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At least 1,135 records · Page 63

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DOE OSTI2023

Resonator-based ion-selective sensor

The present disclosure relates to systems and methods suitable to measure trace amounts of specific ions in fluid samples. An example system includes a resonator having an input coupler and an output coupler. The example system also includes an ion-selective membrane (ISM) optically coupled to at least a portion of the resonator. The system additionally includes a light source configured to illuminate the resonator by way of the input coupler. Furthermore, the system includes a detector configured to receive output light by way of the output coupler and provide information indicative a concentration of a specific ion proximate to tire ISM.

Zhang, Xufeng↗

DOE OSTI2023

Targeted near-infrared imaging by metal-organic frameworks

Metal-organic frameworks (MOFs) comprising amines on the organic linker can be used for cell targeting. In particular, primary amine groups represent one of the most versatile chemical moieties for conjugation to biologically relevant molecules, including antibodies and enzymes. Different chemical conjugation schemes can be used to conjugate biological molecules to the amino functionality on the organic linker. For example, carbodiimide chemistry can be used to link a primary amine to available carboxyl groups on the protein. For example, sulfhydryl crosslinking chemistry can be used via Traut's reagent scheme. As a demonstration of the invention, the ability of EpCAM antibody-targeted MOFs to bind to a human epithelial cell line (A549), a common target for imaging studies, was confirmed with confocal microscopy.

Sava Gallis, Dorina F.↗

DOE OSTI2023

Wireless power transfer to biomedical implants

Various examples are provided for wireless power transfer to implants. In one example, a system includes a radio frequency (RF) power source and a transmitter (TX) array comprising an excitation coil and resonant coils distributed about the excitation coil. The TX array can transfer power from the RF power source to a biomedical implant inserted below a skin surface of a subject when the TX array is positioned on the skin surface adjacent to the biomedical implant. A receiver (RX) coil of the biomedical implant can inductively couple with the TX array for the power transfer. The resonant coils can allow power transfer when the RX coil is not aligned with the excitation coil.

Lin, Jenshan↗

DOE OSTI2023

Control of power converters having integrated capacitor blocked transistor cells

Various examples of power converters including Integrated Capacitor Blocked Transistor (ICBT) cells and methods of control of power converters having ICBT cells are described. In one example, a power converter includes an upper arm including a plurality of upper ICBT cells connected in series to form a series connection path and a lower arm including a plurality of lower ICBT cells connected in series in the series connection path. A controller can be configured to provide a control signal pair to each of the upper ICBT cells and a complementary control signal pair to each of the lower ICBT cells to control the converter output. A capacitor voltage controller can be configured to balance a voltage potential among ICBT capacitors in at least one of the upper arm and the lower arm.

Yu, Jianghui↗

DOE OSTI2023

Gas-Liquid Flow Modeling for Renewable Fuels Production

Aerobic/anaerobic and gas fermentation pathways have emerged as promising new technologies for the generation of renewable fuels/chemicals from biomass derived sugars, and mixtures of greenhouse/energy rich gas streams (CO2/CH4/H2/CO) via microbial action. Example pathways include sugars-to-ethanol conversion, biomethanation (CO2/H2 to CH4), biogas upgrading, CO fermentation and wet-waste conversion. Gas and liquid phase transport, mass-transfer, and mixing physics at large length scales can significantly affect microbial conversion rates, particularly when the microbial reaction requires a narrow set of conditions. These phenomena are difficult to study in small-scale bench-top reactors that are typically well-mixed. Predictive computational fluid dynamics (CFD) based simulations can therefore aid in the scale-up, design and optimization of these reactors. This work presents multiphase Euler-Euler CFD simulations of at-scale (~500 m3) bioreactors. Our mathematical model treats the gas and liquid as interpenetrating phases. This approach reduces the computational complexity of tracking individual gas bubbles that are several orders of magnitude smaller than reactor dimensions. We solve the Reynolds averaged Navier-Stokes (RANS) multiphase equations that account for phase and chemical species transport, interphase mass and momentum transfer and uses a phenomenological model for gas uptake by microbes. We use a customized solver derived from open-source CFD toolbox, OpenFOAM [1], to perform these simulations, which has been validated against small-scale reactors in our previous work [2]. There is currently a knowledge-gap regarding bubble-size distributions when using gas mixtures with vastly different properties, which can have a significant impact overall mass-transfer. For example, hydrogen bubbles are more buoyant compared to other relatively heavier gases (CO2/CH4/CO), resulting in a large distribution of residence times and bubble sizes. This work therefore develops a deeper understanding of bubble dynamics and interphase mass transfer in such heterogenous gas mixtures through well-resolved computational models. We use a population balance model (PBM) for bubble-size-distribution modeling that is validated against small-scale experiments in our solver with an uncertainty quantification study for bubble coalescence and break-up model parameters. Results pertaining to multiple simulations of gas-fermentation reactors are presented where gas mixtures with varying compositions of CO2/CH4/CO/H2 are imposed at the sparger boundaries. The spatio-temporal variations in bubble-size distribution and mass transfer coefficient are analyzed for varying superficial velocities and gas-compositions for varying sizes of bubble-column and airlift reactors. This work will also examine the performance of different reactor designs, viz. bubble column reactor, airlift reactor with an internal draft tube, and a stirred-tank reactor with Rushton impellers. Reactor mass-transfer coefficient, gas hold-up, and dissolved gas distribution are critically analyzed among reactors, and sensitivity studies pertaining to gas flow rates and reactor geometry will be presented. [1] Weller, H., Tabor, G., Jasak, H. and Fureby, C., A tensorial approach to computational continuum mechanics using object-oriented techniques, Computers in physics, 12, 6, 620--631, 1998. [2] Rahimi, M., Sitaraman, H., Humbird, D. and Stickel, J., Computational fluid dynamics study of full-scale aerobic bioreactors: Evaluation of gas-liquid mass transfer, oxygen uptake, and dynamic oxygen distribution, Chemical Engineering Research and Design, 139: 283-295.

BIOMASS FUELS↗

DOE OSTI2023

Cybersecurity Considerations for State Procurement of Solar Assets

This tool provides an overview of existing procurement programs and example language that prioritizes cybersecurity language and references that can readily be applied to state solar cybersecurity practices . The tool also identifies sample language for procurement agreements, contracts, and grants which can serve as lower entry points for state officials interested in pursuing this subject matter more immediately. As this approach may be novel for many states, the information therein should be considered as a model only . The programs and example language included are not exhaustive and should be evaluated in accordance with state processes and policies .

14 SOLAR ENERGY↗

DOE OSTI2023

Criticality Safety Evaluation Project Development for University of California Berkely Nuclear Criticality Safety Pipeline Course

The Nuclear Criticality Safety Division at Lawrence Livermore National Laboratory (LLNL) has taken a unique approach to developing criticality safety evaluation topics in support of the University of California Berkeley criticality safety pipeline course. The evaluation topics are designed to go beyond the typical evaluation examples used for many training courses including vault storage and variations on storage arrays. These types of evaluations provide in-depth analysis into the fundamentals of criticality safety and are complex but may be far off from what a new criticality safety engineer may actually be evaluating. To provide more practical examples of criticality safety evaluation topics that are better fit for the knowledge level of a criticality safety engineer in-training, variations of current and future operations and research operations performed at LLNL are used as evaluation topics. Additionally, an emphasis on research is included in all evaluation topics as it allows students to take advantage of the concepts learned in class to apply them for process improvement, engineering equipment that is favorable for criticality safety, and negotiation tactics to work with operations personnel. The process used by LLNL to develop project topics for the pipeline course is provided in this paper. The intent is to provide an alternative technique for training students and potentially younger staff members in criticality safety on developing criticality safety evaluations.

42 ENGINEERING↗

DOE OSTI2023

Apparatus and method for providing workload distribution of threads among multiple compute units

In some examples, thermal aware optimization logic determines a characteristic (e.g., a workload or type) of a wavefront (e.g., multiple threads). For example, the characteristic indicates whether the wavefront is compute intensive, memory intensive, mixed, and/or another type of wavefront. The thermal aware optimization logic determines temperature information for one or more compute units (CUs) in one or more processing cores. The temperature information includes predictive thermal information indicating expected temperatures corresponding to the one or more CUs and historical thermal information indicating current or past thermal temperatures of at least a portion of a graphics processing unit (GPU). The logic selects the one or more compute units to process the plurality of threads based on the determined characteristic and the temperature information. The logic provides instructions to the selected subset of the plurality of CUs to execute the wavefront.

Rao, Karthik↗

DOE OSTI2023

High voltage switch with cascaded transistor topology

A switching apparatus includes three or more series-connected transistors, and it further includes a balancing network. The balancing network includes a resistor network configured to divide a voltage from a voltage source across the series-connected transistors. The resistor network includes at least two resistive legs connected in parallel. In each resistive leg, two or more resistors are connected in series. The balancing network may further comprise at least one capacitive leg of series-connected capacitors connected across the series-connected transistors, and it may further comprise at least one leg of series-connected avalanche diodes connected across the series-connected transistors for overvoltage protection. In example embodiments, the series-connected transistors are JFETs. In other example embodiments, the series-connected transistors may be HEMTs or GaN transistors.

Gill, Lee↗

DOE OSTI2023

Streaming authentication and multi-level security for communications networks using quantum cryptography

Message authenticators for quantum-secured communications facilitate low-latency authentication with assurances of security. Low-latency message authenticators are especially valuable in infrastructure systems where security and latency constraints are difficult to satisfy with conventional non-quantum cryptography. For example, a message transmitter receives a message and derives an authentication tag for the message based at least in part on an authenticator that uses one or more quantum keys. The message transmitter outputs the message and its authentication tag. A message receiver receives a message and authentication tag for the message. The message receiver derives a comparison tag for the message based at least in part on an authenticator that uses one or more quantum keys. The message receiver checks whether the message is authentic based on a comparison of the authentication tag and the comparison tag. In example implementations, the authenticator uses stream-wise cyclic redundancy code operations.

Hughes, Richard J.↗

DOE OSTI2023

Separable self-aligning waveguide connector using a ball detent assembly having ball elements engaged with mating divots

Provided herein are various examples of separable waveguide couplers. In one example, a collar element is provided to surround a member comprising a faying surface, a waveguide conduit, and alignment protrusions arranged radially about a perimeter of the faying surface, where the collar element is configured to accept insertion of a mating member comprising a mating faying surface and a mating waveguide conduit. A ball detent assembly is provided having a spring element that retains ball elements in holes formed through the collar element. The waveguide conduit and the mating waveguide conduit are configured to be aligned radially by at least engagement of the alignment protrusions with alignment channels in the mating member and restrained axially by at least engagement of the ball elements with mating divots in the mating member.

Weems, Weyman Albert↗

DOE OSTI2023

Electrode configuration for extended plasma confinement

Methods and systems are provided for plasma confinement utilizing various electrode and valve configurations. In one example, a device includes a first electrode positioned to define an outer boundary of an acceleration volume, a second electrode arranged coaxially with respect to the first electrode and positioned to define an inner boundary of the acceleration volume, at least one power supply to drive an electric current along a Z-pinch plasma column between the first second electrodes, and a set of valves to provide gas to the acceleration volume to fuel the Z-pinch plasma column, wherein an electron flow of the electric current is in a first direction from the second electrode to the first electrode. In additional or alternative examples, a shaping part is conductively connected to the second electrode to, in a presence of the gas, cause a gas breakdown of the gas to generate a sheared flow velocity profile.

Meier, Eric T.↗

DOE OSTI2023

Gain balanced nonlinear optical interferometer

A nonlinear fiber interferometer is disclosed suitable for fiber sensor and other applications. A first nonlinear fiber section amplifies probe and conjugate sidebands of a pump through four-wave mixing. A second section introduces a phase shift to be measured, for example from a sensor. A third nonlinear fiber section amplifies with phase-sensitive gain to increase signal-to-noise ratio. Based on phase-sensitive output power of probe and/or conjugate components, the phase shift can be measured. Superior performance can be obtained by balancing gain between the (first and third) nonlinear sections. Non-fiber, for example photonic integrated circuit, embodiments are disclosed. Differential sensing, alternative detection schemes, sensing applications, associated methods, and other variations are disclosed.

Lukens, Joseph M.↗

DOE OSTI2023

Apparatus and method for extended plasma confinement

Shumlak, Uri↗

DOE OSTI2023

Passively pumped, polycrystalline ceramic high and ultra-high vacuum chambers

A sealed, passively pumped, polycrystalline ceramic vacuum chamber and method for fabricating the chamber are disclosed. The body of the vacuum chamber is made from a polycrystalline ceramic, for example, alumina. The vacuum chamber includes one or more windows made from a transparent ceramic, for example, sapphire, to accommodate optical access, while remaining amorphous-glass free to minimize or eliminate helium permeation. The vacuum chamber components are joined via laser welding or furnace brazing and the completed chamber is bakeable at temperatures up to 400° C. The vacuum chamber can operate at high or ultra-high vacuum pressures for an extended period through the use of one or more getter-based pumps. The vacuum chamber may include one or more atomic sources depending upon the application.

Walker, Charles A.↗

DOE OSTI2023

Accelerated Aging of PV Cables - The Development of Methods Towards Combined-Accelerated Stress Testing

PV cables allow the collection and distribution of electricity from modules to the energy grid. Durable cabling allows continuous operation of PV installations. Cables with a life less than that of the modules must be replaced - reducing electricity generation and adding to the system operating expense. We have examined the durability of a variety of representative cable samples using artificial UV weathering (IEC TS 62788-7-2) and combined accelerated stress testing (C-AST). Jackets in this study include PV-rated (polyolefin), building wire (PVC/PA), and multi-conductor (rubber, as in PV trackers), with some examples of black and red cables. Characterizations at read points include appearance (camera and optical microscope), surface roughness (linear profilometry), instrumented indentation, surface morphology (SEM), chemical composition (EDS), thermal decomposition (TGA), phase transition (DSC), crystalline structure (WAXS), and polymer chemical structure (FTIR). Complimentary examinations confirm damage to the external and interior layer(s) of less durable samples, including changes in morphology (e.g., cracking), chemistry (e.g., oxidation), structure, and mechanical performance (e.g., through-thickness modulus and hardness). The results may be generally compared to other examples from the field (PV installations) or after accelerated testing (IEC 61215). The methods in this study are presently being applied in a follow-on C-AST study, incorporating both dynamic and kinematic fixtures.

balance of systems↗

DOE OSTI2023

Assessing the Impact of Mass Production on Microreactor Costs

Microreactors have attracted significant attention and investment. By virtue of their smaller size (typically less than ~20 MWe), they are expected to be significantly easier to build, demonstrate, and deploy than larger reactors. This has led to several U.S. companies pursuing active demonstration efforts with a wide variety of designs under development. For example, the Ultra Safe Nuclear Corporation (USNC), has recently announced they are planning to build a microreactor assembly plant in Alabama. The cost reduction of the microreactors via factory fabrication and mass production is expected to be the primary driver to the economic competitiveness of microreactors. While several entities are focused on first-of-a-kind demonstration of the technology, it is important to provide insights on longer-term considerations for mass production. The evaluation shown here was conducted primarily in collaboration with Munro & Associates Inc. The findings of this microreactor factory fabrication and mass production study were recently published in. In this paper, we start by summarizing the findings of this study. Next, we apply these findings to quantify the cost reduction of a heat pipe-cooled fast reactor (as an example of microreactors).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

DOE OSTI2024

Perspective on Solar Energy Materials, Design and Discovery, Defects, Disorder, and Interfaces

The energy transition still faces a daunting math. Currently, more than three quarters of final energy consumption occurs in form of fuels vs less than one quarter in electricity. On the other hand, renewable energy additions come almost exclusively in the form of electricity (dominantly photovoltaics and wind). Thus, meeting the terawatt challenge requires enormous growth in renewables, sufficient to convert excess electricity into fuels, as well as the development of non-electricity based solar fuel technologies, for example via solar thermochemical routes. In this presentation, we will review successes and challenges in photovoltaic materials from silicon to CdTe to halide perovskites and potential emerging materials, with a particular perspective on the role of first principles calculations and predictions. Materials design and discovery is evolving to incorporate defects, disorder, and interfaces. These phenomena play also an important role in the thermochemical generation of hydrogen, allowing to utilize synergies between renewable electricity and fuels in computational research. At the same time, machine learning approaches are increasingly geared toward properties of non-ideal materials, for example defect formation, allowing the screening for more complex material behavior as needed for the respective applications.

fuels↗