Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “fourier analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Optical Properties of Iron Silicates in the Infrared to Millimeter as a Function of Wavelength and Temperature

The Optical Properties of Astronomical Silicates with Infrared Techniques program utilizes multiple instruments to provide spectral data over a wide range of temperatures and wavelengths. Experimental methods include Vector Network Analyzer and Fourier transform spectroscopy transmission, and reflection/scattering measurements. From this data, we can determine the optical parameters for the index of refraction, n, and the absorption coefficient, k. The analysis of the laboratory transmittance data for each sample type is based upon different mathematical models, which are applied to each data set according to their degree of coherence. Presented here are results from iron silicate dust grain analogs, in several sample preparations and at temperatures ranging from 5 to 300 K, across the infrared and millimeter portion of the spectrum (from 2.5 to 10,000/micron or 4000 to 1/cm).

Dust↗
NASA NTRS2019

A Study of the 20 Day Superorbital Modulation in the High-Mass X-Ray Binary IGR J16493-4348

We report on Nuclear Spectroscopic Telescope Array (NuSTAR), Neil Gehrels Swift Observatory(Swift) X-ray Telescope (XRT), and Swift Burst Alert Telescope (BAT) observations of IGR J16493-4348, a wind-fed supergiant X-ray binary showing significant superorbital variability. From a discrete Fourier transform of the BAT light curve,we refine its superorbital period to be 20.058±0.007 days. The BAT dynamic power spectrum and a fractional root mean square analysis both show strong variations in the amplitude of the superorbital modulation, but no observed changes in the period are found. The superorbital modulation is significantly weaker between MJD 55,700 and MJD 56,300. The joint NuSTAR and XRT observations, which were performed near the minimum and maximum of one cycle of the 20 day superorbital modulation, show that the flux increases by more than a factor of two between superorbital minimum and maximum. We find no significant changes in the 3-50 keV pulse profiles between superorbital minimum and maximum, which suggests a similar accretion regime. Modeling the pulse-phase-averaged spectra we find a possible Fe Kα emission line at 6.4 keV at superorbital maximum. This feature is not significant at superorbital minimum. While we do not observe any significant differences between the pulse-phase-averaged spectral continua apart from the overall flux change, we find that the hardness ratio near the broad main peak of the pulse profile increases from superorbital minimum to maximum. This suggests the spectral shape hardens with increasing luminosity. We discuss different mechanisms that might drive the observed superorbital modulation.

Coley, Joel B.↗
NASA NTRS2020

Aerodynamic Parameter Estimation Using Reconstructed Turbulence Measurements

A classical method for reconstructing atmospheric turbulence from onboard measurements of airdata and inertial sensors was improved and implemented for real-time computation. The reconstructed turbulence measurements were then included in a system identification analysis to estimate nondimensional stability and control derivatives in a longitudinal short period model using the maximum likelihood equation-error method in the frequency domain with Fourier-transform data. Flight test results using a subscale transport-type airplane showed that the power spectra for the reconstructed vertical gusts resembled the von Kármán turbulence model. Flight data in moderate and severe turbulence exhibited a decorrelation of the modeling data that increased the accuracy of parameter estimation results using the reconstructed turbulence. In particular, pitch rate and angle-of-attack rate derivatives could both be identified from flight data about straight and level flight without special maneuvers or prior information.

Jared A Grauer↗
NASA NTRSDate not supplied

Composition Reanalyses at NASA’s Global Modeling and Assimilation Office

Scientific Assessments of Ozone Depletion 2018 and 2022 report the recovery of Antarctic ozone, consistent with diminishing concentrations of halogens in the stratosphere. Both the size and the depth of the springtime ozone holes exhibit downward trends, particularly in September. Superimposed on the recovery trend are significant year-to-year fluctuations arising from dynamical variability potentially influenced by climate forcing and volcanic eruptions. Since 2018 the Antarctic stratosphere has experienced a wild parade of austral spring seasons with a sudden stratospheric warming and exceptionally high ozone in 2019 followed by large and long-lasting ozone holes in the following years, prompting questions about the speed and detectability of Antarctic ozone recovery and its potential connections to human-induced climate change. From the Australian New Years’ wildfires of 2020 to volcanic aerosols to the unprecedented injection of water vapor by the Hunga volcanic eruption, recent scientific literature on the subject investigates many factors that may or may not have contributed to this remarkable interannual variability. This presentation summarizes dynamical influences on springtime Antarctic stratospheric ozone in recent years and discusses these results in the context of long-term trends. In particular, this work seeks to isolate dynamical and chemical contributions to the Antarctic springs since 2019 using a consistent methodological framework. Our analysis uses constituent and meteorological fields from the MERRA-2 Stratospheric Composition Reanalysis of Aura MLS (M2-SCREAM) in combination with data from the Atmospheric Chemistry Experiment – Fourier Transform Spectrometer and from ozone sondes. Using the high spatial and temporal resolution of M2-SCREAM, we analyze the daily evolution of southern polar ozone, HCl, N2O, and water vapor in dynamical flow-following coordinates relative to the location, size, and shape of the polar vortex. For vertically integrated stratospheric ozone we emphasize the importance of the wave-influenced geometry of the polar vortex and its vertical alignment. The ultimate purpose of this project is to contribute to the quantification of the speed of the Antarctic ozone recovery and associated uncertainties.

Krzysztof Wargan↗
NASA NTRS1992

Bispectral analysis of equatorial spread F density irregularities

Bispectral analysis has been applied to density irregularities at frequencies 5-30 Hz observed with a sounding rocket launched from Peru in March 1983. Unlike the power spectrum, the bispectrum contains statistical information about the phase relations between the Fourier components which make up the waveform. In the case of spread F data from 475 km the 5-30 Hz portion of the spectrum displays overall enhanced bicoherence relative to that of the background instrumental noise and to that expected due to statistical considerations, implying that the observed f exp -2.5 power law spectrum has a significant non-Gaussian component. This is consistent with previous qualitative analyses. The bicoherence has also been calculated for simulated equatorial spread F density irregularities in approximately the same wavelength regime, and the resulting bispectrum has some features in common with that of the rocket data. The implications of this analysis for equatorial spread F are discussed, and some future investigations are suggested.

Labelle, J.↗
DOE OSTI2026

Jahn–Teller distortion controls electron transfer in photoexcited Cu( I ) donor–acceptor systems

The Jahn–Teller distortion (JTD) is a defining structural response to electronic excitation in Cu( I )-based transition metal complexes, yet its role in photoinduced electron transfer (PET) remains largely unexplored. Here, we demonstrate that the JTD governs charge separation (CS) through a vibronically controlled conical intersection in heteroleptic Cu( I ) bisphenanthroline–naphthalene diimide (CuHETPHEN-NDI) donor–acceptor dyads. Using 20-fs broadband transient absorption spectroscopy combined with coherent vibrational wavepacket (CVWP) analysis and quantum chemical calculations, we directly track nuclear motions that steer the system from the metal-to-ligand charge-transfer ( 1 MLCT) state to the CS state. Steric bulkiness of the pendant groups at the 2,9-positions of the phenanthroline ligand systematically slows both JTD and CS. Short-time Fourier transformation and Fourier filtering analyses identify two key vibrational signatures: a low-frequency breathing mode (∼100 cm −1 ) via a bond distance change between Cu and ligated Ns (Cu–N) that modulates the NDI anion absorption and acts as a vibronic coupling coordinate, and a higher-frequency mode (∼313 cm −1 ) that evolves along the PET trajectory. Normal mode analysis and potential energy surface calculations show that the JTD brings the 1 MLCT and CS states into degeneracy, while the Cu–N breathing motion dynamically modulates donor–acceptor electronic coupling to enable ultrafast nonadiabatic electron transfer. Steric hindrance exerted by the groups at the 2,9 positions of the phenanthroline ligands suppresses this vibronic coupling, leading to faster CVWP decoherence for the 313 cm −1 mode and slower CS. These findings unravel JTD-controlled vibronic coupling at conical intersection as a governing factor for CS and provide insight into designing Cu-based photosensitizers by harnessing structural dynamics to control PET.

Kim, Pyosang [Argonne National Laboratory (ANL), A↗
DOE OSTI2023

Likelihood-based signal and noise analysis for docking of models into cryo-EM maps

Fast, reliable docking of models into cryo-EM maps requires understanding of the errors in the maps and the models. Likelihood-based approaches to errors have proven to be powerful and adaptable in experimental structural biology, finding applications in both crystallography and cryo-EM. Indeed, previous crystallographic work on the errors in structural models is directly applicable to likelihood targets in cryo-EM. Likelihood targets in Fourier space are derived here to characterize, based on the comparison of half-maps, the direction- and resolution-dependent variation in the strength of both signal and noise in the data. Because the signal depends on local features, the signal and noise are analysed in local regions of the cryo-EM reconstruction. The likelihood analysis extends to prediction of the signal that will be achieved in any docking calculation for a model of specified quality and completeness. A related calculation generalizes a previous measure of the information gained by making the cryo-EM reconstruction.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Tailoring the Interfacial Interactions of Porous Polymer Membranes to Accelerate Atomic Layer Deposition: The Latent Path to Antifouling Membranes

Atomic layer deposition (ALD) is a powerful strategy to engineer hybrid organic-inorganic membranes with emergent functionalities. The combination of atomic-level thickness control, a wide materials palette, and unprecedented conformality allows the physiochemical properties (e.g., hydrophilicity) of mesoporous polymer membranes to be precisely tuned. The nucleation of ALD material growth on polymer surfaces relies on Lewis acid-base interactions and remains an overlooked motif with tremendous potential to accelerate ALD nucleation and growth. Strategies to enhance these interactions could enable desirable properties such as antifouling behavior to be imparted on inert polymer surfaces that lack the necessary functional groups for ALD nucleation. Here, in this study, we demonstrate that the reactivity of polyacrylonitrile (PAN) membranes toward ALD metal oxide (MO) precursors with Lewis acid characteristics is enhanced by introducing strong Lewis base functional groups (amidoxime: Am) on the PAN backbone (Am-PAN). The resulting Lewis acid-base interactions accelerate the MO nucleation in Am-PAN and reduce the number of deposition cycles required to achieve hydrophilicity compared with the untreated PAN membrane. Unveiling the reaction mechanism, in situ Fourier transform infrared (FTIR) spectroscopy measurements established enhanced interaction dynamics between the ALD MO precursors and the Am-PAN membrane, unlike the PAN membrane. Spectroscopic ellipsometry and thermogravimetric analysis measurements revealed higher MO loadings in Am-PAN membranes compared to PAN membranes for the same number of ALD cycles. We found that strong Lewis acid-base interactions accelerated the ALD for a range of materials including Al 2 O 3 , TiO 2 , SnO 2 , and ZnO. More broadly, our work demonstrates that tailoring metal-precursor-polymer interactions is a powerful strategy to accelerate and modulate the ALD. We used this design strategy to fabricate Al 2 O 3 -Am-PAN hybrid membranes that showed 2-fold higher antifouling capability compared to pristine PAN membranes prepared with an equivalent number of Al 2 O 3 ALD cycles. Our approach expands the scope of design options for fouling-resistant porous hybrid inorganic-organic membranes and may ultimately reduce the operational costs of water treatment.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Evaluation of Common Thermoplastic Polymers in High-Pressure Cycling Hydrogen Under Ambient and Cold Environments as Applicable to the Hydrogen Infrastructure

Thermoplastic polymers are required to perform unfailingly under stringent conditions of changing pressures (35 MPa to 70 MPa) and temperatures (-40°C to +85°C) in storage and fueling operations. Although diffusivity in glassy polymers appear to be an order of magnitude lower than elastomers, polymer microstructural attributes such as degree of crystallinity and presence of polar and non-polar groups on the main chain with and without branching can play a substantial role in influencing their behaviors in hydrogen environments. In the work described here, the effect of high-pressure hydrogen cycling on PEEK, PTFE, PA11, HDPE, POM (and different commercial grades of these polymers) under ambient and cold (-40°C) conditions is addressed. Ex-situ characterization for polymer changes included density measurements for impact of hydrogen retention, hardness changes using nanoindentation, storage modulus and glass transition changes using dynamic mechanical and thermal analysis (DMTA), degree of crystallization with Differential Scanning Calorimetry (DSC) and tensile testing following ASTM D412. In other evaluations, solid-state nuclear magnetic resonance (NMR), attenuated total reflectance Fourier transform infra-red spectroscopy (ATRFTIR), X-ray diffraction (XRD), and X-ray CT results are presented. The overall impact of these evaluations is to establish a technical basis for the behaviors of common thermoplastics in cycling hydrogen environments under ambient and cold temperatures while establishing the relationship between polymer structure-based properties and hydrogen transport effects.

Menon, Nalini C.↗
DOE OSTI2023

Cell wall response of field grown Populus to Septoria infection

Due to its ability to spread quickly and result in tree mortality, Sphaerulina musiva (Septoria) is one of the most severe diseases impacting Populus . Previous studies have identified that Septoria infection induces differential expression of phenylpropanoid biosynthesis genes. However, more extensive characterization of changes to lignin in response to Septoria infection is lacking. To study the changes of lignin due to Septoria infection, four field grown, naturally variant Populus trichocarpa exhibiting visible signs of Septoria infection were sampled at health, infected, and reaction zone regions for cell wall characterization. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), and acid hydrolysis were applied to identify changes to the cell wall, and especially lignin. FTIR and subsequent principal component analysis revealed that infected and reaction zone regions were similar and could be distinguished from the non-infected (healthy) region. NMR results indicated the general trend that infected region had a higher syringyl:guaiacyl ratio and lower p -hydroxybenzoate content than the healthy regions from the same genotype. Finally, Klason lignin content in the infected and/or reaction zone regions was shown to be higher than healthy region, which is consistent with previous observations of periderm development and metabolite profiling. These results provide insights on the response of Populus wood characteristics to Septoria infection, especially between healthy and infected region within the same genotype.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1974

Single-tone parameter estimation from discrete-time observations

Estimation of the parameters of a single-frequency complex tone from a finite number of noisy discrete-time observations is discussed. The appropriate Cramer-Rao bounds and maximum-likelihood (ML) estimation algorithms are derived. Some properties of the ML estimators are proved. The relationship of ML estimation to the discrete Fourier transform is exploited to obtain practial algorithms. The threshold effect of one algorithm is analyzed and compared to simulation results. Other simulation results verify other aspects of the analysis.

Rife, D. C.↗
NASA NTRS1986

The nonlinear development of Gortler vortices in growing boundary layers

The development of Gortler vortices in boundary layers over curved walls in the nonlinear regime is investigated. The growth of the boundary layer makes a parallel flow analysis impossible except in the high wavenumber regime so in general the instability equations must be integrated numerically. Here the spanwise dependence of the basic flow is described using Fourier series expansion whilst the normal and streamwise variations are taken into account using finite differences. The calculations suggest that a given disturbance imposed at some position along the wall will eventually reach a local equilibrium state essentially independent of the initial conditions. In fact, the equilibrium state reached is qualitatively similar to the large amplitude high wave-number solution described asymptotically by Hall (1982). In general, it is found that the nonlinear interactions are dominated by a mean field type of interaction between the mean flow and the fundamental. Thus, even though higher harmonics of the fundamental are necessarily generated, most of the disturbance energy is confined to the mean flow correction and the fundamental. A major result of the calculations is finding that the downstream velocity field develops a strongly inflection character as the flow moves downstream. The latter result suggests that the major effect of Gortler vortices on boundary layers of practical importance might be to make them highly receptive to rapidly growing Rayleigh modes of instability.

Hall, Philip↗
NASA NTRS1988

The nonlinear development of Goertler vortices in growing boundary layers

The development of Goertler vortices in boundary layers over curved walls in the nonlinear regime is investigated. The growth of the boundary layer makes a parallel flow analysis impossible except in the high wavenumber regime so in general the instability equations must be integrated numerically. Here the spanwise dependence of the basic flow is described using Fourier series expansion while the normal and streamwise variations are taken into account using finite differences. The calculations suggest that a given disturbance imposed at some position along the wall will eventually reach a local equilibrium state essentially independent of the initial conditions. In fact, the equilibrium state reached is qualitatively similar to the large amplitude high wave-number solution described asymptotically by Hall (1982). In general, it is found that the nonlinear interactions are dominated by a mean field type of interaction between the mean flow and the fundamental. Thus, even though higher harmonics of the fundamental are necessarily generated, most of the disturbance energy is confined to the mean flow correction and the fundamental. A major result of the calculations is finding that the downstream velocity field develops a strongly inflectional character as the flow moves downstream. The latter result suggests that the major effect of Goertler vortices on boundary layers of practical importance might be to make them highly receptive to rapidly growing Rayleigh modes of instability.

Hall, Philip↗
NASA NTRS1990

Resolution of the 1D regularized Burgers equation using a spatial wavelet approximation

The Burgers equation with a small viscosity term, initial and periodic boundary conditions is resolved using a spatial approximation constructed from an orthonormal basis of wavelets. The algorithm is directly derived from the notions of multiresolution analysis and tree algorithms. Before the numerical algorithm is described these notions are first recalled. The method uses extensively the localization properties of the wavelets in the physical and Fourier spaces. Moreover, the authors take advantage of the fact that the involved linear operators have constant coefficients. Finally, the algorithm can be considered as a time marching version of the tree algorithm. The most important point is that an adaptive version of the algorithm exists: it allows one to reduce in a significant way the number of degrees of freedom required for a good computation of the solution. Numerical results and description of the different elements of the algorithm are provided in combination with different mathematical comments on the method and some comparison with more classical numerical algorithms.

Liandrat, J.↗
NASA NTRS1990

Maximum likelihood estimates of polar motion parameters

Two estimators developed by Jeffreys (1940, 1968) are described and used in conjunction with polar-motion data to determine the frequency (Fc) and quality factor (Qc) of the Chandler wobble. Data are taken from a monthly polar-motion series, satellite laser-ranging results, and optical astrometry and intercompared for use via interpolation techniques. Maximum likelihood arguments were employed to develop the estimators, and the assumption that polar motion relates to a Gaussian random process is assessed in terms of the accuracies of the estimators. The present results agree with those from Jeffreys' earlier study but are inconsistent with the later estimator; a Monte Carlo evaluation of the estimators confirms that the 1968 method is more accurate. The later estimator method shows good performance because the Fourier coefficients derived from the data have signal/noise levels that are superior to those for an individual datum. The method is shown to be valuable for general spectral-analysis problems in which isolated peaks must be analyzed from noisy data.

Wilson, Clark R.↗
NASA NTRS1993

Gravity wave forcing in the middle atmosphere due to reduced ozone heating during a solar eclipse

We present an analysis of the gravity wave structure and the associated forcing of the middle atmosphere induced by the screening of the ozone layer from solar heating during a solar eclipse. Fourier integral techniques and numerical evaluation of the integral solutions were used to assess the wave field structure and to compute the gravity wave forcing of the atmosphere at greater heights. Our solutions reveal dominant periods of a few hours, characteristic horizontal and vertical scales of about 5000 to 10,000 km and 200 km, respectively, and an integrated momentum flux in the direction of eclipse motion of about 5.6 x 10 exp 8 N at each height above the forcing level. These results suggest that responses to solar eclipses may be difficult to detect above background gravity wave and tidal fluctuations until well into the thermosphere. Conversely, the induced body forces may penetrate to considerable heights because of the large wave scales and will have significant effects at levels where the wave field is dissipated.

Fritts, David C.↗
NASA NTRS2000

The intensities of methane in the 3-5 mu m region revisited

The analysis of the linestrengths of the infrared spectrum of methane (12 and 13) in the 3-5 mu m region has been revisited onthe basis of new measurements from Fourier transform spectra recorded at Kitt Peak under various optical densities.

Methane High resolution Infrared Absolute intensit↗
NASA NTRS2013

Optical Properties of Iron Silicates in the Infrared to Millimeter as a Function of Wavelength and Temperature

The Optical Properties of Astronomical Silicates with Infrared Techniques (OPASI-T) program utilizes multiple instruments to provide spectral data over a wide range of temperature and wavelengths. Experimental methods include Vector Network Analyzer (VNA) and Fourier Transform Spectroscopy (FTS) transmission, and reflection/scattering measurements. From this data, we can determine the optical parameters for the index of refraction, n, and the absorption coefficient, k. The analysis of the laboratory transmittance data for each sample type is based upon different mathematical models, which are applied to each data set according to their degree of coherence. Presented here are results from iron silicate dust grain analogs, in several sample preparations and at temperatures ranging from 5-300 K, across the infrared and millimeter portion of the spectrum (from 2.5-10,000 μm or 4,000-1 cm(exp −1).

Optical↗