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At least 1,135 records · Page 63

Microstructure-failure mode correlations in braided composites

Explication of the fracture processes of braided composites is needed for modeling their behavior. Described is a systematic exploration of the relationship between microstructure, loading mode, and micro-failure mechanisms in carbon/epoxy braided composites. The study involved compression and fracture toughness tests and optical and scanning electron fractography, including dynamic in-situ testing. Principal failure mechanisms of low sliding, buckling, and unstable crack growth are correlated to microstructural parameters and loading modes; these are used for defining those microstructural conditions which are strength limiting.

Filatovs, G. J.↗

Evolution of the 1997-98 El Nino and La Nina: the Role of Altimetry in ENSO Studies and Prediction

El Nino and the Southern Oscillation (ENSO) are known to be a quasi-periodic coupled ocean-atmosphere phenomenon occurring roughly every 3-7 years. Its largest oceanic manifestations are found in the equatorial Pacific, but it is of global climatic significance. During the flight of the TOPEX]Poseidon altimeter, the equatorial Pacific was in the midst of an unusual period of prolonged ENSO warming in the mid-1990's. In 1997, the tropical Pacific witnessed the development of a major El Nino event, rivaling in strength the 1982-83 El Nino. The intensity of this El Nino, and its rapid intensification early in the calendar year, caught the scientific community by surprise. None of the forecast models, statistical or dynamical, captured these features of the 1997 El Nino, although those models that assimilated in situ ocean observations did better than most in predicting that the event would occur in 1997. The onset of the El Nino coincided with the occurrence of several westerly wind events in the western Pacific rather than to delayed oscillator physics. However, western Pacific sea levels were anomalously elevated a year and a half prior to the onset, which may have helped precondition the system to a particularly strong ENSO episode. The coming of La Nina was foreshadowed by large-scale drops in sea level in the western tropical Pacific and cyclonic wind stress curl anomalies far beyond the +\- 8 degrees latitude bounds of the TAO mooring array. In past El Nino events, the evolution of the coupled system could only be studied from the perspective of in situ observations. The 1997-1998 El Nino event will be the first time a major El Nino event will have been observed from start to finish via remotely-sensed measurements of sea surface topography, sea surface temperature, sea surface winds, ocean color, and precipitation. These observations have considerable potential for advancing coupled climate forecasts on time scales from seasons to decades. This presentation will address questions along the lines of: (1) What are the scientific problems in ENSO that can benefit most from altimetry data? (2) Are there any precursors in the global ocean-atmosphere system for the 1997-98 extreme event? (3) Is there a unique role of altimetry in detecting potential precursors?(4) Has Topex/Poseidon data been adequately used to improve ENSO forecasts? Is there any firm evidence? (6) What is the status of the transition of El Nino into a La Nina?

Busalacchi, Antonio J.↗

GMS-based"Future Time" Rainfall Data Assimilation for Mesoscale Weather Prediction over Korean Peninsula and Future Prospects with GPM Satellite Measurements

This study examines the use of satellite-derived nowcasted (short-term forecasted) rainfall over 3-hour time periods to gain an equivalent time increment in initializing a nonhydrostatic mesoscale model used for predicting convective rainfall events over the Korean peninsula. Infrared (IR) window measurements from the Japanese Geostationary Meteorological Satellite (GMS) are used to specify latent heating for a spinup period of the model - but in future time -- thus initializing in advance of actual time in the framework of a prediction scenario. The main scientific objective of the study is to investigate the strengths and weaknesses of this approach insofar as data assimilation, in which the nowcasted assimilation data are derived independently of the prognostic model itself. Although there have been various recent improvements in formulating the dynamics, thermodynamics, and microphysics of mesoscale models, as well as computer advances which allow the use of high resolution cloud-resolving grids and explicit latent heating over regional domains, spinup remains at the forefront of unresolved mesoscale modeling problems. In general, non-realistic spinup limits the skill in predicting the spatial-temporal distribution of convection and precipitation, primarily in the early hours of a. forecast, stemming from standard prognostic variables not representing the initial diabatic heating field produced by the ambient convection and cloud fields. The long-term goal of this research is to improve short-range (12-hour) quantitative precipitation forecasting (QPF) over the Korean peninsula through the use of innovative data assimilation methods based on geosynchronous satellite measurements. As a step in th~s direction, a non-standard data assimilation experiment in conjunction with GMS-retrieved nowcasted rainfall information introduced to the mesoscale model is conducted. The 3-hourly precipitation forecast information is assimilated through nudging the associated diabatic heating during the early stages of a forecast period. This procedure is expected to enhance details in the moisture field during model integration, and thus improve spinup performance, assuming the errors in the future time latent heating data ate less than intrinsic model background errors.

Smith, Eric A.↗

Flight Test of an Adaptive Controller and Simulated Failure/Damage on the NASA NF-15B

The method of flight-testing the Intelligent Flight Control System (IFCS) Second Generation (Gen-2) project on the NASA NF-15B is herein described. The Gen-2 project objective includes flight-testing a dynamic inversion controller augmented by a direct adaptive neural network to demonstrate performance improvements in the presence of simulated failure/damage. The Gen-2 objectives as implemented on the NASA NF-15B created challenges for software design, structural loading limitations, and flight test operations. Simulated failure/damage is introduced by modifying control surface commands, therefore requiring structural loads measurements. Flight-testing began with the validation of a structural loads model. Flight-testing of the Gen-2 controller continued, using test maneuvers designed in a sequenced approach. Success would clear the new controller with respect to dynamic response, simulated failure/damage, and with adaptation on and off. A handling qualities evaluation was conducted on the capability of the Gen-2 controller to restore aircraft response in the presence of a simulated failure/damage. Control room monitoring of loads sensors, flight dynamics, and controller adaptation, in addition to postflight data comparison to the simulation, ensured a safe methodology of buildup testing. Flight-testing continued without major incident to accomplish the project objectives, successfully uncovering strengths and weaknesses of the Gen-2 control approach in flight.

Buschbacher, Mark↗

Precision Lunar Laser Ranging For Lunar and Gravitational Science

Laser ranging to retroreflector arrays placed on the lunar surface by the Apollo astronauts and the Soviet Lunar missions over the past 39 years have dramatically increased our understanding of gravitational physics along with Earth and Moon geophysics, geodesy, and dynamics. Significant advances in these areas will require placing modern retroreflectors and/or active laser ranging systems at new locations on the lunar surface. Ranging to new locations will enable better measurements of the lunar librations, aiding in our understanding of the interior structure of the moon. More precise range measurements will allow us to study effects that are too small to be observed by the current capabilities as well as enabling more stringent tests of Einstein's theory of General Relativity. Setting up retroreflectors was a key part of the Apollo missions so it is natural to ask if future lunar missions should include them as well. The Apollo retroreflectors are still being used today, and nearly 40 years of ranging data has been invaluable for scientific as well as other studies such as orbital dynamics. However, the available retroreflectors all lie within 26 degrees latitude of the equator, and the most useful ones within 24 degrees longitude of the sub-earth meridian. This clustering weakens their geometrical strength.

Merkowitz, S. M.↗

TPSAS-NF1676L-12387-DND

Fast-time wake prediction models are semi-empirical, and are designed to predict aircraft wake vortex information behind a generating aircraft. They are developed using theoretical concepts and often calibrated with data obtained from field measurements, laboratory studies, or numerical simulations. They rely upon inputs representing the generating aircraft (such as weight, airspeed, wingspan, lateral position, and altitude) and atmospheric environment (such as ambient winds, turbulence, and temperature lapse rate). Other input may include the type of aircraft (e.g., B-747- 400). Output from these models may include time histories of the wake vortex strength, and position, as well as a prediction of the uncertainties in strength and position. Fast-time models should provide solutions in a fraction of a second, and hence is an enabling technology able to perform in a real-time operational system, such as dynamic spacing systems envisioned by the Aircraft Vortex Spacing System or other Super Density Operations concepts. Other applications of fast-time models include 1) guidance for wake separation standards for new aircraft, 2) optimization of separation standards for existing aircraft, 3) guidance for setting vertical separation standards during cruise, 4) accident reconstructions, and 5) testing of new concepts for safe increases in airport capacity for both single and multiple runway configurations. Fast-time models are based on a number of assumptions which limit their accuracy and range of application. For example, they do not predict the meandering vortex paths that can result from the wake interaction with atmospheric turbulence. However, these models should account for the mean vortex position and may predict the level of uncertainty. This presentation describes a study in which comparative evaluations of fast-time wake transport and decay models were conducted using data sets from previous field programs taken at MEM (1995), DFW (1997, 1999, 2000), and Denver (2005, 2006) airports. These data sets contain, meteorological data, lidar measurements of wake vortices, and the aircraft parameters associated with these vortices.

Fred H Proctor↗

Exploring the Photogenerated Charge Transfer Mechanism in Cu 2 O@MoS 2 Heterojunction Photocatalyst Using Transient Absorption Spectroscopy

Both heterojunction and core–shell photocatalysts have demonstrated promising performance in photocatalytic CO 2 conversions to fuels. However, fundamental knowledge of heterojunctions in core–shell structures is highly desired to facilitate the design of future photocatalysts. By combining advanced experimental characterizations and density functional theory (DFT) calculations, the role of the Cu 2 O@MoS 2 heterojunction in photocatalytic CO 2 conversions to fuels was investigated. We discovered that the charge dynamics and electron transfer properties of Cu2O@MoS 2 photocatalysts are altered by the heterojunction and Cu 2 O underlayer due to the electron transfer from Cu 2 O to MoS 2 and the change in CO 2 adsorption strength on the hybrid catalyst surface. Consequently, more electrons can travel to the surrounding liquid environment to be consumed by CO 2 reduction. This study provides experimental and theoretical investigations of the fundamental mechanisms of heterojunction core–shell photocatalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lifetime Predictions of a Titanium Silicate Glass with Machined Flaws

A dynamic fatigue study was performed on a Titanium Silicate glass to assess its susceptibility to delayed failure and to compare the results with those of a previous study. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions. The material strength and lifetime was seen to increase due to the removal of residual stress through grinding and polishing. Influence on time-to-failure is addressed for the case with and without residual stress present. Titanium silicate glass otherwise known as ultra-low expansion (ULE)* glass is a candidate for use in applications requiring low thermal expansion characteristics such as telescope mirrors. The Hubble Space Telescope s primary mirror was manufactured from ULE glass. ULE contains 7.5% titanium dioxide which in combination with silica results in a homogenous glass with a linear expansion coefficient near zero. delayed failure . This previous study was based on a 230/270 grit surface. The grinding and polishing process reduces the surface flaw size and subsurface damage, and relieves residual stress by removing the material with successively smaller grinding media. This results in an increase in strength of the optic during the grinding and polishing sequence. Thus, a second study was undertaken using samples with a surface finish typically achieved for mirror elements, to observe the effects of surface finishing on the time-to-failure predictions. An allowable stress can be calculated for this material based upon modulus of rupture data; however, this does not take into account the problem of delayed failure, most likely due to stress corrosion, which can significantly shorten lifetime. Fortunately, a theory based on fracture mechanics has been developed enabling lifetime predictions to be made for brittle materials susceptible to delayed failure. Knowledge of the factors governing the rate of subcritical flaw growth in a given environment enables the development of relations between lifetime, applied stress and failure probability for the material under study. Dynamic fatigue is one method of obtaining the necessary information to develop these relationships. In this study, the dynamic fatigue method was used to construct a time-to-failure diagram for polished ULE glass.

Tucker, Dennis S.↗

Dynamic Structural Change of Plant Epidermal Cell Walls under Strain

Abstract The molecular foundations of epidermal cell wall mechanics are critical for understanding structure–function relationships of primary cell walls in plants and facilitating the design of bioinspired materials. To uncover the molecular mechanisms regulating the high extensibility and strength of the cell wall, the onion epidermal wall is stretched uniaxially to various strains and cell wall structures from mesoscale to atomic scale are characterized. Upon longitudinal stretching to high strain, epidermal walls contract in the transverse direction, resulting in a reduced area. Atomic force microscopy shows that cellulose microfibrils exhibit orientation‐dependent rearrangements at high strains: longitudinal microfibrils are straightened out and become highly ordered, while transverse microfibrils curve and kink. Small‐angle X‐ray scattering detects a 7.4 nm spacing aligned along the stretch direction at high strain, which is attributed to distances between individual cellulose microfibrils. Furthermore, wide‐angle X‐ray scattering reveals a widening of (004) lattice spacing and contraction of (200) lattice spacing in longitudinally aligned cellulose microfibrils at high strain, which implies longitudinal stretching of the cellulose crystal. These findings provide molecular insights into the ability of the wall to bear additional load after yielding: the aggregation of longitudinal microfibrils impedes sliding and enables further stretching of the cellulose to bear increased loads.

59 BASIC BIOLOGICAL SCIENCES↗

Dynamics of lava flow - Thickness growth characteristics of steady two-dimensional flow

The thickness growth characteristics of flowing lava are investigated using a heat balance model and a two-dimensional model for flow of a Bingham plastic fluid down an inclined plane. It is found that yield strength plays a crucial role in the thickening of a lava flow of given flow rate. To illustrate this point, downstream thickness profiles and yield strength distributions were calculated for flows with mass flow rates of 10,000 and 100,000 kg/m-sec. Higher flow rates led to slow cooling rates which resulted in slow rate of increase of yield strength and thus greater flow lengths.

Park, S.↗

Dynamics of the earth's ring current - Theory and observation

The development of currents within an arbitrary distribution of particles trapped in the geomagnetic field is described. These currents combine to form the earth's ring current and thus are responsible for the worldwide depressions of surface magnetic field strength during periods of magnetic activity known as magnetic storms. Following a brief review of trapped particle motion in magnetic fields, ring current development is described and presented in terms of basic field and particle distribution parameters. Experimental observations then are presented and discussed within the theoretical framework developed earlier. New results are presented which, in the area of composition and charge state observations, hold high promise in solving many long standing ring current problems. Finally, available experimental results will be used to assess the present understanding as to ring current sources, generation, and dissipation.

Williams, D. J.↗

Dynamic Evolution in the Symbiotic R Aquarii

We report on multiple Chandra observations spanning a period of 5 years as well as a more recent XMM observation of the nearby symbiotic binary R Aqr. Spectral analysis of these four observations reveals considerable variability in hardness ratios and in the strength and ionization levels of emission lines which provides insight into white dwarf accretion processes as well as continuum and line formation mechanisms. Chandra imaging of the central source also shows the formation and evolution of a new south west jet. This growing body of high-resolution X-ray data of R Aqr provides a unique glimpse into white dwarf wind-accretion processes and jet formation.

DePasquale, J. M.↗

From Weibel seeds to dynamo beyond pair-plasmas

Bridging the spatiotemporal scales of magnetic seed field generation and subsequent dynamo amplification in the weakly collisional intracluster medium presents an extreme numerical challenge. We perform collisionless turbulence simulations with initially unmagnetised electrons that capture both magnetic seed generation via the electron Weibel instability and the ensuing dynamo amplification. Going beyond existing pair-plasma studies, we use an ion-to-electron mass ratio of 100 for which we find electron and ion dynamics are sufficiently decoupled. These simulations are enabled by the 10-moment collisionless fluid solver of Gkeyll, which evolves the full pressure tensor for all species. The electron heat-flux closure regulates pressure isotropisation and effectively sets the magnetic Reynolds number. We investigate how the strength of the closure influences the transition between a regime reminiscent of previous kinetic pair-plasma simulations and a regime exhibiting dynamo behaviour qualitatively similar to magnetohydrodynamics.

astrophysical plasmas↗

The Phase-Locking of Tropical North Atlantic and the Contribution of ENSO

The Tropical North Atlantic (TNA) is characterized by significant interannual variability in sea surface temperature (SST), which is phase-locked to the boreal spring. In this study, the phase-locking of TNA is investigated by adopting a linear stochastic-dynamical model (SDM) using seasonally modulated TNA feedbacks together with the seasonal modulation of ENSO forcing. In the observations, the role of local TNA feedbacks and ENSO forcing in TNA phase-locking are equivalently important with both preferring the peak of TNA variability to appear in the boreal spring. Besides, the seasonal modulation of TNA feedbacks and ENSO forcing strength are both mainly controlled by thermodynamic processes. In most climate models, the contribution of ENSO on TNA phase-locking is weaker than that in observations. The strength of ENSO-related TNA phase-locking is highly correlated with the relationship between ENSO and TNA, which is mainly determined by the amplitude of ENSO and its teleconnection patterns.

54 ENVIRONMENTAL SCIENCES↗

Multilayered Ordered Protein Arrays Self-Assembled from a Mixed Population of Virus-like Particles

Biology shows many examples of spatially controlled assembly of cells and biomacromolecules into hierarchically organized structures, to which many of the complex biological functions are attributed. While such biological structures have inspired the design of synthetic materials, it is still a great challenge to control the spatial arrangement of individual building blocks when assembling multiple types of components into bulk materials. Here, in this study, we report self-assembly of multilayered, ordered protein arrays from mixed populations of virus-like particles (VLPs). We systematically tuned the magnitude of the surface charge of the VLPs via mutagenesis to prepare four different types of VLPs for mixing. A mixture of up to four types of VLPs selectively assembled into higher-order structures in the presence of oppositely charged dendrimers during a gradual lowering of the ionic strength of the solution. The assembly resulted in the formation of three-dimensional ordered VLP arrays with up to four distinct layers including a central core, with each layer comprising a single type of VLP. A coarse-grained computational model was developed and simulated using molecular dynamics to probe the formation of the multilayered, core-shell structure. Our findings establish a simple and versatile bottom-up strategy to synthesize multilayered, ordered materials by controlling the spatial arrangement of multiple types of nanoscale building blocks in a one-pot fabrication.

59 BASIC BIOLOGICAL SCIENCES↗

Radiation Belt Response to Fast Reverse Shock at Geosynchronous Orbit

Fast reverse shocks (FRSs) cause the magnetosphere to expand, by contrast to the well-known compressions caused by the impact of fast forward shocks (FFS). Usually, FFSs are more geoeffective than FRSs, and consequently the inner magnetosphere dynamic responses to both shock types can be quite different. In this study, we investigate for the first time the radiation belt response to an FRS impact using multi-satellite observations and numerical simulations. Spacecraft on the dayside observed decreases in magnetic field strength and energetic (~40–475 keV) particle fluxes. Timing analysis shows that the magnetic field signature propagated from the dayside to the nightside magnetosphere. Particles with different energies vary simultaneously at each spacecraft, implying a non-dispersive particle response to the shock. Spacecraft located at lower L-shells did not record any significant signatures. The observations indicate a local time dependence of the response associated with the shock inclination, with the clearest signatures being observed in the dusk–midnight sector. Simulations underestimate the amplitude of the magnetic field variations observed on the nightside. The observed decreases in the electron intensities result from a combination of radial gradient and adiabatic effects. The radial gradients in the spectral index appear to be the dominant contributor to the observed variations of electrons seen on the dayside (near noon and dusk) and on the nightside (near midnight). This work shows that even an FRS can affect the radiation belts significantly and provides an opportunity to understand their dynamic response to a sudden expansion of the magnetosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

Role of Dynamic Polarization Interactions in the Electrical Double Layer at Calcite (104) Interfaces with Aqueous Solutions

Reactions at mineral interfaces with aqueous solutions control many geochemical and biogeochemical processes in the Earth’s critical zone. At the molecular level, insights into important properties such as the structure of the electrical double layer (EDL) at specific mineral interfaces continue to improve due to the increasing fidelity of laboratory instrumentation and computational approaches. However, molecular simulation approaches suffer from limited reach into relevant scales of time, length, and system complexity. To span this gap, a novel hybrid approach that couples first principle plane-wave density functional theory (DFT) with classical DFT (cDFT) is demonstrated and applied to calcite (104) interfaces with various electrolytes. In this approach, a region of interest described using DFT interacts with the surrounding medium described using cDFT to arrive at a self-consistent ground state. Benchmarking against experimental observations and entirely first principle DFT simulations demonstrates that this hybrid model efficiently encompasses the key short-range and collective interactions in the EDL. Simulations of calcite (104)/solution interfaces reveal the key static and dynamic polarization interactions that give rise to structuring of ions and water. Ion hydration interactions have the strongest effect on the depth of the first minimum in the density distribution of counterions at the surface, and the position and width of the first density peak is largely determined by the strength of ion-correlation forces. Finer details of ion distributions are controlled by mutual polarization of the calcite surface and interfacial electrolyte. Finally, this new ability to efficiently and rigorously predict EDL structure at mineral surfaces in contact with complex solutions paves the way to accurately modeling sorption, nucleation, dissolution, and growth in realistic systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗