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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

An organogel library for solution NMR analysis of nanoparticle suspensions in non-aqueous samples

Surface contrast solution NMR methods (scNMR) are emerging as powerful tools to investigate the adsorption of small molecule ligands to the surface of nanoparticles (NP), returning fundamental insight into the kinetics and thermodynamics of sorption, as well as structural information on the adsorbed species. A prerequisite for the acquisition of high quality solution NMR data is the preparation of homogeneous and stable samples that return consistent NMR spectra and allow extensive signal averaging. Unfortunately, this condition does not apply to NMR samples containing NPs that often show a tendency to sediment and accumulate at the bottom of the NMR tube over the course of the experiment. We have recently shown that preparing NMR samples in an agarose gel matrix inhibits sedimentation and allows the characterization of small molecule-NP interactions by scNMR. Unfortunately, as the agarose gel only forms in aqueous solution, this sample preparation method cannot be used to stabilize NP suspensions in a non-aqueous environment. In this work, we introduce a library of 48 organogels, based on low molecular-mass organic gelators (LMOGs), to prepare NMR samples of small molecule/NP systems in a wide range of organic solvents. In addition, we present a simple method that takes advantage of 1H transverse relaxation (1H-R2) measurements to screen the library and identify the best gelator to characterize the small molecule-NP interaction of interest in the solvent of choice. We expect the results of this study will enable the preparation of homogeneous and stable samples of NPs in non-aqueous environments, therefore dramatically increasing the applicability of scNMR to the characterization of heterogeneous interactions and to the investigation of the role played by solvent molecules in regulating the kinetics and thermodynamics of sorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Human factors of intelligent computer aided display design

Design concepts for a decision support system being studied at NASA Langley as an aid to visual display unit (VDU) designers are described. Ideally, human factors should be taken into account by VDU designers. In reality, although the human factors database on VDUs is small, such systems must be constantly developed. Human factors are therefore a secondary consideration. An expert system will thus serve mainly in an advisory capacity. Functions can include facilitating the design process by shortening the time to generate and alter drawings, enhancing the capability of breaking design requirements down into simpler functions, and providing visual displays equivalent to the final product. The VDU system could also discriminate, and display the difference, between designer decisions and machine inferences. The system could also aid in analyzing the effects of designer choices on future options and in ennunciating when there are data available on a design selections.

Hunt, R. M.↗
DOE OSTI2020

Heavy flavor dynamics across system size at the LHC

One of the fundamental signatures of the Quark Gluon Plasma has been the suppression of heavy flavor (specifically D mesons), which has been measured via the nuclear modification factor, R AA and azimuthal anisotropies, v n , in large systems. However, multiple competing models can reproduce the same data for R AA to v n . In this talk we break down the competing effects that conspire together to successfully reproduce R AA and v n in experimental data using Trento+v-USPhydro+DAB-MOD. Then using our best fit model we make predictions for R AA and v n across system size for 208 PbPb, 129 XeXe, 40 ArAr, and 16 OO collisions. We find that 0–10% centrality has a non-trivial interplay between the system size and eccentricities such that system size effects are masked in v 2 whereas in 30–50% centrality the eccentricities are approximately constant across system size and, therefore, is a better centrality class to study D meson dynamics across system size.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Pressurized subsampling system for pressured gas-hydrate-bearing sediment: Microscale imaging using X-ray computed tomography

A pressurized subsampling system was developed for pressured gas hydrate (GH)-bearing sediments, which have been stored under pressure. The system subsamples small amounts of GH sediments from cores (approximately 50 mm in diameter and 300 mm in height) without pressure release to atmospheric conditions. The maximum size of the subsamples is 12.5 mm in diameter and 20 mm in height. Moreover, our system transfers the subsample into a pressure vessel, and seals the pressure vessel by screwing in a plug under hydraulic pressure conditions. In this study, we demonstrated pressurized subsampling from artificial xenon-hydrate sediments and nondestructive microscale imaging of the subsample, using a microfocus X-ray computed tomography (CT) system. In addition, we estimated porosity and hydrate saturation from two-dimensional X-ray CT images of the subsamples.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRSDate not supplied

Vibration Anomaly Detection by Clustering in Unmanned Aerial Vehicles.

One of the critical factors affecting flight safety of unmanned aerial vehicles (UAVs) is the amount of vibration they are exposed to during a flight. On one hand, external causes such as wind gusts and turbulences or internal vehicle-centric faults such as incorrect sensor mounting or propeller imbalances can cause high vibrations in UAVs. On the other hand, high vibration itself may induce noise in the onboard miniature sensors of the UAV such as its accelerometers, gyroscopes and GPS that can lead to uncertain state estimation causing the multi-rotor to drift from its desired position or even result in loss-of-control. Hence, it is important to monitor the vibration levels during a UAV flight. This paper specifically looks into vibrations recorded by the autopilot system of a multi-rotor in presence of varying magnitudes of wind. Using data from experimental flights conducted at two separate flight test regions under varying wind conditions, we aim to classify between a nominal and anomalous vibration level for small UAV systems. Further, we analyse other parameters of interest that affect vibrations in UAVs such as UAV air speed and any propeller imbalance signatures. Analysis results from experimental flights demonstrate the effect of wind on vibration magnitude in unmanned aircrafts.

unmanned aviation↗
NASA NTRS2015

Small UAV Automatic Ground Collision Avoidance System Design Considerations and Flight Test Results

The National Aeronautics and Space Administration (NASA) Armstrong Flight Research Center Small Unmanned Aerial Vehicle (SUAV) Automatic Ground Collision Avoidance System (Auto GCAS) project demonstrated several important collision avoidance technologies. First, the SUAV Auto GCAS design included capabilities to take advantage of terrain avoidance maneuvers flying turns to either side as well as straight over terrain. Second, the design also included innovative digital elevation model (DEM) scanning methods. The combination of multi-trajectory options and new scanning methods demonstrated the ability to reduce the nuisance potential of the SUAV while maintaining robust terrain avoidance. Third, the Auto GCAS algorithms were hosted on the processor inside a smartphone, providing a lightweight hardware configuration for use in either the ground control station or on board the test aircraft. Finally, compression of DEM data for the entire Earth and successful hosting of that data on the smartphone was demonstrated. The SUAV Auto GCAS project demonstrated that together these methods and technologies have the potential to dramatically reduce the number of controlled flight into terrain mishaps across a wide range of aviation platforms with similar capabilities including UAVs, general aviation aircraft, helicopters, and model aircraft.

Sorokowski, Paul↗
NASA NTRS2017

Stability of Multi-Planet Systems in the Alpha Centauri System

We evaluate the extent of the regions within the alpha Centauri AB star system where small planets are able to orbit for billion-year timescales (Quarles & Lissauer 2016, Astron. J. 151, 111), as well as how closely-spaced planetary orbits can be within those regions in which individual planets can survive. Although individual planets on low inclination, low eccentricity, orbits can survive throughout the habitable zones of both stars, perturbations from the companion star imply that the spacing of planets in multi-planet systems within the habitable zones of each star must be significantly larger than the spacing of similar multi-planet systems orbiting single stars in order to be long-lived. Because the binary companion induces a forced eccentricity upon the orbits of planets in orbit around either star, appropriately-aligned circumstellar orbits with small initial eccentricities are stable to slightly larger initial semimajor axes than are initially circular orbits. Initial eccentricities close to forced eccentricities can have a much larger affect on how closely planetary orbits can be spaced, and therefore on how many planets may remain in the habitable zones, although the required spacing remains significantly higher than for planets orbiting single stars.

Alpha Centauri AB star system↗
DOE OSTI2018

idpflex: Analysis of Intrinsically Disordered Proteins by Comparing Simulations to Small Angle Scattering Experiments

It is estimated that about 30% of the eucariotic proteome consists of intrinsically dis-ordered proteins (IDP’s), yet their presence in public structural databases is severely underrepresented. IDP’s adopt heterogeneous inter-converting conformations with similar probabilities, preventing resolution of structures with X-Ray diffraction techniques. An alternative technique with wide application on IDP systems is small angle scattering(SAS). SAS can measure average structural features of IDP’s when in vitro solution, or even at conditions mimicking protein concentrations found in the cell’s cytoplasm.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2018

ABSORPTION CHILLER AND STRATIFIED CHILLED-WATER STORAGE TANK CONFIGURATIONS FOR COUPLING TO A SMALL MODULAR REACTOR

Power maneuvers stemming from time-varying loads imposed on nuclear reactors from diurnal changes in demand and renewable intermittency can be detrimental to the life of the reactor. Temperature swings during power maneuvers result in thermal and mechanical stresses in fuel elements and other reactor components. Thermal Energy Storage (TES) reservoirs can be coupled to reactors to absorb these grid instabilities. Previous work has shown chilled-water storage can help shift cooling loads that contribute to the daily peak electric demand from on-peak to off-peak hours. The objective of this work is to evaluate a stratified chilled-water storage tank as a potential TES reservoir for a Small Modular Reactor (SMR) using absorption chillers for chilled-water production. Simulation results reveal absorption chiller performance is hindered when receiving steam from a tap on the low-pressure turbine. A better configuration involves integrating the absorption chillers into a flash vessel system that is thermally coupled to a sensible heat storage system. The sensible heat storage system maintains reactor thermal output at 100% and matches turbine output with demand while producing enough steam to power four large absorption chillers to charge a stratified chilled-water storage tank, which is used to offset cooling loads in an adjacent facility.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2024

Quantifying Quantum Chaos through Microcanonical Distributions of Entanglement

A characteristic feature of “quantum chaotic” systems is that their eigenspectra and eigenstates display universal statistical properties described by random matrix theory (RMT). However, eigenstates of local systems also encode structure beyond RMT. To capture this feature, we introduce a framework that allows us to compare the properties of eigenstates in local systems with those of pure random states. In particular, our framework defines a notion of distance between quantum state ensembles that utilizes the Kullback-Leibler divergence to compare the microcanonical distribution of entanglement entropy (EE) of eigenstates with a reference RMT distribution generated by pure random states (with appropriate constraints). This notion gives rise to a quantitative metric for quantum chaos that not only accounts for averages of the distributions but also higher moments. The differences in moments are compared on a highly resolved scale set by the standard deviation of the RMT distribution, which is exponentially small in system size. As a result, the metric can distinguish between chaotic and integrable behaviors and, in addition, quantify and compare the of chaos (in terms of proximity to RMT behavior) between two systems that are assumed to be chaotic. We implement our framework in local, minimally structured, Floquet random circuits, as well as a canonical family of many-body Hamiltonians, the mixed-field Ising model (MFIM). Importantly, for Hamiltonian systems, we find that the reference random distribution must be appropriately constrained to incorporate the effect of energy conservation in order to describe the ensemble properties of midspectrum eigenstates. The metric captures deviations from RMT across all models and parameters, including those that have been previously identified as strongly chaotic, and for which other diagnostics of chaos such as level spacing statistics look strongly thermal. In Floquet circuits, the dominant source of deviations is the second moment of the distribution, and this persists for all system sizes. For the MFIM, we find significant variation of the KL divergence in parameter space. Notably, we find a small region where deviations from RMT are minimized, suggesting that “maximally chaotic” Hamiltonians may exist in fine-tuned pockets of parameter space. Published by the American Physical Society 2024

Physics↗
NASA NTRS1991

Solid C triple bond N bearing material on outer solar system bodies

Recent telescopic observations have led to the identification of cyanogroup-containing molecules in the dark surface solids of several D-class asteroids, cometary dusts, and the rings of Uranus, as well as the low-albedo atmosphere of Iapetus. The occurrence of the 2.2-micron overtone of C triple-bond N's stretching fundamental mode in all four classes of small solar system bodies is presently suggested to serve as a diagnostic of both exposure duration and degree of modification of surface materials.

Cruikshank, Dale P.↗
DOE OSTI2014

Nuclear spin circular dichroism

Recent years have witnessed a growing interest in magneto-optic spectroscopy techniques that use nuclear magnetization as the source of the magnetic field. Here we present a formulation of magnetic circular dichroism (CD) due to magnetically polarized nuclei, nuclear spin-induced CD (NSCD), in molecules. The NSCD ellipticity and nuclear spin-induced optical rotation (NSOR) angle correspond to the real and imaginary parts, respectively, of (complex) quadratic response functions involving the dynamic second-order interaction of the electron system with the linearly polarized light beam, as well as the static magnetic hyperfine interaction. Using the complex polarization propagator framework, NSCD and NSOR signals are obtained at frequencies in the vicinity of optical excitations. Hartree-Fock and density-functional theory calculations on relatively small model systems, ethene, benzene, and 1,4-benzoquinone, demonstrate the feasibility of the method for obtaining relatively strong nuclear spin-induced ellipticity and optical rotation signals. Comparison of the proton and carbon-13 signals of ethanol reveals that these resonant phenomena facilitate chemical resolution between non-equivalent nuclei in magneto-optic spectra.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Hybrid EMT-TS Simulation Strategies to Study High Bandwidth MMC-Based HVdc Systems

Modular multilevel converters (MMCs) are widely used in the design of modern high-voltage direct current (HVdc) transmission system. High-fidelity dynamic models of MMCs-based HVdc system require small simulation time step and can be accurately modeled in electro-magnetic transient (EMT) simulation programs. The EMT program exhibits slow simulation speed and limitation on the size of the model and brings certain challenges to test the high-fidelity HVdc model in system-level simulations. This paper presents the design and implementation of a hybrid simulation framework, which enables the co-simulation of the EMT model of Atlanta-Orlando HVdc line and the transient stability (TS) model of the entire Eastern Interconnection system. This paper also introduces the implementation of two high-fidelity HVdc line models simulated at different time steps and discusses a dedicated method for sizing the buffer areas on both sides of the HVdc line. The simulation results of the two HVdc models with different sizes of buffer areas are presented and compared.

Liu, Yuan↗
DOE OSTI2018

Diffusion of Sticky Nanoparticles in a Polymer Melt: Crossover from Suppressed to Enhanced Transport

The self-diffusion of a single large particle in a fluid is usually described by the classic Stokes–Einstein (SE) hydrodynamic relation. However, there are many fluids where the SE prediction for nanoparticles diffusion fails. These systems include diffusion of nanoparticles in porous media, in entangled and unentangled polymer melts and solutions, and protein diffusion in biological environments. A fundamental understanding of the microscopic parameters that govern nanoparticle diffusion is relevant to a wide range of applications. Here in this work, we present experimental measurements of the tracer diffusion coefficient of small and large nanoparticles that experience strong attractions with unentangled and entangled polymer melt matrices. For the small nanoparticle system, a crossover from suppressed to enhanced diffusion is observed with increasing polymer molecular weight. We interpret these observations based on our theoretical and simulation insights of the preceding article (paper 1) as a result of a crossover from an effective hydrodynamic core–shell to a nonhydrodynamic vehicle mechanism of transport, with the latter strongly dependent on polymer–nanoparticle desorption time. In conclusion, a general zeroth-order qualitative picture for small sticky nanoparticle diffusion in polymer melts is proposed.

36 MATERIALS SCIENCE↗
NASA NTRS1982

Regoliths on small bodies in the solar system

A regolith is defined as a layer or mantle of loose, incoherent, rocky material of whatever origin, that nearly everywhere forms the surface of the land and rests on coherent bedrock. The regoliths on many planetary bodies are the result of continual impacts, which transform coherent surfaces into fragmental debris. The present investigation is concerned with the special case of regolith formation and evolution on small objects, such as asteroids and meteorite parent bodies. First order models of regolith evolution on asteroidal surfaces are constructed on the basis of data provided by studies of lunar samples and meteorites. It appears that regolith formation proceeds by deposition of discrete layers of the widely spread ejecta primarily from the larger impacts. Moderate-size (100-300 km diameter) asteroids are covered by modest regoliths of the order of one km in depth. Small rocky asteroids develop negligible regoliths.

Housen, K. R.↗