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At least 1,135 records · Page 63

Optimal planning of the joint placement of photovoltaic panels and green roofs under climate change uncertainty

Photovoltaic (PV) panels directly convert sunlight into electricity; but, sunlight also heats the panels, negatively impacting their efficiency. Green roofs are vegetative layers grown on rooftops, mainly to provide added insulation on the roof to save energy. Green roofs also cool near-surface air temperature. Hence, the joint installation of PV panels and green roofs may potentially lead to higher efficiency of PV panels in certain climates. We develop a two-stage stochastic programming model to optimally place PV panels and green roofs under climate change uncertainty to maximize the overall profit from energy generated and saved. We calibrate the model using the literature, industry reports, and the data from different, at times conflicting, climate projections. We then conduct a case study for a mid-size city in the U.S., perform extensive sensitivity and robustness analyses and provide insights.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Local summer insolation and greenhouse gas forcing drove warming and glacier retreat in New Zealand during the Holocene

Geological climate archives from the Holocene Epoch provide baseline information concerning natural climate variability. Temperate mountain glacier extent is sensitive to summer air temperature, thus geological records of past glacier length changes are a useful proxy for this climatic variable. Here we present a new cosmogenic 10 Be chronology of glacier length changes at Dart Glacier in the Southern Alps, New Zealand. Prominent moraines deposited 321 ± 44 yr ago (n = 11) and 7.8 ± 0.3 ka (n = 5) show glaciers during the Little Ice Age were less extensive than during the early Holocene. This pattern of net Holocene glacier retreat is consistent with emerging data from other catchments in New Zealand and across the southern mid-latitudes. Using the physical framework of a transient global climate model simulation, we suggest that cool summers in the early Holocene were promoted by the local summer insolation minimum, together with low atmospheric greenhouse gas concentrations, causing an early Holocene austral glacial maximum. An insolation-driven reduction in seasonality at southern mid-latitudes may reconcile differences between early Holocene temperature reconstructions where climate proxies have different seasonal sensitivities. Furthermore, we suggest that rising greenhouse gas concentrations after 7 ka caused regional-scale glacier retreat and appear to be the dominant driver of multi-millennial summer temperature trends in the southern mid-latitudes during the present interglacial.

58 GEOSCIENCES↗

Comparing the cooling effectiveness of operationalisable urban surface combination scenarios for summer heat mitigation

Extreme summer heat in cities exacerbates the vulnerability of urban communities to heatwaves. Vegetative and reflective urban surfaces can help reduce urban heat. This study investigated the impacts of urban trees, green roofs and cool roofs on heat mitigation during average and extreme summer conditions in temperate oceanic Melbourne, Australia. We simulated the city climate using ‘The Air Pollution Model’ (TAPM) at a 1 km spatial resolution over 10 years, which according to our review of the literature, was the most prolonged period for simulation in Melbourne. During a widespread heatwave event, some of the tested scenarios with combined surface parameters could reduce the extreme values of the energy budget components- sensible heat, latent heat, and storage heat fluxes up to seasonal averages compared to the existing situation for Melbourne (control). The scenario with the highest (reasonable maximum) ground-level vegetation, green roofs, and cool roofs could reduce air temperatures up to 2.4 °C. The simulations suggest that a combined strategy with vegetative and high-albedo surfaces will deliver higher effectiveness with maximum cooling benefits and cost-effectiveness than individual strategies in cities. These results suggest the importance of collaborative strategic planning of urban surfaces to make cities healthier, sustainable, and liveable.

54 ENVIRONMENTAL SCIENCES↗

Effect of seasonal anoxia on geochemical cycling in a stratified pond: Comparison to cooler pond conditions 40 years ago

Seasonal stratification in temperate lakes deeper than a few meters creates favorable conditions for pronounced vertical redox zones, often resulting in anaerobic hypolimnions and significant geochemical changes. Here, this study examined thermocline formation and trace element behavior in a seasonally stratified pond amid rising air temperatures. Over two years, data were collected from Pond B at the US Department of Energy Savannah River Site in Aiken, South Carolina. Pond B, a man-made monomictic reservoir, received cooling water from a nuclear reactor from 1961 to 1964. Strong thermal stratification forms a distinct thermocline in May and progresses downward until November. Compared to the 1980s, this study shows a delayed onset and extended duration of stratification. The prolonged summer stratification reduces deep water oxygen replenishment, extending hypoxic conditions. Trace and major elements sampled in the water column revealed strong correlations between As, Fe, and Mn profiles, with concentrations increasing by 1–2 orders of magnitude in the anaerobic hypolimnion. This period captured the seasonal transition from winter mixing to summer stratification to fall overturn. Under anoxic conditions, Fe(III) reduces to Fe(II) in the sediment, releasing dissolved iron into the water column. The extended anoxic periods likely promoted arsenic release from sediments. Prolonged anoxia may enhance arsenic mobilization and solubility in the lake. This study illustrates how climate-induced changes in seasonal stratification of contaminated waters can convert contaminant sinks into sources, offering insights into the cycling of arsenic and other dissolved ions in stratified lakes and their implications for water quality management.

Anoxic conditions↗

Virtual storage capability of residential buildings for sustainable smart city via model-based predictive control

This paper evaluates the virtual storage capability of a residential air-conditioning (AC) system by utilizing the building mass as a thermal storage to enable sustainable cities through model-based predictive control (MPC). The control-oriented building model was developed with a grey-box model structure based on the experimental data to predict the indoor air temperature. Based on the model, the operation cost-saving potential of the MPC was investigated in a single house with different comfort levels, electricity prices, and prediction horizons. The cost-saving of the MPC was approximately 10.6 % compared to the conventional control. The MPC was expanded to a residential building cluster considering the peak demand charge. In an hourly shedding and load-up scenario, the performances of the MPC and the heuristic prior-based control (PBC) are promising. When shedding was enforced all day, the peak demand saving of the MPC was 36~38 %, whereas that of the PBC was 25.7 % compared to the baseline. In addition, the monthly electricity bill, including the operation and peak demand cost, was investigated with different demand charge rates and weather conditions. The total saving decreased with a low demand charge rate and hot conditions, and the operation cost saving was compromised with more aggressive demand shedding.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A flexible class of priors for orthonormal matrices with basis function-specific structure

Statistical modeling of high-dimensional matrix-valued data motivates the use of a low-rank representation that simultaneously summarizes key characteristics of the data and enables dimension reduction. Low-rank representations commonly factor the original data into the product of orthonormal basis functions and weights, where each basis function represents an independent feature of the data. However, the basis functions in these factorizations are typically computed using algorithmic methods that cannot quantify uncertainty or account for basis function correlation structure a priori. While there exist Bayesian methods that allow for a common correlation structure across basis functions, empirical examples motivate the need for basis function-specific dependence structure. We propose a prior distribution for orthonormal matrices that can explicitly model basis function-specific structure. The prior is used within a general probabilistic model for singular value decomposition to conduct posterior inference on the basis functions while accounting for measurement error and fixed effects. We discuss how the prior specification can be used for various scenarios and demonstrate favorable model properties through synthetic data examples. Finally, we apply our method to two-meter air temperature data from the Pacific Northwest, enhancing our understanding of the Earth system’s internal variability.

97 MATHEMATICS AND COMPUTING↗

The concentration of BTEX in selected urban areas of Malaysia during the COVID-19 pandemic lockdown

Volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene and xylene (BTEX) are air pollutants that harm human health. This study aims to identify BTEX concentrations before the lockdown known as the Movement Control Order was imposed (BMCO), during the implementation of the Movement Control Order (MCO), and then during the Conditional Movement Control Order (CMCO). These orders were introduced during the COVID-19 pandemic in Malaysia. The study utilised data measured by the continuous monitoring of BTEX using online gas chromatography instruments located at three urban area stations. Here, the results showed that the BTEX concentrations reduced by between –38% and –46% during the MCO compared to the BMCO period. The reduction of human mobility during the MCO and CMCO influenced the lower BTEX concentrations recorded at a station within the Kuala Lumpur area. The results of the BTEX diagnostic ratios and principal component analysis showed that the major source of BTEX, especially during the BMCO and CMCO periods, was motor vehicle emissions. Further investigation, using correlation analysis and polar plots, showed that the BTEX concentrations were also influenced by meteorological variables such as wind speed, air temperature and relative humidity.

54 ENVIRONMENTAL SCIENCES↗

Package Development for Reliability Testing of Perovskites

Metal halide perovskite solar cells have reached a critical point in their development. At a current certified record efficiency of 25.7% for a single-junction, research-scale cell, they now garner serious attention from the solar cell industry as a promising route to widespread, low-cost photovoltaics in single- or tandem-junction configurations. However, more work to demonstrate their durability under real-world outdoor test conditions is necessary to ensure the long-term success and deployment of the technology. Differences in chemistry, processes, and their combination result in unique performance limiters for both efficiency and stability. Further, as many active formulations and layer/cell stack combinations are sensitive to temperature, air, and moisture, it is important to separate intrinsic limitations to stability relative to these extrinsic sources. This presents a particular need for the development of an appropriate and reliable package for environmental (i.e., accelerated and outdoor) testing that will permit these different factors to be evaluated and understood.

14 SOLAR ENERGY↗

Drizzle, Turbulence, and Density Currents Below Post Cold Frontal Open Cellular Marine Stratocumulus Clouds

Nine cases of postcold frontal marine stratocumulus clouds exhibiting open cellular mesoscale organization are analyzed to characterize the drizzle, turbulence, and density currents below them. Data collected by the vertically pointing Doppler cloud radar and multiple lidars part of the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic (ENA) site are used in these analyses. A total of 251 drizzle shafts passed over the site with 76 shafts sampled for more than 15 min by the vertically pointing instruments. On average the drizzle shafts were ~18 km wide with below-cloud drizzle water path of ~40 g m −2 , cloud base rain rate of 7.78 mm day −1 , and cloud base drizzle modal diameter of 393 μm. The widths of the drizzle shafts did not exhibit any relationship with the cloud base rain rate, below-cloud drizzle water path, and the total water removed from the cloud. The downdrafts in the lowest 500 m within the drizzle cells strengthened with increasing cloud base rain rates, while the updrafts within drizzle cells did not exhibit this behavior. On average, the surface air density, pressure, water vapor mixing ratio, and wind speed along the background wind during the drizzle shaft were higher by 1.88 g m −3 , 8.60 Pa, 0.24 g kg −1 , and 1.22 m s −1 , respectively, from their background values. On the other hand, the surface air temperature was lower by 0.43 K during the drizzle shaft than its background value. The coincident measurements highlight the drizzle-turbulence-surface coupling in these cloud systems.

59 BASIC BIOLOGICAL SCIENCES↗

Seasonal Dependent Impact of Ice Cloud Longwave Scattering on the Polar Climate

Most climate models neglect cloud longwave (LW) scattering because scattering is considered negligible compared to strong LW absorption by clouds and greenhouse gases. While this rationale is valid for simulating extrapolar regions, it is questionable for the polar regions, where the atmosphere is dry and hence has weak absorption, and ice clouds that have strong scattering capability frequently occur. Using the slab-ocean Community Earth System Model, we show that ice cloud LW scattering can warm winter surface air temperature by 0.8–1.8 K in the Arctic and 1.3–1.9 K in the Antarctic, while this warming becomes much weaker in polar summer. Such scattering effect cannot be correctly assessed when sea surface temperature and sea ice are prescribed as this effect is manifested through a surface-atmosphere coupling. Furthermore, cloud LW scattering is a necessity for the correct simulation of polar climate and surface radiation budget, especially in the winter.

54 ENVIRONMENTAL SCIENCES↗

Quantifying the Occurrence of Record Hot Years Through Normalized Warming Trends

Surface air temperature trends and extreme events are of global concern and they are related. Here we show that the occurrence of record hot years over different latitudes from 1960-2019 are more strongly correlated with the observational annual mean temperature trends normalized by internal variability. Compared with the raw trends showing Arctic amplification, the normalized trends show a tropical amplification over land. Two hot spots with more frequent occurrence of record hot years are identified: northern hemisphere ocean (versus land) and southern hemisphere tropical land (versus mid- and high-latitude lands). Ensemble mean results from 32 Earth system models agree with observations better than individual models, but they do not reproduce observed large differences in correlations across latitudes between normalized trends and record-breaking events over land versus ocean. Furthermore, our results enable the quantification of record hot year occurrence through normalized warming trends and provide new metrics for model evaluation and improvement.

58 GEOSCIENCES↗

The Atlantic Jet Response to Stratospheric Events: A Regime Perspective

The tropospheric response to Sudden Stratospheric Warmings (SSWs) is associated with an equatorward shift in the midlatitude jet and associated storm tracks, while Strong Polar Vortex (SPV) events elicit a contrasting response. Recent analyses of the North Atlantic jet using probability density functions of a jet latitude index have identified three preferred jet latitudes, raising the question of whether the tropospheric response to SSWs and SPVs results from a change in relative frequencies of these preferred jet regimes rather than a systematic jet shift. We explore this question using atmospheric reanalysis data from 1979 to 2018 (26 SSWs and 33 SPVs), and a 202-years integration of the Whole Atmosphere Community Climate Model (92 SSWs and 68 SPVs). Following SSWs, the northern jet regime becomes less common and the central and southern regimes become more common. These changes occur almost immediately following “split” vortex events, but are more delayed following “displacement” events. In contrast, the northern regime becomes more frequent and the southern regime less frequent following SPV events. Following SSWs, composites of 500-hPa geopotential heights, surface air temperatures, and precipitation most closely resemble composites of the southern jet regime, and are generally opposite in sign to the composites of the northern jet regime. These comparisons are reversed following SPVs. Thus, one possible interpretation is that the two southernmost regimes appear to be favored following SSWs, while the southernmost regime becomes less common following SPVs.

54 ENVIRONMENTAL SCIENCES↗

Identifying Key Environmental Factors Explaining Temporal Patterns of DOC Export From Watersheds in the Conterminous United States

The export of dissolved organic carbon (DOC) from a watershed is a key component of the terrestrial biosphere carbon cycle. There is a need to improve our understanding of how and by how much various environmental factors are driving the temporal patterns of DOC export in order to accurately model and evaluate terrestrial carbon storage and fluxes. In this synthesis, we compiled observational data sets from 14 watersheds in the conterminous United States spanning the time period from 1981 to 2017. We used these data sets to examine the relative impacts of various climate, atmospheric deposition, and land cover factors on the temporal patterns of DOC export across watersheds of different sizes and landscape conditions, as well as the time-series autocorrelation of DOC export. Overall, our results suggest that the dominant factor on an annual scale was the amount of precipitation, which had a positive correlation with DOC export from a watershed. Overall increasing nitrogen deposition was coincident with increasing DOC export, and increasing sulfur deposition was coincident with declining DOC export. The seasonal pattern of DOC export was strongly regulated by air temperature, the long-term trend was negatively influenced by increasing sulfur deposition, and no obvious autocorrelation was detected in DOC export. In addition, higher rates of DOC export were positively correlated with greater area of wetlands within a watershed, but was not found to be strongly related to any of the other land cover types.

54 ENVIRONMENTAL SCIENCES↗

Slope-Aspect Induced Climate Differences Influence How Water Is Exchanged Between the Land and Atmosphere

Cross-slope climate differences in the midlatitudes are ecologically important, and impact vegetation-mediated water balance between the earth surface and the atmosphere. We made high-resolution in situ observations of air temperature, relative humidity, soil moisture, insolation, and sap velocity observations on 14 Pacific madrone trees (Arbutus menziesii) spanning adjacent north and south slopes at the University of California's Angelo Coast Range Reserve. To understand the cross-slope response of sap velocity, a proxy for transpiration, to microclimate, we modeled the sap velocity on each slope using a transpiration model driven by ambient environment and parameterized with a Markov Chain Monte Carlo parameter estimation process. The results show that trees on opposing slopes do not follow a shared pattern of physiological response to transpiration drivers. This means that the observed sap velocity differences are not due entirely to observed microclimate differences, but also due to population-level physiological differences, which indicates acclimation to inhabited microclimate. While our present data set and analytical tools do not identify mechanisms of acclimation, we speculate that differing proportions of sun-adapted and shade-adapted leaves, differences in stomatal regulation, and cross-slope root zone moisture differences could explain some of the observed and modeled differences.

54 ENVIRONMENTAL SCIENCES↗

Tower-Based Remote Sensing Reveals Mechanisms Behind a Two-phased Spring Transition in a Mixed-Species Boreal Forest

The boreal forest is a major contributor to the global climate system, therefore, reducing uncertainties in how the forest will respond to a changing climate is critical. One source of uncertainty is the timing and drivers of the spring transition. Remote sensing can provide important information on this transition, but persistent foliage greenness, seasonal snow cover, and a high prevalence of mixed forest stands (both deciduous and evergreen species) complicate interpretation of these signals. We collected tower-based remotely sensed data (reflectance-based vegetation indices and Solar-Induced Chlorophyll Fluorescence [SIF]), stem radius measurements, gross primary productivity, and environmental conditions in a boreal mixed forest stand. Evaluation of this data set shows a two-phased spring transition. The first phase is the reactivation of photosynthesis and transpiration in evergreens, marked by an increase in relative SIF, and is triggered by thawed stems, warm air temperatures, and increased available soil moisture. The second phase is a reduction in bulk photoprotective pigments in evergreens, marked by an increase in the Chlorophyll-Carotenoid Index. Deciduous leaf-out occurs during this phase, marked by an increase in all remotely sensed metrics. The second phase is controlled by soil thaw. Our results demonstrate that remote sensing metrics can be used to detect specific physiological changes in boreal tree species during the spring transition. The two-phased transition explains inconsistencies in remote sensing estimates of the timing and drivers of spring recovery. Our results imply that satellite-based observations will improve by using a combination of vegetation indices and SIF, along with species distribution information.

54 ENVIRONMENTAL SCIENCES↗

Trends in Downwelling Longwave Radiance Over the Southern Great Plains

Downwelling longwave radiation is an important part of the surface energy budget. Spectral trends in the downwelling longwave radiance (DLR) provide insight into the radiative drivers of climate change. In this research, we process and analyze a 23-year DLR record measured by the Atmospheric Emitted Radiance Interferometer (AERI) at the U.S. Department of Energy Atmospheric Radiation Program Southern Great Plains (SGP) site. Two AERIs were deployed at SGP with an overlapping observation period of about 10 years, which allows us to examine the consistency and accuracy of the measurements and to account for discrepancies between them due to errors associated with the instruments themselves. We then analyzed the all-sky radiance trends in DLR, which are associated with the surface warming trend at SGP during this same period and also the complex changes in meteorological conditions. For instance, the observed radiance in the CO2 absorption band follows closely the near-surface air temperature variations. The significant positive radiance trends in weak absorption channels, such as in the wings of the CO 2 band and in the weak absorption channels in the H 2 O vibration-rotational band, show earlier detectability of climate change. The magnitude of the radiance trend uncertainty in the DLR record mainly results from internal climate variability rather than from measurement error, which highlights the importance of continuing the DLR spectral measurements to unambiguously detect and attribute climate change.

54 ENVIRONMENTAL SCIENCES↗

Wintertime Brine Discharge at the Surface of a Cold Polar Glacier and the Unexpected Absence of Associated Seismicity

A subglacial groundwater system beneath Taylor Glacier, Antarctica, discharges hypersaline, iron-rich brine episodically at the glacier surface to create Blood Falls. However, the triggering mechanism for these brine release events is not yet understood. Identifying which fracture processes are observed seismically can help us better characterize the hydrological system at Taylor Glacier, and more generally, provide us with a broader understanding of englacial hydrologic activity in cold glaciers. We document wintertime brine discharge using time-lapse photography. Subfreezing air temperatures during the brine discharge indicate that surface melt-induced hydrofracture is an unlikely trigger for brine release. Further, we analyze local seismic data to test a hypothesis that fracturing generates elevated surface wave energy preceding and/or coinciding with brine release events. Our results show no discernible elevated Rayleigh wave activity prior to or during Blood Falls brine release. Instead, we find a pattern of seismic events dominated by a seasonal signal, with more Rayleigh events occurring in the summer than the winter from the Blood Falls source area. We calculate that the volumetric opening of cracks that would generate Rayleigh waves at our detection limits are of similar size to myriad cracks in glacier ice, lake ice, and frozen sediment in the terminus area. We therefore propose that any fracturing coincident with brine release activity likely consists of a series of smaller opening events that are masked by other seismicity in the local environment.

58 GEOSCIENCES↗

Improving Seasonal Forecast Using Probabilistic Deep Learning

The path toward realizing the potential of seasonal forecasting and its socioeconomic benefits relies on improving general circulation model (GCM) based dynamical forecast systems. To improve dynamical seasonal forecasts, it is crucial to set up forecast benchmarks, and clarify forecast limitations posed by model initialization errors, formulation deficiencies, and internal climate variability. With huge costs in generating large forecast ensembles, and limited observations for forecast verification, the seasonal forecast benchmarking and diagnosing task proves challenging. Here, we develop a probabilistic deep learning-based statistical forecast methodology, drawing on a wealth of climate simulations to enhance seasonal forecast capability and forecast diagnosis. By explicitly modeling the internal climate variability and GCM formulation differences, the proposed Conditional Generative Forecasting (CGF) methodology enables bypassing crucial barriers in dynamical forecast, and offers a top-down viewpoint to examine how complicated GCMs encode the seasonal predictability information. We apply the CGF methodology for global seasonal forecast of precipitation and 2 m air temperature, based on a unique data set consisting 52,201 years of climate simulation. Results show that the CGF methodology can faithfully represent the seasonal predictability information encoded in GCMs. We successfully apply this learned relationship in real-world seasonal forecast, achieving competitive performance compared to dynamical forecasts. Using this CGF as benchmark, we reveal the impact of insufficient forecast spread sampling that limits the skill of the considered dynamical forecast system. Finally, we introduce different strategies for composing ensembles using the CGF methodology, highlighting the potential for leveraging the strengths of multiple GCMs to achieve advantgeous seasonal forecast.

54 ENVIRONMENTAL SCIENCES↗