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At least 1,135 records · Page 63

Recent Progress to Understand and Improve Zeolite Stability in the Aqueous Medium

The work reviewed here attempts to summarize the growing literature on zeolite stability in hot liquid water. This required to first establish the nature, structure and interactions of the active sites in Brønsted and Lewis acidic microporous materials in the presence of liquid water. This understanding was then transferred to zeolite stability and catalyst deactivation. While early results correctly established Si–O–Si hydrolysis as the dominant pathway compared to the Si–O–Al hydrolysis observed in steaming, it also focused extensively on the positive role of framework and extra-framework Al in stabilizing zeolites. However, stability was instead found to more directly correlate with the number of internal structural defects and intraporous water concentration. Stabilization protocols for Brønsted acidic zeolites are described in detail. In the case of Lewis acidic zeolites, their inherent hydrophobic behavior (Si/M >100) makes them more resistant towards water, however, issues such as reversible carbonaceous species formation as well as irreversible metal leaching and fouling remain. Finally, we summarize the most important factors in designing robust and efficient zeolite catalysts made to withstand hot liquid water.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessing Stability of Transition Metal Nitrides in Aqueous Environments: The Case of Molybdenum, Iron, Vanadium and Nickel Nitride

Analysis of the MoN, Mo 2 N, VN, Fe 2 N, Fe 4 N, Ni 3 N stability in the aqueous media was performed based on the thermodynamic data available in HSC Chemistry software. Our analysis show that among all the studied nitrides, cubic Mo 2 N is the most resistant while cubic VN is the least resistant to oxidation and decomposition. The change in temperature up to 100 °C does not significantly influence the formation potentials of transition metal oxides from nitrides; however, pH significantly affects the stability of the studied transition metal nitrides. In the case of Mo 2 N, MoN, and VN changing pH from acidic to neutral and alkaline decreases the stability of the nitrides and the oxide formation potentials shift to more negative values. Additionally, based on thermodynamics, orthorhombic Fe 2 N should be stable only in alkaline conditions, while cubic Fe 4 N and hexagonal Ni 3 N should be the most stable at pH ~ 7 and pH ~ 9. Changing pH from these values decreases the stability of both Fe 4 N and Ni 3 N and the formation of oxy-, hydroxy- species becomes thermodynamically more favorable. Overall, the limited stability of the metal nitrides places severe constraints for their use in aqueous electrocatalytic applications.

36 MATERIALS SCIENCE↗

Application of Benchmarked Kinetic Resistive Wall Mode Stability Codes to ITER, Including Additional Physics

Leading resistive wall mode (RWM) stability codes MARS-K [Y. Liu, et al., Phys. Plasmas 15, 112503 (2008)] and MISK [B. Hu, et al., Phys. Plasmas 12, 057301 (2005)] have been previously benchmarked. The benchmarking has now been extended to include additional physics, and used to project the stability of ITER in a realistic operating space. Due to ITER's relatively low plasma rotation and collisionality, collisions and non-resonance rotational effects were both found to have little impact on stability, and these non-resonance rotational effects also will not self-consistently affect the ITER RWM eigenfunction. Resonances between thermal ions and electrons and the expected level of ITER toroidal rotation were found to be important to stability, as were alpha particles, which are not in rotational resonance. MISK calculations show that without alpha particles, ITER is projected to be unstable to the RWM, but the expected level of alphas is calculated to provide a sufficient level of stability.

Resistive Wall Mode Stability↗

Experimental Images and Videos of Foam Stability (Half-life)

The experimental data obtained in this project is the thermal stability data of various foams measured using the setup established at Temple University during this study. The setup is installed with a portable digital camera which can take images and videos of foam evolution at a given pressure and temperature condition. Consequently, the half-life data was recorded from the images/videos, which are used as a measure of the thermal stability for foams. Over the 3 years of this project, four different surfactants and five different stabilizing agents were studied. The surfactants are, Alfa Olefin Sulfonate (AOS), Sodium Dodecyl Sulphate (SDS), Tergitol (NP-40), and Cetyltrimethylammonium chloride (CTAC). The stabilizing agents are, guar gum, bentonite clay, crosslinking agents, silicon dioxide nanoparticles (60 to 70nm), and graphene oxide dispersions. Foam stability was evaluated at different temperatures between 100C and 200cC, while the foam generation pressure varied between atmospheric pressure (14.7 psi) and 1000 psi. The images are saved as .jpg file and videos are saved as .avi files.

15 GEOTHERMAL ENERGY↗

Synergistic Effects of Turbine Wakes and Atmospheric Stability on Power Production at an Onshore Wind Farm

This report examines the complex interactions between atmospheric stability and turbine-induced wakes on downwind turbine wind speed and power production at a West Coast North American multi-MW wind farm. Wakes are generated when the upwind flow field is distorted by the mechanical movement of the wind turbine blades. This has two consequences for downwind turbines: (1) the downwind turbine encounters wind flows with reduced velocity and (2) the downwind turbine encounters increased turbulence across multiple length scales via mechanical turbulence production by the upwind turbine. This increase in turbulence on top of ambient levels may increase aerodynamic fatigue loads on the blades and reduce the lifetime of turbine component parts. Furthermore, ambient atmospheric conditions, including atmospheric stability, i.e., thermal stratification in the lower boundary layer, play an important role in wake dissipation. Higher levels of ambient turbulence (i.e., a convective or unstable boundary layer) lead to higher turbulent mixing in the wake and a faster recovery in the velocity flow field downwind of a turbine. Lower levels of ambient turbulence, as in a stable boundary layer, will lead to more persistent wakes. The wake of a wind turbine can be divided into two regions: the near wake and far wake, as illustrated in Figure 1. The near wake is formed when the turbine structure alters the shape of the flow field and usually persists one rotor diameter (D) downstream. The difference between the air inside and outside of the near wake results in a shear layer. This shear layer thickens as it moves downstream and forms turbulent eddies of multiple length scales. As the wake travels downstream, it expands depending on the level of ambient turbulence and meanders (i.e., travels in non-uniform path). Schepers estimates that the wake is fully expanded at a distance of 2.25 D and the far wake region begins at 2-5 D downstream. The actual distance traveled before the wake recovers to its inflow velocity is dependent on the amount ambient turbulence, the amount of wind shear, and topographical and structural effects. The maximum velocity deficit is estimated to occur at 1-2 D but can be longer under low levels of ambient turbulence. Our understanding of turbine wakes comes from wind tunnel experiments, field experiments, numerical simulations, and from studies utilizing both experimental and modeling methods. It is well documented that downwind turbines in multi-Megawatt wind farms often produce less power than upwind turbine rows. These wake-induced power losses have been estimated from 5% to up to 40% depending on the turbine operating settings (e.g., thrust coefficient), number of turbine rows, turbine size (e.g., rotor diameter and hub-height), wind farm terrain, and atmospheric flow conditions (e.g., ambient wind speed, turbulence, and atmospheric stability). Early work by Elliott and Cadogan suggested that power data for different turbulent conditions be segregated to distinguish the effects of turbulence on wind farm power production. This may be especially important for downwind turbines within wind farms, as chaotic and turbulent wake flows increase stress on downstream turbines. Impacts of stability on turbine wakes and power production have been examined for a flat terrain, moderate size (43 turbines) wind farm in Minnesota and for an offshore, 80 turbine wind farm off the coast of Denmark. Conzemius found it difficult to distinguish wakes (i.e., downwind velocity deficits) when the atmosphere was convective as large amounts of scatter were present in the turbine nacelle wind speed data. This suggested that high levels of turbulence broke-up the wake via large buoyancy effects, which are generally on the order of 1 km in size. On the other hand, they found pronounced wake effects when the atmosphere was very stable and turbulence was either suppressed or the length scale was reduced as turbulence in this case was mechanically produced (i.e., friction forces). This led to larger reductions at downwind turbines and maximum velocity (power) deficits reached up to 50% (70%) during strongly stable conditions. At an offshore Danish wind farm, Hansen et al. found a strong negative correlation between power deficit and ambient turbulence intensity (i.e., atmospheric stability). Under convective conditions, when turbulence levels were relatively high, smallest power deficits were observed. Power deficits approaching 35 to 40% were found inside the wind farm during stable conditions.

17 WIND ENERGY↗

Stability and Control of Burning Tokamak Plasmas with Resistive Walls: Final Technical Report

This project is focused on theoretical and computational development for quantitative prediction of the stability and control of the equilibrium state evolution in toroidal burning plasmas, including its interaction with the surrounding resistive wall. The stability of long pulse burning plasmas is highly sensitive to the physics of resonant layers in the plasma, sources of momentum and flow, kinetic effects of energetic particles, and boundary conditions at the wall, including feedback control and error fields. In ITER in particular, the low toroidal flow equilibrium state, sustained primarily by energetic alpha particles from fusion reactions, will require the consideration of all of these key elements to predict quantitatively the stability and evolution. The principal investigators on this project have performed theoretical and computational analyses, guided by analytic modeling, to address this physics in realistic configurations. The overall goal has been to understand the key physics mechanisms that describe stable toroidal burning plasmas under active feedback control. Several relevant achievements have occurred during this project, leading to publications and invited conference presentations. In theoretical efforts, with the physics of the resonant layers, resistive wall, and toroidal momentum transport included, this study has extended from cylindrical resistive plasma - resistive wall models with feedback control to toroidal geometry with strong shaping to study mode coupling effects on the stability. These results have given insight into combined tearing and resistive wall mode behavior in simulations and experiment, while enabling a rapid exploration of plasma parameter space, to identify possible domains of interest for large plasma codes to investigate in more detail. Resonant field amplification and quasilinear torques in the presence of error fields and velocity shear have also been investigated. Here it was found, surprisingly, that the Maxwell torque on resonant layers in the plasma which exhibit finite real frequencies ωr in their response is significantly different from the conventional results based on tearing layers with pure real growth (or damping) rates. This observation suggests the possibility that the torque on the tearing layers can lock the plasma rotation to this finite phase velocity, which may lead to locking in which velocity shear is maintained. More broadly, the sources of all torques driving flows in magnetic confinement experiments is not fully understood, and this theoretical work may shed light on puzzling experimental results. It was also found that real frequencies occur over a wide range of plasma response regimes, and are indeed the norm and not the exception, often leading to profound effects on the locking torque. Also, the influence of trapped energetic ions orbiting over the resistive plasma mode structure, a critical effect in burning plasmas, was investigated through analytic modeling and analysis of simulations and experiment. This effort has shown that energetic ions can drive the development of disruptive instabilities, but also damp and stabilize the instabilities, depending on the details of the shear in the equilibrium magnetic field. This finding could be critical to maintaining stable operations in burning plasmas. In the most recent work, a series of simulations have been conducted to study the effect of differential flow and energetic ion effects on entry to the onset of a disruptive instability in the most realistic conditions possible, with preexisting nonlinearly saturated benign instabilities. Throughout this work, the linear and quasilinear theory of resonant layers with differential flow between them, their interaction with resistive wall and error fields, and energetic ions effects, have been used to understand realistic simulations of mode onset and the experimental discharges they represent. These studies will continue to answer remaining questions about the relation between theoretical results obtained in this project and observations of the onset and evolution of disruptive instabilities in experiment.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Stationary stability for evolutionary dynamics in finite populations

Here, we demonstrate a vast expansion of the theory of evolutionary stability to finite populations with mutation, connecting the theory of the stationary distribution of the Moran process with the Lyapunov theory of evolutionary stability. We define the notion of stationary stability for the Moran process with mutation and generalizations, as well as a generalized notion of evolutionary stability that includes mutation called an incentive stable state (ISS) candidate. For sufficiently large populations, extrema of the stationary distribution are ISS candidates and we give a family of Lyapunov quantities that are locally minimized at the stationary extrema and at ISS candidates. In various examples, including for the Moran andWright–Fisher processes, we show that the local maxima of the stationary distribution capture the traditionally-defined evolutionarily stable states. The classical stability theory of the replicator dynamic is recovered in the large population limit. Finally we include descriptions of possible extensions to populations of variable size and populations evolving on graphs.

60 APPLIED LIFE SCIENCES↗

Feedback Control Strategy for Transient Stability Application

Power systems are subjected to a wide range of disturbances during daily operations. Severe disturbances, such as a loss of a large generator, a three-phase bolted fault on a generator bus, or a loss of a transmission line, can lead to the loss of synchronism of a generator or group of generators. The ability of a power system to maintain synchronism during the few seconds after being subjected to a severe disturbance is known as transient stability. Most of the modern methods of controlling transient stability involve special protection schemes or remedial action schemes. These special protection schemes sense predetermined system conditions and take corrective actions, such as generator tripping or generation re-dispatch, in real time to maintain transient stability. Another method is the use of a real-time feedback control system to modulate the output of an actuator in response to a signal. This paper provides a fundamental evaluation of the use of feedback control strategies to improve transient stability in a power system. An optimal feedback control strategy that modulates the real power injected and absorbed by distributed energy-storage devices is proposed. Its performance is evaluated on a four-machine power system and on a 34-machine reduced-order model of the Western North American Power System. The result shows that the feedback control strategy can increase the critical fault clearing time by 60%, thereby improving the transient stability of the power system.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Enhanced Phase Stability of Sm 2 (Fe, Al) 17 C x

Aluminum doping can improve the phase stability of metastable compound Sm 2 Fe 17 C x with a high carbon content (x > 1.5). We investigated the preferential site substitution of Al, chemical bonding, and structural stability in Sm 2 (Fe,Al) 17 C 3 using first-principle calculations. Our results reveal a strong correlation between the preferential substitution of Fe by Al and the atomic site chemical environment, which affects the overall phase stability. Specifically, Al preferentially occupies the 9d site in Sm 2 (Fe,Al) 17 C 3 . At the same time, Al prefers the site 6c in its parent phase Sm 2 (Fe,Al) 17 . Partial replacement of Fe with Al leads to a more negative formation energy, indicating enhanced thermodynamic stability. Crystal Orbital Hamilton Population (COHP) and Crystal Orbital Bond Index (COBI) analysis suggest that insertion of carbon weakens the bonding strength of Sm-Fe (18f) and Sm-Fe (18h), resulting in metastability of Sm 2 Fe 17 C x . Doping Al strengthens Al-Fe, Al-Sm, Sm-Fe (18f, 18h) and Fe–C bonding in Sm 2 (Fe,Al) 17 C 3 , as revealed by calculated COHP and COBI. These effects contribute to improved phase stability in the Al-doped 2:17 interstitial compound.

chemical bonding↗

STABILITY OF GAS CLOUDS IN GALACTIC NUCLEI: AN EXTENDED VIRIAL THEOREM

Cold gas entering the central 1–10{sup 2} pc of a galaxy fragments and condenses into clouds. The stability of the clouds determines whether they will be turned into stars or can be delivered to the central supermassive black hole (SMBH) to turn on an active galactic nucleus (AGN). The conventional criteria to assess the stability of these clouds, such as the Jeans criterion and Roche (or tidal) limit, are insufficient here, because they assume the dominance of self-gravity in binding a cloud, and neglect external agents, such as pressure and tidal forces, which are common in galactic nuclei. We formulate a new scheme for judging this stability. We first revisit the conventional Virial theorem, taking into account an external pressure, to identify the correct range of masses that lead to stable clouds. We then extend the theorem to further include an external tidal field, which is equally crucial for the stability in the region of our interest—in dense star clusters, around SMBHs. We apply our extended Virial theorem to find new solutions to controversial problems, namely, the stability of the gas clumps in AGN tori, the circum-nuclear disk in the Galactic Center, and the central molecular zone of the Milky Way. The masses we derive for these structures are orders of magnitude smaller than the commonly used Virial masses (equivalent to the Jeans mass). Moreover, we prove that these clumps are stable, contrary to what one would naively deduce from the Roche (tidal) limit.

79 ASTRONOMY AND ASTROPHYSICS↗

An Experimental Investigation of the Effect of Propellers Used as Aerodynamic Brakes on Stability and Control

Tests were made of a model representative of a single-engine tractor-type airplane for the purpose of determining the stability and control effects of a propeller used as an aerodynamic brake. The tests were made with single-and dual-rotation propellers to show the effect of type of propeller rotation, and with positive thrust to provide basic data with which to compare the effects of negative thrust. Four configurations of the model were used to give the effects of tilting the propeller thrust axis down 5 deg., raising the horizontal tail, and combining both tilt and raised tail. Results of the tests are reported herein. The effects of negative thrust were found to be significant. The longitudinal stability was increased because of the loss of wing lift and increase of the angle of attack of the tail. Directional stability and both longitudinal and directional control were decreased because of the reduced velocity at the tail. These effects are moderate for moderate braking but become pronounced with full-power braking, particularly at high values of lift coefficient. The effects of model configuration changes were small when compared with the over-all effects of negative-thrust operation; however, improved stability and control characteristics were exhibited by the model with the tilted thrust axis. Raising the horizontal tail improved the longitudinal characteristics, but was detrimental to directional characteristics. The use of dual-rotation propeller reduced the directional trim charges resulting from the braking operation. A prototype airplane was assumed and handling qualities were computed and analyzed for normal (positive thrust) and braking operation with full and partial power. The results of these analyses are presented for the longitudinal characteristics in steady and accelerated flight, and for the directional characteristics in high- and low-speed flight. It was found that by limiting the power output of the engine (assuming the constant-speed propeller will function in the range of blade angles required for negative thrust) the stability and control characteristics may be held within the limits required for safe operation. Braking with full power, particularly at low speeds, is dangerous, but braking with very small power output is satisfactory from the standpoint of control. The amount of braking produced with zero power output is equal to or better than that produced by conventional spoiler-type brakes.

AIRPLANES, MILITARY↗

A formulation of stability for spacecraft formations

A formulation of stability for a set of spacecraft in formation flight is presented. First, a formation is defined in a precise mathematical form in terms of control interactions. Then, stability is formulated based on input-to-output stability with respect to a partitioning of the formation dynamics. This formulation of stability is shown to be useful in characterizing disturbance propagation in the formation as a function of the partition interconnection topology, and also in analyzing the robustness of sensing, communication, and control topologies. Stability results are presented for hierarchical, cyclic, and disturbance attenuating formations.

formation flyer↗

Stability Study of the RERTR Fuel Microstructure

The irradiation stability of the interaction phases at the interface of fuel and Al alloy matrix as well as the stability of the fission gas bubble superlattice is believed to be very important to the U-Mo fuel performance. In this paper the recent result from TEM characterization of Kr ion irradiated U-10Mo-5Zr alloy will be discussed. The focus will be on the phase stability of Mo2-Zr, a dominated second phase developed at the interface of U-10Mo and the Zr barrier in a monolithic fuel plate from fuel fabrication. The Kr ion irradiations were conducted at a temperature of 200 degrees C to an ion fluence of 2.0E+16 ions/cm2. To investigate the thermal stability of the fission gas bubble superlattice, a key microstructural feature in both irradiated dispersion U-7Mo fuel and monolithic U-10Mo fuel, a FIB-TEM sample of the irradiated U-10Mo fuel (3.53E+21 fission/cm3) was used for a TEM in-situ heating experiment. The preliminary result showed extraordinary thermal stability of the fission gas bubble superlattice. The implication of the TEM observation from these two experiments on the fuel microstructural evolution under irradiation will be discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Grid Stability Awareness System (GSAS) (Final Scientific/Technical Report)

The project team developed a software suite named Grid Stability Awareness System (GSAS) for power system near real-time stability monitoring and analysis based on synchrophasor measurement. The software suite consists of five analytical tools: an oscillation monitoring tool, a voltage stability monitoring tool, a transient instability monitoring tool, an angle difference monitoring tool, and an event detection tool. These tools have been integrated into one framework to provide power grid operators with both real-time or near real-time stability status of a power grid and historical information about system stability status. These tools are being considered for real-time use in the operation environment.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Protein Mutation Stability Ternary Classification using Neural Networks and Rigidity Analysis

Discerning how a mutation affects the stability of a protein is central to the study of a wide range of diseases. Machine learning and statistical analysis techniques can inform how to allocate limited resources to the considerable time and cost associated with wet lab mutagenesis experiments. In this work we explore the effectiveness of predicting the change in the stability of a protein due to a mutation using a neural network classfier. Assessing the accuracy of our approach is dependent on the use of experimental data about the effects of mutations performed in vitro. Because the experimental data is prone to discrepancies when similar experiments have been performed by multiple laboratories, the use of the data near the juncture of stabilizing and destabilizing mutations is question- able. We address this later problem via a systematic approach in which we explore the use of a three-way classification scheme with stabilizing, destabilizing, and inconclusive labels. For a systematic search of potential classification cutoff values our classfier achieved 68 percent accuracy on ternary classification for cutoff values of -0.6 and 0.7 with a low rate of classifying stabilizing as destabilizing and vice versa.

Neural Network, Classification, protein stability,↗

Ab-initio simulations of chemical stability indicators of the bis-DGA-type molecule and its radiation degradation products

For hydrometallurgical treatment of the high level liquid waste (HLLW) in the DIAMEX and SANEX processes, organic compounds of the bis-DGA family are used as cation extractants in apolar solvents. For the compound of m-xylylene-bis-diglycolamide high distribution coefficients for Eu and Am were found. Since the environment of the process is highly radioactive and acidic (nitric acid), it is necessary to ensure the stability of the extractants. In order to analyse the process theoretically, the molecule of m-xylylene-bis- diglycolamide and two of its degradation products were simulated by the DFT computational methods (PBE, RPBE, BLYP, B3LYP) available within the simulation environment DMol{sup 3} 6.1 and Gaussian 09 software. The local chemical stability of some locations of the molecule was assessed from the calculated stability indicators (electrostatic potential, Fukui function, HOMO localization). In connection with the chemical treatment, especially the stability against an electrophilic attack was tested. The results of calculated bond orders and spatial distribution of electrostatic potential and HOMO were are successfully correlated with the local and general stability determined by the experiment. These results should be helpful for the further development of the separation process. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries

The stability of the electrolytes for all-vanadium redox flow battery was investigated with ex-situ heating/cooling treatment and in-situ flow-battery testing methods. The effects of inorganic and organic additives have been studied. The additives containing the ions of potassium, phosphate, and polyphosphate are not suitable stabilizing agents because of their reactions with V(V) ions, forming precipitates of KVSO6 or VOPO4. Of the chemicals studied, polyacrylic acid and its mixture with CH3SO3H are the most promising stabilizing candidates which can stabilize all the four vanadium ions (V2+, V3+, VO2+, and VO2+) in electrolyte solutions up to 1.8 M. However, further effort is needed to obtain a stable electrolyte solution with >1.8 M V5+ at temperatures higher than 40 °C.

74 ATOMIC AND MOLECULAR PHYSICS↗

Towards the Robust Small-Signal Stability Region of Power Systems Under Perturbations Such as Uncertain and Volatile Wind Generation

This paper addresses how to extend the concept of small-signal stability region (SSSR) to that of robust small-signal stability region (RSSSR), within which the system can remain stable even under perturbations caused by uncertain and volatile nodal injections, such as renewable generation. We first employ the structured perturbation theory to formulate the perturbations of nodal injections in state space. Both the intensity and the locations of perturbations can be taken into account. Then, we leverage the stability radius theory and structured singular value theory to define the RSSSR in parameter subspace, enabling a systematic analysis of small-signal stability of power systems under perturbations in a region-wise manner. The hyperplane-approximation method can be employed to construct a linear closed-form approximation of RSSSR boundaries. Case studies on the modified two-area system and New England 39-node system illustrate the new concept of RSSSR and its potential applications.

power system stability analysis↗