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At least 1,117 records · Page 62

Three-dimensional modelling of trace species in the Arctic lower stratosphere

A three-dimensional radiative-dynamical-chemical model has been developed and used to study some aspects of modeling the polar lower stratosphere. The model includes a comprehensive gas-phase chemistry scheme as well as a treatment of heterogeneous reactions occurring on the surface of polar stratospheric clouds. Tracer transport is treated by an accurate, nondispersive scheme with little diffusion suited to the representation of strong gradients. Results from a model simulation of early February 1990 are presented and used to illustrate the importance of the model transport scheme. The model simulation is also used to examine the potential for Arctic ozone destruction and the relative contributions of the chemical cycles responsible.

Chipperfield, Martyn↗

Trace gas emissions to the atmosphere by biomass burning in the west African savannas

Savanna fires and atmospheric carbon dioxide (CO2) detection and estimating burned area using Advanced Very High Resolution Radiometer_(AVHRR) reflectance data are investigated in this two part research project. The first part involves carbon dioxide flux estimates and a three-dimensional transport model to quantify the effect of north African savanna fires on atmospheric CO2 concentration, including CO2 spatial and temporal variability patterns and their significance to global emissions. The second article describes two methods used to determine burned area from AVHRR data. The article discusses the relationship between the percentage of burned area and AVHRR channel 2 reflectance (the linear method) and Normalized Difference Vegetation Index (NDVI) (the nonlinear method). A comparative performance analysis of each method is described.

Frouin, Robert J.↗

Electron reversal ionizer for detection of trace species using a spherical cathode

A reversal electron, high-current ionizer capable of focusing a beam of electrons to a reversal region employs an indirectly heated cathode having a concave emitting surface of width of W less than 2r, where r is the radius of curvature and preferably a ratio of width to radius approximately equal to one for optimum high current for a given cathode width.

Boumsellek, Said↗

Measurement of HO2 and other trace gases in the stratosphere using a high resolution far-infrared spectrometer

This report covers the time period 1 January 1994 to 31 December 1994. During this reporting period we had our fourth Upper Atmosphere Research Satellite (UARS) correlative balloon flight; the data from this flight have been reduced and submitted to the UARS CDHF. We have spent most of the past year analyzing data from this and past flights. For example, using data from our September 1989 balloon flight we have demonstrated for the first time ever that the rates of production and loss of ozone are in balance in the upper stratosphere. As part of this analysis, we have completed the most detailed study to date of radical partitioning throughout the stratosphere. We have also produced the first measurement of HBr and HOBr mixing ratio profiles over a full diurnal cycle.

Traub, Wesley A.↗

Airborne boundary layer flux measurements of trace species over Canadian boreal forest and northern wetland regions

Airborne heat, moisture, O3, CO, and CH4 flux measurements were obtained over the Hudson Bay lowlands (HBL) and northern boreal forest regions of Canada during July - August 1990. The airborne flux measurements were an integral part of the NASA/Arctic Boundary Layer Expedition (ABLE) 3B field experiment executed in collaboration with the Canadian Northern Wetlands Study (NOWES). Airborne CH4 flux measurements were taken over a large portion of the HBL. The surface level flux of CH4 was obtained from downward extrapolations of multiple-level CH4 flux measurements. Methane source strengths ranged from -1 to 31 mg m(exp -2)/d, with the higher values occurring in relatively small, isolated areas. Similar measurements of the CH4 source strength in the boreal forest region of Schefferville, Quebec, ranged from 6 to 27 mg m(exp -2)/d and exhibited a diurnal dependence. The CH4 source strengths found during the ABLE 3B expedition were much lower than the seasonally averaged source strength of 51 mg m(exp -2)/d found for the Yukon-Kuskokwim delta region of Alaska during the previous ABLE 3A study. Large positive CO fluxes (0.31 to 0.53 parts per billion by volume (ppbv) m/s) were observed over the inland, forested regions of the HBL study area, although the mechanism for the generation of these fluxes was not identified. Repetitive measurements along the same ground track at various times of day near the Schefferville site also suggested a diurnal dependence for CO emissions. Measurements of surface resistance to the uptake of O3 (1.91 to 0.80 s/cm) for the HBL areas investigated were comparable to those observed near the Schefferville site (3.40 to 1.10 s/cm). Surface resistance values for the ABLE 3B study area were somewhat less than those observed over the Yukon-Kuskokwim delta during the previous ABLE 3A study. The budgets for heat, moisture, O3, CO, and CH4 were evaluated. The residuals from these budget studies indicated, for the cases selected, a moderate net photochemical production of O3 present in the boundary layer over the HBL that coincided with an in situ destruction of CO, although the mechanism responsible for the destruction of CO was not identified. Results from the O3 budget analysis indicate the importance of in situ photochemical production and its possible dominance over surface deposition to the local O3 budget at the Schefferville site. Measurements of the in situ production of O3 indicated a direct relationship between the presence of biomass burning or large-scale pollution effects. Residuals from budget calculations for conserved quantities (heat, moisture, and CH4) were compared with their respective surface fluxes to provide a measure of the internal self-consistency of the flux measurements.

Ritter, John A.↗

AASE-2 observations of trace carbon species distributions in the mid to upper troposphere

We report tropospheric (altitudes greater than 5 km) observations of CO2, CO, CH4, and light hydrocarbons (C2-C4) over the latitude range from 90 deg N to 23 deg S recorded onboard the NASA DC-8 aircraft during the winter 1992 Second Airborne Arctic Stratospheric Expedition (AASE-2). Mixing ratios for these species exhibited significant north-south gradients with maximum values in subpolar and arctic regions and minima over the southern tropics. At latitudes greater than 40 deg N, the mixing ratios of most species increased significantly over the course of the 3-month measurement period. Also at high northern latitudes, the variations of all relatively long-lived reactive carbon species were linearly correlated with fluctuations of CO2 with CO, CH4, C2H6, C2H2, C3H8, and n-C4H10 exhibiting average enhancement ratios in terms of ppbv(X)/ppmb(CO2) of 13.8, 8.4, 0.21, 0.075, 0.085, and 0.037, respectively.

Anderson, B. E.↗

Latitude variations of stratospheric trace gases

We present vertical column abundances of H2O, N2O, HNO3, NO2, O3, HF, HCl, and ClNO3, determined from solar absorption spectra measured by the JPL MkIV interferometer from the NASA DC-8 aircraft. These observations, taken in 1987 and 1992, covered latitudes ranging from 85 deg S to 85 deg N. Although most gases display latitude symmetry, large asymmetries in H2O, HNO3, and O3 are apparent, which can be ascribed to processes enhanced by the colder Antarctic winter temperatures.

Toon, G. C.↗

Column measurements of stratospheric trace species over Are, Sweden in the winter of 1991-1992

Total vertical column amounts of stratospheric HCl, HF, ClONO2 and HNO3 are reported from high resolution infrared solar absorption spectra taken during the European Arctic Stratospheric Ozone Experiment (EASOE) in the winter of 1991-1992. These ground based measurements were made near Are in North Sweden (63.4 deg N, 13.1 deg E) at an altitude of 800 m using a Fourier transform spectrometer and tunable diode laser heterodyne spectrometer. On 9th January 1992 the HCl vertical column dropped to 1.2 x 10(exp 15) molecules/sq cm from a November average of 3.6 x 10(exp 15) molecules/sq cm. The HCl drop occurred at a time when Are was below the polar vortex and the lower stratospheric ClO column above Are was elevated to approximately 2 x 10(exp 15) molecules/sq cm as measured by the Microwave Limb Sounder experiment on the Upper Atmosphere Research Satellite. These measurements indicate conversion of lower stratospheric chlorine from reservoir to chemically active forms.

Bell, W.↗

Short term responses of nitrogen trace gas emissions to nitrogen fertilization in tropical sugar cane: Variations due to soils and management practices

Nitrogen (N) fertilization of agricultural systems is thought to be a major source of the increase in atmospheric N2O; NO emissions from soils have also been shown to increase due to N fertilization. While N fertilizer use is increasing rapidly in the developing world and in the tropics, nearly all of our information on gas emissions is derived from studies of temperate zone agriculture. Using chambers, we measured fluxes of N2O and NO following urea fertilization in tropical sugar cane systems growing on a variety of soil types in the Hawaiian Islands, USA. On the island of Maui, where urea is applied in irrigation lines and soils are mollisols and inceptisols, N2O fluxes were elevated for a week or less following fertilization; maximum average fluxes were typically less than 30 ng cm(exp -2)/ h. NO fluxes were often an order of magnitude less than N2O. Together, N2O and NO represented from 0.01 - 0.5% of the applied N. In fields on the island of Hawaii, where urea is broadcast on the surface and soils are andisols, N2O fluxes were similar in magnitude to Maui but remained elevated for much longer periods after fertilization. NO emissions were 2-5 times higher than N2O through most of the sampling periods. Together the gases loss represented approximately 1. 1 - 3% of the applied N. Laboratory studies indicate that denitrification is a critical source of N2O in Maui, but that nitrification is more important in Hawaii. Experimental studies suggest that differences in the pattern of N2O/NO and the processes producing them are a result of both carbon availability and placement of fertilizer, and that the more information-intensive fertilizer management practice results in lower emissions.

Matson, P. A.↗

Deforestation and Biogenic Trace Emissions from Brazilian Cerrado

The overall goal of NASA's SCAR (Smoke, Cloud and Radiation) Program is to obtain physical and chemical properties of the smoke produced by biomass burning and the effects of the smoke on the earth's radiation balance and climate. It is a joint project with the Brazilian government and their organizations, including INPE (Instituto Nacional Pesquisas Espaciais) who actively participate in all activities. Appropriate estimates of the biomass buming in the tropics is therefore essential to determine its effect on the atmosphere and on climate. The SCAR series of experiments is designed with that purpose. The present study of evaluating the burnt-out areas is to augment the data collected to date to help evaluate the effect of biomass burning.

Sinha, Ravi↗

Heterogeneous Photocatalytic Oxidation of Atmospheric Trace Contaminants

Heterogeneous photocatalysis involves the use of a light-activated catalyst at room temperature in order to carry out a desired reaction. In the presence of molecular oxygen, illumination of the n-type semiconductor oxide titanium dioxide (TiO2) provides for production of highly active forms of oxygen, such as hydroxyl radicals, which are able to carry out the complete oxidative destruction of simple hydrocarbons such as methane, ethane, ethylene, propylene, and carbon monoxide. This broad oxidation potential, coupled with the ability with sufficient residence time to achieve complete oxidation of simple hydrocarbon contaminants to carbon dioxide and water, indicated that heterogeneous photocatalysis should be examined for its potential for purification of spacecraft air. If a successful catalyst and photoreactor could be demonstrated at the laboratory level, such results would allow consideration of photocatalysts as a partial or complete replacement of adsorption systems, thereby allowing for reduction in lift-off weight of a portion of the life support system for the spacecraft, or other related application such as a space station or a conventional commercial aircraft. The present research was undertaken to explore this potential through achievement of the following plan of work: (a) ascertain the intrinsic kinetics of conversion of pollutants of interest in spacecraft, (b) ascertain the expected lifetime of catalysts through examination of most likely routes of catalyst deactivation and regeneration, (c) model and explore experimentally the low pressure drop catalytic monolith, a commercial configuration for automotive exhaust control, and (d) examine the kinetics of multicomponent conversions. In the recent course of this work, we have also discovered how to increase catalyst activity via halide promotion which has allowed us to achieve approximately 100% conversion of an aromatic contaminant (toluene) in a very short residence time of 5-6 milliseconds.

Ollis, David F.↗

Heterogeneous Photocatalytic Oxidation of Atmospheric Trace Contaminants

Heterogeneous photocatalysis involves the use of a light-activated catalyst at room temperature in order to carry out a desired reaction. In the presence of molecular oxygen, illumination of the n-type semiconductor oxide titanium dioxide (TiO2) provides for production of highly active forms of oxygen, such as hydroxyl radicals, which are able to carry out the complete oxidative destruction of simple hydrocarbons such as methane, ethane, ethylene, propylene, and carbon monoxide. This broad oxidation potential, coupled with the ability with sufficient residence time to achieve complete oxidation of simple hydrocarbon contaminants to carbon dioxide and water, indicated that heterogeneous photocatalysis should be examined for its potential for purification of spacecraft air. If a successful catalyst and photoreactor could be demonstrated at the laboratory level, such results would allow consideration of photocatalysts as a partial or complete replacement of adsorption systems, thereby allowing for reduction in lift-off weight of a portion of the life support system for the spacecraft, or other related application such as a space station or a conventional commercial aircraft. The present research was undertaken to explore this potential through achievement of the following plan of work: (a) ascertain the intrinsic kinetics of conversion of pollutants of interest in spacecraft, (b) ascertain the expected lifetime of catalysts through examination of most likely routes of catalyst deactivation and regeneration (c) model and explore experimentally the low pressure drop catalytic monolith, a commercial configuration for automotive exhaust control (d) examine the kinetics of multicomponent conversions. In the recent course of this work, we have also discovered how to increase catalyst activity via halide promotion which has allowed us to achieve approximately 100% conversion of an aromatic contaminant (toluene) in a very short residence time of 5-6 milliseconds.

Ollis, David F.↗

AASE-2 Observations of Trace Carbon Species Distributions in the Mid to Upper Troposphere

We report tropospheric (altitudes greater than 5 km) observations of CO2, CO, CH4, and light hydrocarbons (C2-C4) over the latitude range from 90 deg N to 23 deg S recorded onboard the NASA DC-8 aircraft during the winter 1992 Second Airborne Arctic Stratospheric Expedition (AASE-II). Mixing ratios for these species exhibited significant north-south gradients with maximum values in subpolar and arctic regions and minima over the southern tropics. At latitudes greater than 40 deg N, the mixing ratios of most species increased significantly over the course of the 3-month measurement period. Also at high northern latitudes, the variations of all relatively long-lived reactive carbon species were linearly correlated with fluctuations of CO2 with CO, CH4, C2H6, C2H2, C3H8, and n-C4H10 exhibiting average enhancement ratios in terms of ppbv(X)/ppmv(CO2) of 13.8, 8.4, 0.21, 0.075, 0.085, and 0.037, respectively.

Anderson, B. E.↗

Trace Element Abundance Measurements on Cosmic Dust Particles

The X-Ray Microprobe on beamline X-26A at the National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory was used to determine the abundances of elements from Cr through Sr in individual interplanetary dust particles (IDPs) collected from the Earth's stratosphere and the Scanning Transmission X-ray Microscope (STXM) on beamline X-1A at the NSLS was used to determine the carbon abundances and spatial distributions in IDPs. In addition, modeling was performed in an attempt to associate particular types of IDPs with specific types of parent bodies, and thus to infer the chemistry, mineralogy, and structural properties of those parent bodies.

Flynn, George↗

Stratospheric and Mesospheric Trace Gas Studies Using Ground-Based mm-Wave Receivers

The goal of the proposed work was to understand the latitude structure of nitric oxide in the mesosphere and lower thermosphere. The problem was portrayed by a clear difference between predictions of the nitric oxide distribution from chemical/dynamical models and data from observations made by the Solar Mesosphere Explorer (SMEE) in the early to mid eighties. The data exhibits a flat latitude structure of NO, the models tend to produce at equatorial maximum.

daZafra, Robert L.↗

Tracing Chromospheric Evaporation in Radio and Soft X-rays

There are three publications in refereed journals and several presentations at scientific conferences resulted from this work, over a period of 6 months during 1995/1996. In the first paper, the discovery of the chromospheric evaporation process at radio wavelengths is described. In the second paper, the radio detection is used to quantify electron densities in the upflowing heated plasma in flare loops, which is then compared with independent other density measurements from soft X-rays, or the plasma frequency of electron beams originating in the acceleration region. In the third paper, the diagnostic results of the chromospheric evaporation process are embedded into a broader picture of a standard flare scenario. Abstracts of these three papers are attached.

Aschwanden, Markus J.↗

Tracing Ca K grains through the chromosphere into the transition region

The propagation of Ca K grains from the lower chromosphere into the transition region is studied. Data from the solar ultraviolet measurement of emitted radiation (SUMER) and the VTT at Inzana (Tenerife) instruments were used. The purpose of the study was to investigate the formation of shock waves in the chromosphere. The most dynamical features in the chromosphere defined by the bright Ca II K emission in the filtergrams and spectrograms were analyzed.

Steffens, S.↗