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At least 1,135 records · Page 63

Effects of indium contents on photocatalytic performance of ZnIn{sub 2}S{sub 4} for hydrogen evolution under visible light

A series of ZnIn{sub x}S{sub 4+y} (x=1.6, 2.0, 2.3, 2.6, 2.9, 3.1) photocatalysts were synthesized via a facile hydrothermal method and characterized by various analytical techniques, such as XRD, EDS, UV–vis DRS, SEM, TEM, BET and PL. The ZnIn{sub x}S{sub 4+y} photocatalysts had a similar crystal structure. With the increase of indium content, the absorption edges of ZnIn{sub x}S{sub 4+y} photocatalysts shifted to longer wavelength, their crystal sizes decreased firstly and then increased and the variation of the specific surface area and total pore volume was exactly opposite. Especially, when x=2.3, ZnIn{sub 2.3}S{sub 4+y} catalyst had smallest crystal size, largest specific surface area and total pore volume. Additionally, the morphology of ZnIn{sub x}S{sub 4+y} greatly depended on the contents of indium. The photocatalytic activity of ZnIn{sub x}S{sub 4+y} was evaluated by photocatalytic hydrogen production from water under visible light. The ZnIn{sub 2.3}S{sub 4+y} sample had the highest photocatalytic activity among these ZnIn{sub x}S{sub 4+y} photocatalysts and its hydrogen production rate was 363 μmol/g h. - Graphical abstract: First, a series of catalysts were synthesized. And then those were characterized by various analytical techniques (such as SEM). finally, The photocatalytic activity of catalyst was evaluated by photocatalytic hydrogen production from water under visible light. - Highlights: • The photocatalytic property was studied upon visible-light irradiation. • ZnIn{sub x}S{sub 4+y} photocatalysts show superior photocatalytic activity. • The catalyst of grain size, morphology and BET are related to indium content. • ZnIn{sub x}S{sub 4+y} photocatalysts were synthesized via a facile hydrothermal method.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Phenological shifts in lake stratification under climate change

One of the most important physical characteristics driving lifecycle events in lakes is stratification. Already subtle variations in the timing of stratification onset and break-up (phenology) are known to have major ecological effects, mainly by determining the availability of light, nutrients, carbon and oxygen to organisms. Despite its ecological importance, historic and future global changes in stratification phenology are unknown. Here, we used a lake-climate model ensemble and long-term observational data, to investigate changes in lake stratification phenology across the Northern Hemisphere from 1901 to 2099. Under the high-greenhouse-gas-emission scenario, stratification will begin 22.0 ± 7.0 days earlier and end 11.3 ± 4.7 days later by the end of this century. It is very likely that this 33.3 ± 11.7 day prolongation in stratification will accelerate lake deoxygenation with subsequent effects on nutrient mineralization and phosphorus release from lake sediments. Further misalignment of lifecycle events, with possible irreversible changes for lake ecosystems, is also likely.

54 ENVIRONMENTAL SCIENCES↗

(Invited) Fuel Cell Component Durability for Million Mile Fuel Cell Trucks

While significant advances have been made and early commercial fuel cell light-duty vehicles (LDVs) are starting to be produced, fuel cells in the heavy-duty-vehicle (HDV) transportation sector (including trucks, long-haul semitrailers, maritime, trains, etc.) are nascent, despite the fact that advantages of fuel cells compared to both diesel and electric powertrains are very compelling in terms of emissions, charging time, efficiency, power-to-weight ratio, among others. However, the fuel-cell technology for HDVs requires a paradigm shift in fuel-cell research and development compared to LDVs, where the emphasis becomes efficiency and improvements in durability instead of a focus on increased power densities and lower cell costs. Heavy-duty applications require significantly longer vehicle lifetimes (>25,000 hours/1,000,000 miles for heavy-duty trucks), and therefore require improved fuel cell durability compared to light-duty vehicles. In 2020, HFTO formed the Million Mile Fuel Cell Truck Consortium (M2FCT) that includes a core team of five national laboratories to overcome durability and efficiency challenges in PEMFCs for heavy-duty applications with an initial focus on long-haul trucks. While targets and testing protocols have been developed for light-duty vehicles, the same level of targets and testing protocols have not been established for heavy-duty transportation. With operational times of greater than > 25,000 hours required, the need for well-developed accelerated stress tests (ASTs) is amplified. Results from these ASTs demonstrate the need for more durable electrode layers and well-controlled potential variations. Finally, this presentation will provide an overview of the DOE's Fuel Cell R&D approach, highlighting past and current activities, as well as strategies to enable fuel cell competiveness for heavy-duty applications.

25 ENERGY STORAGE↗

Measurement of the Stopping Power of Water for Carbon Ions Using Inverted Doppler Shift Attenuation

Carbon ion therapy has gained importance in cancer treatment due to its locally well confined dose distribution, but there is a significant lack of experimental data which is needed for dose calculations and estimation of biological damage. Since tissue is mainly comprised of water, the energy-dependent stopping power of water is the critical measure. Importantly, previous data gathered from experiments with light ions has been limited to water vapour and ice and neglected water in its liquid phase. Additionally, theoretical models regarding the stopping power cannot yet describe the complex charge transfer interactions of the projectile at velocities in the range of the mean velocity of the valence electrons of the traversed medium. There are also discrepancies in the amount of phase effects concerning water and water vapour cross sections. Despite its importance there exists no experimental data for the stopping power of water for carbon ions in the energy region between 1 MeV and 5 MeV. This may be due to the short track length of carbon ions which makes traditional transmission experiments unfeasible. Therefore a project was launched to measure the stopping power of liquid water for carbon ions in the vicinity of the Bragg peak which corresponds to the energy regime of the maximum stopping power. For this measurement the inverted Doppler shift attenuation method was used. This uses the gamma quanta emitted from excited carbon nuclei which are produced by means of the {sup 12}C(α,α'){sup 12}C* reaction. The recorded γ-spectra contain the information of the projectiles velocity at the time they decay to their ground state and an internal clock provided by the exponential decay law. The deceleration of the projectile is directly connected to the stopping power which can be determined with this method as a function of the projectiles kinetic energy. Further measurements have been carried out to improve the experimental method. The setup and the preliminary results of this study will be presented. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Electrochemistry and Spectroelectrochemistry of the Pu (III/IV) and (IV/VI) Couples in Nitric Acid Systems

The solution chemistry of Pu in nitric acid is explored via electrochemistry and spectroelectrochemistry. By utilizing and comparing these techniques, an improved understanding of Pu behavior and its dependence on nitric acid concentration can be achieved. Here the Pu (III/IV) couple is characterized using cyclic voltammetry, square wave voltammetry, and a spectroelectrochemical Nernst step. Results indicate the formal reduction potential of the couple shifts negative with increasing acid concentration and reversible electrochemistry is no longer attainable above 6 M HNO3. Spectroelectrochemistry is also used to explore the irreversible oxidation of Pu(IV) to Pu(VI) and shine light on the mechanism and acid dependence of the redox reaction.

Lines, Amanda M.↗

Effect of CO 2 -brine-rock reactions on pore architecture and permeability in dolostone: Implications for CO 2 storage and EOR

Geologic carbon sequestration (GCS) is considered a feasible technology for storing substantive volumes of greenhouse gases in subsurface geological formations. In the reservoir, far from carbon dioxide (CO 2 ) injection wells or in post-injection scenarios, diffusion dominates over advection. This condition conjoins with spatially distributed geochemical reactions to induce heterogeneous changes in pore architecture, i.e. pore body and throat sizes or surface roughness. These changes can affect CO 2 transport properties and storage capacity. In this work, we investigated mineral dissolution and precipitation in dolomite samples saturated with a CO 2 -saturated brine at 93 °C and 34.5 MPa, aged without flow. Two rock types samples, i.e. intergranular- and vuggy-dominant, were selected to investigate changes in pore size, porosity and permeability under reactive conditions. Mineral dissolution and precipitation were characterized using scanning electron microscopy. Changes in pore size were quantified via time-domain nuclear magnetic resonance (TD-NMR) transverse relaxation time (T 2 ) and diffusion coefficient (D) distributions. We show that mineral dissolution likely occurs in highly permeable pathways. These observations are confirmed through analysis of (T 2 ) and diffusion coefficient (D) distributions. In contrast to results during CO 2 -enriched brine continuous injection, mineral precipitation was observed in micropores. The leftward shift of the T 2 peaks, corresponding to micropores, also evidenced mineral precipitation in lowpermeability zones. However, microscale alterations resulted only in a subtle increase in porosity and permeability. Results in this study shed light on effects of geochemical reactions on alteration of rock properties in diffusion-dominated regions during CO 2 storage.

58 GEOSCIENCES↗

Iodine (I) Expulsion at Photoirradiated Mixed Halide Perovskite Interface. Should I Stay or Should I Go?

Visible light irradiation of the mixed halide perovskite film in contact with a solvent (dichloromethane, DCM) in which the film otherwise is stable, leads to selective expulsion of iodide (I) from the film with concurrent shift in the band edge to lower wavelengths. Here we have now employed mixed halide perovskites to uncover the influence of A-site cation (Methyl ammonium, MA and Cesium, Cs) on the mobility of iodide ions under photoirradiation. In the absence of solvent contact, the mixed halide perovskite films undergo photoinduced segregation with a rate constant that decreases with increasing Cs content. Interestingly, the iodide expulsion rate in DCM is strongly dependent on the rate of photoinduced segregation. At Cs atomic concentrations higher than 50%, the films become stable as the iodide expulsion is largely suppressed. The role of A-site cation in dictating the mobility of halide ions is discussed.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Moisture Sources of Precipitation in the Great Lakes Region: Climatology and Recent Changes

Abstract Given the critical role of precipitation on hydroclimate, we quantified the contributions of moisture source regions to precipitation in the Great Lakes Region (GLR) using multiple reanalysis data sets. Results show that the Great Plains (GPs) and the GLR itself are the primary sources of moisture. The moisture sources for the double peaks in the GLR precipitation that occur in June and September are identified, which is caused by a shift in the peak timing of moisture contribution from the GLR and GPs. In particular, moisture from the GPs contributes more to the heavy precipitation, while moisture from the GLR contributes more to the light precipitation. We also found a statistically significant ( p < 0.05) increasing trend in the moisture contribution from the mid‐Pacific, caused by an intensified zonal moisture transport from the mid‐Pacific through changes in atmospheric circulation.

54 ENVIRONMENTAL SCIENCES↗

Luminescent down shifting effect of Ce-doped yttrium aluminum garnet thin films on solar cells

Ce-doped yttrium aluminum garnet (YAG:Ce) thin films as luminescent down shifting (LDS) materials are introduced into the module of crystalline silicon solar cells. The films are deposited by RF magnetron sputtering on the lower surface of the quartz glass. They convert ultraviolet and blue light into yellow light. Experiments show that the introduction of YAG:Ce films improves the conversion efficiency from 18.45% of the cells to 19.27% of the module. The increasing efficiency is attributed to LDS effect of YAG:Ce films and the reduced reflection of short wavelength photons. Two intentionally selected samples with similar reflectivities are used to evaluate roughly the effect of LDS alone on the solar cells, which leads to a relative increase by 2.68% in the conversion efficiency.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Improved spatial calibration for the CXRS system on EAST

A Charge eXchange Recombination Spectroscopy (CXRS) diagnostic system has been developed to measure profiles of ion temperature and rotation since 2014 on EAST. Several techniques have been developed to improve the spatial calibration of the CXRS diagnostic. The sightline location was obtained by measuring the coordinates of three points on each sightline using an articulated flexible coordinate measuring arm when the vessel was accessible. After vacuum pumping, the effect of pressure change in the vacuum vessel was evaluated by observing the movement of the light spot from back-illuminated sightlines on the first wall using the newly developed articulated inspection arm. In addition, the rotation of the periscope after vacuum pumping was derived by using the Doppler shift of neutral beam emission spectra without magnetic field. Combining these techniques, improved spatial calibration was implemented to provide a complete and accurate description of the EAST CXRS system. Due to the effects of the change of air pressure, a ∼0.4° periscope rotation, yielding a ∼20 mm movement of the major radius of observation positions to the lower field side, was derived. Results of Zeeman splitting of neutral beam emission spectra with magnetic field also showed good agreement with the calibration results.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A LIS Validation Study at the KSC-ER using LDAR and Field Mill Data

The chance of having the TRMM satellite pass over east central Florida when there is lightning over the NASA Kennedy Space Center (KSC) and USAF Eastern Range (ER) is small; however, such a condition did occur on September 21, 1998 (Day 264). Starting at about 20:40 GMT, the Lightning Imaging Sensor (LIS) reported 5 flashes during a 90 second interval that the KSC-ER was within the sensor field of view. Ground-based instrumentation, the Lightning Detection and Ranging (LDAR) system and a network of electric field mills (FM), detected 6 flashes in the same interval. In this paper, we will compare the times and locations of the optical pulses that were detected by LIS with the times and locations of RF sources (LDAR) and the charges that were deposited by the flash (FM network). We will show that LIS responded to all flashes that the LDAR and FM network detected; however, two discharges that were separated by less than 1 second in time and by about 10 km in space were grouped as one flash by the LIS data processing algorithm. In spite of the fact that all flashes occurred near the edge of the LIS field of view, the locations of the LIS events were consistent with both the LDAR and FM locations (the latter are usually within 1-2 kilometers of each other and often are co-located). Two of the 5 flashes reported by LIS were shifted north by about 8 km from the corresponding LDAR and FM locations. The LIS flash times tended to be after the first LDAR pulse was detected and before the last, and the integrated light signal (per LIS event) was surprisingly constant over the 5 flashes that were detected by LIS. In the future, we plan to study more correlated events and will try to determine whether and how the LIS light signal is related to the charge transfer in the flash and/or the number and spatial extent of RF sources.

Koshak, William J.↗

Pulsar Pair Cascades in Magnetic Fields with Offset Polar Caps

Neutron star magnetic fields may have polar caps (PC) that are offset from the dipole axis, through field-line sweepback near the light cylinder or non-symmetric currents within the star. The effects of such offsets on electron-positron pair cascades are investigated, using simple models of dipole magnetic fields with small distortions that shift the PCs by different amounts or directions. Using a Monte Carlo pair cascade simulation, we explore the changes in the pair spectrum, multiplicity and energy flux across the PC, as well as the trends in pair flux and pair energy flux with spin-down luminosity, L(sub sd). We also give an estimate of the distribution of heating flux from returning positrons on the PC for different offsets. We find that even modest offsets can produce significant increases in pair multiplicity, especially for pulsars that are near or beyond the pair death lines for centered PCs, primarily because of higher accelerating fields. Pair spectra cover several decades in energy, with the spectral range of millisecond pulsars (MSPs) two orders of magnitude higher than for normal pulsars, and PC offsets allow significant extension of all spectra to lower pair energies. We find that the total PC pair luminosity L(sub pair) is proportional to L(sub sd), with L(sub pair) approximates 10(exp -3) L(sub sd) for normal pulsars and L(sub pair) approximates 10(exp -2) L(sub sd) for MSPs. Remarkably, the total PC heating luminosity for even large offsets increases by less than a factor of two, even though the PC area increases by much larger factors, because most of the heating occurs near the magnetic axis.

Harding, Alice K.↗

Small-angle light scattering symmetry breaking in polymer-dispersed liquid crystal films with inhomogeneous electrically controlled interface anchoring

We have described the method of analyzing and reporting on the results of calculation of the small-angle structure of radiation scattered by a polymer-dispersed liquid crystal film with electrically controlled interfacial anchoring. The method is based on the interference approximation of the wave scattering theory and the hard disk model. Scattering from an individual liquid crystal droplet has been described using the anomalous diffraction approximation extended to the case of droplets with uniform and nonuniform interface anchoring at the droplet–polymer boundary. The director field structure in an individual droplet is determined from the solution of the problem of minimizing the volume density of the free energy. The electrooptical effect of symmetry breaking in the angular distribution of scattered radiation has been analyzed. This effect means that the intensities of radiation scattered within angles +θ{sub s} and–θ{sub s} relative to the direction of illumination in the scattering plane can be different. The effect is of the interference origin and is associated with asymmetry of the phase shift of the wavefront of an incident wave from individual parts of the droplet, which appears due to asymmetry of the director field structure in the droplet, caused by nonuniform anchoring of liquid crystal molecules with the polymer on its surface. This effect is analyzed in the case of normal illumination of the film depending on the interfacial anchoring at the liquid crystal–polymer interface, the orientation of the optical axes of droplets, their concentration, sizes, anisometry, and polydispersity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Materials That Enhance Efficiency and Radiation Resistance of Solar Cells

A thin layer (approximately 10 microns) of a novel "transparent" fluorescent material is applied to existing solar cells or modules to effectively block and convert UV light, or other lower solar response waveband of solar radiation, to visible or IR light that can be more efficiently used by solar cells for additional photocurrent. Meanwhile, the layer of fluorescent coating material remains fully "transparent" to the visible and IR waveband of solar radiation, resulting in a net gain of solar cell efficiency. This innovation alters the effective solar spectral power distribution to which an existing cell gets exposed, and matches the maximum photovoltaic (PV) response of existing cells. By shifting a low PV response waveband (e.g., UV) of solar radiation to a high PV response waveband (e.g. Vis-Near IR) with novel fluorescent materials that are transparent to other solar-cell sensitive wavebands, electrical output from solar cells will be enhanced. This approach enhances the efficiency of solar cells by converting UV and high-energy particles in space that would otherwise be wasted to visible/IR light. This innovation is a generic technique that can be readily implemented to significantly increase efficiencies of both space and terrestrial solar cells, without incurring much cost, thus bringing a broad base of economical, social, and environmental benefits. The key to this approach is that the "fluorescent" material must be very efficient, and cannot block or attenuate the "desirable" and unconverted" waveband of solar radiation (e.g. Vis-NIR) from reaching the cells. Some nano-phosphors and novel organometallic complex materials have been identified that enhance the energy efficiency on some state-of-the-art commercial silicon and thin-film-based solar cells by over 6%.

Sun, Xiadong↗

Improvement of the interfacial Dzyaloshinskii-Moriya interaction by introducing a Ta buffer layer

We report systematic measurements of the interfacial Dzyaloshinskii-Moriya interaction (iDMI) by employing Brillouin light scattering in Pt/Co/AlO{sub x} and Ta/Pt/Co/AlO{sub x} structures. By introducing a tantalum buffer layer, the saturation magnetization and the interfacial perpendicular magnetic anisotropy are significantly improved due to the better interface between heavy metal and ferromagnetic layer. From the frequency shift between Stokes- and anti-Stokes spin-waves, we successively obtain considerably larger iDM energy densities (D{sub max} = 1.65 ± 0.13 mJ/m{sup 2} at t{sub Co} = 1.35 nm) upon adding the Ta buffer layer, despite the nominally identical interface materials. Moreover, the energy density shows an inverse proportionality with the Co layer thickness, which is the critical clue that the observed iDMI is indeed originating from the interface between the Pt and Co layers.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enhanced visible-light photocatalytic activity of Bi2O2CO3 nanoplates by Fe-doping in the degradation of rhodamine B

Highlights: • Fe-doped Bi{sub 2}O{sub 2}CO{sub 3} nanoplates were prepared using a solvothermal method. • Fe doping in Bi{sub 2}O{sub 2}CO{sub 3} was found to greatly decrease the corresponding band gap energy. • The photocatalytic activity of Fe-doped Bi{sub 2}O{sub 2}CO{sub 3} was significantly enhanced in the photocatalytic degradation of RhB. - Abstract: In this study, Fe-doped Bi{sub 2}O{sub 2}CO{sub 3} nanoplates were fabricated using a facile solvothermal approach. The successful substitution of Bi{sup 3+} by Fe{sup 3+} was identified by a shift in the (010) diffraction peak of Bi{sub 2}O{sub 2}CO{sub 3} at 2θ = 30.2°. A controllable amount of Fe doping in Bi{sub 2}O{sub 2}CO{sub 3} was utilized to gradually tailor the band gap energy from 3.39 eV to 2.68 eV, resulting in the absorption edge switched from ultraviolet light to visible-light region. Compared to the pure Bi{sub 2}O{sub 2}CO{sub 3}, Fe-doped Bi{sub 2}O{sub 2}CO{sub 3} nanoplates exhibited an enhanced visible-light photocatalytic activity. With the gradual increase of Fe dopant amount, the photocatlytic activity of Fe-doped Bi{sub 2}O{sub 2}CO{sub 3} increased initially, and then slightly decreased. Further reactive species trapping experiments demonstrated that holes (h{sup +}) and superoxide anion radicals (O{sub 2}{sup −}) played important roles in the photocatalytic oxidation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Self‐Trapped and Free Exciton Dynamics in Vacuum‐Deposited Cesium Copper Iodide Thin Films

Abstract Highly photoluminescent, lead‐free perovskites are of interest for displays and solid‐state light‐emitting devices. In this report, streak camera‐based time‐resolved emission and transient absorption spanning visible to deep‐ultraviolet (UV) wavelengths are utilized to study self‐trapped and free exciton dynamics in vacuum‐deposited cesium copper halide thin films of CsCu 2 I 3 and Cs 3 Cu 2 I 5 . Self‐trapped exciton emission of CsCu 2 I 3 exhibits more noticeable changes with time in the peak position and width than Cs 3 Cu 2 I 5 . UV‐to‐blue emission is detectable for both compositions, where free exciton emission is distinct for CsCu 2 I 3 . Transient absorption shows loss of ground‐state bleach signals at early time delays for both, and the bleach signal shifts toward higher energy as time delay increases, likely due to strains induced by the newly created self‐trapped excitons. Global analysis performed on the transient absorption results yields time constants in these materials that build an overall dynamic scheme. This work aids in building a complete picture regarding light emission in these promising materials.

36 MATERIALS SCIENCE↗

Comprehensive characterization of extracellular vesicles produced by environmental (Neff) and clinical (T4) strains of Acanthamoeba castellanii

We conducted a comprehensive comparative analysis of extracellular vesicles (EVs) from two Acanthamoeba castellanii strains, Neff (environmental) and T4 (clinical). Morphological analysis via transmission electron microscopy revealed slightly larger Neff EVs (average = 194.5 nm) compared to more polydisperse T4 EVs (average = 168.4 nm). Nanoparticle tracking analysis (NTA) and dynamic light scattering validated these differences. Proteomic analysis of the EVs identified 1,352 proteins, with 1,107 common, 161 exclusive in Neff, and 84 exclusively in T4 EVs. Gene ontology and Kyoto Encyclopedia of Genes and Genomes (KEGG) mapping revealed distinct molecular functions and biological processes and notably, the T4 EVs enrichment in serine proteases, aligned with its pathogenicity. Lipidomic analysis revealed a prevalence of unsaturated lipid species in Neff EVs, particularly triacylglycerols, phosphatidylethanolamines (PEs), and phosphatidylserine, while T4 EVs were enriched in diacylglycerols and diacylglyceryl trimethylhomoserine, phosphatidylcholine and less unsaturated PEs, suggesting differences in lipid metabolism and membrane permeability. Metabolomic analysis indicated Neff EVs enrichment in glycerolipid metabolism, glycolysis, and nucleotide synthesis, while T4 EVs, methionine metabolism. Furthermore, RNA-seq of EVs revealed differential transcript between the strains, with Neff EVs enriched in transcripts related to gluconeogenesis and translation, suggesting gene regulation and metabolic shift, while in the T4 EVs transcripts were associated with signal transduction and protein kinase activity, indicating rapid responses to environmental changes. In this novel study, data integration highlighted the differences in enzyme profiles, metabolic processes, and potential origins of EVs in the two strains shedding light on the diversity and complexity of A. castellanii EVs and having implications for understanding host-pathogen interactions and developing targeted interventions for Acanthamoeba-related diseases.

59 BASIC BIOLOGICAL SCIENCES↗