Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “activation potential”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,135 records · Page 63

An Introduction to Los Alamos National Laboratory [Slides]

The Weapon Systems Engineering Division (W) provides the system engineering and program management necessary to sustain the safety, reliability, and security of the Los Alamos National Laboratory’s assets in the active United States nuclear stockpile - the B61, W76, W78 and W88. The Division generates key certification data for Annual Assessment supporting the Laboratory Director's letter to the President on the health of those warheads. This role demands ongoing surveillance of the active stockpile and evaluation of the potential impact of any issues through design, engineering, fabrication, testing using state-of-the-art computational simulation tools and engineering test facilities. The Division works in close liaison with the several production facilities across the nuclear security complex as well as with the customers in the US Navy and Air Force.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Enhancing Risk Analysis of Accidental Release Using CFD Modeling and Machine Learning

This project report presents the results from the AU31 project that is entitled “Enhancing Risk Analysis of Accidental Release Using CFD Modeling and Machine Learning” performed between FY2021 and FY2022. The technical objective of this project is to enhance risk analysis of accidental release of radioactive materials and provide novel risk forecasting and capabilities for assessing unplanned hazardous chemical releases for the U.S. Department of Energy (DOE). The approach includes a cross-platform finite element analysis of airborne chemical release, machine learning (ML) for simulation and forecasting, and a big data approach to data management, transformation and analysis capable of handling petabyte-scale unstructured and structured data. The outcome of these findings were assembled and accessible as a final output via an intuitive web hosted geospatial-based user interface for demonstration and general dissemination. These new results also provide a mechanism of combining this knowledge in a risk analysis framework tool. The geospatial analysis and output can utilize 5 years of qualified meteorological data to illustrate projected plume footprints that are generated from computational aspects of this study. Specifically, we show the development of a geospatial risk analysis capabilities to respond to and plan for accidental release of radioactive materials and to provide a risk forecasting tool for assessing hazardous chemical releases for the DOE. The focus of this effort is germane to common practices in risk analysis; and it is highly relevant to the timely and transparent release of information related to materials at risk including hazardous materials and chemical vapors and rapid assessment of the potential impacts on the workforce at active sites across the DOE complex.

42 ENGINEERING↗

Advanced Simulation and Computing: ASC FY24 Implementation Plan

The DOE National Nuclear Security Administration (NNSA) Stockpile Stewardship Program (SSP) is an integrated technical program for maintaining the safety, security, and reliability of the U.S. nuclear stockpile. The SSP incorporates nuclear test data, computational modeling and simulation, and experimental facilities to advance understanding of nuclear weapons. The suite of data analyzed comes from activities including previous nuclear tests, stockpile surveillance, experimental research, and development and engineering programs. This integrated national program requires the continued use of experimental facilities and the computational capabilities to support the SSP missions. These component parts, in addition to an appropriately scaled production capability, enable NNSA to support stockpile requirements. The ultimate goal of the SSP, and thus of the Advanced Simulation and Computing (ASC) program, is to ensure that the U.S. maintains a safe, secure, and effective strategic deterrent. The ASC program is a cornerstone of the SSP, providing simulation capabilities and computational resources to support the annual stockpile assessment and certification process, study advanced nuclear weapons design and manufacturing processes, analyze accident scenarios and weapons aging, and provide the tools to enable stockpile Life Extension Programs (LEPs) and the resolution of Significant Finding Investigations (SFIs). This work requires a balance of resources, including technical staff, hardware, simulation software, and computer science solutions. The ASC program focuses on increasing the predictive capabilities in a three-dimensional (3D) simulation environment while maintaining support to the SSP. The Program continues to improve its unique tools for understanding and solving progressively more difficult stockpile problems (sufficient resolution, dimensionality, and scientific details), and quantifying critical margins and uncertainties. Resolving each issue requires increasingly difficult analyses because the aging process has progressively moved the stockpile further from the original test base. While the focus remains on the U.S. nuclear weapons program, where possible, the Program also enables the use of high-performance computing (HPC) and simulation tools to address broader national security needs, such as foreign nuclear weapon assessments and nuclear counterterrorism. The 2022 Nuclear Posture Review (NPR) calls for NNSA to “deliver a modern, adaptive nuclear security enterprise based on an integrated strategy for risk management, production-based resilience, science and technology innovation, and workforce initiatives.” Furthermore, “NNSA will establish a Science and Technology Innovation Initiative to accelerate the integration of science and technology (S&T) throughout its activities.” Executing this strategy necessitates the continued emphasis on developing and sustaining high-quality scientific and engineering staff, as well as supporting computational and experimental capabilities. These components constitute the foundation of the nuclear weapons program. The continued success of the SSP and LEPs is predicated upon the ability to credibly certify the stockpile, without a return to underground nuclear tests (UGTs). Shortly after the nuclear test moratorium entered into force in 1992, the Accelerated Strategic Computing Initiative (ASCI) was established to provide an extensive simulation capability to underpin stockpile certification. While computing and simulation have always been essential to the success of the nuclear weapons program, the program goal of ASCI was to execute NNSA’s vision of using these tools in support of the stockpile stewardship mission. The ASCI program was essential to the successful demonstration of the SSP, providing critical nuclear weapons simulation and modeling capabilities. ASCI officially evolved into the ASC program in fiscal year (FY) 2005, but the mission remains essentially the same: provide the simulation and computational capabilities that underpin the ability to maintain a safe, secure, effective nuclear weapon stockpile, without returning to underground nuclear testing. The capabilities that the ASC program provides at the national laboratories play a vital role in the nuclear security enterprise and are necessary for fulfilling the stockpile stewardship and life extension requirements outlined for NNSA. The Program develops modern simulation tools that provide insights into stockpile aging issues, provide the computational and simulation tools that enable designers and analysts to certify the current stockpile and life-extended nuclear weapons, and inform the decision-making process when any modifications in nuclear warheads or the associated manufacturing processes are deemed necessary. Furthermore, ASC is enhancing the predictive simulation capabilities that are essential to evaluate weapons effects, design experiments, and ensure test readiness. The ASC program continues to improve its unique tools to solve stockpile problems— with a focus on sufficient resolution, dimensionality, and scientific detail—to enable Quantification of Margins and Uncertainties (QMU) and to resolve the increasingly difficult analyses needed for stockpile stewardship. The needs of the Stockpile Management and Production Modernization programs (formerly Directed Stockpile Work) also drive the requirements for simulation and computational resources. These requirements include planned LEPs, stockpile support activities, and mitigation efforts against the potential for technical surprise. All of the weapons within the current stockpile are in some stage of the life extension process. The simulation and computational capabilities are crucial for successful execution of these life extensions and for ensuring NNSA can certify these life-extended weapons without conducting a UGT.

97 MATHEMATICS AND COMPUTING↗

The Effect of Metal Promoters in an Mo-Supported HZSM-5 Catalyst for Microwave-Assisted Methane Dehydroaromatization to Aromatics

Microwave (MW)-assisted methane dehydroaromatization (MDHA) using an Mo-supported HZSM-5 catalyst (Mo/HZ5) can convert methane into value-added aromatic products in modular microwave reactor systems, enabling producers to generate revenue from an otherwise wasted resource. Modifying the local environments of active Mo species with metal promoters potentially regulates the reaction/deactivation pathways and improves the heating properties of the Mo/HZ5 under microwaves. Herein, metal promoters (M), including monovalent K+ and bivalent Co2+ and Ni2+, were incorporated to form M-Mo/HZ5 and their MDHA performance was investigated.

metal promoters↗

In-situ/operando study of Cu-based nanocatalysts for CO 2 electroreduction using electrochemical liquid cell TEM

The structure of a nanocatalyst during electrocatalytic reactions often deviates from its pristine structure due to intrinsic properties, or physical and chemical adsorption at the catalytic surfaces. Taking Cu-based catalysts for CO 2 electroreduction reactions (CO 2 RR) as an example, they often experience segregation, leaching, and alloying during reactions. With the recent breakthrough development of high-resolution polymer electrochemical liquid cells, in-situ electrochemical liquid cell transmission electron microscopy (EC-TEM) alongside other advanced microscopy techniques, has become a powerful platform for revealing electrocatalysts restructuring at the atomic level. Considering the complex reactions involving electrified solid-liquid interfaces and catalyst structural evolution with intermediates, systematic studies with multimodal approaches are crucial. In this article, we demonstrate a research protocol for the study of electrocatalysts structural evolution during reactions using the in-situ EC-TEM platform. Using Cu and CuAg nanowire catalysts for CO 2 RR as model systems, we describe the experimental procedures and findings. We highlight the platform’s crucial role in elucidating atomic-scale pathways of nanocatalyst restructuring and identifying catalytic active sites, as well as avoiding potential artifacts to ensure unbiased conclusions. Using the multimodal characterization toolbox, we provide the opportunity to correlate the structure of a working catalyst with its performance. Finally, we discuss advancements as well as the remaining gap in elucidating the structural-performance relationship of working catalysts. We expect this article will assist in establishing guidelines for future investigations of complex electrochemical reactions, such as CO 2 RR and other catalytic processes, using the in-situ EC-TEM platform.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Application of PRIM for understanding patterns in carbon dioxide model-observation differences

Reducing uncertainties in regional carbon balances requires a better understanding of CO 2 transport in synoptic weather systems. Here, we apply the Patient Rule Induction Method (PRIM), a data-mining method to identify high-density regions for a target-class within an input parameter space, to airborne observations of potential temperature, wind speed, water vapor mixing ratio, and CO 2 dry mol fraction gathered during the Atmospheric Carbon and Transport (ACT)-America Summer 2016 and Winter 2017 campaigns. ACT observations were targeted at expert-designated cases of fair weather and near-frontal warm and cold sector air at atmospheric boundary-layer, lower-, and higher free tropospheric levels (ABL, LFT, and HFT, respectively). We investigate atmospheric characteristics of these pre-defined cases and associated CO 2 model-observation-differences in the mesoscale WRF-Chem model. PRIM results separate winter- and summertime observations as well as observations from ABL, LFT, and HFT with enrichment factors of 4.0–20.5 inside the PRIM box compared to the entire dataset but cannot distinguish between near-frontal warm and cold sector observations in the higher free troposphere. Analyzing of the parameter space constrained by PRIM, we find that large magnitude model observation differences preferentially associated with times when atmospheric conditions are less typical. This association suggests that PRIM could provide a useful tool for isolating atmospheric conditions with large-magnitude and non-Gaussian CO 2 -residuals for targeted transport model evaluation and to potentially improve inversion results during synoptically active periods.

Gerken, Tobias [James Madison Univ., Harrisonburg,↗

Study of space shuttle EVA/IVA support requirements. Volume 5: Requirements study for space shuttle emergency 4 support

The requirements for space shuttle emergency intravehicular activity support equipment are discussed. The potential emergencies considered are: (1) contaminated atmosphere, (2) accidental decompression, (3) inability to re-enter, and (4) crewman stranded. Contingency life support systems are described and the effectiveness of each emergency procedure is analyzed.

Copeland, R. J.↗

Key technology for airbreathing hypersonic aircraft.

This paper reviews recent progress in the key hypersonic technologies, which has been good despite a relatively low priority. Successful hypersonic research engine tests have been made. Active cooling system analyses have shown potential for weight savings, alleviation of structural design problems, and long airframe life. Maturing computerized flow field theories permit optimizing engine-airframe performance. Adequate progress in the future requires an expanded technology program emphasizing hydrogen usage. A hydrogen fueled hypersonic research airplane is essential, providing critical flight data and operational experience.

Nagel, A. L.↗

Rocket effluent - Its ice nucleation activity and related properties

To investigate the possibility of inadvertent weather modification from rocket effluent, aerosol samples were collected from an instrumented aircraft subsequent to the Voyager I and II launches. The aerosol's morphology, concentration and size distribution were examined with an electron microscope. The elemental compositions of individual particles were analyzed with an X-ray energy spectrometer. Ice nucleus concentration was measured with a subfreezing thermal diffusion chamber. The particles' physical and chemical properties were related to their ice nucleation activity. A laboratory experiment on rocket propellant exhaust was conducted under controlled conditions. Both laboratory and field experimental results indicated that rocket propellant exhaust can produce active ice nuclei. Their consequences for potential inadvertant weather modification demand additional study.

Parungo, F. P.↗

The Point-Focusing Thermal and Electric Applications Project - A progress report

The paper discusses the Point-Focusing Thermal and Electric Applications Project which encompasses three primary activities: (1) applications analysis and development, in which potential markets for small power systems (less than 10 MWe) are identified and characterized in order to provide requirements for design and information for activities relating to market development; (2) systems engineering and development, for analyses that will define the most appropriate small power system designs based on specific user requirements; and (3) experiment implementation and test, which deals with the design and placement of engineering experiments in various applications environments in order to test the readiness of the selected technology in an operational setting. Progress to date and/or key results are discussed throughout the text.

Marriott, A. T.↗

Unusual behavior in the condensation nuclei concentration at 30 km

The result obtained with an improved balloon-borne condensation nuclei (CN) counter that is capable of operating to altitudes of at least 30 km are presented. Of major interest is the appearance of a quasiannual variation near 30 km which could be described by a sudden concentration increase of unusually small particles occurring in the winter or spring followed by a 1- to 3-month decay period to background levels. The magnitude of the variation has increased dramatically following the recent generally high levels of volcanic activity affecting the lower stratosphere. Several potential explanations for the event are considered, but none appear entirely satisfactory or complete at the present time. The explanation with the fewest drawbacks would attribute the production of growth of the new cn to a highly supersaturated H2SO4 vapor layer generated by any one of several proposed processes in the upper high latitude stratosphere.

Rosen, J. M.↗

Plasma Production by Meteoroid Impact

Material ejected from the surfaces of satellites in the outer solar system plays an important role in the magnetospheres of the outer planets, and may dominate the mass loading, as in the vicinity of the Jovian satellite Io. At least four potential ejection mechanisms can be identified - intrinsic geologic activity, thermal sublimation, sputtering, and micrometeoroid impact vaporization. On all the icy satellites, except possibly Enceladus, sputtering and impact vaporization are the only two potentially important sources of magnetospheric plasma. Sputtering was shown to be an important mass source at both Jupiter and Saturn. The impact mechanism as a plasma source is assessed.

Haff, P. K.↗

The global sulfur cycle

The results of the planetary biology microbial ecology's 1984 Summer Research Program, which examined various aspects of the global sulfur cycle are summarized. Ways in which sulfur flows through the many living and chemical species that inhabit the surface of the Earth were investigated. Major topics studied include: (1) sulfur cycling and metabolism of phototropic and filamentous sulfur bacteria; (2) sulfur reduction in sediments of marine and evaporite environments; (3) recent cyanobacterial mats; (4) microanalysis of community metabolism in proximity to the photic zone in potential stromatolites; and (5) formation and activity of microbial biofilms on metal sulfides and other mineral surfaces. Relationships between the global sulfur cycle and the understanding of the early evolution of the Earth and biosphere and current processes that affect global habitability are stressed.

Sagan, D.↗

Space Station - Opportunity for international cooperation and utilization

In connection with his announcement regarding the development of a permanently manned Space Station, President Reagan invited the United States' friends and allies to join in the Space Station program. The President's invitation was preceded by more than two years of interaction between NASA and some of its potential partners in Space Station planning activities. Attention is given to international participation in Space Station planning, international cooperation on the Space Station, the guidelines for international cooperation, and the key challenges. Questions regarding quid pro quos are considered along with aspects of technology transfer, commercial use, problems of management, and the next steps concerning the Space Station program.

Pedersen, K. S.↗

Utilizing remote sensing of Thematic Mapper data to improve our understanding of estuarine processes and their influence on the productivity of estuarine-dependent fisheries

LANDSAT thematic mapper (TM) data are being used to refine and validate a stochastic spatial computer model to be applied to coastal resource management problems in Louisiana. Two major aspects of the research are: (1) the measurement of area of land (or emergent vegetation) and water and the length of the interface between land and water in TM imagery of selected coastal wetlands (sample marshes); and (2) the comparison of spatial patterns of land and water in the sample marshes of the imagery to that in marshes simulated by a computer model. In addition to activities in these two areas, the potential use of a published autocorrelation statistic is analyzed.

Browder, J. A.↗

Astronomy on a manned Mars mission

Three extra-solar-system astronomical experiments onboard a manned Mars mission are proposed. First, a modest, 50 cm aperture optical-ultraviolet-infrared telescope (or pair used as an interferometer) coupled with the Mars-Sun baseline would increase the number (by a factor of 3.4) and a volume of stars with accurately measured distances via stellar parallax and, therefore, greatly improve upon the cosmic distance scale; the darker sky at Mars would also provide nearly a full astronomical magnitude deeper images of distant and low brightness objects (limited by zodiacal light). Second, a gamma-ray burst detector coupled with similar detectors in other parts of the solar system will be used to reduce the position error boxes and to study the nature of these energetic sources. Third, the long baselines on a Mars mission radio interferometer will provide a view of the radio universe at unprescedented resolution, 4 x 10 to the minus 9th arcsec at 1 mm wavelength, which can potentially resolve the engine in nearby active galaxies. Each of these experiments is relatively inexpensive, taking advantage of the human presence for operation and maintenance, and the long Earth to Mars baseline.

Burns, Jack O.↗

Measurement, data analysis and prediction of pyrotechnic shock from pin-pullers and separation joints

To evaluate the potential for spacecraft damage caused by activation of pyrotechnic mechanisms, pyrotechnic shock tests were conducted on three configurations: pin-pullers on an orthogonal double Hopkinson bar arrangement, pin-pullers on a mock-up of the HALOE (Halogen Occultation Experiment) structure, and a section of separation joint on a single Hopkinson bar. Strains and accelerations were measured. The strains were converted to output stresses, forces and moments. Acceleration shock response spectra are presented for both acceleration- and force-time signals. The devices were attached to the Hopkinson bars with adaptors, which are typical of attachments used in practice. In order to predict the effect of the adaptors, finite element models of the adaptor-bar combinations were analyzed and results are presented with regard to grid size, time interval, and frequency range required to predict the response to pulses of 10 and 100 microsecond duration.

Evans, Maria J.↗