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At least 1,135 records · Page 63

The homunculus of Eta Carinae: An interacting stellar winds paradigm

We simulate the origin and evolution of the bipolar nebula surrounding Eta Car using numerical two-dimensional gasdynamic models. The generalized interacting stellar winds scenario, wherein a stellar wind interacts with an aspherical circumstellar environment, is adopted. The eruption wind of 1840-1860, which is taken to be spherically symmetric, interacts with a preeruption toroidal density environment. Using reasonable assumptions of initial conditions and eruption parameters based on archival data, we have performed over 30 simulations in an effort to bracket the initial parameters which produce models that best match observations. We find that models with high pole-to-equator density contrasts (greater than 100) and toroidal density configurations nicely account for the observed morphology and kinematics of the homunculus.

Frank, Adam↗

Thermophysical Properties of Mars' North Polar Layered Deposits and Related Materials from Mars Odyssey THEMIS

The presence of a thick sequence of horizontal layers of ice-rich material at Mars north pole, dissected by troughs and eroding at its margins, is undoubtedly telling us something about the evolution of Mars climate [1,2] we just don t know what yet. The North Polar Layered Deposits (NPLD) most likely formed as astronomically driven climate variations led to the deposition of conformable, areally extensive layers of ice and dust over the polar region. More recently, the balance seems to have fundamentally shifted to net erosion, as evidenced by the many troughs within the NPLD and the steep, arcuate scarps present near its margins, both of which expose layering. We defined a number of Regions of Interest ROI) for THEMIS to target as part of the Mars Odyssey Participating Scientist program. We use these THEMIS data in order to understand the morphology and color/thermal properties of the NPLD and related materials over relevant (i.e., m to km) spatial scales. We have assembled color mosaics of our ROIs in order to map the distribution of ices, the different layered units, dark material, and underlying basement. The color information from THEMIS is crucial for distinguishing these different units which are less distinct on Mars Orbiter Camera images. We wish to understand the nature of the marginal scarps and their relationship to the dark material. Our next, more ambitious goal is to derive the thermophysical properties of the different geologic materials using THEMIS and Mars Global Surveyor Thermal Emission Spectrometer TES) data.

Vasavada, A. R.↗

Paleobiology, community ecology, and scales of ecological pattern

The fossil record provides a wealth of data on the role of regional processes and historical events in shaping biological communities over a variety of time scales. The Quaternary record with its evidence of repeated climatic change shows that both terrestrial and marine species shifted independently rather than as cohesive assemblages over scales of thousands of years. Larger scale patterns also show a strong individualistic component to taxon dynamics; assemblage stability, when it occurs, is difficult to separate from shared responses to low rates of environmental change. Nevertheless, the fossil record does suggest that some biotic interactions influence large-scale ecological and evolutionary patterns, albeit in more diffuse and protracted fashions than those generally studied by community ecologists. These include: (1) the resistance by incumbents to the establishment of new or invading taxa, with episodes of explosive diversification often appearing contingent on the removal of incumbents at extinction events; (2) steady states of within-habitat and global diversity at longer time scales (10(7)-l0(8) yr), despite enormous turnover of taxa; and (3) morphological and biogeographic responses to increased intensities of predation and substratum disturbance over similarly long time scales. The behavior of species and communities over the array of temporal and spatial scales in the fossil record takes on additional significance for framing conservation strategies, and for understanding recovery of species, lineages, and communities from environmental changes.

NASA Discipline Exobiology↗

A scalable framework for efficient coupling of thermal and microstructural simulations in additive manufacturing

Predicting microstructure evolution in metal additive manufacturing (AM) is important for process optimization, but spatiotemporal scale disparities between thermal transport and microstructure evolution create significant challenges for efficient data transfer between simulation codes. To address this, we present Stork, a scalable framework for coupling thermal and microstructural simulations. Stork uses a sparse data representation to identify and store active solidification sub-volumes, enabling highly parallel quad-linear interpolation from coarse thermal grids to fine microstructure grids without large intermediate storage. We demonstrate the framework by coupling the semi-analytic heat transfer code 3DThesis with the time-parallel cellular automata code Toucan. This approach achieves over two orders of magnitude reduction in data generation time and file size compared to prior workflows. Numerical studies show that quad-linear interpolation preserves grain morphology and crystallographic texture in laser powder bed fusion (LPBF) simulations for coarsening ratios up to 16. Overall, Stork provides a scalable pathway for high-throughput, component-scale AM simulations on modern high-performance computing systems.

36 MATERIALS SCIENCE↗

Visualizing diverse lithium growth and stripping behaviors in anode-free solid-state batteries with operando X-ray tomography

Anode-free solid-state batteries (SSBs), which eliminate the need for lithium metal use during cell assembly, have the potential to enable high energy densities and simplified manufacturing. However, the factors that control lithium growth/stripping at the anode current collector are not well understood. Here, we use operando X-ray microcomputed tomography to comprehensively image and quantify lithium deposition and stripping under various conditions in three different Li|Li 6 PS 5 Cl|current collector cells, revealing diverse behavior that depends on interface morphology, cell resistance, and solid-state electrolyte (SSE) microstructure. A cell with high resistance exhibits extensive lithium filament growth across the entire current collector interface, with filaments that grow around pre-existing pores in the SSE rather than lithium filling these pores. Lithium filament formation is partially reversible, with the cracks shrinking as lithium metal is stripped. Uniform lithium deposition is achievable at low current densities in low-resistance cells, whereas higher current densities in these cells cause an increase in interfacial roughness, which is correlated with subsequent filamentary growth at the edges of the cell. These results provide insight into filamentary vs. planar lithium growth and highlight that the evolution of lithium is sensitively dependent on SSE microstructure and electrochemical processes.

25 ENERGY STORAGE↗

Report on use of Inoculants in Missile Application Alloys

This report documents the status of current inoculant research relevant to missile application alloys and MTCR control language. The information is intended to provide data on current inoculants for us determining the current state of development and identifying potential research directions. Although there has been significant scientific research into the development and synthesis of inoculants, their current availability is limited is traditional powder inoculants employed during casting processes. However, research continues the development of complex oxides, ribbon materials, high entropy alloys, and other inoculant product forms, including the use of inoculants in the melt pools produced during additive manufacturing. Research to date has focused primarily on aluminum and steel alloys with emphasis on refining grain structures and evolving equiaxed morphologies while increasing strength and castability. The primary inoculants in steel and cast irons include TiN, SiC, FeSi75, and Ce which have increased strength properties. Chief inoculants for Al alloys often include TiC, SiC, Al3Sc(x) and TiB2 to aid in precipitation and refinement. Ti and Ni alloys have fewer research activities involving inoculants, although TiN, TiB, ZrN and LaB6 (for Ti alloys) and WC, Co3FeNb2, and CrFeNb (for Ni alloys) have been used. Sic, Al2O3, Mg and Ti are key inoculants for Mg alloys. Multiple cast alloys from each of the material classes demonstrated increased strength and performance properties using inoculants, with several approaching requirements applicable to missile service environments. The continued evolution of advanced manufacturing capabilities is making it easier to produce high temperature near net shape structural materials using inoculant powders. These shapes may include the geometric shapes addressed within the MTCR (tubes and limited wall thicknesses). The use of inoculants may enable further development of high temperature alloys into near net shapes traditionally produced via casting processes due to limited ductility. This may decrease material and manufacturing costs. In addition, inoculation provides controlled kinetics and achievable chemical segregation that enables potential for far-from equilibrium thermodynamic microstructures and chemistries that could provide new metastable alloy states and subsequent properties to address co-design engineering constraints, including needs for increased strength and ductility. It is recommended that specific material combinations within these alloy classes be carefully watched as the materials evolve, with controls aimed at those having material properties above current MTCR levels. This specifically includes the use of refractory inoculants in alloys, and the application of inoculants in high strength and high temperature alloys via additive manufacturing processes, with care to link capabilities to product forms similar to the current requirements on tube geometries and material feed stocks. The continued development of nanoparticle inoculants will increase strength and ductility of high strength castings and additive manufactured metallic components. For example, adding inoculants into the casting of maraging steels and other precipitation strengthened alloys may drastically elevate mechanical properties above the control limit of current regulations.

36 MATERIALS SCIENCE↗

SN 1987 A: A Unique Laboratory for Shock Physics

Supernova 1987 A has given us an unprecedented view of the evolution of the explosion debris and its interaction with circumstellar matter. The outer supernova debris, now expanding with velocities approx.8000 km/s, encountered the relatively dense circumstellar ring formed by presupernova mass loss in the early 1990s. The shock interaction is manifested by UV-optical "hotspots", an expanding X-ray ring, an expanding ring of knotty non-thermal radio emission, and a ring of thermal IR emission from silicate dust Recent ultraviolet observations of the emissions from the reverse shock and the ring with the HST/COS reveal new details about the shock interaction. Lyman alpha emission from the reverse shock is much stronger than H alpha and they have different emission morphologies, pointing to different emission mechanisms. The reverse shock was detected for the first time in C IV 1550. The N V to C IV brightness ratio indicates the N/C abundance ratio in the expanding debris is about 100X solar, about 3X N/C in the inner ring.

Sonneborn, George↗

The Multiphasic Teeth of Chiton Articulatus , an Abrasion‐Resistant and Self‐Sharpening Tool for Hard Algae Collection

Abstract Chiton articulatus is a species of mollusk living in the tropical Pacific intertidal rocky shores of Mexico. This species feeds on solid waste organic sources, including hard crustose algae that grow on rocky substrates, by grazing on them with its radula, a flexible chitinous membrane lined with mineralized major lateral teeth. In this study, the composition, morphology, and resulting mechanics of the mature teeth of this species, which have yet to be examined, are revealed. The results show the presence of multiphasic mature teeth, each consisting of aligned hard magnetite nanoparticles on the leading edge of the tooth underneath which are magnetite lamellae, followed by goethite, lepidocrocite, and eventually hydroxyapatite near the trailing edge. This multiregional structure demonstrates a gradation in hardness as well as different microstructural features integrated with tough interfaces. The combination of these microstructural and phase arrangements results in an abrasion‐resistant tough structure with a self‐sharpening ability. The results of this work will help contribute to developing new bioinspired designs while also helping to understand the evolution and feeding habits of these intriguing invertebrates.

36 MATERIALS SCIENCE↗

Finding Peas in the Early Universe with JWST

The Early Release Observations (EROs) of JWST beautifully demonstrate the promise of JWST in characterizing the universe at Cosmic Dawn. We analyze the Near Infrared Spectrograph ERO spectra of three z ~ 8 galaxies to determine their metallicities, gas temperatures, and ionization. These galaxies offer the first opportunity to understand the physical properties of Epoch-of-Reionization galaxies through detailed rest-optical emission-line spectroscopy. We show that these objects have metal abundances $12+\mathrm{log}[{\rm{O}}/{\rm{H}}]\,\approx$ 6.9–8.3, based on both the T e method and on a recent calibration of the R 23 metallicity indicator. Since the spectra are some of the earliest science data from JWST, we compare several line ratios with values expected from robust physics, to validate our measurement procedures. We compare the abundances and emission-line ratios to a nearby sample of Green Pea galaxies—a population of nearby emission-line galaxies whose UV properties resemble Epoch-of-Reionization galaxies, and which often have large Lyman continuum escape fractions. The JWST data show striking further similarities between these high-redshift galaxies and nearby Green Peas. The z ~ 8 galaxies span the metallicity range covered by Green Peas. They also show the compact morphology that is typical of emission-line-dominated galaxies at all redshifts. Based on these similarities with Green Peas, it is likely that these are the first rest-optical spectra of galaxies that are actively driving cosmological reionization.

79 ASTRONOMY AND ASTROPHYSICS↗

Structural and chemical evolutions of a magnesium vanadium oxide cathode under electrochemical cycling in magnesium batteries

The design of cathode materials that remain chemically and structurally stable during repetitive ion insertion and extraction poses a significant challenge in developing multivalent batteries. The cycling stability of traditional metal oxide-based cathode is challenged by sluggish diffusion of multivalent cations and parasitic reactivity at interfacial regimes, including the cathode electrolyte interphase layer (CEI). Understanding the reactions at the cathode-electrolyte interface, particularly those induced by non-stoichiometric surface layers, is a crucial design parameter for both cathode materials and electrolytes. Here, in this study, we employed multimodal analysis, including in situ and ex situ X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS) to examine the surface reactions and subsequent structural and chemical evolutions of the CEI on high voltage magnesium vanadium oxide (MgV 2 O 4 ) spinel cathode during the Mg 2+ insertion/extraction processes. The results revealed that the presence of non-stoichiometric surface layers in the magnesium vanadium oxide cathode drive the decomposition of bis(trifluoromethanesulfonyl)imide (TFSI - ) anion, leading to the formation of the CEI layer. The CEI layer could inhibit the Mg 2+ ion transfer processes. Accompanying this reactivity-driven degradation, the magnesium vanadium oxide cathode undergoes pulverization, forming clusters of nanosized particles. This process likely improves cycling ability by creating new intercalation sites and shortening the diffusion pathway for the Mg 2+ cations. This study demonstrates that controlling surface stoichiometry and engineering morphological properties are critical design parameters for high performance cathodes for multivalent batteries.

25 ENERGY STORAGE↗

A Lens into the Cu Nanograin by In Situ Vibrational Spectroscopy

Cu-based catalysts are uniquely capable of C-C coupling during electrochemical CO 2 reduction (CO 2 R), yet further mechanistic understanding remains hampered by the lack of spectroscopically resolved descriptors that demonstrate how surface adsorbates emerge and evolve within their catalytic environment. Here, in this study, we correlate in situ surface-enhanced Raman spectroscopy (SERS) and surface-enhanced infrared absorption spectroscopy (SEIRAS) to resolve the potential-dependent dynamics during CO 2 R on Cu nanograin catalysts. By building on previous benchmarking of low overpotential performance and nanograin structural evolution, we offer a diagnostic framework linking vibrational signatures to catalytic function, unveiling which species appear, persist, and turnover as the electrified surface and interfacial environment evolve under bias. The onset of linear CO is marked below -0.45 V, coincident with persistent adsorbed *OH/*O domains beyond the CO 2 R onset. In this context, Cu nanograins serve as a platform to dissect contributions of adsorbate coverage. By carefully dissecting the potential dependence of emergent twin-defect/step CO stretch bands (P1-P2), alongside the prototypical terrace-site CO stretch band (P3), we provide important context for interpreting coupled spectroscopic trends driven by coverage effects and resolve this for the evidently complex nanograin morphology. Together, these observations highlight the intertwined roles of surface stabilization and interfacial flux in steering multicarbon product formation. By directly linking vibrational signatures to catalytic behavior, this work aims to bridge the gap between observation and control and help guide toward a predictive framework of fine-tuned selectivity for CO 2 R.

Fonseca Guzman, Maria V. [University of California↗

Lunar Science Conference, 8th, Houston, Tex., March 14-18, 1977, Proceedings. Volume 1 - The moon and the inner solar system. Volume 2 - Petrogenetic studies of mare and highland rocks. Volume 3 - Planetary and lunar surfaces

Solar system processes are considered along with the origin and evolution of the moon, planetary geophysics, lunar basins and crustal layering, lunar magnetism, the lunar surface as a planetary probe, remote observations of lunar and planetary surfaces, earth-based measurements, integrated studies, physical properties of lunar materials, and asteroids, meteorites, and the early solar system. Attention is also given to studies of mare basalts, the kinetics of basalt crystallization, topical studies of mare basalts, highland rocks, experimental studies of highland rocks, geochemical studies of highland rocks, studies of materials of KREEP composition, a consortium study of lunar breccia 73215, topical studies on highland rocks, Venus, and regional studies of the moon. Studies of surface processes, are reported, taking into account cratering mechanics and fresh crater morphology, crater statistics and surface dating, effects of exposure and gardening, and the chemistry of surfaces.

Merril, R. B.↗

Mineralogical, Elemental, and Tomographic Reconnaissance Investigation for CLPS (METRIC)

METRIC is a robotic science laboratory that can determine the mineralogy, elemental chemistry, micromorphology, and thermophysical properties of planetary regolith. The METRIC suite comprises METRIC XRD/F, an X-ray diffraction/X-ray fluorescence instrument that can determine the mineralogy and elemental chemistry of regolith samples; METRIC XCT, a micro X-ray computed tomography instrument that can be used to evaluate grain/crystallite sizes and textures; METRIC IRS, an imaging spectrometer mounted on a rover that can determine mineralogy and thermophysical properties at the landing site; and a pneumatic sample collection, processing, distribution system developed by Honeybee Robotics. The payload elements could be deployed on a static lander or a rover. Data returned from the METRIC payload would inform origin, formation, and evolution of rocky planetary bodies. METRIC XRD/F draws on heritage from the CheMin instrument on the Mars Science Laboratory (MSL) Curiosity rover [1], with a few important improvements. Like CheMin, METRIC XRD/F operates in transmission geometry and uses piezoelectric actuators on sample cells in a tuning fork geometry to induce convective grain motion of the regolith to create a randomly oriented powder. MSL CheMin uses an energy-sensitive CCD to collect XRD patterns and XRF spectra simultaneously from the same sample cell, resulting in qualitative XRF data. METRIC XRD/F uses two different sample cells, one optimized for XRD and one optimized for XRF, and a silicon drift detector to detect fluoresced X-rays. This improvement to the XRF capabilities provides quantitative geochemical data of major elements down to Z = 11 and allows for the detection of minor and trace elements that are critical for evaluating geologic evolution of the Moon (e.g., P and Th). Modest improvements to the XRD geometry and hardware allow for better angular resolution and the ability to distinguish between members of the pyroxene group. METRIC XCT uses the same geometry and much of the same hardware as METRIC XRD/F, where a CCD would capture images of a regolith sample in a 3 mm diameter sample tube that is rotated 360° in steps <1°. Image brightness can be used to infer compositional data, where brighter materials indicate a higher Z, much like scanning electron microscopy. Data from METRIC XCT complement those from METRIC XRD/F. Particle size, shape, and texture can provide petrologic and provenance information, whereas vesicle size and morphology in volcanic or impact melt lithologies can inform cooling rates. METRIC IRS is a hyperspectral thermal imager that can be mounted to a lander or rover to provide mineralogical data from the broader landing site and help determine whether the samples analyzed by METRIC XRD/F and XCT are representative. The METRIC IRS spectral range (8–14 μm) and resolution (10.8 cm-1) allow for quantitative mineralogy from modelling Reststrahlen bands of major rock-forming minerals (e.g., silicates, phosphates). Radiance cubes can be processed and modelled with an onboard high-performance computer to determine mineral abundances of plagioclase, high-Ca pyroxene, pigeonite, orthopyroxene, olivine, and glass. Regolith samples can be acquired, processed, and delivered to the X-ray instruments via multiple sample handling systems, but the pneumatic sampling systems developed by Honeybee Robotics [e.g., 2] are best suited for relatively low-cost missions that are being competed for the Moon (e.g., NASA’s Payloads and Research Investigations for the Surface of the Moon program). There are pneumatic sampling systems that collect surface material and other systems that pneumatically drill up to ~1 m below the surface, providing material that has not been space weathered and has not been affected by the lander’s exhaust. [1] Blake, D. F., Vaniman, D., Achilles, C., Anderson, R., Bish, D., et al. (2012). Space Sci. Rev. 170, 341-478. https://doi.org/10.1007/s11214-012-9905-1. [2] Zacny, K., Betts, B., Hedlund, M., Long, P., Gramlich, M., Tura, K., Chu, P., Jacob, A., Garcia, A. (2014). IEEE Aerospace Conference, 3-7 March 2014, Big Sky, MT, U.S.A.

X-ray diffraction↗

Volcano evolution on Mars

The diversity of volcanic activity on Mars throughout geologic time was one of the major factors that has controlled the spatial distribution of surface mineralogies. The traditional view of Martian volcanism is one in which effusive activity has dominated the entire preserved geologic history of the planet, with the minor exception of phreatomagnetic activity and associated volcano ground-ice interactions. However, two lines of evidence have caused reconsidering of this view, and have led to the possible role of explosive volcanism on Mars. First, detailed analysis of high resolution Viking Orbiter images has provided good evidence for explosive activity on Hecates Tholus and Alba Patera. Secondly, the problems believed to exist in associating explosive volcanism with silicic magmas on Mars, and the consequent unusual magmatic evolutionary trend for Martian volcanoes from silica-rich to silica-poor, may now be circumvented by the consideration of basatic plinian activity similar in kind to terrestrial eruptions such as the 1886 Tarawera eruption. The morphologic evidence for an early phase of explosive activity on Mars is briefly reviewed, and a model is presented for the emplacement of ash-flow deposits on Martian volcanoes. The volcanoes Alba Patera and Olympus Mons are considered in this context, along with some of the older Martian tholi and paterae

Mouginis-Mark, Pete↗

Strain-Driven Evolution of Structural and Carrier Recombination Dynamics in Germanium

Strain engineering in group-IV semiconductors, in particular germanium (Ge), offers a promising route for advancing next-generation optoelectronic device performance. High minority carrier lifetime serves as a direct indicator of superior material quality and device efficiency. Several factors govern the minority carrier lifetime in both strained Ge and strained GeSn, such as strain level, epilayer thickness, defects, surface roughness, and Sn alloying. In this study, the impact of biaxial strain on effective minority carrier lifetimes of tensile-strained Ge (0% ..epsilon..-Ge/Al?As, 0.78% ..epsilon..-Ge/In0.115?Ga0.885?As, and 0.93% ..epsilon..-Ge/In0.16?Ga0.84?As) and compressively strained GeSn (-0.53% c-Ge0.97?Sn0.03/Al?As) epilayers, grown by molecular beam epitaxy, was experimentally investigated via the microwave-reflection photoconductive decay (..mu..-PCD) technique as a simultaneous function of thickness and strain. The structural and strain-relaxation properties were analyzed by high-resolution x-ray diffraction and Raman spectroscopy, while surface morphology analysis using atomic force microscopy provided insights into the surface roughness of strained Ge-based epilayers. Defect characterization by cross-section transmission electron microscopy revealed superior crystalline quality of ..epsilon..-Ge in one epilayer, while twin boundary formation was observed in the other. We investigated the carrier recombination dynamics in epitaxially strained Ge by extracting the bulk recombination lifetime and surface recombination velocity using the thickness-dependent minority carrier lifetime. High effective minority carrier lifetimes of approximately 60-340 ns were achieved at high strain levels with minimal dependence on the thickness of the strained Ge-based epilayers by means of the ..mu..-PCD technique. Minority carrier lifetimes in Ge-based epilayers exhibit a quadratic dependence on the biaxial strain, ranging from -0.88% (compressive) to +1.6% (tensile). The analysis of the carrier recombination dynamics in strained Ge-based heterostructures offers a pathway to designing group-IV based optoelectronic devices.

36 MATERIALS SCIENCE↗

Controlling morphology and improving reproducibility of magnetized liner inertial fusion experiments

X-ray imaging indicates magnetized liner inertial fusion (MagLIF) stagnation columns have a complicated quasi-helical structure with significant variations in x-ray brightness along the column. In this work, we describe MagLIF experiments aimed at controlling these stagnation structures by varying the initial liner geometry and composition. First, by varying the initial aspect ratio of the liner, we demonstrate a change in the stagnation structures that is consistent with helical magneto Rayleigh–Taylor (MRT) instabilities feedthrough from the outer-to-inner surfaces of the liner. Second, to minimize the seed for such instabilities, we incorporate a dielectric coating on the outer surface of the beryllium liner, which has previously been shown to reduce the growth of the electrothermal instability, a likely seed for MRT growth. Using this coating, we achieve a stagnation column with significantly reduced helical structure and axial variation in x-ray brightness. We discuss how this coating changes the evolution of structures through stagnation along with the spatial uniformity of neutron production. Finally, we show that these more uniform stagnations also result in improved reproducibility in stagnation temperatures and primary DD neutron yield.

Ampleford, D. J. (ORCID:0000000237422421)↗

In-situ spectroscopic ellipsometry for real-time characterization of the effects of high-flux helium plasmas on tungsten surfaces

Tungsten samples were exposed to He plasmas generated by an RF source (Γ i = 3.5 x 10 16 He cm -2 s -1 , ion energy = 92 eV.) The range of exposure conditions selected here is conducive to the growth of nearsurface He bubbles, and at higher fluence, the formation of W nanotendrils ranging between 50 — 100 nm in diameter. The evolution of these surface features was probed using a fixed-angle ellipsometer (280 — 1000 nm wavelength range) with direct line-of-sight to the sample. Over the parameter space explored here, changes in the two angles (p, S) that define the polarization of the reflected light followed a distinct trajectory with increasing plasma fluence. Ex-situ ellipsometry of 22 additional tungsten specimens tested at a wide range of plasma fluences and temperatures mapped onto these in-situ results well. We used helium ion microscopy and focused ion beam profiling to provide a direct calibration of the ellipsometry measurements. Our results indicate that for a reproducible process such as the growth helium-induced surface morphologies, ellipsometry is a practical in-situ diagnostic to study how fusion plasmas modify materials. To study more general effects of plasmas on surfaces, including co-deposition and sputtering, different approaches to modelling the optical properties of the exposed surfaces are also considered.

36 MATERIALS SCIENCE↗

Electrodeposition of Metals in Microgravity Conditions

Metal electrodeposition may introduce various morphological variations depending on the electrolytic conditions including cell configurations. For liquid electrolytes, a precise study of these deposits may be complicated by convective motion due to buoyancy. Zero-gravity (0-G) condition provided by drop shaft or parabolic flight gives a straightforward mean to avoid this effect: we present here 0-G electrodeposition experiments, which we compare to ground experiments (1-G). Two electrochemical systems were studied by laser interferometry, allowing to measure the concentration variations in the electrolyte: copper deposition from copper sulfate aqueous solution and lithium deposition from an ionic liquid containing LiTFSI. For copper, concentration variations were in good agreement with theory. For lithium, an apparent induction time was observed for the concentration evolution at 1-G: due to this induction time and to the low diffusion coefficient in ionic liquid, the concentration variations were hardly measurable in the parabolic flight 0-G periods of 20 seconds.

Nishikawa, K.↗