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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Heat generation in electric double layer capacitors with neat and diluted ionic liquid electrolytes under large potential window between 5 and 80 °C

Here, this study investigates the effect of temperature on the heat generation and the associated electrochemical phenomena occurring in IL-based EDLCs. The EDLCs consisted of two identical activated carbon electrodes with neat Pyr14TFSI or Pyr14TFSI diluted in propylene carbonate (PC) as electrolytes. The instantaneous heat generation rate at each electrode was measured by isothermal calorimetry between 5 and 80 °C under constant current cycling and potential window of 2.5 V. First, the instantaneous heat generation rate was similar at each electrode in neat IL. However, it was smaller at the negative electrode in diluted IL and featured endothermic dips growing with increasing temperature > 40 °C due to overscreening effects, ion desolvation, and/or decomposition of PC. The irreversible heat generation was similar in each half-cell and decreased with increasing temperature due to the reduction in internal resistance, particularly with neat IL. The irreversible heat generation exceeded Joule heating in all cases, especially at high temperature and low current. This was attributed to ion desorption and charge redistribution in the porous electrodes. Finally, the reversible heat generation for both electrolytes was larger at the positive than at the negative electrode due to the difference in anion and cation sizes.

25 ENERGY STORAGE↗
DOE OSTI2022

Unsupervised discovery of nonlinear plasma physics using differentiable kinetic simulations

Plasma supports collective modes and particle–wave interactions that lead to complex behaviour in, for example, inertial fusion energy applications. While plasma can sometimes be modelled as a charged fluid, a kinetic description is often crucial for studying nonlinear effects in the higher-dimensional momentum–position phase space that describes the full complexity of the plasma dynamics. We create a differentiable solver for the three-dimensional partial-differential equation describing the plasma kinetics and introduce a domain-specific objective function. Using this framework, we perform gradient-based optimization of neural networks that provide forcing function parameters to the differentiable solver given a set of initial conditions. We apply this to an inertial-fusion-relevant configuration and find that the optimization process exploits a novel physical effect.

plasma nonlinear phenomena↗
DOE OSTI2020

Spin-1 Kitaev-Heisenberg model on a honeycomb lattice

We study the Kitaev-Heisenberg model with spin-1 local degree of freedom on a honeycomb lattice numerically by the infinite density matrix renormalization group method on a cylinder geometry. By tuning the relative value of the Kitaev and Heisenberg exchange couplings, we obtain the phase diagram with two spin liquid phases and four symmetry-broken phases. Here, we identify that the spin liquid phases are gapless by calculating the central charge at the pure Kitaev points without the Heisenberg interactions. Comparing to its spin-1/2 counterpart, the position and number of gapless modes of the spin-1 case are quite different. Due to the approximate Z 2 local conservations, the expectation value of the Wilson loop operator measuring the flux of each plaquette stays near to 1, and the static spin-spin correlations remain short range in the entire spin liquid phases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1969

Sferics

The properties of sferics (the electric and magnetic fields generated by electrified clouds and lightning flashes) are briefly surveyed; the source disturbance and the influence of propagation being examined. Methods of observing sferics and their meteorological implications are discussed. It is concluded that close observations of electrostatic and radiation fields are very informative, respectively, upon the charge distribution and spark processes in a cloud; that ground-level sferics stations can accurately locate the positions of individual lightning flashes and furnish valuable knowledge on the properties of the discharges; but that satellite measurements only provide general information on the level of thundery activity over large geographical regions.

Pierce, E. T.↗
NASA NTRS1971

Sounding rocket flight report: MUMP 9 and MUMP 10

The results of the launching of two Marshall-University of Michigan Probes (MUMP 9 and MUMP 10), Nike-Tomahawk sounding rocket payloads, are summarized. The MUMP 9 paylaod included an omegatron mass analyzer, a molecular fluorescence densitometer, a mini-tilty filter, and a lunar position sensor. This complement of instruments permitted the determination of the molecular nitrogen density and temperature in the altitude range from approximately 143 to 297 km over Wallops Island, Virginia, during January 1971. The MUMP 10 payload included an omegatron mass analyzer, an electron temperature probe (Spencer, Brace, and Carignan, 1962), a cryogenic densitometer, and a solar position sensor. This complement of instruments permitted the determination of the molecular nitrogen density and temperature and the charged particle density and temperature in the altitude range from approximately 145 to 290 km over Wallops Island, Virginia, during the afternoon preceding the MUMP 9 launch in January 1971. A general description of the payload kinematics, orientation analysis, and the technique for the reduction and analysis of the data is given.

Grassl, H. J.↗
NASA NTRS1980

A three-dimensional spacecraft-charging computer code

A computer code is described which simulates the interaction of the space environment with a satellite at geosynchronous altitude. Employing finite elements, a three-dimensional satellite model has been constructed with more than 1000 surface cells and 15 different surface materials. Free space around the satellite is modeled by nesting grids within grids. Applications of this NASA Spacecraft Charging Analyzer Program (NASCAP) code to the study of a satellite photosheath and the differential charging of the SCATHA (satellite charging at high altitudes) satellite in eclipse and in sunlight are discussed. In order to understand detector response when the satellite is charged, the code is used to trace the trajectories of particles reaching the SCATHA detectors. Particle trajectories from positive and negative emitters on SCATHA also are traced to determine the location of returning particles, to estimate the escaping flux, and to simulate active control of satellite potentials.

Rubin, A. G.↗
NASA NTRS1991

Report of the x ray and gamma ray sensors panel

Overall five major areas of technology are recommended for development in order to meet the science requirements of the Astrotech 21 mission set. These are: detectors for high resolution gamma ray spectroscopy, cryogenic detectors for improved x ray spectral and spatial resolution, advanced x ray charge coupled devices (CCDs) for higher energy resolution and larger format, extension to higher energies, liquid and solid position sensitive detectors for improving stopping power in the energy range 5 to 500 keV and 0.2 to 2 MeV. Development plans designed to achieve the desired capabilities on the time scales required by the technology freeze dates have been recommended in each of these areas.

Szymkowiak, Andrew↗
NASA NTRS1993

HILT - A heavy ion large area proportional counter telescope for solar and anomalous cosmic rays

The HILT sensor has been designed to measure heavy ion elemental abundances, energy spectra, and direction of incidence in the mass range from He to Fe and in the energy range 4 to 250 MeV/nucleon. With its large geometric factor of 60 sq cm sr the sensor is optimized to provide compositional and spectral measurements for low intensity cosmic rays (i.e. for small solar energetic particle events and for the anomalous component of cosmic rays). The instrument combines a large area ion drift chamber-proportional counter system with two arrays of 16 Li-drift solid state detectors and 16 CsI crystals. The multi dE/dx-E technique provides a low background mass and energy determination. The sensor also measures particle direction. Combining these measurements with the information on the spacecraft position and attitude in the low-altitude polar orbit, it will be possible to infer the ionic charge of the ions from the local cutoff of the Earth's magnetic field. The ionic charge in this energy range is of particular interest because it provides unique clues to the origin of these particles and has not been investigated systematically so far. Together with the other instruments on board SAMPEX (LEICA, MAST, and PET), a comprehensive measurement of the entire solar and anomalous particle population will be achieved.

Klecker, Berndt↗
NASA NTRS2011

Two Azimuthally Separated Regions of Cusp Ion Injection Observed via Energetic Neutral Atoms

The low-energy neutral atom (LENA) imager on the IMAGE spacecraft can detect energetic neutral atoms produced by ion injection into the cusp through a charge exchange with the Earth's hydrogen exosphere. We examined the occurrence of the LENA cusp signal during positive IMF B(sub z) in terms of the arrival direction and the IMF clock angle theta(sub CA). Results of statistical analyses show that the occurrence frequency is high on the postnoon side when theta(sub CA) is between approximately 20 degrees and approximately 50 degrees. This is ascribed to ion injection caused by cusp reconnection typical of positive IMF B(sub z). Our results also show that there is another situation of high occurrence frequency, which can be identified with theta(sub CA) of approximately 30 degrees to approximately 80 degrees. When theta(sub CA) is relatively large (60 degrees - 80 degrees), occurrence frequencies are high at relatively low latitudes over a wide extent spanning both prenoon and postnoon sectors. This feature suggests that the ion injection is caused by reconnection at the dayside magnetopause. Its postnoon side boundary shifts toward the prenoon as theta(sub CA) decreases. When theta(sub CA) is less than approximately 50 degrees, the high occurrence frequency exists well inside the prenoon sector, which is azimuthally separated from the postnoon region ascribed to cusp reconnection. The prenoon region, which is thought due to ion injection caused by dayside reconnection, may explain the recent report that proton aurora brightening occurs in the unanticipated prenoon sector of the northern high-latitude ionosphere for IMF B(sub y) greater than 0 and B(sub z) greater than 0.

Abe, M.↗
DOE OSTI2026

Multiple Coulomb scattering for muon energy reconstruction in SBND Monte Carlo simulations

The Short Baseline Near Detector (SBND) is a liquid argon time projection chamber (LArTPC) located 110 meters downstream of the Booster Neutrino Beam target at Fermilab \cite{SBN}. The LArTPC is a detector technology with unprecedented position and calorimetric resolution for precise neutrino studies. The most dominant neutrino interaction topology in SBND is charged-current quasi-elastic muon neutrino-argon interactions, where the final state consists of a muon and a proton. Here, muons often travel long distances, sometimes exiting the detector before stopping. This loss of information creates a challenge for accurate energy estimation. There have been efforts in the MicroBooNE and ICARUS collaborations to improve energy estimation using a phenomenon known as Multiple Coulomb Scattering (MCS), which describes the jagged path taken by muons through a detector due to continuous Coulomb interactions with argon atoms. Building on these efforts, my project aims to improve an MCS-based approach to estimating the energies of exiting muons in SBND.

Puig, Xilonem Angeles [Mt. Holyoke Coll.; Fermilab↗
NASA NTRS2000

Long Life Nickel Electrodes for Nickel-Hydrogen Cells: Fiber Substrates Nickel Electrodes

Samples of nickel fiber mat electrodes were investigated over a wide range of fiber diameters, electrode thickness, porosity and active material loading levels. Thickness' were 0.040, 0.060 and 0.080 inches for the plaque: fiber diameters were primarily 2, 4, and 8 micron and porosity was 85, 90, and 95%. Capacities of 3.5 in. diameter electrodes were determined in the flooded condition with both 26 and 31% potassium hydroxide solution. These capacity tests indicated that the highest capacities per unit weight were obtained at the 90% porosity level with a 4 micron diameter fiber plaque. It appeared that the thinner electrodes had somewhat better performance, consistent with sintered electrode history. Limited testing with two-positive-electrode boiler plate cells was also carried out. Considerable difficulty with constructing the cells was encountered with short circuits the major problem. Nevertheless, four cells were tested. The cell with 95% porosity electrodes failed during conditioning cycling due to high voltage during charge. Discharge showed that this cell had lost nearly all of its capacity. The other three cells after 20 conditioning cycles showed capacities consistent with the flooded capacities of the electrodes. Positive electrodes made from fiber substrates may well show a weight advantage of standard sintered electrodes, but need considerably more work to prove this statement. A major problem to be investigated is the lower strength of the substrate compared to standard sintered electrodes. Problems with welding of leads were significant and implications that the electrodes would expand more than sintered electrodes need to be investigated. Loading levels were lower than had been expected based on sintered electrode experiences and the lower loading led to lower capacity values. However, lower loading causes less expansion and contraction during cycling so that stress on the substrate is reduced.

Rogers, Howard H.↗
NASA NTRS1945

An Experimental Investigation of the Effect of Propellers Used as Aerodynamic Brakes on Stability and Control

Tests were made of a model representative of a single-engine tractor-type airplane for the purpose of determining the stability and control effects of a propeller used as an aerodynamic brake. The tests were made with single-and dual-rotation propellers to show the effect of type of propeller rotation, and with positive thrust to provide basic data with which to compare the effects of negative thrust. Four configurations of the model were used to give the effects of tilting the propeller thrust axis down 5 deg., raising the horizontal tail, and combining both tilt and raised tail. Results of the tests are reported herein. The effects of negative thrust were found to be significant. The longitudinal stability was increased because of the loss of wing lift and increase of the angle of attack of the tail. Directional stability and both longitudinal and directional control were decreased because of the reduced velocity at the tail. These effects are moderate for moderate braking but become pronounced with full-power braking, particularly at high values of lift coefficient. The effects of model configuration changes were small when compared with the over-all effects of negative-thrust operation; however, improved stability and control characteristics were exhibited by the model with the tilted thrust axis. Raising the horizontal tail improved the longitudinal characteristics, but was detrimental to directional characteristics. The use of dual-rotation propeller reduced the directional trim charges resulting from the braking operation. A prototype airplane was assumed and handling qualities were computed and analyzed for normal (positive thrust) and braking operation with full and partial power. The results of these analyses are presented for the longitudinal characteristics in steady and accelerated flight, and for the directional characteristics in high- and low-speed flight. It was found that by limiting the power output of the engine (assuming the constant-speed propeller will function in the range of blade angles required for negative thrust) the stability and control characteristics may be held within the limits required for safe operation. Braking with full power, particularly at low speeds, is dangerous, but braking with very small power output is satisfactory from the standpoint of control. The amount of braking produced with zero power output is equal to or better than that produced by conventional spoiler-type brakes.

AIRPLANES, MILITARY↗
DOE OSTI2026

Electrostatic Gating of Ionic Conductance through Heterogeneous van der Waals Nanopores

Nanofluidic ionic transistors typically require gate voltages above 1 V and operate only at submillimolar ionic strengths, limiting their biocompatible applications. We demonstrate ionic transistors consisting of single sub-10 nm nanopores drilled in van der Waals (vdW) heterostructures with internal gate electrodes made of few-layer graphene. These devices deliver up to 10-fold current modulation at gate voltages as low as 0.3 V in 10 mM KCl, and ∼2-fold modulation at near-physiological 100 mM KCl. Baseline conductance with no gate shows surface-charge-dominated transport below 100 mM KCl, consistent with negatively charged hBN walls and ∼5 nm opening of the pores. The surface charge and the electrochemical asymmetry introduced by the three-electrode configuration govern the device’s behavior: negative gate voltage (V G ) enriches ionic concentrations and enhances current, whereas positive V G induces a local depletion zone that suppresses transport. The current modulation by V G is dependent on the polarity of the transmembrane potential and leads to ion current rectification. Molecular dynamics simulations of a nanopore in a hBN–graphene–hBN stack reveal confinement and surface charge-dependent suppression of the relative permittivity of interfacial water. Continuum modeling with radially varying interfacial water permittivity reproduces the asymmetric I–V characteristics and explains how the embedded gate sculpts local potential and ion concentrations. By enabling sub-0.5 V control of ionic transport at up to 100 mM salt concentrations, these devices address a key need in nanofluidics to create low-power ionic circuits and biosensing.

Materials science↗
NASA NTRS2003

Assessment and Control of Spacecraft Charging Risks on the International Space Station

Electrical interactions between the F2 region ionospheric plasma and the 160V photovoltaic (PV) electrical power system on the International Space Station (ISS) can produce floating potentials (FP) on the ISS conducting structure of greater magnitude than are usually observed on spacecraft in low-Earth orbit. Flight through the geomagnetic field also causes magnetic induction charging of ISS conducting structure. Charging processes resulting from interaction of ISS with auroral electrons may also contribute to charging albeit rarely. The magnitude and frequency of occurrence of possibly hazardous charging events depends on the ISS assembly stage (six more 160V PV arrays will be added to ISS), ISS flight configuration, ISS position (latitude and longitude), and the natural variability in the ionospheric flight environment. At present, ISS is equipped with two plasma contactors designed to control ISS FP to within 40 volts of the ambient F2 plasma. The negative-polarity grounding scheme utilized in the ISS 160V power system leads, naturally, to negative values of ISS FP. A negative ISS structural FP leads to application of electrostatic fields across the dielectrics that separate conducting structure from the ambient F2 plasma, thereby enabling dielectric breakdown and arcing. Degradation of some thermal control coatings and noise in electrical systems can result. Continued review and evaluation of the putative charging hazards, as required by the ISS Program Office, revealed that ISS charging could produce a risk of electric shock to the ISS crew during extra vehicular activity. ISS charging risks are being evaluated in ongoing ISS charging measurements and analysis campaigns. The results of ISS charging measurements are combined with a recently developed detailed model of the ISS charging process and an extensive analysis of historical ionospheric variability data, to assess ISS charging risks using Probabilistic Risk Assessment (PRA) methods. The PRA analysis (estimated frequency of occurrence and severity of the charging hazards) are then used to select the hazard control strategy that provides the best overall safety and mission success environment for ISS and the ISS crew. This paper presents: 1) a summary of ISS spacecraft charging analysis, measurements, observations made to date, 2) plans for future ISS spacecraft charging measurement campaigns, and 3) a detailed discussion of the PRA strategy used to assess ISS spacecraft charging risks and select charging hazard control strategies

Koontz, Steve↗
DOE OSTI2021

Ferromagnetism out of charge fluctuation of strongly correlated electrons in κ -(BEDT-TTF) 2 Hg(SCN) 2 Br

We perform magnetic susceptibility and magnetic torque measurements on the organic κ-(BEDT-TTF) 2 Hg(SCN) 2 Br, which is recently suggested to host an exotic quantum dipole-liquid in its low-temperature insulating phase. Below the metal-insulator (MI) transition temperature, the magnetic susceptibility follows a Curie–Weiss law with a positive Curie–Weiss temperature, and a particular M∝ $\sqrt{H}$ curve is observed. The emergent ferromagnetically interacting spins amount to about 1/6 of the full spin moment of localized charges. Taking account of the possible inhomogeneous quasi-charge-order that forms a dipole-liquid, we construct a model of antiferromagnetically interacting spin chains in two adjacent charge-ordered domains, which are coupled via fluctuating charges on a Mott-dimer at the boundary. We find that the charge fluctuations can draw a weak ferromagnetic moment out of the spin singlet domains.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Electrical properties of the middle atmosphere

Probe techniques have been utilized extensively to measure middle atmospheric electrical properties such as the polar components of conductivity, ion mobility and density. The most variable of these parameters is conductivity, which is dependent on both charge mobility and concentration. Overall conductivity variations, attributable to different geophysical conditions, can exceed several orders of magnitude at some altitudes. Also, measurements of conductivity over the 20 to 90 km region indicate a general exponential increase with altitude, exceeding seven orders of magnitude during certain conditions. Gerdien condensers, on occasion, have measured very low-mobility positive ions in addition to the more commonly observed molecular species. These smaller mobility values appear to indicate the presence of very large ions at some altitudes, possibly charged particulates, having mass sizes greater than those identifiable by presently flown mass spectrometers. The presence of these large ions is of importance to middle atmospheric electrodynamics as a potential causal mechanism for measured large electric fields.

Mitchell, John D.↗
DOE OSTI2019

An investigation on the impact of halidization on substituted dimethoxybenzenes

Functionalized organic molecules are emerging as charge storage materials in electrochemical technologies as the breadth and diversity of the organic design space offers the possibility of purpose-built materials with property sets optimized for a particular application. First developed as overcharge protection materials in lithium-ion batteries, substituted dialkoxybenzenes represent a potentially promising molecular platform for advancing soluble charge storage materials. In this study, we systematically substitute a series of halide groups at the 2- and 5-positions of the 1,4-dimethoxybenzene core, investigate the impact the halide groups have on molecular properties using electrochemical and spectroscopy methods, and compare these results to those of 2,5-dimethyl-1,4-dimethoxybenzene (25DDB), a previously reported derivative. In general, we observe that introduction of heavy halogen atoms leads to decreased gravimetric capacity as compared to 25DDB, but concomitantly improves solubility and redox potentials. As the halide functional group increases in size, the active material becomes less stable in its oxidized state as evinced by both cyclic voltammetry and bulk electrolysis cycling. None of the halogenated species are as stable as 25DDB indicating that these materials may be better suited for applications with more rapid cycling conditions (e.g., redox shuttling). More broadly, these results may serve as a useful data set for computational methods for materials discovery and optimization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

The imaging Time-of-Propagation detector at Belle II

Here, we report on the construction, operation, and performance of the Time-of-Propagation detector with imaging used for the Belle II experiment running at the Super-KEKB e + e - collider. This detector is located in the central barrel region and uses Cherenkov light to provide particle identification among hadrons. The Cherenkov light is radiated in highly polished bars of synthetic fused silica (quartz) and transported to the ends of the bars via total internal reflection. One bar end is instrumented with finely segmented micro-channel-plate photomultiplier tubes to record the light, while the other end has a mirror attached to reflect the photons back to the instrumented end. Both the propagation times and hit positions of the Cherenkov photons are measured; these depend on the Cherenkov angle and together provide good discrimination among charged pions, kaons, and protons with momenta up to around 4 GeV/ c . To date, the detector has been used to record and analyze almost 600 fb −1 of Belle II data.

43 PARTICLE ACCELERATORS↗