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At least 1,135 records · Page 63

Extracting and Interpreting Electrochemical Impedance Spectra (EIS) from Physics-Based Models of Lithium-Ion Batteries

This paper implements a highly efficient algorithm to extract electrochemical impedance spectra (EIS) from physics-based battery models (e.g., a P2D model). The mathematical approach is different from how EIS is practiced experimentally. Experimentally, the voltage (current) is harmonically perturbed over a wide range of frequencies and the amplitude and phase shift of the corresponding current (voltage) is measured. The experimental approach can be implemented in simulation software, but is computationally expensive. The approach here is to determine locally linear state-space models from the full physical model. The four Jacobian matrices that are the basis of the state-space models can be derived by numerical differentiation of the physical model. The EIS is then extracted from the state-space model using computationally efficient matrix-manipulation techniques. The algorithm can evaluate the full EIS at an instant in time during a transient, independent of whether the battery is in a stationary state. The approach is also able to separate the full-cell impedance to evaluate partial EIS, such as for a battery anode alone. Although such partial EIS is difficult to measure experimentally, the partial EIS provides valuable insights in interpreting the full-cell EIS.

25 ENERGY STORAGE↗

Observed changes in hydroclimate attributed to human forcing

Observational and modeling studies indicate significant changes in the global hydroclimate in the twentieth and early twenty-first centuries due to anthropogenic climate change. In this review, we analyze the recent literature on the observed changes in hydroclimate attributable to anthropogenic forcing, the physical and biological mechanisms underlying those changes, and the advantages and limitations of current detection and attribution methods. Changes in the magnitude and spatial patterns of precipitation minus evaporation (P–E) are consistent with increased water vapor content driven by higher temperatures. While thermodynamics explains most of the observed changes, the contribution of dynamics is not yet well constrained, especially at regional and local scales, due to limitations in observations and climate models. Anthropogenic climate change has also increased the severity and likelihood of contemporaneous droughts in southwestern North America, southwestern South America, the Mediterranean, and the Caribbean. An increased frequency of extreme precipitation events and shifts in phenology has also been attributed to anthropogenic climate change. While considerable uncertainties persist on the role of plant physiology in modulating hydroclimate and vice versa, emerging evidence indicates that increased canopy water demand and longer growing seasons negate the water-saving effects from increased water-use efficiency.

54 ENVIRONMENTAL SCIENCES↗

The Relationship Between Different VSAR Doppler Resolutions

It is often useful to think of the Doppler resolution of a vertical synthetic aperture radar in terms of the distance spanned by a resolution cell on the ground in unit meters, yet Doppler shift is fundamentally a measure of frequency, so there is a disconnect. This memo derives relationships between frequently invoked Doppler resolution expressions when they are expressed in ground-projected units (meters), angular units (radians), range-rate units (meters/second), and frequency units (Hertz).

47 OTHER INSTRUMENTATION↗

Multi-physics Topology OPtimization and Additive Manufacturing for High-temperature Heat Exchangers

This research significantly advances the understanding of high-temperature heat exchanger design through an integrated approach that combines topology optimization (TO), triply periodic minimal surface (TPMS) structures, additive manufacturing (AM) and thermohydraulic testing. Each of these components contributes uniquely to a unified, high-performance design, fabrication and testing workflow. Topology optimization serves as the foundation of the design methodology by providing a systematic way to determine the most effective material layout for separating hot and cold fluids while maximizing thermal performance. The researchers introduced a novel three-material optimization framework using two density fields to represent hot fluid, cold fluid, and solid domains. This approach enables automated discovery of optimal shapes and flow paths that cannot be intuitively designed, especially under constraints imposed by manufacturing technologies. Furthermore, constraints such as minimal wall thickness and overhang angles were embedded into the optimization process, ensuring that resulting designs are not only thermally efficient but also manufacturable using modern additive techniques. In parallel, the study delves into the use of Gyroid-based TPMS geometries for constructing the core of the heat exchanger. TPMS structures are known for their high surface area, excellent fluid mixing capabilities, and minimal pressure drop characteristics. The researchers applied a data-driven modeling framework using Heteroscedastic Sparse Gaussian Process Regression (HSGPR) combined with genetic algorithms. This allowed for the rapid evaluation and optimization of key geometric parameters such as frequency, iso-value, and phase shift. The result was a set of Gyroid structures tailored for high heat transfer and low flow resistance, demonstrating clear improvements over conventional straight-channel designs. After the designing process, additive manufacturing played a critical role by turning these highly complex, optimized geometries into physical components. Utilizing Laser Powder Bed Fusion (LPBF) with Haynes 282, the study demonstrated the feasibility of fabricating these heat exchangers at high precision. Post-processing methods, including dilation-erosion operations, were applied to ensure local features adhered to self-supporting constraints. The fabricated structures were then subjected to thermohydraulic testing under conditions representative of supercritical CO 2 Brayton cycles, validating the predicted performance and confirming the viability of the full design-to-fabrication pipeline. Finally, thermohydraulic testing across the above studies served as a crucial experimental validation of advanced heat exchanger. Under consistent high-temperature and high-pressure conditions using supercritical CO 2 , the testing demonstrated that both TO and Gyroid-based TPMS designs significantly outperformed conventional straight-channel HXs. The TO design achieved a 115% increase in UA and NTU and a 27.6% boost in gravimetric power density, while the data-driven optimized Gyroid design delivered a 166% increase in UA and NTU and improved effectiveness from 68.7% to 86.1%. These results validate the simulation models, confirm the manufacturability of complex geometries under AM constraints, and provide key insights into design-performance trade-offs, thereby advancing the development of high-efficiency, compact heat exchangers for extreme environments.

36 MATERIALS SCIENCE↗

Optimizing Magnetic Force Microscopy Resolution and Sensitivity to Visualize Nanoscale Magnetic Domains

Magnetic force microscopy (MFM) enables mapping local magnetic fields across a sample surface with nanoscale resolution. To perform MFM, an atomic force microscopy (AFM) probe whose tip has been magnetized vertically (i.e., perpendicular to the probe cantilever) is oscillated at a fixed height above the sample surface. The resultant shifts in the oscillation phase or frequency, which are proportional to the magnitude and sign of the vertical magnetic force gradient at each pixel location, are then tracked and mapped. Although the spatial resolution and sensitivity of the technique increases with decreasing lift height above the surface, this seemingly straightforward path to improved MFM images is complicated by considerations such as minimizing topographical artifacts due to shorter range van der Waals forces, increasing the oscillation amplitude to further improve sensitivity, and the presence of surface contaminants (in particular water due to humidity under ambient conditions). In addition, due to the orientation of the probe's magnetic dipole moment, MFM is intrinsically more sensitive to samples with an out-of-plane magnetization vector. Here, high-resolution topographical and magnetic phase images of single and bicomponent nanomagnet artificial spin-ice (ASI) arrays obtained in an inert (argon) atmosphere glovebox with <0.1 ppm O 2 and H 2 O are reported. Further, optimization of lift height and drive amplitude for high resolution and sensitivity while simultaneously avoiding the introduction of topographical artifacts is discussed, and detection of the stray magnetic fields emanating from either end of the nanoscale bar magnets (~250 nm long and <100 nm wide) aligned in the plane of the ASI sample surface is shown. Likewise, using the example of a Ni-Mn-Ga magnetic shape memory alloy (MSMA), MFM is demonstrated in an inert atmosphere with magnetic phase sensitivity capable of resolving a series of adjacent magnetic domains each ~200 nm wide.

47 OTHER INSTRUMENTATION↗

Electronic frequency discriminator

Digital comparator permits discrimination at accuracy of reference frequency. The compare circuit is a shift register element.

Reid, W. J.↗

Nuclear magnetic resonance properties of lunar samples.

Nuclear magnetic resonance spectra of Na-23, Al-27, and P-31 in fines samples 10084,60 and 14163,168 and in crystalline rock samples 12021,55 and 14321,166, have been recorded over a range of frequencies up to 20 MHz. A shift in the field at which maximum absorption occurs for all of the spectra relative to the field at which maximum absorption occurs for terrestrial analogues is attributed to a sample-dependent magnetic field at the Na, Al, and P sites opposing the laboratory field. The magnitude of these fields internal to the samples is sample dependent and varies from 5 to 10 G. These fields do not correlate with the iron content of the samples. However, the presence of single-domain particles of iron distributed throughout the plagioclase fraction that contains the principal fraction of Na and Al is inferred from electron magnetic resonance spectra shapes.

Kline, D.↗

Skylab electronic technological advancements

The present work describes three electronic devices designed for use in the Skylab airlock module: the teleprinter system, the quartz crystal microbalance contamination monitor (QCM), and the speaker. Design considerations, operation, characteristics, and system development are described for these systems, with accompanying diagrams, graphs, and photographs. The teleprinter is a thermal dot printer used to produce hard copy messages by electrically heating print elements in contact with heat-sensitive paper. The QCM was designed to estimate contamination buildup on optical surfaces of the earth resources experiment package. A vibrating quartz crystal is used as a microbalance relating deposited mass to shifts in the crystal's resonant frequency. Audio devices provide communication between crew members and between crew and STDN, and also provide audible alarms, via the caution and warning system, of out-of-limit-conditions.

Hornback, G. L.↗

Jovian electron bursts - Correlation with the interplanetary field direction and hydromagnetic waves

The bursts of relativistic electrons detected on Pioneer 10 upstream from Jupiter and within 400 Jovian radii of the planet have been found to be correlated with the interplanetary magnetic field. In three examples, electrons with energies between 3 and 6 MeV escaping from Jupiter's magnetosphere were observed only when the interplanetary magnetic field was along the Jupiter-spacecraft line. Large-amplitude interplanetary waves with characteristic periods of 10 min were found to be well correlated with intervals during which the field was along the Jupiter-spacecraft line. Abrupt changes in the field away from the preferred direction caused equally abrupt terminations of the waves with an accompanying reduction in the electron flux. These results are consistent with propagation of the electrons from Jupiter to Pioneer along the magnetic field lines. Hydromagnetic wave generation by Jovian charged particles, presumably the relativistic electrons themselves, as they travel upstream, appears to be an attractive explanation for the origin of the waves. At the observed frequency, hydromagnetic waves are Doppler-shifted to the gyrofrequency of the relativistic electrons. A plasma instability that appears capable of explaining the observations is a cyclotron overstability that occurs when the velocity of runaway electrons exceeds the velocity of hydromagnetic waves.

Smith, E. J.↗

Directional laser velocimeter with doppler velocity simulator

Technique uses phase-shift networks at optical and baseband frequencies and, as such, is optical adaptation of previously-existing microwave technology. Application is planned for wind-tunnel velocity measurements. Alternative configuration produces finite fringes that move in one direction or other as measured particle approaches or recedes.

Franke, J. M.↗

A source of plasma turbulence at the ionopause of Venus

The microscopic aspects of the interaction of the solar wind with the ionosphere of Venus are explored, in light of simultaneous suprathermal ion and low frequency electric field signal measurements by Pioneer Venus instruments which suggest that the two ionopause phenomena may be causally related. Both parallel and perpendicular propagating waves are examined for instability, in the presence of planetary ions added to the flowing ionosheath plasma, by linear Vlasov theory. While for the low beta plasma conditions of the ionopause neither electrostatic nor electromagnetic parallel propagating waves are found to be unstable, perpendicular propagating electrostatic waves are unstable and have the proper frequency-wavelength relation to be Doppler shifted into the observed 100-Hz channel.

Daniell, R. E., Jr.↗

A search for the Sunyaev-Zel'dovich effect at millimeter wavelengths

It is believed that X-ray emission from clusters of galaxies represents thermal bremsstrahlung from a hot plasma. According to Sunyaev and Zel'dovich (1972), the plasma column density and temperature derived from this model imply a measurable distortion of the cosmic background radiation (CBR) in the cluster direction. This distortion results from the Compton scattering of the CBR photons by the electrons in the plasma, resulting in an average increase of each photon. This process, known as the Sunyaev-Zel'dovich effect, is photon conserving and 'shifts' the CBR spectrum to higher frequencies. The result is a decrease of flux at frequencies below 7.5 per cm (the Rayleigh-Jeans region), and an increase above. The investigation is concerned with measurements of the Sunyaev-Zel'dovich effect at frequencies in the range from 3 to 10 per cm. Attention is given to the employed observing and analysis technique, and an initial null result for the cluster Abell 1795.

Meyer, S. S.↗

A review of ionospheric effects on Earth-space propagation

A short description is given of each ionospheric total electron content (TEC) effect upon radio waves, along with a representative value of the magnitude of each of these effects under normal ionospheric conditions. A discussion is given of the important characteristics of average ionospheric TEC behavior and the temporal and spatial variability of TEC. Radio waves undergo several effects when they pass through the Earth's ionosphere. One of the most important of these effects is a retardation, or group delay, on the modulation or information carried on the radio wave that is due to its encounter with the free, thermal electrons in the Earth's ionosphere. Other effects the ionosphere has on radio waves include: radio frequency (RF) carrier phase advance; Doppler shift of the RF carrier of the radio wave; Faraday rotation of the plane of polarization of linearly polarized waves; angular refraction or bending of the radio wave path as it travels through the ionosphere; and amplitude and phase scintillations.

Klobuchar, J. A.↗

Crystal Oscillators Operate Beyond Rated Frequencies

Amplifiers with single-pole frequency responses used in their "roll-off" regions. Class of crystal oscillators based on use of negative-voltage-gain amplifiers at frequencies well into "roll-off" frequency regions of their gain-versus-frequency curves. Defining characteristic helps keep costs of oscillators low; not necessary to use more expensive amplifiers that have flat frequency responses out to desired operating frequencies. Enables amplifier to produce phase shift necessary for oscillation, reducing cost further by eliminating need for some of passive components in oscillators of more conventional design.

Kleinberg, Leonard L.↗

An evaluation of some alternative approaches for reducing fan tone noise

The potential of two alternative approaches for reducing fan ton noise was investigated in this study. One of these approaches increases the number of rotor blades to shift the tone noise to higher frequencies that are not rated as strongly by the perceived noise scale. This alternative fan also would have a small number of long chord stator vanes which would reduce the stator response and lower rotor-stator interaction noise. Comparison of the conventional and alternative fan concepts showed that this alternative approach has as large or larger a perceived tone noise reduction potential as the conventional approach. The other alternative, a high Mach number inlet, is evaluated both for its noise attenuation and for its change in noise directivity.

Dittmar, James H.↗

Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons - Effect of ionization

In order to test the hypothesis of ionized PAHs as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.

De Frees, D. J.↗

Convectively generated stratospheric gravity waves - The role of mean wind shear

A two-dimensional numerical simulation of mid-latitude squall lines is used to study the properties of storm-induced stratospheric gravity waves. Owing to the tendency for convective cells to form at the forward edge of a squall line, and then propagate toward the rear, the simulated storms preferentially generate gravity waves that propagate toward the rear of the storm. This anisotropy in gravity wave generation leads to a net vertical transfer of momentum into the stratosphere. Cases with and without stratospheric mean wind shear are compared. In the latter case Doppler shifting of the waves to lower frequencies leads to wave breaking and enhanced wave - mean-flow interaction.

Holton, J. R.↗

Experimental study of the use of vortex generators to reduce fluctuating pressure loads in shock wave turbulent boundary layer interactions

Fluctuating wall pressure measurements have been made in a separated shock wave/turbulent boundary layer interaction produced by an unswept compression corner in a Mach 5 flow. Wheeler doublet vortex generators were placed 15.8 boundary layer thicknesses upstream of the corner to study their effect on the fluctuating pressure loads produced by the translating separation shock. The vortex generators produced significant three-dimensionality in an otherwise two-dimensional interaction. They reduced the upstream influence and the length of the region of shock motion by 60% and 64%, respectively, decreased the maximum wall pressure rms by 23%, and shifted the fluctuations to a higher frequency band. The maximum fraction of energy in the 100-500 Hz frequency band is decreased by 11%. These changes are due to a fuller boundary layer profile, a weaker separation shock, and increased boundary layer turbulence causing increased separation shock jitter.

Barter, John W.↗