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DOE OSTI2015

Structure and dynamics of POPC bilayers in water solutions of room temperature ionic liquids

Molecular dynamics simulations in the NPT ensemble have been carried out to investigate the effect of two room temperature ionic liquids (RTILs), on stacks of phospholipid bilayers in water. We consider RTIL compounds consisting of chloride ([bmim][Cl]) and hexafluorophosphate ([bmim][PF{sub 6}]) salts of the 1-buthyl-3-methylimidazolium ([bmim]{sup +}) cation, while the phospholipid bilayer is made of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC). Our investigations focus on structural and dynamical properties of phospholipid and water molecules that could be probed by inelastic and quasi-elastic neutron scattering measurements. The results confirm the fast incorporation of [bmim]{sup +} into the lipid phase already observed in previous simulations, driven by the Coulomb attraction of the cation for the most electronegative oxygens in the POPC head group and by sizeable dispersion forces binding the neutral hydrocarbon tails of [bmim]{sup +} and of POPC. The [bmim]{sup +} absorption into the bilayer favours the penetration of water into POPC, causes a slight but systematic thinning of the bilayer, and further stabilises hydrogen bonds at the lipid/water interface that already in pure samples (no RTIL) display a lifetime much longer than in bulk water. On the other hand, the effect of RTILs on the diffusion constant of POPC (D{sub POPC}) does not reveal a clearly identifiable trend, since D{sub POPC} increases upon addition of [bmim][Cl] and decreases in the [bmim][PF{sub 6}] case. Moreover, because of screening, the electrostatic signature of each bilayer is only moderately affected by the addition of RTIL ions in solution. The analysis of long wavelength fluctuations of the bilayers shows that RTIL sorption causes a general decrease of the lipid/water interfacial tension and bending rigidity, pointing to the destabilizing effect of RTILs on lipid bilayers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2015

Radio–far-infrared correlation in “blue cloud” galaxies with 0 < z < 1.2

We study the radio–far-infrared (FIR) correlation in “blue cloud” galaxies chosen from the PRism MUltiobject Survey up to redshift (z) of 1.2 in the XMM-LSS field. We use rest-frame emission at 1.4 GHz in the radio and both monochromatic (at 70 μm) and bolometric (between 8 and 1000 μm) emission in the FIR. To probe the nature of the correlation up to z ∼1.2, where direct detection of blue star-forming galaxies is impossible with current technology, we employ the technique of image stacking at 0.325 and 1.4 GHz in the radio and in six infrared bands, 24, 70, 160, 250, 350, and 500 μm. For comparison, we also study the correlation for more luminous galaxies that are directly detected. The stacking analysis allows us to probe the radio–FIR correlation for galaxies that are up to two orders of magnitude fainter than the ones detected directly. The k correction in the infrared wavebands is obtained by fitting the observed spectral energy distribution with a composite mid-IR power law and a single temperature graybody model. We find that the radio luminosity at 1.4 GHz (L{sub 1.4 GHz}) is strongly correlated with monochromatic FIR luminosity at 70 μm (L{sub 70 μm}) having slope 1.09 ± 0.05 and with bolometric luminosity (L{sub TIR}) having slope 1.11 ± 0.04. The quantity q{sub TIR}(=log{sub 10}[L{sub TIR}/(3.75×10{sup 12}L{sub 1.4 GHz})]) is observed to decrease with redshift as q{sub TIR}∝(1+z){sup −0.16±0.03} probably caused due to the nonlinear slope of the radio–FIR correlation. Within the uncertainties of our measurement and the limitations of our flux-limited and color-selected sample, we do not find any evolution of the radio–FIR correlation with redshift.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2022

Balancing Predictive and Reactive Science Planning for Mars 2020 Perseverance

The design of the science planning process for a space science mission needs to find a balance between operational and resource constraints and scientific decision-making. Science planning has previously been characterized as either predictive or reactive. Predictive science planning is needed when constraints drive science activities to be planned far in advance. For example, a combination of long one-way light time plus high-stakes science decisions drove the Cassini-Huygens mission to Saturn to have an extremely predictive planning process. On the other extreme, reactive science planning is needed when constraints drive science activities to be planned based on the results of the previous plan. For example, the Mars Exploration Rover mission interacted with the surface of Mars, and so the planning team needed to know the state of the rover at the end of each planning cycle before starting the next cycle. Operational and resource constraints that require management on intermediate timescales has led to the development of a science planning process between these two extremes. For example, the Mars Science Laboratory is a technically complex rover and has a parallel predictive process that allows the operations team to manage engineering constraints several days in advance while maintaining the reactive tactical planning process similar to that of MER. The Mars 2020 Perseverance rover is a technically complex rover in the MSL style, but has an added layer of science complexity: it is tasked with collecting a returnable cache of scientifically valuable samples of Mars within prime mission. Thus, the science planning process also needs to accommodate high-stakes longer-term science decisions in the style of Cassini. In order to balance the push-pull of these constraints, we have developed a science campaign-focused operational paradigm for Mars 2020 Perseverance that allows for both predictive planning to accommodate technological complexity and high-stakes science decisions as well as reactive planning to accommodate the realities of interacting with the martian surface. This paradigm influenced the design of operational processes and operational tools.

Spanovich, Nicole↗

DOE OSTI2011

SMALL-SCALE STRUCTURE IN THE SLOAN DIGITAL SKY SURVEY AND {Lambda}CDM: ISOLATED {approx}L{sub *} GALAXIES WITH BRIGHT SATELLITES

We use a volume-limited spectroscopic sample of isolated galaxies in the Sloan Digital Sky Survey to investigate the frequency and radial distribution of luminous (M{sub r} {approx}< -18.3) satellites like the Large Magellanic Cloud (LMC) around {approx}L{sub *} Milky Way (MW) analogs and compare our results object-by-object to {Lambda}CDM predictions based on abundance matching in simulations. We show that 12% of MW-like galaxies host an LMC-like satellite within 75 kpc (projected), and 42% within 250 kpc (projected). This implies {approx}10% have a satellite within the distance of the LMC, and {approx}40% of L{sub *} galaxies host a bright satellite within the virialized extent of their dark matter halos. Remarkably, the simulation reproduces the observed frequency, radial dependence, velocity distribution, and luminosity function of observed secondaries exceptionally well, suggesting that {Lambda}CDM provides an accurate reproduction of the observed universe to galaxies as faint as L {approx} 10{sup 9} L{sub sun} on {approx}50 kpc scales. When stacked, the observed projected pairwise velocity dispersion of these satellites is {sigma} {approx_equal} 160 km s{sup -1}, in agreement with abundance-matching expectations for their host halo masses. Finally, bright satellites around L{sub *} primaries are significantly redder than typical galaxies in their luminosity range, indicating that environmental quenching is operating within galaxy-size dark matter halos that typically contain only a single bright satellite. This redness trend is in stark contrast to the MW's LMC, which is unusually blue even for a field galaxy. We suggest that the LMC's discrepant color might be further evidence that it is undergoing a triggered star formation event upon first infall.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2012

THE CHARACTERISTIC STAR FORMATION HISTORIES OF GALAXIES AT REDSHIFTS z {approx} 2-7

A large sample of spectroscopically confirmed star-forming galaxies at redshifts 1.4 {<=} z{sub spec} {<=} 3.7, with complementary imaging in the near- and mid-IR from the ground and from the Hubble Space Telescope and Spitzer Space Telescope, is used to infer the average star formation histories (SFHs) of typical galaxies from z {approx} 2 to 7. For a subset of 302 galaxies at 1.5 {<=} z{sub spec} < 2.6, we perform a detailed comparison of star formation rates (SFRs) determined from spectral energy distribution (SED) modeling (SFRs[SED]) and those calculated from deep Keck UV and Spitzer/MIPS 24 {mu}m imaging (SFRs[IR+UV]). Exponentially declining SFHs yield SFRs[SED] that are 5-10 times lower on average than SFRs[IR+UV], indicating that declining SFHs may not be accurate for typical galaxies at z {approx}> 2. The SFRs of z {approx} 2-3 galaxies are directly proportional to their stellar masses (M{sub *}), with unity slope-a result that is confirmed with Spitzer/IRAC stacks of 1179 UV-faint (R>25.5) galaxies-for M{sub *} {approx}> 5 Multiplication-Sign 10{sup 8} M{sub Sun} and SFRs {approx}> 2 M{sub Sun} yr{sup -1}. We interpret this result in the context of several systematic biases that can affect determinations of the SFR-M{sub *} relation. The average specific SFRs at z {approx} 2-3 are remarkably similar within a factor of two to those measured at z {approx}> 4, implying that the average SFH is one where SFRs increase with time. A consequence of these rising SFHs is that (1) a substantial fraction of UV-bright z {approx} 2-3 galaxies had faint sub-L* progenitors at z {approx}> 4; and (2) gas masses must increase with time from z = 2 to 7, over which time the net cold gas accretion rate-as inferred from the specific SFR and the Kennicutt-Schmidt relation-is {approx}2-3 times larger than the SFR. However, if we evolve to higher redshift the SFHs and masses of the halos that are expected to host L* galaxies at z {approx} 2, then we find that {approx}< 10% of the baryons accreted onto typical halos at z {approx}> 4 actually contribute to star formation at those epochs. These results highlight the relative inefficiency of star formation even at early cosmic times when galaxies were first assembling.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2024

Going With the Flow: Sedimentary Evolution of the Jezero Western Fan, Mars

Sedimentary fans developed at the mouths of Martian valleys have been interpreted as the deposits of sustained surface water flow on early Mars building either fluvial fan systems or deltas into standing bodies of water. Whilst much insight has been gleaned from orbital observations, it is only possible to constrain the character, relative timing and persistence of ancient aqueous activity on Mars through detailed on-the-ground interrogation of sedimentary successions built during fan growth. A prominent sedimentary fan deposit at the western margin of Jezero crater – the Western fan – has been interpreted from orbital data/observations to be a river delta that prograded into an ancient lake basin during the Late Noachian-Early Hesperian epochs on Mars (~3.6-3.8 Ga). The Western fan deposit forms a point-sourced depositional system developed at the mouth of Neretva Vallis, a valley system that is incised across the crater rim and has an extensive extra-crater catchment draining over diverse ancient geological units in Nili Planum. The mechanism of crater rim breaching remains unconstrained. Between 2022 and 2023, the Mars 2020 Perseverance rover explored the Western fan, with the objective of characterizing its paleoenvironmental context and collecting a diverse suite of sedimentary rock samples for return to Earth via the Mars Sample Return mission. Perseverance has now completed her traverse across the Western fan having commenced in the distal downstream sectors exposed at the erosional front of the fan and then crossing across its upper exposed surface toward the fan apex region near the mouth of Neretva Vallis. This transect provides a unique window into a Martian sediment routing system at a time when climate conditions permitted the flow of surface water. In this contribution, we review the overall sedimentary architecture of the fan and develop a model for its evolution based on detailed mapping of lithofacies changes across the fan. A first-order synoptic overview is presented.

Mars 2020↗

DOE OSTI2013

HST/WFC3 near-infrared spectroscopy of quenched galaxies at z ∼ 1.5 from the WISP survey: Stellar population properties

We combine Hubble Space Telescope (HST) G102 and G141 near-IR (NIR) grism spectroscopy with HST/WFC3-UVIS, HST/WFC3-IR, and Spitzer/IRAC [3.6 μm] photometry to assemble a sample of massive (log (M {sub star}/M {sub ☉}) ∼ 11.0) and quenched (specific star formation rate <0.01 Gyr{sup –1}) galaxies at z ∼ 1.5. Our sample of 41 galaxies is the largest with G102+G141 NIR spectroscopy for quenched sources at these redshifts. In contrast to the local universe, z ∼ 1.5 quenched galaxies in the high-mass range have a wide range of stellar population properties. We find that their spectral energy distributions (SEDs) are well fitted with exponentially decreasing star formation histories and short star formation timescales (τ ≤ 100 Myr). Quenched galaxies also show a wide distribution in ages, between 1 and 4 Gyr. In the (u – r){sub 0}-versus-mass space quenched galaxies have a large spread in rest-frame color at a given mass. Most quenched galaxies populate the z ∼ 1.5 red sequence (RS), but an important fraction of them (32%) have substantially bluer colors. Although with a large spread, we find that the quenched galaxies on the RS have older median ages (3.1 Gyr) than the quenched galaxies off the RS (1.5 Gyr). We also show that a rejuvenated SED cannot reproduce the observed stacked spectra of (the bluer) quenched galaxies off the RS. We derive the upper limit on the fraction of massive galaxies on the RS at z ∼ 1.5 to be <43%. We speculate that the young quenched galaxies off the RS are in a transition phase between vigorous star formation at z > 2 and the z ∼ 1.5 RS. According to their estimated ages, the time required for quenched galaxies off the RS to join their counterparts on the z ∼ 1.5 RS is of the order of ∼1 Gyr.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

Connect the Dots: In Situ 4-D Seismic Monitoring of CO 2 Storage With Spatio-Temporal CNNs

4-D seismic imaging has been widely used in CO 2 sequestration projects to monitor the fluid flow in the volumetric subsurface region that is not sampled by wells. Ideally, real-time monitoring and near-future forecasting would provide site operators with great insights to understand the dynamics of the subsurface reservoir and assess any potential risks. However, due to obstacles such as high deployment cost, availability of acquisition equipment, exclusion zones around surface structures, only very sparse seismic imaging data can be obtained during monitoring. That leads to an unavoidable and growing knowledge gap over time. The operator needs to understand the fluid flow throughout the project lifetime and the seismic data are only available at a limited number of times. This is insufficient for understanding reservoir behavior. To overcome those challenges, we have developed spatio-temporal neural-network-based models that can produce high-fidelity interpolated or extrapolated images effectively and efficiently. Specifically, our models are built on an autoencoder, and incorporate the long short-term memory (LSTM) structure with a new loss function regularized by optical flow. We validate the performance of our models using real 4-D post-stack seismic imaging data acquired at the Sleipner CO 2 sequestration field. We employ two different strategies in evaluating our models. Numerically, we compare our models with different baseline approaches using classic pixel-based metrics. We also conduct a blind survey and collect a total of 20 responses from domain experts to evaluate the quality of data generated by our models. Finally, via both numerical and expert evaluation, we conclude that our models can produce high-quality 2-D/3-D seismic imaging data at a reasonable cost, offering the possibility of real-time monitoring or even near-future forecasting of the CO 2 storage reservoir.

4-D seismic imaging↗

NASA NTRS2013

HST-WFC3 Near-Infrared Spectroscopy of Quenched Galaxies at zeta approx 1.5 from the WISP Survey: Stellar Populations Properties

We combine Hubble Space Telescope (HST) G102 and G141 near-IR (NIR) grism spectroscopy with HST/WFC3- UVIS, HST/WFC3-IR, and Spitzer/IRAC [3.6 microns] photometry to assemble a sample of massive (log(Mstar/M solar mass) at approx 11.0) and quenched (specific star formation rate < 0.01 G/yr(exp −1) galaxies at zeta approx 1.5. Our sample of 41 galaxies is the largest with G102+G141 NIR spectroscopy for quenched sources at these redshifts. In contrast to the local universe, zeta approx 1.5 quenched galaxies in the high-mass range have a wide range of stellar population properties. We find that their spectral energy distributions (SEDs) are well fitted with exponentially decreasing star formation histories and short star formation timescales (τau less than or equal to 100 M/yr). Quenched galaxies also show a wide distribution in ages, between 1 and 4 G/yr. In the (u − r)0-versus-mass space quenched galaxies have a large spread in rest-frame color at a given mass. Most quenched galaxies populate the zeta appro. 1.5 red sequence (RS), but an important fraction of them (32%) have substantially bluer colors. Although with a large spread, we find that the quenched galaxies on the RS have older median ages (3.1 G/yr) than the quenched galaxies off the RS (1.5 G/yr). We also show that a rejuvenated SED cannot reproduce the observed stacked spectra of (the bluer) quenched galaxies off the RS. We derive the upper limit on the fraction of massive galaxies on the RS at zeta approx 1.5 to be <43%.We speculate that the young quenched galaxies off the RS are in a transition phase between vigorous star formation at zeta > 2 and the zeta approx 1.5 RS. According to their estimated ages, the time required for quenched galaxies off the RS to join their counterparts on the z approx. 1.5 RS is of the order of approx. 1G/yr.

HST WFC#↗

DOE OSTI2011

Low interfacial trap density and sub-nm equivalent oxide thickness in In{sub 0.53}Ga{sub 0.47}As (001) metal-oxide-semiconductor devices using molecular beam deposited HfO{sub 2}/Al{sub 2}O{sub 3} as gate dielectrics

We investigated the passivation of In{sub 0.53}Ga{sub 0.47}As (001) surface by molecular beam epitaxy techniques. After growth of strained In{sub 0.53}Ga{sub 0.47}As on InP (001) substrate, HfO{sub 2}/Al{sub 2}O{sub 3} high-{kappa} oxide stacks have been deposited in-situ after surface reconstruction engineering. Excellent capacitance-voltage characteristics have been demonstrated along with low gate leakage currents. The interfacial density of states (D{sub it}) of the Al{sub 2}O{sub 3}/In{sub 0.53}Ga{sub 0.47}As interface have been revealed by conductance measurement, indicating a downward D{sub it} profile from the energy close to the valence band (medium 10{sup 12} cm{sup -2}eV{sup -1}) towards that close to the conduction band (10{sup 11} cm{sup -2}eV{sup -1}). The low D{sub it}'s are in good agreement with the high Fermi-level movement efficiency of greater than 80%. Moreover, excellent scalability of the HfO{sub 2} has been demonstrated as evidenced by the good dependence of capacitance oxide thickness on the HfO{sub 2} thickness (dielectric constant of HfO{sub 2}{approx}20) and the remained low D{sub it}'s due to the thin Al{sub 2}O{sub 3} passivation layer. The sample with HfO{sub 2} (3.4 nm)/Al{sub 2}O{sub 3} (1.2 nm) as the gate dielectrics has exhibited an equivalent oxide thickness of {approx}0.93 nm.

36 MATERIALS SCIENCE↗

DOE OSTI2010

THE GREAT OBSERVATORIES ORIGINS DEEP SURVEY: CONSTRAINTS ON THE LYMAN CONTINUUM ESCAPE FRACTION DISTRIBUTION OF LYMAN-BREAK GALAXIES AT 3.4 < z < 4.5

We use ultra-deep ultraviolet VLT/VIMOS intermediate-band and VLT/FORS1 narrowband imaging in the GOODS Southern field to derive limits on the distribution of the escape fraction (f{sub esc}) of ionizing radiation for L {>=} L*{sub z=3} Lyman-break galaxies (LBGs) at redshift 3.4-4.5. Only one LBG, at redshift z = 3.795, is detected in its Lyman continuum (LyC; S/N {approx_equal} 5.5), the highest redshift galaxy currently known with a direct detection. Its ultraviolet morphology is quite compact (R{sub eff} = 0.8 kpc physical). Three out of seven active galactic nuclei are also detected in their LyC, including one at redshift z = 3.951 and z{sub 850} = 26.1. From stacked data (LBGs), we set an upper limit to the average f{sub esc} in the range 5%-20%, depending on how the data are selected (e.g., by magnitude and/or redshift). We undertake extensive Monte Carlo simulations that take into account intergalactic attenuation, stellar population synthesis models, dust extinction, and photometric noise in order to explore the moments of the distribution of the escaping radiation. Various distributions (exponential, log-normal, and Gaussian) are explored. We find that the median f{sub esc} is lower than {approx_equal}6% with an 84% percentile limit not larger than 20%. If this result remains valid for fainter LBGs down to current observational limits, then the LBG population might be not sufficient to account for the entire photoionization budget at the redshifts considered here, with the exact details dependent upon the assumed ionizing background and QSO contribution thereto. It is possible that f{sub esc} depends on the UV luminosity of the galaxies, with fainter galaxies having higher f{sub esc}, and estimates of f{sub esc} from a sample of faint LBGs from HUDF (i{sub 775} {<=}28.5) are in broad quantitative agreement with such a scenario.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2025

Highly Tunable Valley Polarization of Potential-Trapped Moiré Excitons in WSe 2 /WS 2 Heterojunctions

Moiré superlattices created by stacking atomic layers of transition metal dichalcogenide semiconductors have emerged as a class of fascinating artificial photonic and electronic materials. An appealing attribute of these structures is the inheritance of the valley degree of freedom from the constituent monolayers. Recent studies show evidence that the valley polarization of the moiré excitons is highly tunable. In heterojunctions of WSe 2 /WS 2 , marked improvement in valley polarization is observed by increasing optical excitation power, a behavior that is quite distinct from the monolayers, and lacks a clear understanding so far. Here, in this Letter, we show that this highly tunable valley property arises from filling of the moiré superlattice, which provides an intriguing mechanism for engineering these quantum opto-valleytronic platforms. Our data further demonstrate that the long-range electron-hole exchange interaction, despite being significantly weakened in the junctions, is the dominant source of moiré exciton intervalley scattering at low population. Using magnetic field tuning, we quantitatively determine the exchange interaction strength to be 0.03 and 0.24 meV for 0° and 60° twisted samples, respectively, in our experiments, about 1 order of magnitude weaker than that in the monolayers.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2017

CARMA Survey toward Infrared-bright Nearby Galaxies (STING). IV. Spatially Resolved {sup 13}CO in Spiral Galaxies

We present a {sup 13}CO(J=1→0) mapping survey of 12 nearby galaxies from the CARMA STING sample. The line intensity ratio R≡I[{sup 12}CO(J=1→0)]/I[{sup 13}CO(J=1→0)] is derived to study the variations in molecular gas properties. For 11 galaxies where it can be measured with high significance, the spatially resolved R on (sub)kiloparsec scales varies by up to a factor of 3–5 within a galaxy. Lower R values are usually found in regions with weaker {sup 12}CO. We attribute this apparent trend to a bias against measuring large R values when {sup 12}CO is weak. Limiting our analysis to the {sup 12}CO-bright regions that are less biased, we do not find that R on (sub)kiloparsec scales correlate with galactocentric distance, velocity dispersion, or the star formation rate. The lack of correlation between star formation rate and R indicates that the CO optical depth is not sensitive to stellar energy input, or that any such sensitivity is easily masked by other factors. Extending the analysis to all regions with {sup 12}CO emission by spectral stacking, we find that 5 out of 11 galaxies show higher stacked R for galactocentric radii of ≳1 kpc and Σ{sub SFR}≲0.1 M{sub ⊙} yr{sup −1} kpc{sup −2}, which could result from a greater contribution from diffuse gas. Moreover, significant galaxy-to-galaxy variations are found in R, but the global R does not strongly depend on dust temperature, inclination, or metallicity of the galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2011

WEAK-LENSING PEAK FINDING: ESTIMATORS, FILTERS, AND BIASES

Large catalogs of shear-selected peaks have recently become a reality. In order to properly interpret the abundance and properties of these peaks, it is necessary to take into account the effects of the clustering of source galaxies, among themselves and with the lens. In addition, the preferred selection of magnified galaxies in a flux- and size-limited sample leads to fluctuations in the apparent source density that correlate with the lensing field. In this paper, we investigate these issues for two different choices of shear estimators that are commonly in use today: globally normalized and locally normalized estimators. While in principle equivalent, in practice these estimators respond differently to systematic effects such as magnification and cluster member dilution. Furthermore, we find that the answer to the question of which estimator is statistically superior depends on the specific shape of the filter employed for peak finding; suboptimal choices of the estimator+filter combination can result in a suppression of the number of high peaks by orders of magnitude. Magnification and size bias generally act to increase the signal-to-noise {nu} of shear peaks; for high peaks the boost can be as large as {Delta}{nu} {approx} 1-2. Due to the steepness of the peak abundance function, these boosts can result in a significant increase in the observed abundance of shear peaks. A companion paper investigates these same issues within the context of stacked weak-lensing mass estimates.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2017

Lensing Constraints on the Mass Profile Shape and the Splashback Radius of Galaxy Clusters

The lensing signal around galaxy clusters can, in principle, be used to test detailed predictions for their average mass profile from numerical simulations. However, the intrinsic shape of the profiles can be smeared out when a sample that spans a wide range of cluster masses is averaged in physical length units. This effect especially conceals rapid changes in gradient such as the steep drop associated with the splashback radius, a sharp edge corresponding to the outermost caustic in accreting halos. We optimize the extraction of such local features by scaling individual halo profiles to a number of spherical overdensity radii, and apply this method to 16 X-ray-selected, high-mass clusters targeted in the Cluster Lensing And Supernova survey with Hubble. By forward-modeling the weak- and strong-lensing data presented by Umetsu et al., we show that, regardless of the scaling overdensity, the projected ensemble density profile is remarkably well described by a Navarro–Frenk–White (NFW) or Einasto profile out to R∼2.5 h{sup −1} Mpc, beyond which the profiles flatten. We constrain the NFW concentration to c{sub 200c}=3.66±0.11 at M{sub 200c}≃1.0×10{sup 15} h{sup −1} M{sub ⊙}, consistent with and improved from previous work that used conventionally stacked lensing profiles, and in excellent agreement with theoretical expectations. Assuming the profile form of Diemer and Kravtsov and generic priors calibrated from numerical simulations, we place a lower limit on the splashback radius of the cluster halos, if it exists, of R{sub sp}{sup 3D}/r{sub 200m}>0.89 (R{sub sp}{sup 3D}>1.83 h{sup −1} Mpc) at 68% confidence. The corresponding density feature is most pronounced when the cluster profiles are scaled by r{sub 200m}, and smeared out when scaled to higher overdensities.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2018

Solvent-pore interactions in the Eagle Ford shale formation

In this work, the effect of solvent extraction on pore space was examined on a suite of samples from the Eagle Ford Shale Formation with varying lithologies and maturities. Several solvents -toluene, cyclohexane, methanol, dichloromethane, and hydrochloric acid- were contacted with shale samples, extracting the compatible organic matter. The porosity in these extracted shale samples was compared to unmodified samples. The amount and type of organic matter extracted were determined using Gas Chromatography - Mass Spectrometry, and the porosity was determined by (Ultra) Small Angle Neutron Scattering. Mostly alkanes and aromatics were detected in the extracts, but other portions of bitumen may also have been present. Only higher molecular weight alkanes were extracted with hydrochloric acid, suggesting that physical dissolution of carbonate minerals may have liberated this portion of organic matter and the solvent was not able to penetrate the bitumen and kerogen to extract the lower molecular weight alkanes. Lastly, a decrease in porosity with extraction was observed and attributed to a dominant mechanism of kerogen swelling due to kerogen-solvent interaction.

02 PETROLEUM↗

DOE OSTI2011

Macroalgae for CO 2 Capture and Renewable Energy - A Pilot Project

The objective of this project was to demonstrate, at a pilot scale, the beneficial use of carbon dioxide (CO 2 ) through a technology designed to capture CO 2 from fossil-fuel fired power plant stack gas, generating macroalgae and converting the macroalgae at high efficiency to renewable methane that can be utilized in the power plant or introduced into a natural gas pipeline. The proposed pilot plant would demonstrate the cost-effectiveness and CO 2 / NO x flue-gas removal efficiency of an innovative algal scrubber technology where seaweeds are grown out of water on specially-designed supporting structures contained within greenhouses where the plants are constantly bathed by recycled nutrient sprays enriched by flue gas constituents. The work described in this document addresses Phase 1 of the project only. The scope of work for Phase 1 includes the completion of a preliminary design package; the collection of additional experimental data to support the preliminary and detailed design for a pilot scale utilization of CO 2 to cultivate macroalage and to process that algae to produce methane; and a technological and economic analysis to evaluate the potential of the system. Selection criteria for macroalgae that could survive the elevated temperatures and potential periodic desiccation of near desert project sites were identified. Samples of the selected macroalgae species were obtained and then subjected to anaerobic digestion to determine conversions and potential methane yields. A Process Design Package (PDP) was assembled that included process design, process flow diagram, material balance, instrumentation, and equipment list, sizes, and cost for the Phase 2 pilot plant. Preliminary economic assessments were performed under the various assumptions made, which are purposely conservative. Based on the results, additional development work should be conducted to delineate the areas for improving efficiency, reducing contingencies, and reducing overall costs.

09 BIOMASS FUELS↗

DOE OSTI2016

The ALMA spectroscopic survey in the Hubble Ultra Deep Field: continuum number counts, resolved 1.2 mm extragalactic background, and properties of the faintest dusty star-forming galaxies

We present an analysis of a deep (1σ = 13 μJy) cosmological 1.2 mm continuum map based on ASPECS, the ALMA Spectroscopic Survey in the Hubble Ultra Deep Field. In the 1 arcmin{sup 2} covered by ASPECS we detect nine sources at >3.5σ significance at 1.2 mm. Our ALMA-selected sample has a median redshift of z=1.6±0.4, with only one galaxy detected at z > 2 within the survey area. This value is significantly lower than that found in millimeter samples selected at a higher flux density cutoff and similar frequencies. Most galaxies have specific star formation rates (SFRs) similar to that of main-sequence galaxies at the same epoch, and we find median values of stellar mass and SFRs of 4.0×10{sup 10} M{sub ⊙} and ∼40 M{sub ⊙} yr{sup −1}, respectively. Using the dust emission as a tracer for the interstellar medium (ISM) mass, we derive depletion times that are typically longer than 300 Myr, and we find molecular gas fractions ranging from ∼0.1 to 1.0. As noted by previous studies, these values are lower than those using CO-based ISM estimates by a factor of ∼2. The 1 mm number counts (corrected for fidelity and completeness) are in agreement with previous studies that were typically restricted to brighter sources. With our individual detections only, we recover 55% ± 4% of the extragalactic background light (EBL) at 1.2 mm measured by the Planck satellite, and we recover 80% ± 7% of this EBL if we include the bright end of the number counts and additional detections from stacking. The stacked contribution is dominated by galaxies at z∼1--2, with stellar masses of (1–3) × 10{sup 10} M {sub ⊙}. For the first time, we are able to characterize the population of galaxies that dominate the EBL at 1.2 mm.

79 ASTRONOMY AND ASTROPHYSICS↗