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At least 1,135 records · Page 63

Anionic Pt in Silicate Melts at Low Oxygen Fugacity: Speciation, Partitioning and Implications for Core Formation Processes on Asteroids

Most siderophile element concentrations in planetary mantles can be explained by metal/ silicate equilibration at high temperature and pressure during core formation. Highly siderophile elements (HSE = Au, Re, and the Pt-group elements), however, usually have higher mantle abundances than predicted by partitioning models, suggesting that their concentrations have been set by late accretion of material that did not equilibrate with the core. The partitioning of HSE at the low oxygen fugacities relevant for core formation is however poorly constrained due to the lack of sufficient experimental constraints to describe the variations of partitioning with key variables like temperature, pressure, and oxygen fugacity. To better understand the relative roles of metal/silicate partitioning and late accretion, we performed a self-consistent set of experiments that parameterizes the influence of oxygen fugacity, temperature and melt composition on the partitioning of Pt, one of the HSE, between metal and silicate melts. The major outcome of this project is the fact that Pt dissolves in an anionic form in silicate melts, causing a dependence of partitioning on oxygen fugacity opposite to that reported in previous studies.

Medard, E.↗

Effect of Silicon on Activity Coefficients of Platinum in Liquid Fe-Si, With Application to Core Formation

Earth's core contains approximately 10% of a light element that is likely a combination of S, C, Si, and O, with Si possibly being the most abundant light element. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of Pt (with Re and Ru in progress or planned) between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle Pt concentrations.

Righter, K.↗

A Search for O2 in CO-Depleted Molecular Cloud Cores With Herschel

The general lack of molecular oxygen in molecular clouds is an outstanding problem in astrochemistry. Extensive searches with the Submillimeter Astronomical Satellite, Odin, and Herschel have only produced two detections; upper limits to the O2 abundance in the remaining sources observed are about 1000 times lower than predicted by chemical models. Previous atomic oxygen observations and inferences from observations of other molecules indicated that high abundances of O atoms might be present in dense cores exhibiting large amounts of CO depletion. Theoretical arguments concerning the oxygen gas-grain interaction in cold dense cores suggested that, if O atoms could survive in the gas after most of the rest of the heavy molecular material has frozen out onto dust, then O2 could be formed efficiently in the gas. Using Herschel HIFI, we searched a small sample of four depletion cores-L1544, L694-2, L429, and Oph D-for emission in the low excitation O2 N(sub J)=3(sub 3)-1(sub 2) line at 487.249 GHz. Molecular oxygen was not detected and we derive upper limits to its abundance in the range of N(O2)/N (H2) approx. = (0.6-1.6) x10(exp -7). We discuss the absence of O2 in the light of recent laboratory and observational studies.

ISM: abundances↗

Core Formation on Asteroid 4 Vesta: Iron Rain in a Silicate Magma Ocean

Geochemical observations of the eucrite and diogenite meteorites, together with observations made by NASA's Dawn spacecraft, suggest that Vesta resembles H chondrites in bulk chemical composition, possibly with about 25% of a CM-chondrite like composition added in. For this model, the core is 15% by mass (or 8 volume %) of the asteroid. The abundances of moderately siderophile elements (Ni, Co, Mo, W, and P) in eucrites require that essentially all of the metallic phase in Vesta segregated to form a core prior to eucrite solidification. Melting in the Fe-Ni-S system begins at a cotectic temperature of ~940 deg. C. Only about 40% of the total metal phase, or 3-4 volume % of Vesta, melts prior to the onset of silicate melting. Liquid iron in solid silicate initially forms isolated pockets of melt; connected melt channels, which are necessary if the metal is to segregate from the silicate, are only possible when the metal phase exceeds about 5 volume %. Thus, metal segregation to form a core does not occur prior to the onset of silicate melting.

Kiefer, Walter S.↗

Validation of SMAP Surface Soil Moisture Products with Core Validation Sites

The NASA Soil Moisture Active Passive (SMAP) mission has utilized a set of core validation sites as the primary methodology in assessing the soil moisture retrieval algorithm performance. Those sites provide well calibrated in situ soil moisture measurements within SMAP product grid pixels for diverse conditions and locations.The estimation of the average soil moisture within the SMAP product grid pixels based on in situ measurements is more reliable when location specific calibration of the sensors has been performed and there is adequate replication over the spatial domain, with an up-scaling function based on analysis using independent estimates of the soil moisture distribution. SMAP fulfilled these requirements through a collaborative CalVal Partner program.This paper presents the results from 34 candidate core validation sites for the first eleven months of the SMAP mission. As a result of the screening of the sites prior to the availability of SMAP data, out of the 34 candidate sites 18 sites fulfilled all the requirements at one of the resolution scales (at least). The rest of the sites are used as secondary information in algorithm evaluation. The results indicate that the SMAP radiometer-based soil moisture data product meets its expected performance of 0.04 cu m/cu m volumetric soil moisture (unbiased root mean square error); the combined radar-radiometer product is close to its expected performance of 0.04 cu m/cu m, and the radar-based product meets its target accuracy of 0.06 cu m/cu m (the lengths of the combined and radar-based products are truncated to about 10 weeks because of the SMAP radar failure). Upon completing the intensive CalVal phase of the mission the SMAP project will continue to enhance the products in the primary and extended geographic domains, in co-operation with the CalVal Partners, by continuing the comparisons over the existing core validation sites and inclusion of candidate sites that can address shortcomings.

SMAP↗

3D Printed Structural Core with MMOD Protection

Deep space exploration requires large habitats for both orbital and surface missions. The weight of a habitat is driven largely by its structure and future vehicles require lighter weight structures to minimize launch mass and cost. Unlike honeycomb core materials used in the past, a 3D printed core can be analyzed and optimized for specific load environments, further cutting down mass of the vehicle. Multi-functional structures can integrate features into the primary structure that are traditionally added mass. MMOD (Micro Meteor and Orbital Debris) protection, for example, can be integrated directly into the primary structure of a habitat. This minimizes the mass of the structure and eliminates the need for additional MMOD layers and attachment hardware. This project seeks to develop 3D printed structural core that can be optimized for flights loads and provide integrated MMOD protection.

Hagen, Richard↗

Decadal Polar Motion of the Earth Excited by the Convective Outer Core From Geodynamo Simulations

Long time geodetic observation records show that the orientation of the Earth's rotation axis with respect to the terrestrial reference frame, or polar motion, changes on a broad range of timescales. Apart from external torques from the luni-solar tides, these changes are excited by interactions among different components of the Earth system. The convective fluid outer core has long been conjectured a likely contributor to the observed polar motion on timescales upward of decades, such as the 30 year Markowitz wobble. We investigated the electromagnetic coupling scenario across the core-mantle boundary via numerical geodynamo simulation for different geodynamo parameters (Rayleigh numbers and magnetic Rossby numbers). Our simulated polar motion varies strongly with the dynamo parameters, while its excitation on decadal timescales appear to converge asymptotically within the adopted range of numerical Rossby numbers. Three strongest asymptotic modes emerge from numerical results, with periods around 30, 40, and 60 years for the prograde excitation and around 24, 30, and 60 years for the retrograde excitation. Their amplitudes are all larger than 5 times 10 (sup minus 8), or approximately 10 milliseconds of arc.The results suggest that the electromagnetic core-mantle coupling could explain a substantial portion, if not all, of the observed decadal polar motion. In particular, the predicted 60 year polar motion deserves special attention for future observations and studies.

Kuang, W.↗

Using Machine Learning to Predict Core Sizes of High-Efficiency Turbofan Engines

With the rise in big data and analytics, machine learning is transforming many industries. It is being increasingly employed to solve a wide range of complex problems, producing autonomous systems that support human decision-making. For the aircraft engine industry, machine learning of historical and existing engine data could provide insights that help drive for better engine design. This work explored the application of machine learning to engine preliminary design. Engine core-size prediction was chosen for the first study because of its relative simplicity in terms of number of input variables required (only three). Specifically, machine-learning predictive tools were developed for turbofan engine core-size prediction, using publicly available data of two hundred manufactured engines and engines that were studied previously in NASA aeronautics projects. The prediction results of these models show that, by bringing together big data, robust machine-learning algorithms and automation, a machine learning-based predictive model can be an effective tool for turbofan engine core-size prediction. The promising results of this first study paves the way for further exploration of the use of machine learning for aircraft engine preliminary design.

Tong, Michael T.↗

Chapter 6: Sulfur on Mars from the Atmosphere to the Core

Observations of the martian surface from orbiting spacecraft and in situ landers and rovers, as well as analyses of martian meteorites in terrestrial laboratories, have consistently indicated that Mars is a sulfur-rich planet. The global inventory of sulfur, from the atmosphere to the core, carries widespread implications of potential geophysical, geochemical, climatological, and astrobiological significance. For example, the sulfur content of the core carries implications for core density; the speciation of igneous sulfur minerals reflects the oxidation state of the magma from which they formed; sulfur-bearing gases may have exerted control on the temperatures at the surface of early Mars; and the widespread availability of sulfur on Mars would have provided an abundant source for energy and nutrients to fuel sulfur-metabolizing microbes, such as those that arose during the emergence of primitive life on Earth. Here we provide an overview of martian sulfur and its relevance to these areas of interest, including a discussion of analytical techniques and results acquired by space missions and meteorite analyses to date. We review current studies modeling the potential effects of sulfur-bearing gases on the past martian climate and possible constraints on atmospheric composition implied by sulfur isotopic data. We also explore the importance of sulfur to the search for extinct or extant life on Mars. Finally, we summarize a few areas of interest to future work, including advances in space exploration technology and preparation for Mars sample return.

Climate↗

Analysis of WFPC-2 Core Samples for MMOD Discrimination

An examination of the Hubble Space Telescope Wide Field Planetary Camera 2 (WFPC-2) radiator assembly was conducted at NASA Goddard Space Flight Center during the summer of 2009. Immediately apparent was the predominance of impact features, identified as simple or complex craters, resident only in the thermal paint layer; similar features were observed during a prior survey of the WFPC-1 radiator. Larger impact features displayed spallation zones, darkened areas, and other features not observed in impacts onto bare surfaces. Craters were extracted by coring the radiator in the NASA Johnson Space Center’s Space Exposed Hardware cleanroom and were subsequently examined using scanning electron microscopy/energy dispersive X-ray spectroscopy to determine the likely origin, e.g., micrometeoritic or orbital debris, of the impacting projectile. Recently, a selection of large cores was re-examined using a new technique developed to overcome some limitations of traditional crater imaging and analysis. This technique, motivated by thin section analysis, examines a polished, lateral surface area revealed by cross-sectioning the core sample. This paper reviews the technique, the classification rubric as extended by this technique, and results to date.

Anz-Meador, P.↗

Bioinspired Honeycomb Core Design: An Experimental Study of the Role of Corner Radius, Coping, and Interface

The honeybee’s nest has inspired the design of engineering honeycomb core that primarily abstract the hexagonal cell shape and exploit its mass minimizing properties to construct lightweight panels. This work explored three additional design features that are part of the natural honeybee comb but have not been traditionally considered as design features of interest in honeycomb design: the radius at the corner of each cell, the coping at the top of the cell walls, and the interface between cell arrays. These features were first characterized in natural honeycomb using optical and X-ray techniques, and then incorporated into honeycomb core design, and fabricated using an additive manufacturing process. The honeycomb cores were then tested in out-of-plane compression and bending, and since all three design features added mass to the overall structure, all metrics were examined per unit mass to assess performance gains. The study concluded that the addition of an interface increases specific flexural modulus but has little benefit in out-of-plane compression; coping radius positively impacts specific flexural strength; but that the corner radius has no significant effect in bending, and actually is slightly detrimental for out-of-plane compression testing.

honeycomb↗

DGEN Aeropropulsion Research Turbofan Core/Combustor-Noise Measurements-Experiment and Modal Structure at Core-Nozzle Exit

Data from a recent core/combustor-noise source-diagnostic test utilizing a small turbo-fan engine are analyzed. The campaign continued the exploration begun in a baseline test, but with more extensive acoustic instrumentation. Both tests were aimed at developing a better understanding of propulsion-noise sources and their impact on the farfield noise signature, in order to enable improved turbofan noise-prediction methods and noise-mitigation techniques. Simultaneous high-data-rate acoustic measurements (93 channels in total) were obtained using a circumferential sensor array at the core-nozzle exit in conjunction with sideline and farfield microphone arrays for several relevant engine operational points. Measurements were repeated for different circumferential and sideline array configurations, as well as for redundancy. The unsteady pressure field at the core-nozzle exit is documented in detail. Previous work suggested that the±1azimuthal duct mode could be cut-on at this location, which would have implications for combustor-noise modeling and prediction. The modal decomposition of the combustor noise at the core-nozzle exit verifies this observation. Select farfield sound-pressure-level spectra are also presented.

Aeroacoustics↗

In Vitro Selections with RNAs of Variable Length Converge on a Robust Catalytic Core

In vitro selection is a powerful tool that can be used to understand basic principles of molecular evolution. We used in vitro selection to understand how changes in length and the accumulation of point mutations enable the evolution of functional RNAs. Using RNA populations of various lengths, we performed a series of in vitro experiments to select for ribozymes with RNA ligase activity. We identified a core ribozyme structure that was robust to changes in RNA length, high levels of mutagenesis, and increased selection pressure. Elaboration on this core structure resulted in improved activity which we show is consistent with a larger trend among functional RNAs in which increasing motif size can lead to an exponential improvement in fitness. We conclude that elaboration on conserved core structures is a preferred mechanism in RNA evolution. This conclusion, drawn from selections of RNAs from random sequences, is consistent with proposed evolutionary histories of specific biological RNAs. More generally, our results indicate that modern RNA structures can be used to infer ancestral structures. Our observations also suggest a mechanism by which structural outcomes of early RNA evolution would be largely reproducible even though RNA fitness landscapes consist of disconnected clusters of functional sequences.

In vitro evolution↗

A remnant planetary core in the hot-Neptune desert

The interiors of giant planets remain poorly understood. Even for the planets in the Solar System, difficulties in observation lead to large uncertainties in the properties of planetary cores. Exoplanets that have undergone rare evolutionary processes provide a route to understanding planetary interiors. Planets found in and near the typically barren hot-Neptune ‘desert’ (a region in mass–radius space that contains few planets) have proved to be particularly valuable in this regard. These planets include HD149026b, which is thought to have an unusually massive core, and recent discoveries such as LTT9779b and NGTS-4b, on which photoevaporation has removed a substantial part of their outer atmospheres. Here we report observations of the planet TOI-849b, which has a radius smaller than Neptune’s but an anomalously large mass of 39.1(+2.7−2.6) Earth masses and a density of 5.2(+0.7−0.8) grams per cubic centimetre, similar to Earth’s. Interior-structure models suggest that any gaseous envelope of pure hydrogen and helium consists of no more than 3.9(+0.8−0.9) per cent of the total planetary mass. The planet could have been a gas giant before undergoing extreme mass loss via thermal self-disruption or giant planet collisions, or it could have avoided substantial gas accretion, perhaps through gap opening or late formation. Although photoevaporation rates cannot account for the mass loss required to reduce a Jupiter-like gas giant, they can remove a small (a few Earth masses) hydrogen and helium envelope on timescales of several billion years, implying that any remaining atmosphere on TOI-849b is likely to be enriched by water or other volatiles from the planetary interior. We conclude that TOI-849b is the remnant core of a giant planet.

David J. Armstrong↗

Stratigraphy of the Apollo 17 Landslide Core 73002 From FMR Maturity and VNIR and Mössbauer Spectroscopy

A suite of samples from the Apollo missions to the Moon (1969-1973) were set aside and stored under controlled conditions to have unexamined lunar samples available decades later for analyses that take advantage of evolved sample handling techniques, maturation of then existing instrumentation, and development of new analytical techniques and instrumentation [e.g., 1]. One preserved sample is the Apollo 17 double drive tube core (73001/2) that was driven into the lunar surface on the landslide deposit at Station 3 on the South Massif in the Taurus-Littrow valley [2]. The deeper section (73001) was stored frozen in a Core Sample Vacuum Container (CSVC) to maximize preservation of lunar volatiles. We report here, as a part of the Apollo Next Generation Sample Analysis (ANGSA) Initiative [1,3], stratigraphy for the upper core section (73002) with respect to maturity (ferromagnetic resonance (FMR) maturity index Is/FeO [4-6]), visible-near-IR (VNIR) spectroscopy, and, for representative samples, grain-size analysis and Mössbauer spectroscopy. Stratigraphy provides data to model the dynamics of lunar landslide deposits and their post-emplacement evolution in comparison to impact-driven mixing on an airless body and stratigraphic context for volatile and (if any) organic behavior. Reported by [7] are preliminary results for multispectral imaging and hyperspectral scanning of the first dissection pass of 73002.

R. V. Morris↗

STIG: A Two-Speed Transmission Aboard the Mars2020 Coring Drill

The coring drill, part of the Sampling & Caching Subsystem (SCS) aboard the Mars2020 rover, demands a wide range of drill bit torque and speed capabilities during sample acquisition operations. The two driving operating points are high speed, low torque for rotary-percussive coring, as well as low speed, high torque for separating the rock core sample from its parent rock. The spindle twin-input transmission (STIG) allows these and other operating points to be reached with an actuator of substantially less peak power and maximum current draw than that of a single-speed actuator. Rather than containing gearing of its own, the transmission interfaces to an actuator with two outputs of different gear ratios, allowing the transmission to select one of the two of the outputs to be coupled to the drill bit. This paper describes the design, capabilities, and challenges associated with the transmission and the dual-output actuator.

Szwarc, Timothy↗

Determining Surface Exposure Ages of Regolith Grains in Lunar Core Sample 73002 By Investigating Solar Particle Irradiation Damage

Space weathering causes the surface soils of airless bodies like the Moon to be micro-structurally and chemically altered by exposure to micrometeoroid bombardment and solar wind irradiation. These alterations accumulate in surface grains with continued residence in the uppermost millimeters of regolith. Low energy solar wind ions (largely H+ and He+) produce a layer of radiation damage as they become implanted in grain surfaces. Also present are solar energetic particle (SEP) tracks, which are nanoscale lineations within grain interiors formed by heavy, high-energy ions (mainly Fe group nuclei) penetrating up to millimeters below the surface. Recent work has determined that the width of solar wind-damaged rims on anorthite and olivine, and their respective SEP track densities are correlated with each other and with grain surface exposure age. Core sample 73002, recently released under the Apollo Next Generation Sample Analysis (ANGSA) Program, has provided an opportunity to study material collected from the light mantle formation in the Taurus-Littrow Valley during Apollo 17. The light mantle is thought to have been deposited vial and slide originating from the neighboring South Massif. Spectral analysis of bulk core soils found a plagioclase rich composition, confirming a highlands origin of the formation. Spectral profiles and ferromagnetic resonance (FMR) measurements of bulk soils sampled at cm-intervals from 73002 indicate that regolith up to~9.5 cm in depth have maturity indices consistent with longer durations of surface processing than samples deeper in the core. Thus, this upper ~9 cm layer likely represents the maximum extent of an in-situ reworking zone which may have persisted over 5 to 17million years. Here we present an analysis of grain exposure ages within the in-situ reworking zone of 73002derived from SEP track density measurements via transmission electron microscopy.

J A McFadden↗

Flight Performance and Stability of Space Launch System Core Stage Thrust Vector Control

The Space Launch System (SLS) Core Stage (CS) Thrust Vector Control (TVC) system is comprised of eight mechanical feedback Shuttle heritage Type III TVC actuators and four RS-25 engines, each attached to a Shuttle heritage gimbal block/bearing. The Core Stage TVC shares vehicle control authority with the SLS 5-segment Solid Rocket Boosters (SRBs) during boost phase flight, and is the sole means of vehicle flight control during in exoatmospheric flight following SRB separation. TVC responses during Green Run Hot Fire (GRHF) testing revealed that the TVC did not meet its performance specifications. Step and frequency responses exhibited unexpected departures from prior laboratory data and modeled behavior. Post-test analysis determined that the characteristics of the structure and gimbal friction are significantly influenced by the thrust-loaded conditions, and the command avionics exhibited a small but important gain nonlinearity. Using the available test data, the design team augmented the flight control TVC models to bound the observed results and include the additional fidelity needed for vehicle flight control analysis so as to build sufficient rationale for flight certification. Prior to the Green Run tests, “simplex” linear models typically used for flight control analysis did not include gimbal friction and other nonlinearities owing to long-standing assumptions that these effects were negligible in the Shuttle Orbiter TVC system. Following the Green Run findings, simulation analysis of the flight dynamics in the time and frequency domain revealed the propensity for a flight control limit cycle oscillation (LCO) if friction and structural compliances fell near the edges of test-predicted bounds. While the “most probable” models did not predict an in-flight LCO, the SLS Program conservatively proceeded with a system-wide evaluation and ultimate acceptance of the possibility for a small amplitude, low-frequency TVC LCO in flight. A final validation of the extensive test and modeling effort occurred when the first flight of SLS successfully demonstrated the fully integrated performance of the vehicle’s TVC system This paper is the final installment in a seven-paper series surveying the design, engineering, test validation, and flight performance of the Core Stage Thrust Vector Control system. In this paper, the development of flight rationale in light of the TVC responses observed in Green Run is discussed, along with a review of the flight telemetry illustrating the correlation of the preflight predictions with the observed performance.

John H. Wall↗