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At least 1,135 records · Page 63

Development and Testing of the New Surface LER Climatology for OMI UV Aerosol Retrievals

Ozone Monitoring Instrument (OMI) onboard Aura satellite retrieved aerosols properties using UV part of solar spectrum. The OMI near UV aerosol algorithm (OMAERUV) is a global inversion scheme which retrieves aerosol properties both over ocean and land. The current version of the algorithm makes use of TOMS derived Lambertian Equivalent Reflectance (LER) climatology. A new monthly climatology of surface LER at 354 and 388 nm have been developed. This will replace TOMS LER (380 nm and 354nm) climatology in OMI near UV aerosol retrieval algorithm. The main objectives of this study is to produce high resolution (quarter degree) surface LER sets as compared to existing one degree TOMS surface LERs, to product instrument and wavelength consistent surface climatology. Nine years of OMI observations have been used to derive monthly climatology of surface LER. MODIS derived aerosol optical depth (AOD) have been used to make aerosol corrections on OMI wavelengths. MODIS derived BRDF adjusted reflectance product has been also used to capture seasonal changes in the surface characteristics. Finally spatial and temporal averaging techniques have been used to fill the gaps around the globes, especially in the regions with consistent cloud cover such as Amazon. After implementation of new surface data in the research version of algorithm, comparisons of AOD and single scattering albedo (SSA) have been performed over global AERONET sites for year 2007. Preliminary results shows improvements in AOD retrievals globally but more significance improvement were observed over desert and bright locations. We will present methodology of deriving surface data sets and will discuss the observed changes in retrieved aerosol properties with respect to reference AERONET measurements.

Aerosol↗

Jet-Surface Interaction Test: Flow Measurements Results

Modern aircraft design often puts the engine exhaust in close proximity to the airframe surfaces. Aircraft noise prediction tools must continue to develop in order to meet the challenges these aircraft present. The Jet-Surface Interaction Tests have been conducted to provide a comprehensive quality set of experimental data suitable for development and validation of these exhaust noise prediction methods. Flow measurements have been acquired using streamwise and cross-stream particle image velocimetry (PIV) and fluctuating surface pressure data acquired using flush mounted pressure transducers near the surface trailing edge. These data combined with previously reported far-field and phased array noise measurements represent the first step toward the experimental data base. These flow data are particularly applicable to development of noise prediction methods which rely on computational fluid dynamics to uncover the flow physics. A representative sample of the large flow data set acquired is presented here to show how a surface near a jet affects the turbulent kinetic energy in the plume, the spatial relationship between the jet plume and surface needed to generate surface trailing-edge noise, and differences between heated and unheated jet flows with respect to surfaces.

Flow↗

Land Surface Microwave Emissivity Dynamics: Observations, Analysis and Modeling

Land surface microwave emissivity affects remote sensing of both the atmosphere and the land surface. The dynamical behavior of microwave emissivity over a very diverse sample of land surface types is studied. With seven years of satellite measurements from AMSR-E, we identified various dynamical regimes of the land surface emission. In addition, we used two radiative transfer models (RTMs), the Community Radiative Transfer Model (CRTM) and the Community Microwave Emission Modeling Platform (CMEM), to simulate land surface emissivity dynamics. With both CRTM and CMEM coupled to NASA's Land Information System, global-scale land surface microwave emissivities were simulated for five years, and evaluated against AMSR-E observations. It is found that both models have successes and failures over various types of land surfaces. Among them, the desert shows the most consistent underestimates (by approx. 70-80%), due to limitations of the physical models used, and requires a revision in both systems. Other snow-free surface types exhibit various degrees of success and it is expected that parameter tuning can improve their performances.

Modeling↗

Jet-Surface Interaction Noise from High-Aspect Ratio Nozzles: Test Summary

Noise and flow data have been acquired for a 16:1 aspect ratio rectangular nozzle exhausting near a simple surface at the NASA Glenn Research Center as part of an ongoing effort to understand, model, and predict the noise produced by current and future concept aircraft employing a tightly integrated engine airframe designs. The particular concept under consideration in this experiment is a blended-wing-body airframe powered by a series of electric fans exhausting through slot nozzle over an aft deck. The exhaust Mach number and surface length were parametrically varied during the test. Far-field noise data were acquired for all nozzle surface geometries and exhaust flow conditions. Phased-array noise source localization data and in-flow pressure data were also acquired for a subset of the isolated (no surface) and surface configurations; these measurements provide data that have proven useful for modeling the jet-surface interaction noise source and the surface effect on the jet-mixing noise in round jets. A summary of the nozzle surface geometry, flow conditions tested, and data collected are presented.

Propulsion Noise↗

Fast-Time Simulation for Evaluating the Impact of Estimated Flight Ready Time Uncertainty on Surface Metering

NASA has been developing and demonstrating new concepts and technologies for Integrated Arrival, Departure, and Surface (IADS) traffic management capabilities under the Airspace Technology Demonstration 2 (ATD-2) project. One of the IADS capabilities in the ATD-2 project is surface metering enabled by a tactical surface scheduler to provide controllers with the pushback advisories for departures at gates. The tactical surface scheduler uses the estimated flight ready times provided by airlines, called Earliest Off-Block Times (EOBTs), as input to calculate the target off-block times for pushback advisories. However, the EOBTs are often inaccurate and deviate from the actual flight ready times, which may reduce the benefits of surface metering. In this paper, a linear regression model is developed to model the EOBT uncertainty distribution over time based on actual EOBT data collected at Charlotte airport. This EOBT model is integrated with a tactical surface scheduler and a fast-time simulation tool. To evaluate the impact of the EOBT accuracy on airport surface operations, fast-time simulations are implemented for selected traffic scenarios under different levels of modelled EOBT accuracy. The simulation results show that the EOBT uncertainty affects several performance metrics related to the surface metering, such as gate hold, taxi time reduction, and target takeoff time predictability, which in turn influences ATD-2's scheduler performance.

tactical surface scheduler↗

Fast-Time Simulation for Evaluating the Impact of Estimated Flight Ready Time Uncertainty on Surface Metering

NASA has been developing and demonstrating new concepts and technologies for Integrated Arrival, Departure, and Surface (IADS) traffic management capabilities under the Airspace Technology Demonstration 2 (ATD-2) project. One of the IADS capabilities in the ATD-2 project is surface metering enabled by a tactical surface scheduler to provide controllers with the pushback advisories for departures at gates. The tactical surface scheduler uses the estimated flight ready times provided by airlines, called Earliest Off-Block Times (EOBTs), as input to calculate the target off-block times for pushback advisories. However, the EOBTs are often inaccurate and deviate from the actual flight ready times, which may reduce the benefits of surface metering. In this paper, a linear regression model is developed to model the EOBT uncertainty distribution over time based on actual EOBT data collected at Charlotte airport. This EOBT model is integrated with a tactical surface scheduler and a fast-time simulation tool. To evaluate the impact of the EOBT accuracy on airport surface operations, fast-time simulations are implemented for selected traffic scenarios under different levels of modelled EOBT accuracy. The simulation results show that the EOBT uncertainty affects several performance metrics related to the surface metering, such as gate hold, taxi time reduction, and target takeoff time predictability, which in turn influences ATD-2's scheduler performance.

tactical surface scheduler↗

Analysis and Comparison of Surface Roughness Effects on Pressure Data from SLS Wind Tunnel Test

Unsteady flows are becoming a more characterized field of study as advancements in technology is allowing for more high-speed, time-resolved data acquisition. It is important to understand these flows as the shock-wave boundary-layer interactions and separation they are involved with can generate extreme loads caused by high pressure and temperature on the body of a flight vehicle. It is vital to characterize these loads, as they can impede upon the structural integrity of a high-speed system. A common instrument utilized today to characterize pressure distributions caused by unsteady flows are unsteady pressure transducers. Set flush with the surface of a flight vehicle or wind tunnel model, these transducers can provide a pressure distribution, capturing the frequency of unsteady loads that could impinge upon the test article. A couple negative aspects of this instrumentation is that they are expensive, have long lead times, and a pressure distribution can only be determined in one discrete location where the transducer is installed. An optical diagnostic known as unsteady pressure-sensitive paint (uPSP) can help to satisfy these deficiencies. This is a spray paint that can be applied to a surface of a model to provide a global pressure distribution across the whole painted region.2 A complete picture of the fluid dynamic pressures occurring on the surface of a test article can be analyzed, especially in locations where it may have been impossible to install a transducer. Pressure-sensitive paint is also less expensive than traditional pressure transducers, which are, on average, about $2,000 each including the cost of installation.3 Unsteady PSP will not replace unsteady pressure transducers, but the transducers can be used to validate the PSP response to the flow and measure frequencies higher than the frequency response of the paint. One issue that can arise using these tools simultaneously, is that the surface roughness of the uPSP can affect the pressure readings of the transducers. Applying the uPSP to the surface of the model is going to affect the flow in some way as the topography of the model is now different than if it was not painted. One study with steady PSP conducted by Amer, Obara, and Liu at NASA Langley concluded that the PSP surface roughness was minimally intrusive at different test conditions with various lift, drag, etc., however, it was noted that data from some pressure transducers had decreased, likely due to the uneven application of the PSP in the localized region of the transducers.9 Sugioka et. al. tested various formulations of uPSP to study surface roughness effects on a Common Research Model (CRM) in transonic flow. The influence of uPSP on the surface of the model, depending on how it was formulated, was noted to have the possibility of relocating the shock wave present in the flow. This study was conducted to examine and compare transducer data acquired in December 2017 of a 4% scale model of the Space Launch System (SLS) performed at NASA Ames Research Center (ARC) Unitary Plan Wind Tunnel (UPWT). One goal of the test was to demonstrate to the customer the potential of the uPSP system developed at NASA ARC. The effect of uPSP on transducer signals also became an interest in this experiment and is the reason for this data analysis. The results of this study were discussed with the SLS team to help them make decisions regarding the next test on an SLS model with the PSP and Unitary Plan Wind Tunnel teams.

pressure-sensitive paint↗

An Overview of LO-DuSST (Lunar Occupancy Dust Surface Separation Technologies) Objectives

Of the myriad of issues facing lunar exploration and maintaining an extended lunar presence, lunar dust is possibly the most pervasive. These jagged, chemically reactive, electrostatically charged, sometimes magnetic particles can impact every aspect of a lunar surface mission ranging from abrading extra-vehicular activity (EVA) suits to disrupting lunar vehicle thermal management systems to impeding efficacy of excavation equipment to impacting lunar inhabitant health. NASA’s Lunar Occupancy Dust Surface Separation Technologies (LO-DuSST) task, as a part of the broader Lunar Surface Innovation Initiative (LSII) project, seeks to implement synergistic active and passive lunar dust management and mitigation technologies for an array of applications. One such application is protection of power generation capabilities via solar panel arrays. Plasma dust lofting coupled with a piezoelectric-driven vibration technology will be demonstrated on solar panel surfaces contaminated with lunar dust simulant. Intrinsically low adhesion coatings will be applied to these surfaces to enhance dust removal. Electrostatic repulsion in confined geometries and materials to manage high velocity lunar dust wear will also be investigated. Collectively, these active and passive mitigation technologies will facilitate lunar surface operations including occupancy logistics, landing pad operations, power generation, and transportation. Initial results regarding lunar simulant-contaminated solar panel performance experiments, dust lofting using an electron beam, surface interactions of high velocity lunar dust arising from lunar lander plume-surface interactions, and lunar dust simulant-material interaction experiments will be discussed.

Lunar dust↗

Surface melting over the Greenland ice sheet from enhanced resolution passive microwave brightness temperatures (1979–2019)

Surface melting is a major component of the Greenland ice sheet (GrIS) surface mass balance, affecting sea level rise through direct runoff and the modulation on ice dynamics and hydrological processes, supraglacially, englacially and subglacially. Passive microwave (PMW) brightness temperature observations are of paramount importance in studying the spatial and temporal evolution of surface melting in view of their long temporal coverage (1979–to date) and high temporal resolution (daily). However, a major limitation of PMW datasets has been the relatively coarse spatial resolution, being historically of the order of tens of kilometres. Here, we use a newly released passive microwave dataset (37 GHz, horizontal polarization) made available through the NASA MeASUREs program to study the spatiotemporal evolution of surface melting over the GrIS at an enhanced spatial resolution of 3.125 Km. We assess the outputs of different detection algorithms through data collected by Automatic Weather Stations (AWS) and the outputs of the MAR regional climate model. We found that surface melting is well captured using a dynamic algorithm based on the outputs of MEMLS model, capable to detect sporadic and persistent melting. Our results indicate that, during the reference period 1979–2019 (1988–2019), surface melting over the GrIS increased in terms of both duration, up to ~4.5 (2.9) days per decade, and extension, up to 6.9 % (3.6 %) of the GrIS surface extent per decade, according to the MEMLS algorithm. Furthermore, the melting season has started up to ~4 (2.5) days earlier and ended ~7 (3.9) days later per decade. We also explored the information content of the enhanced resolution dataset with respect to the one at 25 km and MAR outputs through a semi-variogram approach. We found that the enhanced product is more sensitive to local scale processes, hence confirming the potential interest of this new enhanced product for studying surface melting over Greenland at a higher spatial resolution than the historical products and monitor its impact on sea level rise. This offers the opportunity to improve our understanding of the processes driving melting, to validate modelled melt extent at high resolution and potentially to assimilate this data in climate models.

Surface melting↗

Large Vehicle Lunar Landing Surface Interaction and In-Situ Resource Based Risk Mitigation: Landing & Launch Pads

A key capability required for the exploration of planetary bodies is the ability to land on the surface. Previous work performed by NASA and other institutions has primarily focused on landing small spacecraft on planetary surfaces and the associated small-to-medium thrusters required for the soft landing. In the case of human exploration—particularly the establishment of long duration exploration and habitation outposts—the ability to land large landers, such as the SpaceX Starship, is necessary. These larger landing systems require the use of more powerful engines, with higher engine exhaust temperatures and higher landing loads. Understanding the excavation of material by the engines, as well as the potential for the landing legs to sink into the subsurface, is key in ensuring reliable and safe landings. A further improvement in landing reliability can be achieved by constructing landing / launch pads, especially with in-situ resources. Some material excavation by the plume is inevitable, leaving at least a portion of the surface scoured and uneven under the lander and ejecting regolith particles and rocks at very high velocities. One possible solution would be to robotically build landing / launch pads (ideally autonomously) at the destination using in-situ materials. In this case, the first one or few landers will need to land on unimproved surfaces at higher risk; however, they would bring the required equipment to build the landing pads with mostly local resources, thus increasing the reliability of safe landing for subsequent larger landers. A number of methods to build in-situ landing and launch pads have already been developed. These methods include no or some addition of required binder additives to the local regolith material, different processing approaches and result in varying landing pad strengths. A sub-scale rocket engine plume, was used to simulate some of the conditions of a landing on the Moon to assess the effectiveness of various materials for an in-situ built landing pad, The GO2/GCH4 rocket engine fired on 1m2 area coupons of representative pad materials. The results will allow continued development towards materials that satisfy the landing pad properties required for the effective risk reduction and increased reliability for landing people and equipment on the lunar surface. This work contained two parts: (1) computer modeling of a large rocket engine plume interacting with regolith on the Moon, using the Granular Gas Flow Solver (GGFS) provided by CFD Research Corporation as well as other computational fluid dynamics codes (CFD) such as Loci/CHEM. (2) Developing landing/launch pad materials that could be used for in-situ construction on the lunar surface in the future, to mitigate the calculated effects of a large vehicle rocket engine landing and launching on the Moon. The resulting computed values of plume impingement surface temperature, stagnation pressure, gas velocity, shear stress and heat flux were then matched as closely as possible in the Earth’s atmosphere in a sub-scale rocket engine GO2/CH4 test which was provided by Masten Space Systems in Mojave, California. The rocket engine was mounted on a test stand with vertical translation capabilities so that the landing operations of a lander could be simulated (Figure 1).The pad materials test coupons were placed at the surface of a large bin containing simulated lunar basalt regolith and subjected to a test firing as shown in Figure 2. The results of this testing will be presented with related findings, analysis and discussion.

Plume Surface Interaction↗

Effect of Rain-Adjusted Satellite Sea Surface Salinity on ENSO Predictions from the GMAO S2S Forecast System

ENSO has a significant impact on climate variability throughout the world and so has been the key focus for improving coupled ocean-atmosphere forecasts. Assimilation of altimetry and in situ data lead to improved short-term forecasts of the coupled system. However, few studies have focused on improving the near-surface density/mixing through assimilation of satellite sea surface salinity (SSS). For expediency, most projects that do assimilate SSS do so as if these data were observed at the top model layer instead of at the surface. In rainy regions where buoyant water sits as a fresh lens at the surface, this assumption is likely invalid. Therefore, we adjust SSS so that it more accurately represents the salinity at the first model layer. The Rain Impact Model (RIM) uses a simple diffusion model to determine the near surface salinity gradient (i.e., 1 cm to 5 m). Satellite SSS data are modified using this near-surface salinity gradient, so the salinity values are now valid at the first model layer (we call this SSS@5m). We assess the impact of satellite SSS observations for near-surface dynamics within ocean reanalyses and how these impact dynamical ENSO forecasts using the NASA GMAO S2S coupled system. For all reanalysis experiments, all available along-track sea level and in situ observations are assimilated for 2011 to 2020 using the LETKF scheme (Penny et al., 2013). One reanalysis assimilates Aquarius /SMAP SSS as before. An additional reanalysis is performed assimilating the SSS@5m data. Validation statistics are compared for experiments that assimilate SSS (sub-optimally as before) versus the SSS@5m. We also compare results of coupled forecasts that are initialized from these reanalyses in spring. For all but the big La Niña in 2017, all NINO3.4 forecasts were improved by using the RIM. We will show that improved SSS estimates upgrades density and near-surface mixing leading to more accurate coupled air/sea interaction and better forecasts.

ENSO↗

Replication of Segments of STS-94 as a Lunar Surface Mission

The Artemis exploration plan will progress from initial Commercial Lunar Payloads Services (CLPS) landers to human landings to an established surface infrastructure supporting four crew for surface missions of a month or greater. NASA teams are currently working with partners to define the surface assets that will comprise this infrastructure, including habitation and laboratory facilities. However, design engineers often have limited insight into the laboratory capabilities needed inside a pressurized habitat or the demands such a facility will place upon crew availability. The Space Shuttle STS-94 Microgravity Science Laboratory (MSL-1) mission is used as an intravehicular activity science analog for the Surface Habitat. The STS-94 primary physical science instruments and crew activity in support of physical science investigations will be examined. Based on recent reference concepts for the Surface Habitat, options for incorporating the instruments and options for dividing physical science tasks among the Surface Habitat crew are discussed, based on STS94 crew tasks and assumptions for Surface Habitat operations. Crew size considerations are raised along with recommendations to reassess some of the current assumptions. Having shown that STS-94’s physical science investigations can be applied to a lunar surface mission, recommendations are made for increased attention to pressurized laboratory objectives, capabilities, and crew size.

Surface Habitat↗

Heat-Exchange Driven Aircraft for Low Altitude and Surface Exploration of Venus: Phase 1 Study Final Report

Exploration of Venus below its clouds has long been impaired by the planet’s massive CO2 atmosphere, corrosive trace gases, and high opacity. Except for a few narrow spectral windows, the 20 km thick global cloud cover blocks light over the entirety of the ultraviolet through thermal infrared spectrum, impeding orbital studies of the surface and lower portion of the atmosphere. In addition to the cloud opacity, Rayleigh scattering through 80 bars of CO 2 in the lower 40 km of the atmosphere results in a Rayleigh scattering depth between 25 and1 in the visible through near infrared portion of the spectrum. That optically thick scattering, combined with the uniform angular distribution of the illumination provided by the highly diffusing clouds overhead greatly reduces even very large surface albedo contrasts (Crisp, pers. Comm.). To date, the surface has only been mapped via synthetic aperture radar by the Magellan mission at scales of 120 to 300 m/pixel. In addition to contributing to the difficulty of performing studies of the surface from orbit, the extreme temperatures and pressures at the surface also create a challenging environment to utilize a lander for exploration. The longest-lived lander on Venus’ surface survived for 2 hours. Hence, limited access to observe the surface and lower atmosphere of Venus arguably puts the surface and lower atmosphere of Venus as one of the least explored regions of the inner Solar System.

NIAC Phase I↗

Improving adhesive bonding of short carbon fiber thermoplastic composites to aluminum alloys with a hybrid laser-plasma surface modification strategy

This study investigates hybrid laser–plasma surface modification strategies for metal–CFRTP (carbon-fiber-reinforced thermoplastic polymer) dissimilar joints to improve their bonding performance, in contrast to existing literature that mostly focuses on either plasma or laser treatment alone. By conducting double cantilever beam (DCB) tests on adhesively-bonded AA5052 and CFRPA66 (carbon-fiber-reinforced polyamide 66) joints, as an example of metal–CFRTP joints, it was found that laser engraving on the metal surface combined with plasma treatment on the CFRTP surface significantly improved the specific fracture energy of the joint by 187% and 31% compared to as-received and plasma-treated-only joints, respectively. However, the hybrid treatment of laser engraving and plasma on the investigated CFRTP surface did not improve the bonding performance of the joints. The underlying mechanisms related to hybrid laser-plasma surface modification strategies were further investigated by examining the surface and cross-sectional morphologies after DCB testing using microscopy. Computational modeling was performed to elucidate the interaction between grooves on the metal substrate and the CFRTP–adhesive interfacial bonding in metal–CFRTP joints. This study provides new insights into developing surface modification methods for achieving strong metal–CFRTP adhesive joints, aimed at lightweighting structural components in automotive, aerospace, and other applications.

Adhesive bonding↗

Discovery of Stable Surfaces with Extreme Work Functions by High‐Throughput Density Functional Theory and Machine Learning

Abstract The work function is the key surface property that determines the energy required to extract an electron from the surface of a material. This property is crucial for thermionic energy conversion, band alignment in heterostructures, and electron emission devices. This work presents a high‐throughput workflow using density functional theory (DFT) to calculate the work function and cleavage energy of 33,631 slabs (58,332 work functions) that are created from 3,716 bulk materials. The number of calculated surface properties surpasses the previously largest database by a factor of ≈27. Several surfaces with an ultra‐low (<2 eV) and ultra‐high (>7 eV) work function are identified. Specifically, the (100)‐Ba‐O surface of BaMoO 3 and the (001)‐F surface of Ag 2 F have record‐low (1.25 eV) and record‐high (9.06 eV) steady‐state work functions. Based on this database a physics‐based approach to featurize surfaces is utilized to predict the work function. The random forest model achieves a test mean absolute error (MAE) of 0.09 eV, comparable to the accuracy of DFT. This surrogate model enables rapid predictions of the work function (≈ 10 5 faster than DFT) across a vast chemical space and facilitates the discovery of material surfaces with extreme work functions for energy conversion and electronic device applications.

97 MATHEMATICS AND COMPUTING↗

The Interplay Between Ferroelectricity and Electrochemical Reactivity on the Surface of Binary Ferroelectric Al x B 1–x N

Polarization dynamics and domain structure evolution in ferroelectric Al 0.93 B 0.07 N are studied using piezoresponse force microscopy and spectroscopies in ambient and controlled atmosphere environments. The application of negative unipolar and bipolar first-order reverse curve (FORC) waveforms leads to a protrusion-like feature on the Al 0.93 B 0.07 N surface and a reduction of electromechanical response due to electrochemical reactivity. A surface change is also observed on the application of fast alternating current bias. At the same time, the application of positive biases does not lead to surface changes. Comparatively in a controlled glove box atmosphere, stable polarization patterns can be observed, with minuscule changes in surface morphology. This surface morphology change is not isolated to applying biases to free surface, a similar topographical change is also observed at the electrode edges when cycling a capacitor in an ambient environment. The study suggests that surface electrochemical reactivity may have a significant impact on the functionality of this material in the ambient environment. However, even in the controlled atmosphere, the participation of the surface ions in polarization switching phenomena and ionic compensation is possible.

36 MATERIALS SCIENCE↗

Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations

Abstract Surface chemistry of MXenes is of great interest as the terminations can define the intrinsic properties of this family of materials. The diverse and tunable terminations also distinguish MXenes from many other 2D materials. Conventional fluoride‐containing reagents etching approaches resulted in MXenes with mixed fluoro‐, oxo‐, and hydroxyl surface groups. The relatively strong chemical bonding of MXenes’ surface metal atoms with oxygen and fluorine makes post‐synthetic covalent surface modifications of such MXenes unfavorable. In this minireview, we focus on the recent advances in MXenes with uniform surface terminations. Unconventional methods, including Lewis acidic molten salt etching (LAMS) and bottom‐up direct synthesis, have been proven successful in producing halide‐terminated MXenes. These synthetic strategies have opened new possibilities for MXenes because weaker surface chemical bonds in halide‐terminated MXenes facilitate post‐synthetic covalent surface modifications. Both computational and experimental results on surface termination‐dependent properties are summarized and discussed. Finally, we offer our perspective on the opportunities and challenges in this exciting research field.

Jiang, Mengni↗

Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations

Abstract Surface chemistry of MXenes is of great interest as the terminations can define the intrinsic properties of this family of materials. The diverse and tunable terminations also distinguish MXenes from many other 2D materials. Conventional fluoride‐containing reagents etching approaches resulted in MXenes with mixed fluoro‐, oxo‐, and hydroxyl surface groups. The relatively strong chemical bonding of MXenes’ surface metal atoms with oxygen and fluorine makes post‐synthetic covalent surface modifications of such MXenes unfavorable. In this minireview, we focus on the recent advances in MXenes with uniform surface terminations. Unconventional methods, including Lewis acidic molten salt etching (LAMS) and bottom‐up direct synthesis, have been proven successful in producing halide‐terminated MXenes. These synthetic strategies have opened new possibilities for MXenes because weaker surface chemical bonds in halide‐terminated MXenes facilitate post‐synthetic covalent surface modifications. Both computational and experimental results on surface termination‐dependent properties are summarized and discussed. Finally, we offer our perspective on the opportunities and challenges in this exciting research field.

Jiang, Mengni↗