Development of lithium diffused radiation resistant solar cells Final report
Fabrication and analysis of lithium diffused radiation resistant solar cells
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Fabrication and analysis of lithium diffused radiation resistant solar cells
Boron diffusion on silicon investigated for use in solar cells
Volt-ampere characteristics and maximum power distributions of lithium-diffused p-n solar cells
Boron diffused radiation resistant solar cells
Fabrication techniques to improve initial efficiency and radiation tolerance of radiation hardened lithium-diffused silicon solar cells
TiPdAg and Al contact systems on p/n cells for humidity resistance and strength
Expandable rigidizable solar shields operational, structural and thermal performance tests conducted with spherical models for cryogenically fueled space vehicles
Lithium diffused radiation resistant solar cells
The work performed to investigate the effect of various process parameters on the performance of lithium doped P/N solar cells is described. Effort was concentrated in four main areas: (1) the starting material, (2) the boron diffusion, (3) the lithium diffusion, and (4) the contact system. Investigation of starting material primarily involved comparison of crucible grown silicon (high oxygen content) and Lopex silicon (low oxygen content). In addition, the effect of varying growing parameters of crucible grown silicon on lithium cell output was also examined. The objective of the boron diffusion studies was to obtain a diffusion process which produced high efficiency cells with minimal silicon stressing and could be scaled up to process 100 or more cells per diffusion. Contact studies included investigating sintering of the TiAg contacts and evaluation of the contact integrity.
Lithium-doped solar cells have been fabricated with initial lot efficiencies averaging 11.9 percent in an air mass zero (AMO) solar simulator and a maximum observed efficiency of 12.8 percent. The best lithium-doped solar cells are approximately 15 percent higher in maximum power than state-of-the-art n-p cells after moderate to high fluences of 1-MeV electrons and after 6-7 months exposure to low flux irradiation by a Sr-90 beta source, which approximates the electron spectrum and flux associated with near Earth space. Furthermore, lithium-doped cells were found to degrade at a rate only one tenth that of state-of-the-art n-p cells under 28-MeV electron irradiation. Excellent progress has been made in quantitative predictions of post-irradiation current-voltage characteristics as a function of cell design by means of capacitance-voltage measurements, and this information has been used to achieve further improvements in lithium-doped cell design.
Cost-effective solar-cell package is proposed for development of practical solar-cell system. Since cells are enclosed in inexpensive plastic tubes, forced-air-cooling loop is proposed to maintain cell temperature at adequate levels. Loop must include desiccant to remove moisture from hermetic enclosures to prevent cell corrosion.
Non-reflective vertical junction silicon cells provide high conversion efficiency radiation-resistant solar cells. New techniques of oxidation growth and the use of photolithography enable the use of an orientation dependent etch producing grooves 5 to 10 microns wide over 100 microns deep. These silicon wafers are then processed into solar cells with all of the processes performed at temperatures compatible with producing high efficiency solar cells. Most of the photogenerated carriers are created in the walls where they are within a few microns of the collecting junction. Consequently, degradation of carrier diffusion length due to radiation has a considerably reduced effect on collection efficiency. These 2 cm x 2 cm vertical junction silicon solar cells have exceeded 13% AMO efficiency and have shown superior radiation resistance.
The progress of work on the evacuated receiver, lens design, lens die fabrication, and improvements on components, production techniques, and performance testing is discussed.
The finalization of designs, fabrication of the new lens, receiver, and tracking box and a review of the contract status are presented.
Testing and evaluation results for the structural design of the concentrating solar collector and the attitude control system are reported.
Materials were surveyed to provide candidates for an all metal electrode paste system. These consisted of a major constituent metal powder, a low melting metal powder suitable for a liquid phase sintering medium, and a powder material suitable as an etchant for silicon dioxide at sintering temperatures. By means of thermal gravimetric analysis a suitable binder was identified for low temperature fired inks. The all metal ink concept was first demonstrated with the silver system to avoid the problems of limited process windows encountered with base metal systems. A number of solid materials capable of selectively etching silicon dioxide at modest temperatures were identified. A paste with silver fluoride was screened onto N-type silicon with 5 ohm cm resistivity. The resulting contact pads had excellent adhesion but were not electrically ohmic. Metallurgically, these contacts have equal or better grain structure as commercial inks fired at the same temperatures.
Materials were surveyed to provide candidates for an all metal electrode paste system. These consisted of a major constituent metal powder, a low melting metal powder suitable for a liquid phase sintering medium, and a powder material suitable as an etchant for silicon dioxide at sintering temperatures. By means of thermal gravimetric analysis a suitable binder was identified for low temperature fired inks.
Two quarterly reports describe first 6 months of development on single family, multifamily, and commercial installations in Minneapolis area. Reports discuss basic requirements, and reasons for selecting specific configurations. Systems consist of liquid cooled flat plate collectors, two fluid loops, and gas-fired forced-air auxiliary heat source.