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At least 1,117 records · Page 62
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NASA NTRS2003

Interplay Between Thin Film Ferroelectric Composition, Microstructure and Microwave Phase Shifter Performance

One of the keys to successfully incorporating ferroelectric films into Ku-band (12 to 18 GHz) phase shifters is to establish the composition, microstructure, and thickness required to meet the tuning needs, and tailor the film properties to meet these needs. Optimal performance is obtained when the film composition and device design are such that the device performance is limited by odd mode dielectric losses, and these losses are minimized as much as possible while still maintaining adequate tunability. The parameters required to maintain device performance will vary slightly depending on composition, but we can conclude that the best tuning-to-loss figures of merit (K-factor) are obtained when there is minimal variation between the in-plane and out-of-plane lattice parameters, and the full-width half maximum values of the BSTO (002) peaks are less than approximately 0.04 deg. We have observed that for phase shifters in which the ferroelectric crystalline quality and thickness are almost identical, higher losses are observed in films with higher BaISr ratios. The best performance was observed in phase shifters with Ba:Sr = 30:70. The superiority of this composition was attributed to several interacting factors: the B a: Sr ratio was such that the Curie temperature (180 K) was far removed from room temperature, the crystalline quality of the film was excellent, and there was virtually no difference between the inplane and out-of-plane lattice parameters of the film.

Mueller, Carl H.↗
NASA NTRS2003

Micro-optical Distributed Sensors for Aero Propulsion Applications

The objective of this research is to develop micro-opto-mechanical system (MOMS)-based sensors for time- and space-resolved measurements of flow properties in aerodynamics applications. The measurement technique we propose uses optical resonances in dielectric micro-spheres that can be excited by radiation tunneling from optical fibers. It exploits the tunneling-induced and morphology-dependent shifts in the resonant frequencies. The shift in the resonant frequency is dependent on the size, shape, and index of refraction of the micro-sphere. A physical change in the environment surrounding a micro-bead can change one or more of these properties of the sphere thereby causing a shift in frequency of resonance. The change of the resonance frequency can be detected with high resolution by scanning a frequency-tunable laser that is coupled into the fiber and observing the transmission spectrum at the output of the fiber. It is expected that, in the future, the measurement concept will lead to a system of distributed micro-sensors providing spatial data resolved in time and space. The present project focuses on the development and demonstration of temperature sensors using the morphology-dependent optical resonances although in the latter part of the work, we will also develop a pressure sensor. During the period covered in this report, the optical and electronic equipment necessary for the experimental work was assembled and the experimental setup was designed for the single sensor temperature measurements. Software was developed for real-time tracking of the optical resonance shifts. Some preliminary experiments were also carried out to detect temperature using a single bead in a water bath.

Arnold, S.↗
NASA NTRS2003

High Resolution Spectroscopy to Support Atmospheric Measurements

Spectroscopic parameters (such as line position, intensity, broadening and shifting coefficients and their temperature dependences, line mixing coefficients etc.) for various molecular species of atmospheric interest are determined. In order to achieve these results, infrared spectra of several molecular bands are obtained using high-resolution recording instruments such as tunable diode laser spectrometer and Fourier transform spectrometers. Using sophisticated analysis routines (Multispectrum nonlinear least squares technique) these high-resolution infrared spectra are processed to determine the various spectral line parameters that are cited above. Spectra were taken using the McMath-Pierce Fourier transform spectrometer (FTS) at the National Solar Observatory on Kitt Peak, Arizona as well as the Bruker FTS at the Pacific Northwest National Laboratory (PNNL) at Richland, Washington. Most of the spectra are acquired not only at room temperature, but also at several different cold temperatures. This procedure is necessary to study the variation of the spectral line parameters as a function of temperature in order to simulate the Earth's and other planetary atmospheric environments. Depending upon the strength or weakness of the various bands recorded and analyzed, the length(s) of the absorption cells in which the gas samples under study are kept varied from a few centimeters up to several meters and the sample temperatures varied from approximately +30 C to -63 C. Research on several infrared bands of various molecular species and their isotopomers are undertaken. Those studies are briefly described.

Venkataraman, Malathy Devi↗
NASA NTRS2003

Novel High Efficient Organic Photovoltaic Materials

Solar energy is a renewable, nonpolluting, and most abundant energy source for human exploration of a remote site or outer space. In order to generate appreciable electrical power in space or on the earth, it is necessary to collect sunlight from large areas and with high efficiency due to the low density of sunlight. Future organic or polymer (plastic) solar cells appear very attractive due to their unique features such as light weight, flexible shape, tunability of energy band-gaps via versatile molecular or supramolecular design, synthesis, processing and device fabrication schemes, and much lower cost on large scale industrial production. It has been predicted that supramolecular and nano-phase separated block copolymer systems containing electron rich donor blocks and electron deficient acceptor blocks may facilitate the charge carrier separation and migration due to improved electronic ultrastructure and morphology in comparison to polymer composite system. This presentation will describe our recent progress in the design, synthesis and characterization of a novel block copolymer system containing donor and acceptor blocks covalently attached. Specifically, the donor block contains an electron donating alkyloxy derivatized polyphenylenevinylene (RO-PPV), the acceptor block contains an electron withdrawing alkyl-sulfone derivatized polyphenylenevinylene (SF-PPV). The key synthetic strategy includes the synthesis of each individual block first, then couple the blocks together. While the donor block has a strong PL emission at around 560 nm, and acceptor block has a strong PL emission at around 520 nm, the PL emissions of final block copolymers are severely quenched. This verifies the expected electron transfer and charge separation due to interfaces of donor and acceptor nano phase separated blocks. The system therefore has potential for variety light harvesting applications, including high efficient photovoltaic applications.

Sun, Sam↗
NASA NTRS2003

Laser Velocimeter for Studies of Microgravity Combustion Flowfields

A velocimeter was developed based on modulated filtered Rayleigh scattering (MFRS). The MFRS velocimeter was successfully demonstrated by making one-component velocity measurements in a supersonic expansion using molecular Rayleigh scattering in a jet of N2. These measurements were made in a sweep mode where the Rayleigh scattered profile is cross-correlated with absorption in a static cell to determine velocity. To improve temporal resolution the frequency-locked mode of operation was developed, with an in-situ referencing scheme to compensate for signal fluctuations arising from density variations in the probe volume. Spectroscopic grade (i.e. continuously tunable, single-mode) laser sources with high power (greater than 100 mW) are not commercially available at the wavelength of interest (780 nm). We developed an all-solid-state system with a low power (approximately 10 mW) spectroscopic grade laser source in a Littrow cavity is amplified by a broad-area diode laser. We have demonstrated that the slaved output tracks the injected input but have not yet demonstrated power gain by the end of the grant period.

Varghese, Philip L.↗
NASA NTRS2003

"DUST BUSTER" - A Single Photon Ionization TOF MS for Cometary Dusts

It is hard to predict the properties and composition of dust that will be returned by STARDUST from WED- 2. The most interesting but challenging case would be grains, pg to fg in weight, each carrying its own isotopic signature characteristic of its source zones in a variety of stars. How do we extract the maximum amount of science from such grains? Clearly, the best that can be accomplished is to measure every atom in each grain.Academia Sinica and Argonne National Laboratory (ANL) have entered into a collaboration to develop a SPI TOF MS instrument for analysis of stardust grains. A new instrument will be built at Academia Sinica based on the new TOF mass spectrometer design developed, built and operating at ANL. The instrument is intended for SPI TOF MS analysis of elements from Ca to Cu plus Li after first using SIMS to measure H, C, N, 0, Si, and S. There are still technical challenges facing the technique. We will need to improve submicrometer sample handling, avoid the effects of space charge, and increase the Mamie range of the detector. The most difficult obstacle to overcome may be the fact that the flux density of present high repetition rate, WV lasers is below the level needed to ensure full ionization (saturation) in the source region, which must be several mm in size to achieve the high useful yield needed for analysis of small stardust grains. A potential breakthrough effort is to exploit the novel free electron laser being pioneered at ANL. In principle, this FEL can reach ionization saturation and is tunable up to photon energies of 25 eV, which is higher than the ionization potential of any element.

Chen, C.-Y.↗
NASA NTRS2003

Detecting Protostellar Jets with the Goddard Fabry-Perot Coronagraph, and Modification for Adaptive Optics

The Goddard Fabry-Perot has been used at the Apache Point Observatory 3.5-m telescope to diagnose jets from young Herbig Ae (HD163296) and T Tauri stars (DL Tau and CW Tau), detected by the Space Telescope Imaging Spectrograph coronagraph on the Hubble Space Telescope. The additional spectral discrimination of the Fabry-Perot allows these faint jets to be detected from the ground, to obtain velocities and densities, and to find further extensions. In order to plan what measurements require space coronagraphs, we need to explore the extent to which coronagraphic detections can be made from the ground, including using adaptive optics. Modifications to the Fabry-Perot tunable narrow band coronagraph for possible use with the AEOS 3.65-m telescope will be described.

Woodgate, Bruce E.↗
NASA NTRS2003

Comparison of Synchrotron MicroXANES Determination of Fe(3+)/Sigma Fe with Moessbauer Values for Clean Mineral Separates of Pyroxene from Martian Meteorites

The oxidation state of Fe in Martian meteorites is a parameter of great interest and the ability to determine this value in micrometer scale samples is important. Intense, tunable x-ray sources at large synchrotron storage rings are being exploited to examine the Fe K-absorption edge with energy resolution of approx. 1-1.5eV in spots of 10x15 microns on thin sections of a wide variety of materials including several Martian meteorites. Synchrotron microXANES (SmX) spectroscopy is the technique that provides the most flexible capability for investigating Fe(3+)/Sigma Fe. Variation of Fe(3+)/Sigma Fe is manifested as a function of the energy of the pre-edge to the Fe absorption edge produced by the sample. SmX is at present the only technique that can be used with conventional polished thin sections. Data for a broad spectrum of minerals have been produced and indicate that SmX can be used with a large variety of samples types.

Delaney, J. S.↗
NASA NTRS2003

The James Webb Telescope Instrument Suite Layout: Optical System Engineering Considerations for a Large, Deployable Space Telescope

The James Webb Space Telescope (JWST) is a space-based, infrared observatory designed to study the early stages of galaxy formation in the Universe. The telescope will be launched into an elliptical orbit about the second Lagrange point and passively cooled to 30-50 K to enable astronomical observations from 0.6 to 28 microns. A group from the NASA Goddard Space Flight Center and the Northrop Grumman Space Technology prime contractor team has developed an optical and mechanical layout for the science instruments within the JWST field of view that satisfies the telescope s high-level performance requirements. Four instruments required accommodation within the telescope's field of view: a Near-Infrared Camera (NIRCam) provided by the University of Arizona; a Near-Mared Spectrometer (NIRSpec) provided by the European Space Agency; a Mid-Infrared Instrument (MIRI) provided by the Jet Propulsion Laboratory and a European consortium; and a Fine Guidance Sensor (FGS) with a tunable filter module provided by the Canadian Space Agency. The size and position of each instrument's field of view allocation were developed through an iterative, concurrent engineering process involving the key observatory stakeholders. While some of the system design considerations were those typically encountered during the development of an infrared observatory, others were unique to the deployable and controllable nature of JWST. This paper describes the optical and mechanical issues considered during the field of view layout development, as well as the supporting modeling and analysis activities.

Bos, Brent↗
NASA NTRS2003

Detecting protostellar jets with the Goddard Fabry-Perot coronagraph, and modification for adaptive optics

The Goddard Fabry-Perot has been used at the Apache Point Observatory 3.5-m telescope to diagnose jets from young Herbig Ae (HD163296) and T Tauri stars (DL Tau and CW Tau), detected by the Space Telescope Imaging Spectrograph coronagraph on the Hubble Space Telescope. The additional spectral discrimination of the Fabry-Perot allows these faint jets to be detected from the ground, to obtain velocities and densities, and to find further extensions. In order to plan what measurements require space coronagraphs, we need to explore the extent to which coronagraphic detections can be made from the ground, including using adaptive optics. Modifications to the Fabry-Perot tunable narrow band coronagraph for possible use with the AEOS 3.65-m telescope will be described.

Woodgate, Bruce E.↗
NASA NTRS2003

Technology Development of Miniaturized Far-Infrared Sources for Biomolecular Spectroscopy

The objective of this project was to develop a purely solid-state based, thus miniaturized, far-infrared (FIR) (also known as terahertz (THz)) wave source using III-V semiconductor nanostructures for biomolecular detection and sensing. Many biomolecules, such as DNA and proteins, have distinct spectroscopic features in the FIR wavelength range as a result of vibration-rotation-tunneling motions and various inter- and intra-molecule collective motions. Spectroscopic characterization of such molecules requires narrow linewidth, sufficiently high power, tunable (in wavelength), and coherent FIR sources. Unfortunately, the FIR frequency is one of the least technologically developed ranges in the electromagnetic spectrum. Currently available FIR sources based on non-solid state technology are bulky, inefficient, and very often incoherent. In this project we investigated antimonide based compound semiconductor (ABCS) nanostructures as the active medium to generate FIR radiation. The final goal of this project was to demonstrate a semiconductor THz source integrated with a pumping diode laser module to achieve a compact system for biomolecular applications.

Kono, Junichiro↗
NASA NTRS2003

[Measurements of "Total Water" and Carbon Dioxide from the NASA WB-57 During Crystal-Face]

An existing closed-path tunable diode laser hygrometer (CLH) was employed for the measurements of total water made during CRYSTAL-FACE. This instrument had flown previously on the NASA DC-8 during the SAGE III Ozone Loss and Validation Experiment (SOLVE) and also on the NCAR C-130 during some local flights designed to test the extent of water vapor interference in carbon dioxide measurements. The instrument was largely unchanged from previous studies, but a new inlet appropriate to the WB-57F wingpod was constructed. In order to minimize the impact on the over-subscribed right wingpod and to achieve good thermal control of the inlet temperature, the CLH inlet was made of carbon-fiber/epoxy composite. Considerable effort was spent to design and build the lightest possible mounting hardware and design relatively low-power inlet heaters. As a result, the instrument and mounting hardware came in below the NASA/JSC-imposed weight cap of 35 lbs. Data were obtained on all test flights during May 2002 and during all but one mission flight in July 2002 (the one lost flight was due to an unplugged instrument power cable). Instrument performance during the test flights was good, but the data are not science- quality, as a variety of tests were performed to optimize the inlet configuration and heating. Data on all mission flights is of high quality, despite some difficulties caused by flying through wet low-altitude air masses and dense anvils, which saturated the instrument response.

Avallone, Linnea M.↗
NASA NTRS2003

Fan Beam Emission Tomography for Laminar Fires

Obtaining information on the instantaneous structure of turbulent and transient flames is important in a wide variety of applications such as fire safety, pollution reduction, flame spread studies, and model validation. Durao et al. has reviewed the different methods of obtaining structure information in reacting flows. These include Tunable Laser Absorption Spectroscopy, Fourier Transform Infrared Spectroscopy, and Emission Spectroscopy to mention a few. Most flames emit significant radiation signatures that are used in various applications such as fire detection, light-off detection, flame diagnostics, etc. Radiation signatures can be utilized to maximum advantage for determining structural information in turbulent flows. Emission spectroscopy is most advantageous in the infrared regions of the spectra, principally because these emission lines arise from transitions in the fundamental bands of stable species such as CO2 and H2O. Based on the above, the objective of this work was to develop a fan beam emission tomography system to obtain the local scalar properties such as temperature and mole fractions of major gas species from path integrated multi-wavelength infrared radiation measurements.

Sivathanu, Yudaya↗
NASA NTRS2004

Imaging Spectrophotometry of the Jet/ISM Interaction in IC5063

IC5063 is a somewhat dusty z=0.0110 S0 galaxy with a Seyfert 2 nucleus. It has a triple radio source that spans 3 arcsec, mostly blueshifted H I absorption that spans 700 km/s, and ionization cones that extend for more than 2 arcmins. We obtained fully sampled [O III]\lambda5007 grids at 0."9 and 70 km/s FWHM resolution using the Rutgers Fabry-Perot system on the Blanco 4m telescope. Complementary long-slit spectra using the RC spectrograph on the Blanco, and Taurus Tunable Filter spectral images in H\alpha and [N II]\lambda6583, were also obtained to assess gaseous ionization conditions. We present the results of our analysis, and correlate spectral structures to those visible in archival WFPC2 images. We find that, in the region near the radio triple, gaseous ionization and line velocity width is tightly correlated, in excellent quantitative agreement with the high-velocity shock regime in the diagnostic emission-line ratio diagrams of Dopita & Sutherland. We separate kinematically gas in normal disk rotation that is illuminated by the AGN in the ionization cones from that agitated mechanically by the jet, and assess the energy input from both processes.

Cecil, G.↗
NASA NTRS2004

Tropospheric Methane Over the Pacific Basin During TRACE-P

We received funding for the acquisition, statistical analysis, interpretation, and publication of atmospheric methane data collected during the Transport and Chemical Evolution over the Pacific (TRACE-P) mission, flown February through April of 2001. These high precision measurements were made aboard the NASA DC-8 and P-3B aircraft using a fast response, tunable diode laser system, the DACOM instrument. Our analysis focused on the vertical and geographical distribution of this key trace gas, particularly in the context of other data available from the region such as those from the Pacific NOAA CMDL surface sites, and earlier NASA aircraft missions (such as PEM-West A and B). The paper reporting these results, "Large-Scale Distribution of CH4 in the Western Pacific: Sources and Transport from the Asian Continent" by authors K.B. Bartlett, G.W. Sachse, T. Slate, C. Harward, and D.R. Blake, is attached. The dataset of roughly 13,800 CH4 measurements ranged between 1602 ppb in stratospherically impacted air and 2149 ppb in highly polluted air. Overall, we found that CH4 concentrations were highly correlated with trace gases characteristic of a mix of anthropogenic industrial and combustion sources. They were strikingly correlated with ethane (C2H6) in particular, whose major sources are natural gas leakage and biomass burning. Correlation between the two hydrocarbons indicated that these sources may dominate for CH4 as well at this time.

Bartlett, Karen B.↗
NASA NTRS2003

Large-scale Distribution of CH4 in the Western North Pacific: Sources and Transport from the Asian Continent

Methane (CH4) mixing ratios in the northern Pacific Basin were sampled from two aircraft during the TRACE-P mission (Transport and Chemical Evolution over the Pacific) from late February through early April 2001 using a tunable diode laser system. Described in more detail by Jacob et al., the mission was designed to characterize Asian outflow to the Pacific, determine its chemical evolution, and assess changes to the atmosphere resulting from the rapid industrialization and increased energy usage on the Asian continent. The high-resolution, high-precision data set of roughly 13,800 CH4 measurements ranged between 1602 ppbv in stratospherically influenced air and 2149 ppbv in highly polluted air. Overall, CH4 mixing ratios were highly correlated with a variety of other trace gases characteristic of a mix of anthropogenic industrial and combustion sources and were strikingly correlated with ethane (C2H6) in particular. Averages with latitude in the near-surface (0-2 km) show that CH4 was elevated well above background levels north of 15 deg N close to the Asian continent. In the central and eastern Pacific, levels of CH4 were lower as continental inputs were mixed horizontally and vertically during transport. Overall, the correlation between CH4 and other hydrocarbons such as ethane (C2H6), ethyne (C2H2), and propane (C3H8) as well as the urban/industrial tracer perchloroethene (C2Cl4), suggests that for CH4 colocated sources such as landfills, wastewater treatment, and fossil fuel use associated with urban areas dominate regional inputs at this time. Comparisons between measurements made during TRACE-P and those of PEM-West B, flown during roughly the same time of year and under a similar meteorological setting 7 years earlier, suggest that although the TRACE-P CH4 observations are higher, the changes are not significantly greater than the increases seen in background air over this time interval.

Bartlett, Karen B.↗
NASA NTRS2003

Deposition of Nanostructured Thin Film from Size-Classified Nanoparticles

Materials comprising nanometer-sized grains (approximately 1_50 nm) exhibit properties dramatically different from those of their homogeneous and uniform counterparts. These properties vary with size, shape, and composition of nanoscale grains. Thus, nanoparticles may be used as building blocks to engineer tailor-made artificial materials with desired properties, such as non-linear optical absorption, tunable light emission, charge-storage behavior, selective catalytic activity, and countless other characteristics. This bottom-up engineering approach requires exquisite control over nanoparticle size, shape, and composition. We describe the design and characterization of an aerosol system conceived for the deposition of size classified nanoparticles whose performance is consistent with these strict demands. A nanoparticle aerosol is generated by laser ablation and sorted according to size using a differential mobility analyzer. Nanoparticles within a chosen window of sizes (e.g., (8.0 plus or minus 0.6) nm) are deposited electrostatically on a surface forming a film of the desired material. The system allows the assembly and engineering of thin films using size-classified nanoparticles as building blocks.

Camata, Renato P.↗
NASA NTRS2004

Slit Function Measurement of An Imaging Spectrograph Using Fourier Transform Techniques

Knowledge of a spectrograph slit function is necessary to interpret the unresolved lines in an observed spectrum. A theoretical slit function can be calculated from the sizes of the entrance slit, the detector aperture when it functions as an exit slit, the dispersion characteristic of the disperser, and the point spread function of the spectrograph. A measured slit function is preferred to the theoretical one for the correct interpretation of the spectral data. In a scanning spectrometer with a single exit slit, the slit function is easily measured. In a fixed grating/or disperser spectrograph, illuminating the entrance slit with a near monochromatic light from a pre-monochrmator or a tunable laser and varying the wavelength of the incident light can measure the slit function. Even though the latter technique had been used successfully for the slit function measurements, it had been very laborious and it would be prohibitive to an imaging spectrograph or a multi-object spectrograph that has a large field of view. We explore an alternative technique that is manageable for the measurements. In the proposed technique, the imaging spectrograph is used as a detector of a Fourier transform spectrometer. This method can be applied not only to an IR spectrograph but also has a potential to a visible/UV spectrograph including a wedge filter spectrograph. This technique will require a blackbody source of known temperature and a bolometer to characterize the interferometer part of the Fourier Transform spectrometer. This pa?er will describe the alternative slit function measurement technique using a Fourier transform spectrometer.

Park, Hongwoo↗