deep-Step Planing-Tail Flying-Boat Hull with Various Forebody and Afterbody Shapes

An investigation was made in the Langley 300 mph 7-by 10-foot tunnel to determine the aerodynamic characteristics of a refined deep-step planing-tail hull with various forebody and afterbody shapes. For comparison, tests were made on a streamline body simulating the fuselage of a modern transport airplane. The results of the tests, which include the interference effects of a 21-percent-thick support wing, indicated that for corresponding configurations the hull models incorporating a forebody with a length-beam ratio of 7 had lower minimum drag coefficients than the hull models incorporating a forebody with a length-beam ratio of 5. Longitudinal and lateral stability was generally about the same for all hull models tested and about the same as that of a conventional hull.

Riebe, John M↗

Comparison of Dust Optical Depth From Multi-Sensor Products and MONARCH (Multiscale Online Non-hydrostatic AtmospheRe CHemistry) Dust Reanalysis Over North Africa, the Middle East, and Europe

Aerosol reanalysis datasets are model-based, observationally constrained, continuous 3D aerosol fields with a relatively high temporal frequency that can be used to assess aerosol variations and trends, climate effects, and impacts on socioeconomic sectors, such as health. Here we compare and assess the recently published MONARCH (Multiscale Online Non-hydrostatic AtmospheRe CHemistry) high-resolution regional desert dust reanalysis over northern Africa, the Middle East, and Europe (NAMEE) with a combination of ground-based observations and space-based dust retrievals and products. In particular, we compare the total and coarse dust optical depth (DOD) from the new reanalysis with DOD products derived from MODIS (MODerate resolution Imaging Spectroradiometer), MISR (Multi-angle Imaging SpectroRadiometer), and IASI (Infrared Atmospheric Sounding Interferometer) spaceborne instruments. Despite the larger uncertainties, satellite-based datasets provide a better geographical coverage than ground-based observations, and the use of different retrievals and products allows at least partially overcoming some single-product weaknesses in the comparison. Nevertheless, limitations and uncertainties due to the type of sensor, its operating principle, its sensitivity, its temporal and spatial resolution, and the methodology for retrieving or further deriving dust products are factors that bias the reanalysis assessment. We, therefore, also use ground-based DOD observations provided by 238 stations of the AERONET (AErosol RObotic NETwork) located within the NAMEE region as a reference evaluation dataset. In particular, prior to the reanalysis assessment, the satellite datasets were evaluated against AERONET, showing moderate underestimations in the vicinities of dust sources and downwind regions, whereas small or significant overestimations, depending on the dataset, can be found in the remote regions. Taking these results into consideration, the MONARCH reanalysis assessment shows that total and coarse-DOD simulations are consistent with satellite- and ground-based data, qualitatively capturing the major dust sources in the area in addition to the dust transport patterns. Moreover, the MONARCH reanalysis reproduces the seasonal dust cycle, identifying the increased dust activity that occurred in the NAMEE region during spring and summer. The quantitative comparison between the MONARCH reanalysis DOD and satellite multi-sensor products shows that the reanalysis tends to slightly overestimate the desert dust that is emitted from the source regions and underestimate the transported dust over the outflow regions, implying that the model's removal of dust particles from the atmosphere, through deposition processes, is too effective. More specifically, small positive biases are found over the Sahara desert (0.04) and negative biases over the Atlantic Ocean and the Arabian Sea (−0.04), which constitute the main pathways of the long-range dust transport. Considering the DOD values recorded on average there, such discrepancies can be considered low, as the low relative bias in the Sahara desert (< 50 %) and over the adjacent maritime regions (< 100 %) certifies. Similarly, over areas with intense dust activity, the linear correlation coefficient between the MONARCH reanalysis simulations and the ensemble of the satellite products is significantly high for both total and coarse DOD, reaching 0.8 over the Middle East, the Atlantic Ocean, and the Arabian Sea and exceeding it over the African continent. Moreover, the low relative biases and high correlations are associated with regions for which large numbers of observations are available, thus allowing for robust reanalysis assessment.

Michail Mytilinaios↗

Global Sensitivity Analysis of a Reactive Transport Model for Mineral Scale Formation During Hydraulic Fracturing

Injection of water-based hydraulic fracturing fluid (HFF) into tight shale gas/oil formations can increase formation permeability and enhance production rates, but this process frequently causes mineral scale formation that can occlude pore space and hinder flow. To identify the most important factors that control the formation of mineral scales, we applied a novel global sensitivity analysis method—distance-based generalized sensitivity analysis (DGSA)—to a reactive transport model (RTM) that was previously built and calibrated to simulate precipitation of barite [BaSO4] and iron (hydr)oxide [Fe(OH) 3 ] in shale matrices and on fracture surfaces. Reactive transport simulations were run with model parameters randomly sampled based on assigned uncertainties. Modeling results for barite and Fe(OH)3 formation were clustered using machine-learning algorithms. A list of ranked critical input parameters was obtained after statistical quantification of cumulative distribution functions of input parameters. We found that barite formation is most sensitive to the rate of sulfate ion generation, which is determined by the pyrite dissolution rate coefficient and oxidant availability. In addition, barite formation is sensitive to the initial amounts of barite in HFF and shale, followed by barite thermodynamics/kinetics. For Fe(OH) 3 formation, the ranked factors are Fe(OH)3 precipitation rate coefficients, initial HFF pH, initial Fe(OH) 3 amount in HFF, and oxidant availability. Overall, our results provide insights into managing mineral scale formation during hydraulic fracturing to enhance production. Meanwhile, this study serves as an example of global sensitivity analysis of RTMs using the efficient, straightforward, and open-source DGSA method.

58 GEOSCIENCES↗

Venus - Vertical transport rates in the visible atmosphere

The cloud particles on Venus are sufficiently small for their vertical distribution to be strongly affected by atmospheric turbulence. Reasonably firm estimates of the vertical distribution of cloud particles can be made from current interpretations of refraction, polarization, and absorption band data. These enable very firm upper limits to be placed on average vertical mass diffusion coefficients in the visible atmosphere. These upper limits are independent of the cloud particle composition or mode of formation, and of changes in the particle size distribution with altitude.

Prinn, R. G.↗

Filled Nd(sub z) Fe(sub x) Co(sub 4-x) Sb(sub 12-y) Ge(sub y) Skutterudites: Processing and Thermoelectric Properties

Skutterudites have proven to be a useful thermoelectric system as a result of their enhanced figure of merit (ZT1), cheap material cost, favorable mechanical properties, and good thermal stability. The majority of skutterudite interest in recent years has been focused on binary skutterudites like CoSb3. Binary skutterudites are often double and triple filled, with a range of elements from the lanthanide series, in order to reduce the lattice component of thermal conductivity. Ternary and quaternary skutterudites, such as Co4Ge6Se6 or Ni4Sb8Sn4, provide additional paths to tune the electronic structure. The thermal conductivity can further be improved in these complex skutterudites by the introduction of fillers. The Nd (sub z) Fe (sub x) Co (sub 4-x) Sb (sub 12-y)Ge (sub y) system has been investigated as a p-type thermoelectric material, and is stable up to 600 degrees Centigrade. The influence of Fe and Ge content, along with filler Nd, was investigated on thermoelectric transport properties. In addition to the chemical influence on properties, some processing details of the system will also be addressed.

Electical Conductivity↗

Higher harmonic non-linear flow modes of charged hadrons in Pb-Pb collisions at $\sqrt{s_{\mathrm{NN}}}$ = 5.02 TeV

Anisotropic flow coefficients, v n , non-linear flow mode coefficients, χ n,mk , and correlations among different symmetry planes, ρ n,mk are measured in Pb-Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV. Results obtained with multi-particle correlations are reported for the transverse momentum interval 0.2 < p T < 5.0 GeV/c within the pseudorapidity interval 0.4 < |η| < 0.8 as a function of collision centrality. The v n coefficients and χ n,mk and ρ n,mk are presented up to the ninth and seventh harmonic order, respectively. Calculations suggest that the correlations measured in different symmetry planes and the non-linear flow mode coefficients are dependent on the shear and bulk viscosity to entropy ratios of the medium created in heavy-ion collisions. The comparison between these measurements and those at lower energies and calculations from hydrodynamic models places strong constraints on the initial conditions and transport properties of the system.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

An indirect approach to optimize the reaction rates of thermal NO formation for diesel engines

With stringent emission regulations, it has become more important for modern diesel engine manufacturers to accurately predict engine-out nitrogen oxide (NO x ) emissions across a wide range of operating conditions. Thermal NO is the major source of engine-out NO x in modern diesel engines. For thermal NO formation, several earlier studies have recommended the forward and reverse reaction rate coefficients of the rate-limiting reaction (O + N 2 ⇌ NO + N). However, due to deficiencies in sub-models and inadequacies of reduced chemical mechanisms to represent diesel combustion, these recommended values more often than not need to be adjusted in reduced order combustion models to accurately predict engine-out NO x . Hence, in this work a systematic and computationally efficient approach has been proposed to streamline the process of determining the optimum reaction rate coefficients. Here, to develop the optimization approach, four different production diesel engines with different operating conditions in terms of speed, load, and exhaust-gas recirculation have been considered. Numerical simulations have been performed using a detailed zero-dimensional velocity-composition-frequency transported probability density function (0D-VCF-tPDF) model that uses hundreds of notional particles to capture in-cylinder stratification. Four different combinations of hydrocarbon and NO x chemical mechanisms were used to represent chemistry. It was found that for the rate-limiting reaction, the pre-exponent factors (A f1 , A r1 ) and activation energies (E A,f1 , E A,r1 ) of the forward and reverse reaction rates follow a linear band in A f1 - E A,f1 and A r1 - E A,r1 space where predicted engine-out NO x match the measured values closely. By encompassing such bands from different engines and considering constraints on activation energies, a reduced search domain of pre-exponent factors and activation energies was constructed that is expected to be applicable to any diesel engine. Eventually, computationally efficient three-line and one-line search approaches were proposed to determine the optimum values of the pre-exponent factors and activation energies that led to a minimum error between measured and predicted engine-out NO x . Finally, these three-line and one-line NO x optimization approaches were applied to a fifth production diesel engine for which the 0D-VCF-tPDF model showed a very good predictive performance in terms of predicting peak pressure, 50% burn rate, and engine-out NO x when compared to measured and 3D-CFD values.

33 ADVANCED PROPULSION SYSTEMS↗

Reversible Reactions, Mesh Size, and Segmental Dynamics Control Penetrant Diffusion in Ethylene Vitrimers

The diffusion of two aromatic dyes with nearly identical sizes was measured in ethylene vitrimers with precise linker lengths and borate ester cross-links using fluorescence recovery after photobleaching (FRAP). One dye possessed a reactive hydroxyl group, while the second was inert. The reaction of the hydroxyl group with the network is slow relative to the hopping times of the dye, resulting in a large slowdown by a factor of 50 for a reactive probe molecule. A kinetic model was fit to the fluorescence intensity data to determine rate constants for the reversible reaction of the dye from the network, which confirms the role of slow reaction kinetics. A second network cross-linker was also investigated with a substituted boronic ester showing ∼10,000 times faster exchange kinetics. In this system, the two dyes show the same diffusion coefficient, as the reaction is no longer the rate-limiting step. The role of dense meshes on small and large dyes is also discussed in the context of the existing theories. Finally, these results highlight the potential of dynamic networks to control penetrant transport through synergistic effects of the mesh size, dynamic bond kinetics, and penetrant–network interactions.

confinement↗