Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “degradation rate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Scaled-up fabrication of durable and porous adsorbent-coated minichannels on aluminum for CO 2 separation

A method was developed to fabricate zeolite 13X adsorbent-coated minichannels on aluminum for CO₂ adsorption applications in this study. It emphasizes the innovative use of aluminum as a substrate, which offers airtight assembly, paving the way for highly efficient adsorption systems. An optimized coating process was developed using a slurry of Zeolite 13X, yeast, sugar, and xanthan gum, resulting in durable and highly porous layers that enhance CO₂ capture performance. A PETG peeler was designed to remove the top layer of the yeast-engineered adsorbent coatings, revealing a super porous and foamy structure. The teeth of the peeler were designed and fabricated for high repeatability and rapid prototyping. Breakthrough experiments were conducted on the scaled-up adsorbent bed using gas mixtures of 80% CO₂, 20% N₂, and 20% CO₂, 80% N₂ to represent different industrial scenarios. The performance of the bed was evaluated at flow rates of 160 and 190 cm³ min -1 using a Raman Laser Gas Analyzer (RLGA), demonstrating stable adsorption without degradation across multiple cycles. Computational modeling of integral transport phenomena under the chosen experimental conditions was pursued using gPROMS ProcessBuilder™, and the modeling results were compared with those from the tests for adsorption time, which resulted in an error margin of 2% to 9% for the breakthrough time, confirming the easy reproducibility of the design through modeling. This research advances CO₂ capture technologies by providing an effective and scalable solution for producing aluminum-based adsorbent coated beds, supporting industrial carbon capture efforts.

CO2 capture↗
DOE OSTI2020

Light Exposure Promotes Degradation of Intermediates and Growth of Phosphine-Ligated Gold Clusters

Subnanometer clusters exhibit unique properties not observed at the bulk or nanometer scale. Many applications, however, require clusters to be monodisperse in size and composition.While substantial progress has been made empirically on producing specific-sized gold clusters using different ligands, the mechanisms of cluster formation remain insufficiently understood. Using high mass-resolution electrospray ionization mass spectrometry (ESI-MS), we characterized the formation of cationic triphenylphosphine-ligated gold clusters [Aux(PPh3)y z+] in solution. Our data provides evidence that small hydrogen-containing intermediate “building blocks” (i.e., Au2(PPh3)2H+, Au4(PPh3)4H+, and Au7(PPh3)7H5 2+) are responsible for the growth of larger gold clusters (i.e., Au6(PPh3)6 2+ and Au8(PPh3)7 2+) over several hours. In addition, intermediate degradation and cluster growth are shown to be dependent on irradiation of the reacting solution with light. Specifically, the rate of growth of large clusters is demonstrated to scale with the intensity of light exposure. Complementary theoretical calculations were also performed that provide molecular-level insight into the nature of the bonding between the hydrogens and gold atoms in the intermediate Au-phosphine clusters. Collectively, our joint experimental and theoretical findings advance the understanding of the factors at play in the size-selective synthesis of ligated gold clusters in solution.

Hewitt, Michael A.↗
DOE OSTI2022

Evaluating and Improving Scale–Awareness of a Convective Parameterization Closure Using Cloud–Resolving Model Simulations of Convection

This study aims to evaluate a revised closure of the Zhang-McFarlane (ZM) scheme for deep convection and to further improve its scale awareness. Output from two cloud-resolving model (CRM) simulations of both midlatitude organized (MC3E) and tropical unorganized (TWP-ICE) convection are used for the evaluation. By averaging the CRM output over different subdomain sizes from 64 km to 4 km, convection-associated fields are obtained to represent the fields at different horizontal resolutions of global climate models (GCMs). The convection parameterization closure is then tested using these fields. Results show that the cloud base mass flux M b determined from the closure has a relatively good relationship with CRM-simulated convection at coarse resolutions for both MC3E and TWP-ICE, but their correlation degrades at higher resolutions, especially when approaching the gray zone scale under 10 km. The fluctuation of CAPE consumption rate per unit cloud base mass flux for different convective events is found to be an important factor affecting the correlation. When averaged over the base domain, the cloud base mass flux determined by the closure is found to increase with decreasing subdomain size, implying that the closure is not scale-aware. To improve its scale-awareness, a modified closure is designed to alleviate the overprediction of convection at high GCM resolutions. Furthermore, results show that the modified closure has the scale-aware ability to suppress the overprediction problem at high GCM resolutions for both MC3E and TWP-ICE.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Organic Vacuum Pump Fluids for the Vacuum Pumping of Fusion Power Plants

Vacuum pumps are the heart of the fusion fuel cycle, but most currently proposed pumping technologies are not capable of handling the required flow rates and vacuum pressures. Oil-containing vacuum pumps can readily meet the flow requirements, but vacuum fluids will degrade in fusion-relevant environments due to contact with tritium and exposure to high-energy radiation. Here, in this study, we describe a methodology to screen vacuum fluid candidates and purify these candidate fluids post oxidation, post exposure to deuterium, and post exposure to gamma radiation (<7.5 MGy) to simulate a process in which vacuum fluids can be recovered and regenerated during the fusion fuel cycle. A series of oils, including a highly purified mineral oil, phenyl silicone oil, and a polyphenyl ether, are shown to be suitable candidates for vacuum pumping. Additionally, we describe a simple purification methodology to remove oxidized functionalities and the associated isotopologues induced by contact with deuterium from the candidate vacuum fluids This purification methodology can also be applied to radiological damage with moderate effect. Finally, we demonstrate that the sorbents can be regenerated through electromagnetic microwave digestion.

oxidation↗
DOE OSTI2025

Low-Cost Sulfur Thermal Storage for Solar Industrial Process Heat Applications

Industrial process heat (IPH) is one of the largest energy demands in U.S., representing about 10% of all domestic energy consumption. Fuel costs to generate this industrial process heat are generally a top three cost for industry, a major component in American manufacturing competitiveness. Roughly 60% of US IPH demand (about 6,500 TBtu annually) falls in the medium-temperature range of 100–250 °C. While concentrated solar thermal (CST) technologies can provide a cost-effective source of heat in this temperature range, solar intermittency limits their adoption in industries that operate 24/7. Element 16 Technologies, Inc. developed a low-cost sulfur thermal energy storage (TES) technology to bridge this gap by capturing excess solar heat during the day and dispatching it reliably during non-solar hours. The core innovation is the use of sulfur, an abundant, industrial waste byproduct that costs ten times less than molten salt used in commercial TES systems. The overall goal of the project was to advance the design and development of molten sulfur TES to a manufacturing-relevant prototype stage for solar industrial process heat applications, while establishing and validating a realistic pathway to commercial success. Key tasks included corrosion and mechanical durability testing to identify cost-effective materials, design investigations using physics-based simulation tools, techno-economic evaluations of system lifetime costs, and pilot-scale testing for performance verification. Corrosion testing of steel alloys under cyclic molten sulfur conditions showed that austenitic stainless steels in the 300 series performed particularly well, with no structural degradation of welds or joints. Thermal cyclic testing of pilot sulfur TES units up to 1.5 MWh quantified charge/discharge rates, heat losses, round-trip efficiency and validated the system's capability to operate effectively under intermittent charging conditions. A techno-economic model, informed by sulfur TES performance model validated using pilot test data, showed that hybrid solar+sulfur TES+NG boiler systems are economically competitive with incumbent natural gas boilers for multiple locations in the southwest US. In summary, this project established molten sulfur TES as a technically viable pathway to improve economic competitiveness of American manufacturing by lowering the cost of solar industrial process heat.

14 SOLAR ENERGY↗
DOE OSTI2023

Analysis of Crystalline Defects Caused by Growth on Partially Planarized Spalled (100) GaAs Substrates

We analyze the effect of growth on non-(100) surfaces resulting from incomplete planarization of spalled GaAs wafers on the defect structure of GaAs solar cell layers grown by hydride vapor phase epitaxy (HVPE). Controlled spalling of (100)-oriented GaAs has the potential to reduce substrate costs for III-V epitaxy; however, it creates regularly faceted surfaces that may complicate the growth of high-quality III-V optoelectronic devices. We leverage the anisotropic growth rate of HVPE to planarize these faceted GaAs substrates, reducing the surface roughness and degree of faceting. We observe degraded solar cell performance and material quality in sample areas where facets are not completely removed. We used dark lock-in thermography and photoluminescence to identify recombination in areas that were not fully planarized. We used cathodoluminescence to identify the presence of extended defects in these regions, which are correlated with bandgap fluctuations in the material. We hypothesize that these defects were created by strain from compositional fluctuations in ternary alloys grown on the faceted surfaces. This work elucidates the potential issues of solar cells grown on faceted surfaces and builds understanding toward realizing high performance III-V photovoltaics with the cost-reduction potential of controlled spalling.

14 SOLAR ENERGY↗
NASA NTRS1988

The behavior of a Costas loop in the presence of space telemetry signals

The telemetry modulation index, telemetry bit rate, subcarrier waveform, and subcarrier frequency are shown to be the key system parameters that contribute to the performance degradation of a Costas loop in the presence of space telemetry signals. The effects of the Doppler in the loop are also investigated. The results of this study were input to the Consultative Committee for Space Data Systems (CCSDS) for consideration in the future standard suppressed-carrier space telemetry system.

Nguyen, T. M.↗
NASA NTRS1990

The aerodynamic effect of heavy rain on airplane performance

The National Aeronautics and Space Administration has been conducting a series of tests to determine the effect of heavy rain on airfoil aerodynamics. The results of these tests have shown that heavy rain can significantly increase drag as well as decrease lift and stall angle of attack. This paper describes a recent effort to use the heavy rain airfoil data to determine the aerodynamic effect on a conventional twin-jet transport. The paper reports on the method used to model the heavy rain aerodynamic effect and the resulting performance degradation. The heavy rain performance effect is presented in terms of the diminished climb performance associated with increasing rain rates. The effect of heavy rain on the airplane's ability to escape a performance-limiting wind shear is illustrated through a numerical simulation of a wet microburst encounter. The results of this paper accentuate the need for further testing to determine scaling relationships and flow mechanics, and the full configuration three-dimensional effects of heavy rain.

Vicroy, Dan D.↗
NASA NTRS1992

The behavior of a Costas loop in the presence of space telemetry signals

When the Costas loop is operated in the presence of a residual carrier space telemetry signal, the loop reconstructs its carrier reference from an input signal whose carrier component is not completely suppressed. The telemetry signal investigated in this work is generated by phase shift-keying the data onto a subcarrier and then phase modulating onto the sinusoidal carrier. The telemetry modulation index, telemetry bit rate, subcarrier waveform, and subcarrier frequency are shown to be the key system parameters that contribute to the performance degradation of a Costas loop. Furthermore, the effect of Doppler shift on the loop is also investigated in this work.

Nguyen, Tien M.↗
NASA NTRS1994

Solid rocket combustion simulator technology using the hybrid rocket for simulation

The hybrid rocket is reexamined in light of several important unanswered questions regarding its performance. The well-known heat transfer limited burning rate equation is quoted, and its limitations are pointed out. Several inconsistencies in the burning rate determination through fuel depolymerization are explicitly discussed. The resolution appears to be through the postulate of (surface) oxidative degradation of the fuel. Experiments are initiated to study the fuel degradation in mixtures of nitrogen/oxygen in the 99.9 percent/0.1 percent to 98 percent/2 percent range. The overall hybrid combustion behavior is studied in a 2 in-diameter rocket motor, where a PMMA tube is used as the fuel. The results include detailed, real-time infrared video images of the combustion zone. Space- and time-averaged images give a broad indication of the temperature reached in the gases. A brief outline is shown of future work, which will specifically concentrate on the exploration of the role of the oxidizer transport to the fuel surface, and the role of the unburned fuel that is reported to escape below the classical time-averaged boundary layer flame.

Ramohalli, Kumar↗
NASA NTRS1996

Phospa-s-Triazines and Related Compositions of Improved Hydrolytic and Thermal Stability

The objective of the Program was to synthesize novel degradation inhibitors for perfluoropolyalkylether fluids and to evaluate their performance as well as that of other available inhibitors. Four novel additives: (C3F7OCF(CF3)CF2OC(CF3)2CN)((C6H5)2PN)2, (C3F7O(CF(CF3)CF2O)2C(CF3)2CN)((C6H5)2PN)2, u-(C3F7OCF(CF3)CF2OC(CF3)2CN)2((C6H5)2PN)2 and C3F7(OCF(CF3)CF2)6C6H4OP(O)(OC6H5)2 were prepared, characterized and their thermal stabilities established. The alloys studied were: 440C steel, M-50 steel, Pyrowear 675, Cronidur 30, Ti (4Al, 4Mn), and Ti (6Al, 4V). The additives and metals were evaluated in two different lots of Fomblin Z25, in Krytox 143AC and in Krytox 16256. Phosphate esters were found to be fully effective in arresting perfluoropolyaucylether fluid's degradation at temperatures up to 300 C over 24 h in the presence of alloys in oxygen. The overall rating of additives was: phosphates greater than phosphate/diester mixture greater than phosphine grater vthan or equal to phpospha-s-triazines.

Paciorek, K. J. L.↗
NASA NTRS2012

Interuser Interference Analysis for Direct-Sequence Spread-Spectrum Systems Part I: Partial-Period Cross-Correlation

This presentation discusses an analysis approach to evaluate the interuser interference for Direct-Sequence Spread-Spectrum (DSSS) Systems for Space Network (SN) Users. Part I of this analysis shows that the correlation property of pseudo noise (PN) sequences is the critical factor which determines the interuser interference performance of the DSSS system. For non-standard DSSS systems in which PN sequence s period is much larger than one data symbol duration, it is the partial-period cross-correlation that determines the system performance. This study reveals through an example that a well-designed PN sequence set (e.g. Gold Sequence, in which the cross-correlation for a whole-period is well controlled) may have non-controlled partial-period cross-correlation which could cause severe interuser interference for a DSSS system. Since the analytical derivation of performance metric (bit error rate or signal-to-noise ratio) based on partial-period cross-correlation is prohibitive, the performance degradation due to partial-period cross-correlation will be evaluated using simulation in Part II of this analysis in the future.

Ni, Jianjun (David)↗
NASA NTRS2013

Downscaling Reanalysis over Continental Africa with a Regional Model: NCEP Versus ERA Interim Forcing

Five annual climate cycles (1998-2002) are simulated for continental Africa and adjacent oceans by a regional atmospheric model (RM3). RM3 horizontal grid spacing is 0.44deg at 28 vertical levels. Each of 2 simulation ensembles is driven by lateral boundary conditions from each of 2 alternative reanalysis data sets. One simulation downs cales National Center for Environmental Prediction reanalysis 2 (NCPR2) and the other the European Centre for Medium Range Weather Forecasts Interim reanalysis (ERA-I). NCPR2 data are archived at 2.5deg grid spacing, while a recent version of ERA-I provides data at 0.75deg spacing. ERA-I-forced simulations are recomrp. ended by the Coordinated Regional Downscaling Experiment (CORDEX). Comparisons of the 2 sets of simulations with each other and with observational evidence assess the relative performance of each downscaling system. A third simulation also uses ERA-I forcing, but degraded to the same horizontal resolution as NCPR2. RM3-simulated pentad and monthly mean precipitation data are compared to Tropical Rainfall Measuring Mission (TRMM) data, gridded at 0.5deg, and RM3-simulated circulation is compared to both reanalyses. Results suggest that each downscaling system provides advantages and disadvantages relative to the other. The RM3/NCPR2 achieves a more realistic northward advance of summer monsoon rains over West Africa, but RM3/ERA-I creates the more realistic monsoon circulation. Both systems recreate some features of JulySeptember 1999 minus 2002 precipitation differences. Degrading the resolution of ERA-I driving data unrealistically slows the monsoon circulation and considerably diminishes summer rainfall rates over West Africa. The high resolution of ERA-I data, therefore, contributes to the quality of the downscaling, but NCPR2laterai boundary conditions nevertheless produce better simulations of some features.

Reanalysis↗
NASA NTRS2021

Widespread Megaripple Activity Across the North Polar Ergs of Mars

The most expansive dune fields on Mars surround the northern polar cap where various aeolian bedform classes are modified by wind and ice. The morphology and dynamics of these ripples, intermediate-scale bedforms (termed megaripples and transverse aeolian ridges (TARs)), and sand dunes reflect information regarding regional boundary conditions. We found that populations of polar megaripples and larger TARs are distinct in terms of their morphology, spatial distribution, and mobility. Whereas regionally-restricted TARs appeared degraded and static in long-baseline observations, polar megaripples were not only widespread but migrating at relatively high rates (0.13± 0.03 m/Earth year) and possibly more active than other regions on Mars. This high level of activity is somewhat surprising since there is limited seasonality for aeolian transport due to surficial frost and ice during the latter half of the martian year. A comprehensive analysis of an Olympia Cavi dune field estimated that the advancement of megaripples, ripples, and dunes avalanches accounted for ~1%, ~10%, and ~100%, respectively, of the total aeolian system’s sand fluxes. This included dark-toned ripples that migrated the average equivalent of 9.6±6 m/yr over just 22 days in northern summer - unprecedented rates for Mars. While bedform transport rates are some of the highest yet reported on Mars, the sand flux contribution between the different bedforms does not substantially vary from equatorial sites with lower rates. Seasonal off-cap sublimation winds and summer-time polar storms are attributed as the cause for the elevated activity, rather than cryospheric processes. Plain Language Summary “Megaripples” are distinct wind-driven bedforms that occur on the surface of Earth and Mars, often with sizes between that of smaller ripples and larger dunes. Recent work has found the thin martian atmosphere can mobilize some coarse-grained megaripples, overturning prior notions that these were static relic landforms from a past climate. We mapped megaripples and adjacent bedforms across the north polar sand seas, the most expansive collection of dune fields on Mars. Megaripples were found to be widespread across the region and migrating at relatively high rates relative to other sites on Mars that are at lower latitudes. This enhanced activity is likely related to the greater sand fluxes found for neighboring dunes which are driven by summer-time seasonal winds when polar ice is sublimating. In contrast, other megaripples appear to be stabilized, a likely result of inter-granular ice within low wind areas.

Matthew Chojnacki↗
NASA NTRSDate not supplied

How the Open Data Policy of the Landsat Program Has Advanced Our Understanding of Environmental Change

A time series is a sequence of observations of a phenomenon taken sequentially in time. A crucial characteristic of a time series is the dependence among adjacent observations – techniques for analyzing this dependence are referred to as time series analysis. This analytical approach enables us to predict or forecast future values of a time series, study the impact of various inputs on the observed phenomenon, and examine interrelationships among related time series variables. Within the geographical sciences, time series analysis has historically been limited to coarse-resolution satellite data, as constructing time series of data suitable for studying land cover and land use dynamics, such as Landsat data, were prohibitively costly. A transformative shift occurred in 2008 when the U.S. Government decided to make free and open all past and future data collected by the Landsat satellite program. The decision brought about a paradigm shift away from analyzing individual images or observations to continuous monitoring in time. Of particular relevance to environmental remote sensing is the ability to forecast observations – if we can predict how future observations should behave, we can infer information about how the land surface is changing. In this presentation, we will examine literature examples that showcase scientific gains enabled by time series analysis of satellite data. We will delve into how the analysis of dense time series of satellite data revealed that overall rate of forest disturbance in the Amazon has increased despite a reduction in deforestation; how different types of forest degradation, previously unquantified, are now being accurately assessed in the Caucasus region; and how we now can study the highly dynamic and intricate patterns of shifting cultivation in Southeast Asia.

Pontus Olofsson↗
NASA NTRS2026

Evaluation of AMSOIL® -ANT PGW Coolant Formula Change and Super Space AMSOIL Development

AMSOIL ® Propylene Glycol Water (PGW), is the baselined internal thermal control fluid for multiple manned spacecraft including Gateway (HALO, IHAB, and ALM modules) and Orion. The use of AMSOIL-ANT PGW was originally validated through extensive NASA/Collins materials-compatibility testing (circa 2008–2015). However, in late 2019, AMSOIL implemented an unannounced change in its PG inhibitor package. Because of this reformulation, concerns around materials compatibility arose. Therefore, NASA initiated corrosion rate and coolant stability testing in 2024. Results showed that the reformulated AMSOIL PG produced substantially elevated corrosion rates in aluminum alloys (about two times when compared to the original AMSOIL PG formula) accompanied by visible surface degradation. Coolant stability testing indicated accelerated propylene-glycol breakdown as well, with glycolate levels about nine times higher than the original formulation. Based on these findings, NASA Materials & Processes and Thermal Control Systems groups have baselined the use of the original PGW chemistry for all spacecraft use. In response, AMSOIL produced a reformulated variant, “Super Space AMSOIL” (ANT-SSA), compliant with MPCV 70156.This paper documents the reformulation testing completed, details on the formulation change, and the development of Super Space AMSOIL.

Woody Beringer↗
NASA NTRSDate not supplied

Evaluation of AMSOIL ® -ANT PGW Coolant Formula Change and Super Space AMSOIL ® Development

AMSOIL ® Propylene Glycol Water (PGW), is the baselined internal thermal control fluid for multiple manned spacecraft including Gateway (HALO, IHAB, and ALM modules) and Orion. The use of AMSOIL-ANT PGW was originally validated through extensive NASA/Collins materials-compatibility testing (circa 2008–2015). However, in late 2019, AMSOIL implemented an unannounced change in its PG inhibitor package. Because of this reformulation, concerns around materials compatibility arose. Therefore, NASA initiated corrosion rate and coolant stability testing in 2024. Results showed that the reformulated AMSOIL PG produced substantially elevated corrosion rates in aluminum alloys (about two times when compared to the original AMSOIL PG formula) accompanied by visible surface degradation. Coolant stability testing indicated accelerated propylene-glycol breakdown as well, with glycolate levels about nine times higher than the original formulation. Based on these findings, NASA Materials & Processes and Thermal Control Systems groups have baselined the use of the original PGW chemistry for all spacecraft use. In response, AMSOIL produced a reformulated variant, “Super Space AMSOIL” (ANT-SSA), compliant with MPCV 70156.This paper documents the reformulation testing completed, details on the formulation change, and the development of Super Space AMSOIL.

David Brockett↗