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At least 1,135 records · Page 63

Hot corrosion of low cobalt alloys

The hot corrosion attack susceptibility of various alloys as a function of strategic materials content are investigated. Preliminary results were obtained for two commercial alloys, UDIMET 700 and Mar-M 247, that were modified by varying the cobalt content. For both alloys the cobalt content was reduced in steps to zero. Nickel content was increased accordingly to make up for the reduced cobalt but all other constituents were held constant. Wedge bar test samples were produced by casting. The hot corrosion test consisted of cyclically exposing samples to the high velocity flow of combustion products from an air-fuel burner fueled with jet A-1 and seeded with a sodium chloride aqueous solution. The flow velocity was Mach 0.5 and the sodium level was maintained at 0.5 ppm in terms of fuel plus air. The test cycle consisted of holding the test samples at 900 C for 1 hour followed by 3 minutes in which the sample could cool to room temperature in an ambient temperature air stream.

Stearns, C. A.↗

Mechanism of Pinhole Formation in Membrane Electrode Assemblies for PEM Fuel Cells

The pinhole formation mechanism was studied with a variety of MEAs using ex-situ and in-situ methods. The ex-situ tests included the MEA aging in oxygen and MEA heat of ignition. In-situ durability tests were performed in fuel cells at different operating conditions with hydrogen and oxygen. After the in-situ failure, MEAs were analyzed with an Olympus BX 60 optical microscope and Cambridge 120 scanning electron microscope. MEA chemical analysis was performed with an IXRF EDS microanalysis system. The MEA failure analyses showed that pinholes and tears were the MEA failure modes. The pinholes appeared in MEA areas where the membrane thickness was drastically reduced. Their location coincided with the stress concentration points, indicating that membrane creep was responsible for their formation. Some of the pinholes detected had contaminant particles precipitated within the membrane. This mechanism of pinhole formation was correlated to the polymer blistering.

Stanic, Vesna↗

Modeling and Diagnostic Software for Liquefying-Fuel Rockets

A report presents a study of five modeling and diagnostic computer programs considered for use in an integrated vehicle health management (IVHM) system during testing of liquefying-fuel hybrid rocket engines in the Hybrid Combustion Facility (HCF) at NASA Ames Research Center. Three of the programs -- TEAMS, L2, and RODON -- are model-based reasoning (or diagnostic) programs. The other two programs -- ICS and IMS -- do not attempt to isolate the causes of failures but can be used for detecting faults. In the study, qualitative models (in TEAMS and L2) and quantitative models (in RODON) having varying scope and completeness were created. Each of the models captured the structure and behavior of the HCF as a physical system. It was noted that in the cases of the qualitative models, the temporal aspects of the behavior of the HCF and the abstraction of sensor data are handled outside of the models, and it is necessary to develop additional code for this purpose. A need for additional code was also noted in the case of the quantitative model, though the amount of development effort needed was found to be less than that for the qualitative models.

Poll, Scott↗

Scramjet Tests in a Shock Tunnel at Flight Mach 7, 10, and 15 Conditions

Tests of the Hyper-X scramjet engine flowpath have been conducted in the HYPULSE shock tunnel at conditions duplicating the stagnation enthalpy at flight Mach 7, 10, and 15. For the tests at Mach 7 and 10 HYPULSE was operated as a reflected-shock tunnel; at the Mach 15 condition, HYPULSE was operated as a shock-expansion tunnel. The test conditions matched the stagnation enthalpy of a scramjet engine on an aerospace vehicle accelerating through the atmosphere along a 1000 psf dynamic pressure trajectory. Test parameter variation included fuel equivalence ratios from lean (0.8) to rich (1.5+); fuel composition from pure hydrogen to mixtures of 2% and 5% silane in hydrogen by volume; and inflow pressure and Mach number made by changing the scramjet model mounting angle in the HYPULSE test chamber. Data sources were wall pressures and heat flux distributions and schlieren and fuel plume imaging in the combustor/nozzle sections. Data are presented for calibration of the facility nozzles and the scramjet engine model. Comparisons of pressure distributions and flowpath streamtube performance estimates are made for the three Mach numbers tested.

Rogers, R. C.↗

Nuclear fuel irradiation testbed for nuclear security applications

The nuclear security community has long been interested in the identification and quantification of nuclear material signatures to understand a material’s provenance, use, and ultimate application. New forensics signatures and methods intended for non-traditional or advanced nuclear fuel applications require fuel irradiation experiments to demonstrate viability and validity. Integral fuel irradiations have historically required significant costs and long timelines to design, irradiate, and characterize. This paper describes how a recently developed nuclear fuel irradiation testbed can be used to provide a low cost, rapid turnaround, modular test environment for irradiation and evaluation of nuclear fuel specimens for nuclear security applications. The irradiation testbed houses six small ‘MiniFuel’ samples within hermetically sealed capsules inside targets that can be removed in between each ∼25-day operating cycle of the High Flux Isotope Reactor (HFIR). As many as nine targets can be irradiated using a single irradiation position (reflector region) in HFIR, allowing for varying irradiation temperatures and burnups. A suite of hot cell capabilities have been established to perform post-irradiation examination for measuring performance (e.g., fuel swelling, fission gas release) and facilitating experiment disassembly for subsequent property measurements, microstructural analysis, or chemical assay. This new testbed allows fuel irradiations to be conducted on an accelerated timeframe to enable rapid proof of concept testing and to provide reference material for nuclear fuel security applications. Recent applications using this testbed include the testing of isotopic taggants in UO 2 fuel (intentional forensics), testing of U-10Mo fuel for down-conversion of highly enriched uranium–fueled reactors, and the production of irradiated UO 2 fuel material for signature analysis of its isotopic composition (plutonium, fission gases, etc.).

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

A performance comparison of two small rocket nozzles

An experimental study was conducted on two small rockets (110 N thrust class) to directly compare a standard conical nozzle with a bell nozzle optimized for maximum thrust using the Rao method. In large rockets, with throat Reynolds numbers of greater than 1 x 10(exp 5), bell nozzles outperform conical nozzles. In rockets with throat Reynolds numbers below 1 x 10(exp 5), however, test results have been ambiguous. An experimental program was conducted to test two small nozzles at two different fuel film cooling percentages and three different chamber pressures. Test results showed that for the throat Reynolds number range from 2 x 10(exp 4) to 4 x 10(exp 4), the bell nozzle outperformed the conical nozzle. Thrust coefficients for the bell nozzle were approximately 4 to 12 percent higher than those obtained with the conical nozzle. As expected, testing showed that lowering the fuel film cooling increased performance for both nozzle types.

Arrington, Lynn A.↗

Sister Rod Destructive Examinations (FY22) Appendix E: Mechanical Testing

As a part of the DOE NE High Burnup Spent Fuel Data Project, Oak Ridge National Laboratory (ORNL) is performing destructive examinations (DEs) of high burnup (HBU) (>45 GWd/MTU) spent nuclear fuel (SNF) rods from the North Anna Nuclear Power Station operated by Dominion Energy. The SNF rods, called sister rods or sibling rods, are all HBU and include four different kinds of fuel rod cladding: standard Zircaloy-4 (Zirc-4), low-tin Zirc-4, ZIRLO, and M5. The DEs are being conducted to obtain a baseline of the HBU rod’s condition before dry storage and are focused on understanding overall SNF rod strength and durability. Composite fuel and defueled cladding will be tested to derive material properties. Although the data generated can be used for multiple purposes, one primary goal for obtaining the post-irradiation examination data and the associated measured mechanical properties is to support SNF dry storage licensing and relicensing activities by (1) addressing identified knowledge gaps and (2) enhancing the technical basis for post-storage transportation, handling, and subsequent disposition.This appendix documents the status of the ORNL Phase 1 DE activities related to the mechanical testing of selected sister rods in Phase 1 of the sister rod test program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Irradiation performance of a U-7Mo in Al-Si matrix dispersion full-size fuel plate assembly

The Korea Atomic Energy Research Institute (KAERI) is leading the Ki-Jang Research Reactor (KJRR) project with the intent to develop a new reactor for medical isotope production and other nuclear research purposes. The KJRR core is designed to use high density fuel system where uranium alloyed with 7 wt% molybdenum (U-7Mo) particles are dispersed in a matrix of aluminum alloyed with 5 wt% silicon (Al-5Si) and clad in aluminum alloy 6061 (Al-6061) to form fuel plates. KAERI developed a fabrication facility to construct KJRR fuel assemblies and partnered with the Idaho National Laboratory (INL) to irradiate a full-size fuel assembly, with 21 total fuel plates, in the Advanced Test Reactor (ATR). Irradiation testing and subsequent Post Irradiation Exam (PIE) campaigns were performed successfully over a multi-year project. Monte Carlo neutronic calculations, coupling with a depletion code, were performed based on ATR’s as-run power history which showed that the highest power plate (plate 20) reached 83.1 % end-of-life (EOL) local burnup based on initial 235 U content. Additionally, finite element thermal modeling was performed based as-run power history which showed a beginning-of-life (BOL) peak local heat flux of 184 W/cm 2 . No anomalous fuel performance was observed during the irradiation and target test conditions were achieved. PIE showed favorable performance of the fuel assembly regarding all important phenomena. This paper describes the KJRR fuel assembly irradiation conditions and PIE data to support the conclusion that it performed well, without evidence of unexpected or problematic fuel performance, within an irradiation test designed to bound the KJRR design environment.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Flowsheet Development for the University of Tokyo YAYOI (UTY) Fuel

The Savannah River National Laboratory (SRNL) was requested by H-Canyon Engineering to determine the flowsheet parameters needed to dissolve and store the YAYOI Material Test Reactor (MTR) uranium fuel safely and efficiently. In response to this request, a literature review of existing SRNL MTR dissolution flowsheets and general fuel dissolution literature in the nuclear fuel processing industry was performed to evaluate chemical dissolution parameters required to dissolve the YAYOI fuel and the tin-plated carbon steel product cans (PC). Based on past dissolutions of similar fuel in the H-Canyon and open literature reviews on chemical dissolution of spent nuclear fuel (SNF), the following conclusions and flowsheet recommendations were made.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Low and medium heating value coal gas catalytic combustor characterization

Catalytic combustion with both low and medium heating value coal gases obtained from an operating gasifier was demonstrated. A practical operating range for efficient operation was determined, and also to identify potential problem areas were identified for consideration during stationary gas turbine engine design. The test rig consists of fuel injectors, a fuel-air premixing section, a catalytic reactor with thermocouple instrumentation and a single point, water cooled sample probe. The test rig included inlet and outlet transition pieces and was designed for installation into an existing test loop.

Schwab, J. A.↗

Fuel property effects on USAF gas turbine engine combustors and afterburners

Since the early 1970s, the cost and availability of aircraft fuel have changed drastically. These problems prompted a program to evaluate the effects of broadened specification fuels on current and future aircraft engine combustors employed by the USAF. Phase 1 of this program was to test a set of fuels having a broad range of chemical and physical properties in a select group of gas turbine engine combustors currently in use by the USAF. The fuels ranged from JP4 to Diesel Fuel number two (DF2) with hydrogen content ranging from 14.5 percent down to 12 percent by weight, density ranging from 752 kg/sq m to 837 kg/sq m, and viscosity ranging from 0.830 sq mm/s to 3.245 sq mm/s. In addition, there was a broad range of aromatic content and physical properties attained by using Gulf Mineral Seal Oil, Xylene Bottoms, and 2040 Solvent as blending agents in JP4, JP5, JP8, and DF2. The objective of Phase 2 was to develop simple correlations and models of fuel effects on combustor performance and durability. The major variables of concern were fuel chemical and physical properties, combustor design factors, and combustor operating conditions.

Reeves, C. M.↗

Data Challenges in Multi-Sensor Data Science System for Monitoring a Solvent Extraction Process

Idaho National Laboratory (INL) is maintaining and gaining knowledge into the nuclear fuel cycle by building a test bed to allow researchers the opportunity to study nuclear fuel processing operations. This includes studying solvent extraction processes that use centrifugal contactors. As part of INL’s mission, the goal of this project is to develop a system that utilizes non-traditional measurement sources such as vibration, acoustics, current, light, flow, and temperature in conjunction with data-based, machine learning techniques that will allow for signal discovery. This multisensory data can support the development of safeguards by design, provide operator process awareness, and discover process anomalies. This poster will highlight some of the data collection and analytics challenges for the multi-sensor system as well as the mitigation strategies to build a robust system. Additionally, some preliminary data from the first testing campaign will be shown to help illustrate the data needs of the system.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Atomizing characteristics of swirl can combustor modules with swirl blast fuel injectors

Cold flow atomization tests of several different designs of swirl can combustor modules were conducted in a 7.6 cm diameter duct at airflow rates (per unit area) of 7.3 to 25.7 g/sq cm sec and water flow rates of 6.3 to 18.9 g/sec. The effect of air and water flow rates on the mean drop size of water sprays produced with the swirl blast fuel injectors were determined. Also, from these data it was possible to determine the effect of design modifications on the atomizing performance of various fuel injector and air swirler configurations. The trend in atomizing performance, as based on the mean drop size, was then compared with the trends in the production of nitrogen oxides obtained in combustion studies with the same swirl can combustors.

Ingebo, R. D.↗

Uranium nitride tristructural-isotropic fuel particle

A summary of activities around concept development, design, manufacturing, and early irradiation testing of a novel coated fuel particle, uranium nitride tristructural-isotropic fuel is provided. This fuel particle offers significantly higher uranium density over historic manifestations of coated fuel particles and may be more optimal for a range of advanced reactor applications. After reviewing the design process, steps involving production of this fuel form are discussed. Low burnup irradiation data on this fuel particle are now available, indicating that performance metrics have been met to date based on the original design expectations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Computational Analysis of Dynamic SPK(S8)-JP8 Fueled Combustor-Sector Performance

Civil and military flight tests using blends of synthetic and biomass fueling with jet fuel up to 50:50 are currently considered as "drop-in" fuels. They are fully compatible with aircraft performance, emissions and fueling systems, yet the design and operations of such fueling systems and combustors must be capable of running fuels from a range of feedstock sources. This paper provides Smart Combustor or Fuel Flexible Combustor designers with computational tools, preliminary performance, emissions and particulates combustor sector data. The baseline fuel is kerosene-JP-8+100 (military) or Jet A (civil). Results for synthetic paraffinic kerosene (SPK) fuel blends show little change with respect to baseline performance, yet do show lower emissions. The evolution of a validated combustor design procedure is fundamental to the development of dynamic fueling of combustor systems for gas turbine engines that comply with multiple feedstock sources satisfying both new and legacy systems.

Ryder, R.↗

Detailed measurements in the SSME high pressure fuel turbine with smooth rotor blades

Several tests of the Rocketdyne configuration of the Space Shuttle Main Engine (SSME) High Pressure Fuel Turbopump (HPFTP) Turbine have been completed in the Turbine Test Equipment (TTE) at Marshall Space Flight Center. The tests involved using scaled performance parameters and model measurements to predict the performance of the turbine. The overall performance has been the primary objective of the tests to date, but more detailed measurements are also of interest. During the most recent test of the Rocketdyne configuration of the HPFTP turbine with smooth rotor blades, several different measurement techniques were used to study the turbine inlet and exit velocity profiles, boundary layer thicknesses, turbulence intensities, etc. Data has been obtained using various hot film probes and three-hole cobra probes. Laser Velocimeter measurements were also made. The test plan and test data will be presented and discussed as well as lessons learned on how to obtain the various types of data.

Hudson, Susan T.↗

Fundamental phenomena on fuel decomposition and boundary-layer combustion processes with applications to hybrid rocket motors

The experimental study on the fundamental processes involved in fuel decomposition and boundary-layer combustion in hybrid rocket motors is continuously being conducted at the High Pressure Combustion Laboratory of The Pennsylvania State University. This research will provide a useful engineering technology base in the development of hybrid rocket motors as well as a fundamental understanding of the complex processes involved in hybrid propulsion. A high-pressure, 2-D slab motor has been designed, manufactured, and utilized for conducting seven test firings using HTPB fuel processed at PSU. A total of 20 fuel slabs have been received from the Mcdonnell Douglas Aerospace Corporation. Ten of these fuel slabs contain an array of fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. Diagnostic instrumentation used in the test include high-frequency pressure transducers for measuring static and dynamic motor pressures and fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. The ultrasonic pulse-echo technique as well as a real-time x-ray radiography system have been used to obtain independent measurements of instantaneous solid fuel regression rates.

Kuo, Kenneth K.↗

Biodiesel Ethers: Fatty Acid-Derived Alkyl Ether Fuels as Improved Bioblendstocks for Mixing-Controlled Compression Ignition Engines

In the last 20 years, biodiesel consumption in the United States has swiftly increased to ~2 billion gallons per year as a renewable supplement to fossil fuel. However, further expansion of biodiesel use is currently limited in part by poor cold weather performance, which prevents year-round blending and necessitates blend walls ≤5% v/v. In order to provide a diesel fuel blendstock with improved cold weather performance (cloud point, pour point, and cold filter plug point), while at the same time maintaining other required fuel performance specifications, several biodiesel redox analogues were synthesized and tested. The best performing candidate fuels from this class showed improvement in the derived cetane number (29.3% shorter ignition delay), lower heating value (+4.7 MJ/kg), relative sooting tendency (–7.4 YSI/MJ), and cloud point (15 °C lower) when compared to a B100 biodiesel composed of an identical fatty acid profile. It was observed as a general trend that the reduced form of biodiesel, fatty alkyl ethers (FAEs), shows performance improvements in all fuel property metrics. The suite of improved properties provided by FAEs gives biodiesel producers the opportunity to diversify their portfolio of products derived from lipid and alcohol feedstocks to include long-chain alkyl ethers, a biodiesel alternative with particular applicability for winter weather conditions across the US.

09 BIOMASS FUELS↗