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At least 1,117 records · Page 62

Titanium carbide and titania phases on Antarctic ice particles of probable extraterrrestrial origin

Two unique titania-rich particles, found within ancient Antarctic ice have been discovered and characterized, and are believed to be of extraterrestrial origin. Both particles contain abundant submicron-sized crystals of Magneli phases (Ti(n)O(2n-1). In addition, one particle contains a core of TiC. Whereas the Magneli phases would have been stable in the early solar nebula, and so probably formed there, the TiC is more likely to have condensed in the cool, dusty, carbon-rich outer shell of a red giant star. It is suggested that both particles are interplanetary dust particles whose Magneli phases carry a record of the PO2-T conditions of the early solar nebula. It is further suggested that the TiC grain in particle 705 is remnant interstellar dust.

Zolensky, M. E.↗

Superplastically Formed Titanium Hat-Stiffened Panels

Recent advances in superplastic forming of some metals make it possible to fabricate new shapes. Superplastic forming enables design of structures using mass more efficiently. Parts having intersecting compound contour surfaces made; impossible to fabricate such parts by more conventional methods. Beaded hat-stiffened panel has higher critical buckling strain than conventional hat-stiffened panel.

Davis, Randall C.↗

Finding Platinum-Coating Gaps On Titanium Anodes

Simple procedure makes gaps visible to eye. New gap-detection method consists of plating thin layer of non-silver-colored metal like copper or gold on anode. Contrast in color between plated metal and bare anode material makes gaps stand out. If anode passes inspection, copper or gold plate removable by reversal of test-plating current. Remains to be determined whether test plating and removal damages anode. New method simpler and more economical than previous attempts to identify gaps in platinum.

Bodemeijer, Ronnald↗

Remote compositional mapping of lunar titanium and surface maturity

Lunar ilmenite (FeTiO3) is a potential resource capable of providing oxygen for life support and spacecraft propellant for future lunar bases. Estimates of TiO2 content in mature mare soils can be made using an empirical relation between the 400/500 nm reflectance ratio and TiO2 wt percent. A TiO2 abundance map was constructed for the entire near-side lunar maria accurate to + or - 2 wt percent TiO2 using CCD images obtained at the Tumamoc Hill 0.5 m telescope in Tucson, employing bandpass filters centered at 400 and 560 nm. Highest TiO2 regions in the maria are located in western Mare Tranquillitatis. Greater contrast differences between regions on the lunar surface can be obtained using 400/730 nm ratio images. The relation might well be refined to accommodate this possibly more sensitive indicator of TiO2 content. Another potential lunar resource is solar wind-implanted He-3 which may be used as a fuel for fusion reactors. Relative soil maturity, as determined by agglutinate content, can be estimated from 950/560 nm ration images. Immature soils appear darker in this ratio since such soils contain abundant pyroxene grains which cause strong absorption centered near 950 nm due Fe(2+) crystal field transitions. A positive correlation exists between the amount of He-3 and TiO2 content in lunar soils, suggesting that regions high in TiO2 should also be high in He-3. Reflectance spectrophotometry in the region 320 to 870 nm was also obtained for several regions. Below about 340 nm, these spectra show variations in relative reflectance that are caused by as yet unassigned near-UV absorptions due to compositional differences.

Johnson, J. R.↗

The formation and study of titanium, zirconium, and hafnium complexes

Research involves the preparation and characterization of a series of Ti, Zr, Hf, TiO, and HfO complexes using the poly(pyrazole) borates as ligands. The study will provide increased understanding of the decomposition of these coordination compounds which may lead to the production of molecular oxygen on the Moon from lunar materials such as ilmenite and rutile. The model compounds are investigated under reducing conditions of molecular hydrogen by use of a high temperature/pressure stainless steel autoclave reactor and by thermogravimetric analysis.

Wilson, Bobby↗

Effect of fiber-matrix debonding on notched strength of titanium metal matrix composites

Two specimen configuration of a (0/90)2s SCS-6/Ti-15-3 laminate were tested and analyzed: a center hole (CH) specimen and a double edge notch (DEN) specimen. The two specimen configurations failed at similar stress levels. Two analytical techniques, a 3-D finite-element analysis and a macro-micromechanical analysis were used to predict the overall stress-deformation behavior and the notch-tip fiber-matrix interface stresses in both configurations.

Bigelow, C. A.↗

Analysis of thermomechanical fatigue of unidirectional titanium metal matrix composites

Thermomechanical fatigue (TMF) data was generated for a Ti-15V-3Cr-3Al-3Sn (Ti-15-3) material reinforced with SCS-6 silicon carbide fibers for both in-phase and out-of-phase thermomechanical cycling. Significant differences in failure mechanisms and fatigue life were noted for in-phase and out-of-phase testing. The purpose of the research is to apply a micromechanical model to the analysis of the data. The analysis predicts the stresses in the fiber and the matrix during the thermal and mechanical cycling by calculating both the thermal and mechanical stresses and their rate-dependent behavior. The rate-dependent behavior of the matrix was characterized and was used to calculate the constituent stresses in the composite. The predicted 0 degree fiber stress range was used to explain the composite failure. It was found that for a given condition, temperature, loading frequency, and time at temperature, the 0 degree fiber stress range may control the fatigue life of the unidirectional composite.

Mirdamadi, M.↗

Hydrogen and sliding at alpha/beta interfaces of titanium alloys

Emerging evidence that the sliding between alpha and beta interfaces reported in both Ti-Mn alloys and the Ti-4.5Al-5Mo-1.5Cr ('Corona 5') alloy at room temperature is associated with hydrogen suggests that this may be a general problem contributing to Ti alloys' room-temperature creep. The present evaluation of experimental data indicates that while the hydrogen is concentrated at the Ti-Mn alloys' beta phase, no hydride formation at the alpha/beta interfaces has been reported for either the Ti-Mn alloys or Corona 5. If a hydrogen flux is needed, sliding at the alpha-beta interfaces should be a function of total hydrogen content in the alloy.

Margolin, Harold↗

Notch sensitivity of hydrogenated oxygen-strengthened titanium

While earlier studies have shown that the tensile properties and fracture test intensity factors of oxygen-strengthened Ti remain nearly unaffected by the presence of about 70 ppm (weight) hydrogen, the Charpy V-notch test-determined impact properties of oxygen-bearing Ti are strongly affected by the presence of hydrogen. The present study establishes that, concurrently with the strengthening effect of oxygen, there is a substantial lowering of ductility. The presence of hydrogen has virtually no effect on the notch strength of Ti alloys of either low or high oxygen content, where hydrogen contents lie in the 25-80 range.

Wasz, M. L.↗

Titanium aluminides - Surface composition effects as a function of temperature

Results are presented from an AES investigation of the surface characteristics of pure Ti, Ti-14Al-21Nb (alpha-2 aluminide), and Ti-33Al-6Nb-1.4Ta (gamma aluminide) under ultrahigh vacuum conditions over the 20-1000 C temperature range. The observed variations in surface composition are noted to be dramatic and indicative of a direct relationship between the amount of retained oxygen and carbon on the surface and the quantity of Al in that surface's vicinity. While TiO2 was the main surface oxide for pure Ti and the alpha-2 and gamma aluminides, only metallic peaks were observable at 600 C; at 1000 C, metallic Al and Ti were observed.

Outlaw, R. A.↗

Broadly tunable high-power operation of an all-solid-state titanium-doped sapphire laser system

Broadly tunable and high-power operation of a Ti-doped sapphire laser is obtained with a diode-laser-pumped frequency-doubled Nd:YAG laser as the pump source. A maximum broadband (FWHM = 25 nm) output pulse energy of 720 microJ at 795 nm in a TEM00 mode is obtained for 1850 microJ of energy of 532-nm pump light. A minimum pulse duration of 7 nsec is obtained from a 40-mm-long cavity. With the use of an intracavity prism, the Ti:sapphire laser is tunable continuously over the 696-1000-nm spectral range (with three different mirror sets).

Steele, T. R.↗

Hydrogen environment effects on beryllium and titanium aluminides

The NASP program has intensively studied the hydrogen-environment embrittlement (HEE) susceptibility of Be, alpha(2)-Ti3Al, and gamma-TiAl. Tensile tests are being conducted on candidate aerospace structure and propulsion candidate materials from each of the three groups, at temperatures in the -130 to +204 C range, in both 0.1 MPa and 13.8 MPa He and H2 environments, using SEM and TEM to discern the details of environmental effects. It has been established that while alpha(2) Ti3Al is HEE-susceptible even in the room-temperature and 13.8 MPa environment, neither Be nor gamma-TiAl are susceptible, even at the highest temperature tested.

Fritzemeier, L. G.↗

Continuous fiber-reinforced titanium aluminide composites

An account is given of the fabrication techniques, microstructural characteristics, and mechanical behavior of a lightweight, high service temperature SiC-reinforced alpha-2 Ti-14Al-21Nb intermetallic-matrix composite. Fabrication techniques under investigation to improve the low-temperature ductility and environmental resistance of this material system, while reducing manufacturing costs to competitive levels, encompass powder-cloth processing, foil-fiber-foil processing, and thermal-spray processing. Attention is given to composite microstructure problems associated with fiber distribution and fiber-matrix interfaces, as well as with mismatches of thermal-expansion coefficient; major improvements are noted to be required in tensile properties, thermal cycling effects, mechanical damage, creep, and environmental effects.

Mackay, R. A.↗

Evaluation of a hydrogen resistant titanium aluminide alloy

The Ti-24Al-11Nb (Ti-24-11) alloy heat treated to the fine basketweave microstructure was shown previously to be hydrogen tolerant. In order to assess its limit of hydrogen tolerance, the tensile, creep, fracture toughness, and sustained load crack growth behaviors of this alloy were studied as a function of hydrogen content. All test specimens were thermally charged with internal hydrogen and tested at 25 and 600 C. Coupon specimens were used for developing the hydrogen charging procedures and for studying compatibility of the alloy with high temperature, high pressure gaseous hydrogen. The mechanical test results indicated that the fine basketweave microstructure was tolerant to hydride embrittlement for hydrogen contents up to approximately 1500 wt. ppm, providing that the hydride formed was of the TiH2 type. On the other hand, hydrogen charging experiments indicated that the Ti-24-11 alloy was severely cracked and pulverized under zero load when the hydrogen content exceeded 3000 wt. ppm. X-ray diffraction results revealed that the dichotomous behaviors might be due to the formation of TiH(1.924) type hydrides at higher hydrogen contents. Thus, hydrogen embrittlement in the Ti-24-11 alloy with the fine basketweave microstructure depends on hydrogen content and the nature of the hydrides formed.

Chan, K. S.↗

Fatigue damage in cross-ply titanium metal matrix composites containing center holes

The development of fatigue damage in (0/90) sub SCS-6/TI-15-3 laminates containing center holes was studied. Stress levels required for crack initiation in the matrix were predicted using an effective strain parameter and compared to experimental results. Damage progression was monitored at various stages of fatigue loading. In general, a saturated state of damage consisting of matrix cracks and fiber matrix debonding was obtained which reduced the composite modulus. Matrix cracks were bridged by the 0 deg fibers. The fatigue limit (stress causing catastrophic fracture of the laminates) was also determined. The static and post fatigue residual strengths were accurately predicted using a three dimensional elastic-plastic finite element analysis. The matrix damage that occurred during fatigue loading significantly reduced the notched strength.

Bakuckas, J. G., Jr.↗

Model of the Frictional Heating of Inconel 718 and Titanium (ti-6al-4v) in Helium

A computer model of the frictional heating of metals in an inert environment has been developed. The model incorporates the effects of the heat loss from the samples due to conduction, radiation, and convection to the surroundings. This model allows the measured temperatures to be used to determine the amount of heat produced at the interface during the experiment by the sliding contact of two different metallic samples. The results of the simulation for an experiment run at the NASA White Sands Test Facility (WSTF) show that for the same heat production at the interface the heat losses have a significant effect on the temperatures in the samples. But, the heat losses do not significantly affect the different calculated heat flows (or friction coefficients), at the interface, that are necessary to correlate the measured temperatures.

Skowlund, Christopher T.↗

Damage development in titanium metal matrix composites subjected to cyclic loading

Several layups of SCS-6/Ti-15-3 composites were investigated. Fatigue tests were conducted and analyzed for both notched and unnotched specimens at room temperature and elevated temperatures. Thermo-mechanical fatigue results were analyzed. Test results indicated that the stress in the 0 degree fibers is the controlling factor in fatigue life. The static and fatigue strength of these materials is shown to be strongly dependent on the level of residual stresses and the fiber/matrix interfacial strength. Fatigue tests of notched specimens showed that cracks can initiate and grow many fiber spacings in the matrix materials without breaking fibers. Fiber bridging models were applied to characterize the crack growth behavior. The matrix cracks are shown to significantly reduce the residual strength of notched composites. The notch strength of these composites was accurately predicted using a micromechanics based methodology.

Johnson, W. S.↗

Stress-strain analysis of a (0/90)sub 2 symmetric titanium matrix laminate subjected to a generic hypersonic flight profile

Cross ply laminate behavior of Ti-15V-3Cr-3Al-3Sn (Ti-15-3) matrix reinforced with continuous silicon carbide fibers (SCS-6) subjected to a generic hypersonic flight profile was evaluated experimentally and analytically. Thermomechanical fatigue test techniques were developed to conduct a simulation of a generic hypersonic flight profile. A micromechanical analysis was used. The analysis predicts the stress-strain response of the laminate and of the constituents in each ply during thermal and mechanical cycling by using only constituent properties as input. The fiber was modeled using a thermo-viscoplastic constitutive relation. The fiber transverse modulus was reduced in the analysis to simulate the fiber matrix interface failure. Excellent correlation was found between measured and predicted laminate stress-strain response due to generic hypersonic flight profile when fiber debonding was modeled.

Mirdamadi, Massoud↗