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At least 1,135 records · Page 63

Elevated Forest Canopy Loss After Wildfires in Moist and Cool Forests in the Pacific Northwest

Wildfire frequency, intensity, and rate of spread are increasing across the Western U.S, resulting in more severe ecosystem impacts. Significant tree mortality can occur years after fire events, but this has received little attention compared to the immediate tree loss during a fire. We overlapped forest cover loss data with burn severity maps in the U.S. Pacific Northwest and quantified the total and delayed forest canopy loss after fires. We found that wildfires resulted in total canopy loss fraction (CLF) of 84%, 53%, and 22% within 3 years in areas burned at high, moderate, and low severity, respectively. The delayed canopy loss accounted for approximately 1/3, 1/2, and 2/3 of the total canopy loss for high, moderate, and low severity burns. Delayed canopy loss was greater in moist and cool areas than in dry and warm areas, likely because tree species in wetter environments were less adapted to survive when fires did occur. Across all forests, delayed CLF doubled as temperature increased from the climatological mean to a hot anomaly and tripled as vapor pressure deficit increased from a wet anomaly to a dry anomaly. Fire impacts on forest ecosystems are likely to intensify under future climate scenarios as wildfires expand into areas that historically experienced infrequent fires. The impacts can also be exacerbated by more frequent compound extreme events, such as droughts, heatwaves, and fires. These findings highlight the urgent need for targeted forest management strategies, particularly in mesic forests, to mitigate future fire impacts.

54 ENVIRONMENTAL SCIENCES↗

The Role of Wind‐Moisture Characteristics in Shaping Atmospheric River Flood Hazards

Atmospheric rivers (ARs) are key drivers of extreme precipitation in the Western U.S. Using regionally downscaled thermodynamic global warming (TGW) simulations, we examine how ARs with varying wind and moisture characteristics respond to warming. We classified 812 historical AR events into Gusty-Wet, Gusty-Dry, Calm-Wet, and Calm-Dry groups to evaluate differences in precipitation behavior. ARs with stronger winds and higher moisture content exhibit higher precipitation efficiency (PE) and greater integrated water vapor (IWV). Regionally, Calm ARs show higher IWV accumulation due to slower inland transport and reduced PE. Projections indicate increases in storm-total (sub-Clausius-Clapeyron (CC) scaling) and maximum 3-hourly precipitation (super-CC scaling) across all groups, with the most pronounced changes in Gusty-Wet and Calm-Wet ARs. Spatial differences in surface runoff, PE, and inland reach highlight the importance of AR subtype in shaping future flood hazards. These results offer insights into event-level and regional-scale precipitation changes under evolving environmental conditions.

Zhou, Yang [Lawrence Berkeley National Laboratory ↗

Taxon-specific microbial growth and mortality patterns reveal distinct temporal population responses to rewetting in a California grassland soil

Abstract Microbial activity increases after rewetting dry soil, resulting in a pulse of carbon mineralization and nutrient availability. The biogeochemical responses to wet-up are reasonably well understood and known to be microbially mediated. Yet, the population level dynamics, and the resulting changes in microbial community patterns, are not well understood as ecological phenomena. Here, we used sequencing of 16S rRNA genes coupled with heavy water (H218O) DNA quantitative stable isotope probing to estimate population-specific rates of growth and mortality in response to a simulated wet-up event in a California annual grassland soil. Bacterial growth and mortality responded rapidly to wet-up, within 3 h, and continued throughout the 168 h incubation, with patterns of sequential growth observed at the phylum level. Of the 37 phyla detected in the prewet community, growth was found in 18 phyla while mortality was measured in 26 phyla. Rapid growth and mortality rates were measurable within 3 h of wet-up but had contrasting characteristics; growth at 3 h was dominated by select taxa within the Proteobacteria and Firmicutes, whereas mortality was taxonomically widespread. Furthermore, across the community, mortality exhibited density-independence, consistent with the indiscriminate shock resulting from dry-down and wet-up, whereas growth was density-dependent, consistent with control by competition or predation. Total aggregated growth across the community was highly correlated with total soil CO2 production. Together, these results illustrate how previously “invisible” population responses can translate quantitatively to emergent observations of ecosystem-scale biogeochemistry.

58 GEOSCIENCES↗

Vegetation forcing modulates global land monsoon and water resources in a CO 2 -enriched climate

The global monsoon is characterised by transitions between pronounced dry and wet seasons, affecting food security for two-thirds of the world’s population. Rising atmospheric CO 2 influences the terrestrial hydrological cycle through climate-radiative and vegetation-physiological forcings. How these two forcings affect the seasonal intensity and characteristics of monsoonal precipitation and runoff is poorly understood. Here we use four Earth System Models to show that in a CO 2 -enriched climate, radiative forcing changes drive annual precipitation increases for most monsoon regions. Further, vegetation feedbacks substantially affect annual precipitation in North and South America and Australia monsoon regions. In the dry season, runoff increases over most monsoon regions, due to stomatal closure-driven evapotranspiration reductions and associated atmospheric circulation change. Our results imply that flood risks may amplify in the wet season. However, the lengthening of the monsoon rainfall season and reduced evapotranspiration will shorten the water resources scarcity period for most monsoon regions.

58 GEOSCIENCES↗

Amazonian terrestrial water balance inferred from satellite-observed water vapor isotopes

Atmospheric humidity and soil moisture in the Amazon forest are tightly coupled to the region’s water balance, or the difference between two moisture fluxes, evapotranspiration minus precipitation (ET-P). However, large and poorly characterized uncertainties in both fluxes, and in their difference, make it challenging to evaluate spatiotemporal variations of water balance and its dependence on ET or P. Here, we show that satellite observations of the HDO/H 2 O ratio of water vapor are sensitive to spatiotemporal variations of ET-P over the Amazon. When calibrated by basin-scale and mass-balance estimates of ET-P derived from terrestrial water storage and river discharge measurements, the isotopic data demonstrate that rainfall controls wet Amazon water balance variability, but ET becomes important in regulating water balance and its variability in the dry Amazon. Changes in the drivers of ET, such as above ground biomass, could therefore have a larger impact on soil moisture and humidity in the dry (southern and eastern) Amazon relative to the wet Amazon.

54 ENVIRONMENTAL SCIENCES↗

Diminishing seasonality of subtropical water availability in a warmer world dominated by soil moisture–atmosphere feedbacks

Global warming is expected to cause wet seasons to get wetter and dry seasons to get drier, which would have broad social and ecological implications. However, the extent to which this seasonal paradigm holds over land remains unclear. Here we examine seasonal changes in surface water availability (precipitation minus evaporation, P–E) from CMIP5 and CMIP6 projections. While the P–E seasonal cycle does broadly intensify over much of the land surface, ~20% of land area experiences a diminished seasonal cycle, mostly over subtropical regions and the Amazon. Using land–atmosphere coupling experiments, we demonstrate that 63% of the seasonality reduction is driven by seasonally varying soil moisture (SM) feedbacks on P–E. Declining SM reduces evapotranspiration and modulates circulation to enhance moisture convergence and increase P–E in the dry season but not in the wet season. Our results underscore the importance of SM–atmosphere feedbacks for seasonal water availability changes in a warmer climate.

54 ENVIRONMENTAL SCIENCES↗

Quantification of human contribution to soil moisture-based terrestrial aridity

Abstract Current knowledge of the spatiotemporal patterns of changes in soil moisture-based terrestrial aridity has considerable uncertainty. Using Standardized Soil Moisture Index (SSI) calculated from multi-source merged data sets, we find widespread drying in the global midlatitudes, and wetting in the northern subtropics and in spring between 45°N–65°N, during 1971–2016. Formal detection and attribution analysis shows that human forcings, especially greenhouse gases, contribute significantly to the changes in 0–10 cm SSI during August–November, and 0–100 cm during September–April. We further develop and apply an emergent constraint method on the future SSI’s signal-to-noise (S/N) ratios and trends under the Shared Socioeconomic Pathway 5-8.5. The results show continued significant presence of human forcings and more rapid drying in 0–10 cm than 0–100 cm. Our findings highlight the predominant human contributions to spatiotemporally heterogenous terrestrial aridification, providing a basis for drought and flood risk management.

54 ENVIRONMENTAL SCIENCES↗

Model spread in tropical low cloud feedback tied to overturning circulation response to warming

Among models participating in the Coupled Model Intercomparison Project phase 6 (CMIP6), here we show that the magnitude of the tropical low cloud feedback, which contributes considerably to uncertainty in estimates of climate sensitivity, is intimately linked to tropical deep convection and its effects on the tropical atmospheric overturning circulation. First, a reduction in tropical ascent area and an increased frequency of heavy precipitation result in high cloud reduction and upper-tropospheric drying, which increases longwave cooling and reduces subsidence weakening, favoring low cloud reduction (Radiation-Subsidence Pathway). Second, increased longwave cooling decreases tropospheric stability, which also reduces subsidence weakening and low cloudiness (Stability-Subsidence Pathway). In summary, greater high cloud reduction and upper-tropospheric drying (negative longwave feedback) lead to a more positive cloud feedback among CMIP6 models by contributing to a greater reduction in low cloudiness (positive shortwave feedback). Varying strengths of the two pathways contribute considerably to the intermodel spread in climate sensitivity.

54 ENVIRONMENTAL SCIENCES↗

Human influence on joint changes in temperature, rainfall and continental aridity

Despite the pervasive impact of drought on human and natural systems, the large-scale mechanisms conducive to regional drying remain poorly understood. Here we use a multivariate approach to identify two distinct externally forced fingerprints from multiple ensembles of Earth system model simulations. The leading fingerprint, F M1 (x), is characterized by global warming, intensified wet–dry patterns and progressive large-scale continental aridification, largely driven by multidecadal increases in greenhouse gas (GHG) emissions. The second fingerprint, F M2 (x), captures a pronounced interhemispheric temperature contrast, associated meridional shifts in the intertropical convergence zone and correlated anomalies in precipitation and aridity over California, the Sahel and India. F M2 (x) exhibits nonlinear temporal behaviour: the intertropical convergence zone moves southwards before 1975 in response to increases in hemispherically asymmetric sulfate aerosol emissions, and it shifts northwards after 1975 due to reduced sulfur dioxide emissions and the GHG-induced warming of Northern Hemisphere landmasses. Both fingerprints are statistically identifiable in observations of joint changes in temperature, rainfall and aridity during 1950–2014. Furthermore, we show that the reliable simulation of these changes requires combined forcing by GHGs, direct and indirect effects of aerosols, and large volcanic eruptions. Our results suggest that GHG-induced aridification may be modulated regionally by future reductions in sulfate aerosol emissions.

54 ENVIRONMENTAL SCIENCES↗

Root traits explain plant species distributions along climatic gradients yet challenge the nature of ecological trade-offs

Ecological theory is built on trade-offs, where trait differences among species evolved as adaptations to different environments. Trade-offs are often assumed to be bidirectional, where opposite ends of a gradient in trait values confer advantages in different environments. However, unidirectional benefits could be widespread if extreme trait values confer advantages at one end of an environmental gradient, whereas a wide range of trait values are equally beneficial at the other end. Here, we show that root traits explain species occurrences along broad gradients of temperature and water availability, but model predictions only resembled trade-offs in two out of 24 models. Forest species with low specific root length and high root tissue density (RTD) were more likely to occur in warm climates but species with high specific root length and low RTD were more likely to occur in cold climates. Unidirectional benefits were more prevalent than trade-offs: for example, species with large-diameter roots and high RTD were more commonly associated with dry climates, but species with the opposite trait values were not associated with wet climates. Directional selection for traits consistently occurred in cold or dry climates, whereas a diversity of root trait values were equally viable in warm or wet climates. Explicit integration of unidirectional benefits into ecological theory is needed to advance our understanding of the consequences of trait variation on species responses to environmental change.

54 ENVIRONMENTAL SCIENCES↗

Substantial influence of vapour buoyancy on tropospheric air temperature and subtropical cloud

The molar mass of water vapor is less than that of dry air, making humid air lighter than dry air at the same temperature and pressure. This effect is known as vapor buoyancy and has been considered negligibly small in large-scale climate dynamics. Here we use theory, reanalysis data, and a hierarchy of climate models to show that vapor buoyancy has a similar magnitude to thermal buoyancy in the tropical free troposphere. We further show that vapor buoyancy makes cold air rise and increases subtropical stratiform low clouds by up to 70% of its climatological value. However, some widely used climate models fail to represent vapor buoyancy in the governing equations. Further, this flaw leads to inaccurate simulations of cloud distributions—the largest uncertainty in predicting climate change.

54 ENVIRONMENTAL SCIENCES↗

The hierarchical structure of organic mixed ionic–electronic conductors and its evolution in water

Polymeric organic mixed ionic–electronic conductors underpin several technologies in which their electrochemical properties are desirable. These properties, however, depend on the microstructure that develops in their aqueous operational environment. We investigated the structure of a model organic mixed ionic–electronic conductor across multiple length scales using cryogenic four-dimensional scanning transmission electron microscopy in both its dry and hydrated states. Four-dimensional scanning transmission electron microscopy allows us to identify the prevalent defects in the polymer crystalline regions and to analyse the liquid crystalline nature of the polymer. The orientation maps of the dry and hydrated polymers show that swelling-induced disorder is mostly localized in discrete regions, thereby largely preserving the liquid crystalline order. Therefore, the liquid crystalline mesostructure makes electronic transport robust to electrolyte ingress. Furthermore, this study demonstrates that cryogenic four-dimensional scanning transmission electron microscopy provides multiscale structural insights into complex, hierarchical structures such as polymeric organic mixed ionic–electronic conductors, even in their hydrated operating state.

36 MATERIALS SCIENCE↗

Self-assembly of aramid amphiphiles into ultra-stable nanoribbons and aligned nanoribbon threads

Small molecule self-assembly is an established route for producing high surface area nanostructures with readily customizable chemistries and precise molecular organization. However, these structures are fragile, exhibiting molecular exchange, migration, and rearrangement - among other dynamic instabilities - and ultimately disassociate upon drying. Here we show a small molecule platform, the aramid amphiphile (AA), that overcomes these dynamic instabilities by incorporating a Kevlar-inspired domain into the molecular structure. Strong, anisotropic interactions between AAs suppress molecular exchange and elicit spontaneous self-assembly in water to form nanoribbons with lengths of up to 20 microns. The nanoribbons have a Young’s modulus of 1.7 GPa and tensile strength of 1.9 GPa. Here, we exploit this stability to extend small molecule self-assembly to hierarchically ordered macroscopic materials outside of solvated environments. Through an aqueous shear alignment process, we organize AA nanoribbons into arbitrarily long flexible threads that support 200 times their weight when dried. Tensile tests of the threads provide a benchmark for Young’s moduli (between ~400 and 600 MPa) and extensibilities (between ~0.6 and 1.1%) that depend on the counterion chemistry in solution. This bottom-up approach to macroscopic materials could benefit solid-state applications, historically inaccessible by self-assembled nanomaterials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

More concentrated precipitation decreases terrestrial water storage

Terrestrial water availability is a key determinant of human and ecosystem well-being. Apart from mean precipitation and evaporation changes, it is unknown how daily-scale precipitation concentration into fewer, heavier events affects hydrologic partitioning and the land water balance. Here we show observationally that more concentrated precipitation decreases land water availability across all climates globally, a drying effect as strong in magnitude as the wetting effect of increased total precipitation. Simple and complex land-surface models recover the observed effect, whereas idealized simulations show that it arises from enhanced evaporation caused by hydrologic partitioning changes at the land surface. Projected terrestrial water storage impacts of warming-driven precipitation concentration at about 2 °C of warming shift the land surface to abnormally dry conditions (≥0.5 standard deviation) for 27% of the global population, independent of any total precipitation or irrigation changes. Our results show new key determinants of the land water balance, highlighting its sensitivity to the temporal distribution of precipitation, with broad implications for future water availability.

climate change↗

Dataset of ultralow temperature refrigeration for COVID 19 vaccine distribution solution

Abstract Most COVID-19 vaccines require temperature control for transportation and storage. Two types of vaccine have been developed by manufacturers (Pfizer and Moderna). Both vaccines are based on mRNA and lipid nanoparticles requiring low temperature storage. The Pfizer vaccine requires ultra-low temperature storage (−80 °C to −60 °C), while the Moderna vaccine requires −30 °C storage. However, the last stage of distribution is quite challenging, especially for rural or suburban areas, where local towns, pharmacy chains and hospitals may not have the infrastructure required to store the vaccine at the required temperature. In addition, there is limited data available to address ancillary challenges of the distribution framework for both transportation and storage stages, including safety concerns due to human exposure to large amounts of CO 2 from dry-ice sublimation, issues due to the pressure increase caused by dry-ice sublimation, and the potential issue caused by non-uniform cryogenic temperatures. As such, there is a need for test dataset to assist the development of a quick, effective, secure, and safe solution to mitigate the challenges faced by vaccine distribution logistics.

60 APPLIED LIFE SCIENCES↗

Characterization of spent nuclear fuel canister surface roughness using surface replicating molds

In this study we present a replication method to determine surface roughness and to identify surface features when a sample cannot be directly analyzed by conventional techniques. As a demonstration, this method was applied to an unused spent nuclear fuel dry storage canister to determine variation across different surface features. In this study, an initial material down-selection was performed to determine the best molding agent and determined that non-modified Polytek PlatSil23-75 provided the most accurate representation of the surface while providing good usability. Other materials that were considered include Polygel Brush-On 35 polyurethane rubber (with and without Pol-ease 2300 release agent), Polytek PlatSil73-25 silicone rubber (with and without PlatThix thickening agent and Pol-ease 2300 release agent), and Express STD vinylpolysiloxane impression putty. The ability of PlatSil73-25 to create an accurate surface replica was evaluated by creating surface molds of several locations on surface roughness standards representing ISO grade surfaces N 3 , N 5 , N 7 , and N 8 . Overall, the molds were able to accurately reproduce the expected roughness average (R a ) values, but systematically over-estimated the peak-valley maximum roughness (R z ) values. Using a 3D printed sample cell, several locations across the stainless steel spent nuclear fuel canister were sampled to determine the surface roughness. These measurements provided information regarding variability in normal surface roughness across the canister as well as a detailed evaluation on specific surface features (e.g., welds, grind marks, etc.). The results of these measurements can support development of dry storage canister ageing management programs, as surface roughness is an important factor for surface dust deposition and accumulation. This method can be applied more broadly to different surfaces beyond stainless steel to provide rapid, accurate surface replications for analytical evaluation by profilometry.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Monitoring strain evolution in water-sand systems using distributed acoustic sensing for geohazard early warning

Rainfall-driven hazards such as landslides, debris flows, and earthen dam failures often arise when water changes the internal strain within sand. This study evaluates the ability of distributed acoustic sensing to monitor these strain changes in real time. We embed a fiber-optic cable in a sand-filled glass cylinder and run controlled dry- and wet-sand experiments to measure how strain develops as water infiltrates, saturates, and drains from the sand. The sensing system detects uneven water movement in dry sand and enables millimeter-scale estimates of infiltration rates, and in wet sand it tracks rising water levels, delayed strain peaks after saturation, and abrupt strain shifts during drainage. These results show that fiber-optic sensing captures subtle strain evolution throughout the full water-sand interaction cycle. The study demonstrates that fiber-optic sensing offers promising potential for real-time and cost-effective monitoring and early warning of rainfall-induced geohazards.

58 GEOSCIENCES↗

Phenolic acid-degrading Paraburkholderia prime decomposition in forest soil

Abstract Plant-derived phenolic acids are catabolized by soil microorganisms whose activity may enhance the decomposition of soil organic carbon (SOC). We characterized whether phenolic acid-degrading bacteria enhance SOC mineralization in forest soils when primed with 13C-labeled p-hydroxybenzoic acid (pHB). We further tested whether pHB-induced priming could explain differences in SOC content among mono-specific tree plantations in a 70-year-old common garden experiment. pHB addition primed significant losses of SOC (3–13 µmols C g−1 dry wt soil over 7 days) compared to glucose, which reduced mineralization (-3 to -8 µmols C g−1 dry wt soil over 7 days). The principal degraders of pHB were Paraburkholderia and Caballeronia in all plantations regardless of tree species or soil type, with one predominant phylotype (RP11ASV) enriched 23-fold following peak pHB respiration. We isolated and confirmed the phenolic degrading activity of a strain matching this phylotype (RP11T), which encoded numerous oxidative enzymes, including secretion signal-bearing laccase, Dyp-type peroxidase and aryl-alcohol oxidase. Increased relative abundance of RP11ASV corresponded with higher pHB respiration and expression of pHB monooxygenase (pobA), which was inversely proportional to SOC content among plantations. pobA expression proved a responsive measure of priming activity. We found that stimulating phenolic-acid degrading bacteria can prime decomposition and that this activity, corresponding with differences in tree species, is a potential mechanism in SOC cycling in forests. Overall, this study highlights the ecology and function of Paraburkholderia whose associations with plant roots and capacity to degrade phenolics suggest a role for specialized bacteria in the priming effect.

54 ENVIRONMENTAL SCIENCES↗