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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Hardness Assurance and Testing Techniques for High Resolution (12- to 16-bit) Analog-to-Digital Converters

Discussed are hardness assurance and testing techniques to test and evaluate total dose radiation degradation of high resolution A/D converters. Because high-speed, high-resolution converters are critical parts in a digital signal processing or data acquisition system, the evaluation of performance in the early design phase is very important. Converters from three manufacturers are evaluated.

Analog-to-Digital↗
NASA NTRS2021

Avionics Radiation Hardness Assurance (RHA) Guidelines

Based on the need to develop and adopt timely and up-to-date guidance to ensure that natural space radiation environment threats do not compromise mission success, the NASA Engineering and Safety Center (NESC) was solicited to develop and publish guidance for deriving radiation hardness assurance (RHA) requirements and for evaluating avionics hardware elements with respect to total ionizing dose, total non-ionizing dose, and single event effects. This document contains the outcome of the NESC assessment.

Guidelines↗
NASA NTRS2023

Composite Hard Upper Torso (CHUT) for xEMU Space Suit

The xEMU is the Exploration Mobility Unity or space suit designed for microgravity (cislunar and low earth orbit (LEO)) and lunar surface operations. This suit design allows crewmembers to perform extravehicular exploration, science, construction, maintenance, and contingency operations while unattached to a vehicle for life support in pressure and thermal environments that exceed human capability. The xEMU provides life support, environmental protection, and communications capabilities to the EVA crewmember while allowing sufficient mobility and visibility to perform dexterous EVA tasks. The effort documented in this paper, addressed the design, analysis, manufacturing, full-scale test article testing and validation for a Composite Hard Upper Torso(CHUT)unit. Design and analysis of the CHUT was based on measured B-basis properties of the selected S-glass/epoxy composite, and established final geometry, composite layup and interface details that met requirements. A complete manufacturing and assembly protocol was established for the CHUT starting from composite layup in the tool, to final assembly of all interface metal hardware prior to delivery to NASA for suit integration. Full-scale CHUT test articles underwent static and fatigue pressure testing (2 lifetimes), impact testing at critical stress locations for tool drop/microgravity scenarios, followed by post-impact fatigue testing. Effect of manufacturing defects was evaluated by manufacturing a full-scale CHUT with 0.375”/0.5” defects at critical stress locations, followed by static and life-cycle fatigue testing. In all cases, the CHUT design met or exceeded mass, structural, interface and functional requirements. Two (2) complete CHUT articles were delivered to NASA for full-scale suit integration and testing.

spacesuit↗
NASA NTRSDate not supplied

Design and Testing of a Hard-Fault Protection Circuit for a 1 kV SiC MOSFET Inverter

Due to increasingly high DC link voltages and further advancements in the current density of silicon carbide (SiC) MOSFETs, it has become evident that conventional IGBT protection methods are not sufficient to prevent exceeding the current rating of these devices during low-inductance fault events. This paper explores the use of an air core Rogowski coil topology to mitigate these hard fault events. The design of this circuit resulted in safe shutdown of a low impedance phase-to-phase fault in under one microsecond, tested up to DC link voltages of 1 kV. This paper details the theory, design, simulation, and successful test results of this method.

hard fault protection↗
NASA NTRS2024

Exploration Extravehicular Mobility Unit (xEMU) Hard Upper Torso (HUT) Chamber B Thermal Vacuum Testing Results

NASA’s Exploration Extravehicular Mobility Unit (xEMU) is the government reference next-generation spacesuit design and is engineered to protect astronauts from extreme lunar environmental temperatures. To evaluate the xEMU hardware thermal requirements, the xEMU Testing Team invented, designed, and executed a dual-suit, uncrewed thermal vacuum (TVAC) test at Johnson Space Center’s (JSC) Chamber B. This paper details the test methodology, hardware setup, and results from the xEMU hard upper torso (HUT). Two HUTs, one composite HUT and one aluminum HUT, were tested simultaneously in Chamber B, with different thermal environments. For the aluminum HUT on the Short xEMU (SxEMU) test article, five thermal profiles were tested during five simulated EVAs. For the composite HUT on the second xEMU, eleven unique thermal profiles were tested including both cold and hot environmental cases over the course of five continuous days of testing. The radiative thermal environment was controlled through exposure to liquid-nitrogen shrouds on the chamber walls and through two separate heater cages surrounding each respective test article. Seventy-two temperature sensors were used to collect data in critical locations in the xEMU HUT assembly. This paper will document the testing results and compare the test data against the xEMU HUT and system-level thermal models for model validation.

xEMU↗
DOE OSTI2011

Toward TW-Level, Hard X-Ray Pulses at LCLS

Coherent diffraction imaging of complex molecules such as proteins requires a large number (e.g., {approx} 10{sup 13}/pulse) of hard X-ray photons within a time scale of {approx} 10 fs or less. This corresponds to a peak power of {approx} 1 TW, much larger than that currently generated by LCLS or other proposed X-ray free electron lasers (FELs). We study the feasibility of producing such pulses using a LCLS-like, low charge electron beam, as will be possible in the LCLS-II upgrade project, employing a configuration beginning with a SASE amplifier, followed by a 'self-seeding' crystal monochromator, and finishing with a long tapered undulator. Our results suggest that TW-level output power at 8.3 keV is possible from a total undulator system length around 200 m. In addition power levels larger than 100 GW are generated at the third harmonic. We present a tapering strategy that extends the original 'resonant particle' formalism by optimizing the transport lattice to maximize optical guiding and enhance net energy extraction. We discuss the transverse and longitudinal coherence properties of the output radiation pulse and the expected output pulse energy sensitivity, both to taper errors and to power fluctuations on the monochromatized SASE seed.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

High‐Pressure Synthesis of Ultra‐Incompressible, Hard and Superconducting Tungsten Nitrides

Abstract Transition metal nitrides, particularly those of 5 d metals, are known for their outstanding properties, often relevant for industrial applications. Among these metal elements, tungsten is especially attractive given its low cost. In this high‐pressure investigation of the W–N system, two novel ultra‐incompressible tungsten nitride superconductors, namely W 2 N 3 and W 3 N 5 , are successfully synthesized at 35 and 56 GPa, respectively, through a direct reaction between N 2 and W in laser‐heated diamond anvil cells. Their crystal structure is determined using synchrotron single‐crystal X‐ray diffraction. While the W 2 N 3 solid's sole constituting nitrogen species are N 3‐ units, W 3 N 5 features both discrete N 3‐ as well as N 2 4‐ pernitride anions. The bulk modulus of W 2 N 3 and W 3 N 5 is experimentally determined to be 380(3) and 406(7) GPa, and their ultra‐incompressible behavior is rationalized by their constituting WN 7 polyhedra and their linkages. Importantly, both W 2 N 3 and W 3 N 5 are recoverable to ambient conditions and stable in air. Density functional theory calculations reveal W 2 N 3 and W 3 N 5 to have a Vickers hardness of 30 and 34 GPa, and superconducting transition temperatures at ambient pressure (50 GPa) of 11.6 K (9.8 K) and 9.4 K (7.2 K), respectively. Additionally, transport measurements performed at 50 GPa on W 2 N 3 corroborate with the calculations.

Chemistry↗
DOE OSTI2015

Electron Tomography: A Three-Dimensional Analytic Tool for Hard and Soft Materials Research

Three-dimensional (3D) structural analysis is essential to understand the relationship between the structure and function of an object. Many analytical techniques, such as X-ray diffraction, neutron spectroscopy, and electron microscopy imaging, are used to provide structural information. Transmission electron microscopy (TEM), one of the most popular analytic tools, has been widely used for structural analysis in both physical and biological sciences for many decades, in which 3D objects are projected into two-dimensional (2D) images. In many cases, 2D-projection images are insufficient to understand the relationship between the 3D structure and the function of nanoscale objects. Electron tomography (ET) is a technique that retrieves 3D structural information from a tilt series of 2D projections, and is gradually becoming a mature technology with sub-nanometer resolution. Distinct methods to overcome sample-based limitations have been separately developed in both physical and biological science, although they share some basic concepts of ET. Here, this review discusses the common basis for 3D characterization, and specifies difficulties and solutions regarding both hard and soft materials research. It is hoped that novel solutions based on current state-of-the-art techniques for advanced applications in hybrid matter systems can be motivated. Electron tomography produces quantitative 3D reconstructions for biological and physical sciences from sets of 2D projections acquired at different tilting angles in a transmission electron microscope. Finally, state-of-the-art techniques capable of producing 3D representations such as Pt-Pd core-shell nanoparticles and IgG1 antibody molecules are reviewed.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Superconducting Quantum Metamaterials from Convergence of Soft and Hard Condensed Matter Science

Superconducting quantum metamaterials are expected to exhibit a variety of novel properties, but have been a major challenge to prepare as a result of the lack of appropriate synthetic routes to high-quality materials. Here, the discovery of synthesis routes to block copolymer (BCP) self-assembly-directed niobium nitrides and carbonitrides is described. The resulting materials exhibit unusual structure retention even at temperatures as high as 1000 °C and resulting critical temperature, T c , values comparable to their bulk analogues. Applying the concepts of soft matter self-assembly, it is demonstrated that a series of four different BCP-directed mesostructured superconductors are accessible from a single triblock terpolymer. Resulting materials display a mesostructure-dependent T c without substantial variation of the XRDmeasured lattice parameters. Lastly, field-dependent magnetization measurements of a sample with double-gyroid morphology show abrupt jumps comparable in overall behavior to flux avalanches. Results suggest a fruitful convergence of soft and hard condensed matter science.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Lithium‐Pretreated Hard Carbon as High‐Performance Sodium‐Ion Battery Anodes

Abstract Hard carbon (HC) is the state‐of‐the‐art anode material for sodium‐ion batteries (SIBs). However, its performance has been plagued by the limited initial Coulombic efficiency (ICE) and mediocre rate performance. Here, experimental and theoretical studies are combined to demonstrate the application of lithium‐pretreated HC (LPHC) as high‐performance anode materials for SIBs by manipulating the solid electrolyte interphase in tetraglyme (TEGDME)‐based electrolyte. The LPHC in TEGDME can 1) deliver > 92% ICE and ≈220 mAh g −1 specific capacity, twice of the capacity (≈100 mAh g −1 ) in carbonate electrolyte; 2) achieve > 85% capacity retention over 1000 cycles at 1000 mA g −1 current density (4 C rate, 1 C = 250 mA g −1 ) with a specific capacity of ≈150 mAh g −1 , ≈15 times of the capacity (10 mAh g −1 ) in carbonate. The full cell of Na 3 V 2 (PO 4 ) 3 ‐LPHC in TEGDME demonstrated close to theoretical specific capacity of ≈98 mAh g −1 based on Na 3 V 2 (PO 4 ) 3 cathode, ≈2.5 times of the value (≈40 mAh g −1 ) with nontreated HC. This work provides new perception on the anode development for SIBs.

Xiao, Biwei↗
DOE OSTI2022

Combining Experimental and Theoretical Techniques to Gain an Atomic Level Understanding of the Defect Binding Mechanism in Hard Carbon Anodes for Sodium Ion Batteries

Sodium ion batteries (NIBs) are an attractive alternative to lithium–ion batteries in applications that require large–scale energy storage due to sodium's high natural abundance and low cost. Hard carbon (HC) is the most promising anode material for NIBs; however, there is a knowledge gap in the understanding of the sodium binding mechanism that prevents a rational design of HC. This study tunes sucrose–derived HC via synthesis temperature then evaluates the structural, physical, and electrochemical properties. Neutron total scattering is used to generate structural models by fitting pair distribution functions (PDF) with a combination of molecular dynamics and reverse Monte Carlo methods. From this model, the number and type of structural features are identified, quantified, and correlated to the galvanostatic charge/discharge. A method of PDF “fingerprinting” binding sites using Na probe atoms is developed and analyzing these PDFs reveals an atomistic view of ion binding sites responsible for “defect” storage mechanisms. Combining these techniques results in an atomic–level study that provides a big picture of the Na–binding mechanism in NIBs, which allows for more precise tuning of the structure–property relationships in the future. Finally, the methodologies developed will also enable new strategies for the analysis of amorphous functional materials.

25 ENERGY STORAGE↗
DOE OSTI2023

Revealing the Sodium Storage Mechanisms in Hard Carbon Pores

Abstract Hard carbon (HC) is the most promising anode for the commercialization of sodium‐ion batteries (NIBs); however, a general mechanism for sodium storage in HC remains unclear, obstructing the development of highly efficient anodes for NIBs. To elucidate the mechanism of sodium storage in the pores, operando synchrotron small‐angle X‐ray scattering, wide‐angle X‐ray scattering, X‐ray absorption near edge structure, Raman spectroscopy, and galvanostatic measurements are combined. The multimodal approach provides mechanistic insights into the sodium pore‐filling process for different HC microstructures including the pore sizes that are preferentially filled, the extent to which different pore sizes are filled, and how the defect concentration influences pore filling. It is observed that sodium in the larger pores has an increased pseudo‐metallic sodium character consistent with larger sodium clusters. Furthermore, it is shown that the HCs prepared at higher pyrolysis temperatures have a larger capacity from sodium stored in the pores and that sodium intercalation between graphene layers occurs simultaneously with the pore filling in the plateau region. Opportunities are outlined to improve the performance of HC anodes by fully utilizing the pores for sodium storage, helping to pave the way for the commercialization of sodium ion batteries.

Kitsu Iglesias, Luis↗
DOE OSTI2016

Synthesis of α-MoC 1- x Nanoparticles with a Surface-Modified SBA-15 Hard Template: Determination of Structure-Function Relationships in Acetic Acid Deoxygenation

Surface modification of mesoporous SBA-15 silica generated a hydrophobic environment for a molybdenum diamine (Mo-diamine) precursor solution, enabling direct growth of isolated 1.9 ± 0.4 nm α-MoC 1-x nanoparticles (NPs) inside the pores of the support. The resulting NP catalysts are bifunctional, and compared to bulk α-MoC 1-x and β-Mo 2 C, the NPs exhibit a greater acid-site:H-site ratio and a fraction of stronger acid sites. The greater acid-site:H-site ratio results in higher decarbonylation (DCO) selectivity during acetic acid hydrodeoxygenation (HDO) reactions, and the stronger acid sites lead to higher activity and ketonization (KET) selectivity at high temperatures. Lastly, the hard-templating synthetic method could be a versatile route toward carbide NPs of varying size, composition, and phase, on a range of mesoporous oxide supports.

09 BIOMASS FUELS↗
DOE OSTI2026

Simulating competition in the US bioeconomy to produce hard‐to‐electrify transportation fuels using limited biomass resources

This study presents a novel bioeconomy optimization framework, BiOpt, designed to address critical questions regarding the strategic use of limited US biomass resources for biofuel production. By integrating detailed techno-economic analyses, life cycle assessments, and resource assessment data, BiOpt optimizes resource distributions across competing technologies to maximize economic performance and/or minimize greenhouse gas emissions. Using feedstock scenarios from the 2023 Billion Ton Study, the analysis explores optimal biomass allocations across sustainable aviation fuel, diesel, and marine biofuel conversion pathways given varying production targets and policy incentives. Results demonstrate distinct feedstock preferences and pathway utilizations when prioritizing economic returns vs. emissions reductions. For instance, fats, oils, and greases were highly favored in cost-optimized scenarios, while low-carbon feedstocks such as wet waste dominated greenhouse gas-minimized strategies. The findings underscore the pivotal role of policy incentives and technological advances in shaping biofuel supply chains and provide actionable insights for scaling sustainable biofuel production to decarbonize hard-to-electrify sectors. This framework offers a robust tool for policymakers and stakeholders to evaluate biofuel strategies that balance energy output, economic viability, and environmental impact.

09 BIOMASS FUELS↗
DOE OSTI2018

Inference of the electron temperature in inertial confinement fusion implosions from the hard X-ray spectral continuum

Using the free-free continuum self-emission spectrum at photon energies above 15 keV is one of the most promising concepts for assessing the electron temperature in inertial confinement fusion (ICF) experiments. However, these photons are due to suprathermal electrons whose mean free path is much larger than the thermal one, making their distribution deviate from Maxwellian in a finite-size hotspot. Here, the first study of the free-free X-ray emission from an ICF implosion is conducted, accounting for the kinetic modifications to the electron distribution. These modifications are found to result in qualitatively new features in the hard X-ray spectral continuum. Finally, inference of the electron temperature as if the emitting electrons are Maxwellian is shown to give a lower value than the actual one.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Development and characterization of a wild emmer wheat backcross introgression population for hard winter wheat improvement

Abstract Wild emmer wheat (Triticum turgidumsubsp.dicoccoides) is the tetraploid progenitor of hexaploid bread wheat (Triticum aestivumL.) and is known to be a valuable source of genetic variation for wheat improvement. However, direct evaluation of wild emmer diversity for agronomic potential has limited value unless performed in the backgrounds of adapted cultivars. Here, we present a genetic characterization of a population of 1601 backcross recombinant inbred lines, with an average genome composition of 75% bread wheat and 25% wild emmer. Low‐coverage whole‐genome sequencing allowed introgressions and aneuploidies to be identified at a relatively low cost per sample. We identified a relatively large proportion of small introgressions (median length 38 Mb), and we found introgressions to be distributed across all chromosomes. Approximately 44% of genotyped progeny carried at least one aneuploidy, with monosomies being by far the most common. This population, which we have denoted as the Great Plains Wild Emmer/Hard Winter Wheat introgression population (GPWEW‐IP), is, to our knowledge, the first introgression population developed through the direct hybridization of wild emmer wheat and US‐adapted hard winter wheat. We believe that this population represents a valuable resource for wheat breeders and will accelerate the discovery and integration of useful variation from wild emmer wheat.

Genetics & Heredity↗
DOE OSTI2021

First saturation correction in high energy proton-nucleus collisions. Part II. Single inclusive semi-hard gluon production

Exploiting recently obtained analytic solutions of classical Yang-Mills equations for higher order perturbations in the field of the dilute object (proton), we derive the complete first saturation correction to the single inclusive semi-hard gluon production in high energy proton-nucleus collisions by applying the Lehmann-Symanzik-Zimmermann reduction formula. We thus finalize the program started by Balitsky (see ref. [1]) and independently by Chirilli, Kovchegov and Wertepny (see ref. [2]) albeit using a very different approach to carry out our calculations. We extracted the functional dependence of gluon spectrum on the color charge densities of the colliding objects; thus our results can be used to evaluate complete first saturation correction to the double/multiple inclusive gluon productions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2017

The static hard-loop gluon propagator to all orders in anisotropy

We calculate the (semi-)static hard-loop self-energy and propagator using the Keldysh formalism in a momentum-space anisotropic quark-gluon plasma. The static retarded, advanced, and Feynman (symmetric) self-energies and propagators are calculated to all orders in the momentum-space anisotropy parameter ξ. For the retarded and advanced self-energies/propagators, we present a concise derivation and comparison with previouslyobtained results and extend the calculation of the self-energies to next-to-leading order in the gluon energy, ω. For the Feynman self-energy/propagator, we present new results which are accurate to all orders in ξ. We compare our exact results with prior expressions for the Feynman self-energy/propagator which were obtained using Taylor-expansions around an isotropic state. Here, we show that, unlike the Taylor-expanded results, the all-orders expression for the Feynman propagator is free from infrared singularities. Finally, we discuss the application of our results to the calculation of the imaginary-part of the heavy-quark potential in an anisotropic quark-gluon plasma.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗