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At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Polyimide Nanocomposites Prepared from High-Temperature, Reduced Charge Organoclays

Montmorillonite clays modified with the dihydrochloride salt of 1,3-bis(3-aminophenoxy)benzene (APB) were used in the preparation of polyimide/organoclay hybrid films. Organoclays with varying surface charge based upon APB were prepared and examined for their dispersion behavior in the polymer matrix. High molecular weight poly(amide acid) solutions were prepared in the presence of the organoclays. Films were cast and subsequently heated to 300C to cause imidization. The resulting nanocomposite films, containing 3 wt% of organoclay, were characterized by transmission electron microscopy and X-ray diffraction. The clay's cation exchange capacity (CEC) played a key role in determining the extent of dispersion in the polyimide matrix. Considerable dispersion was observed in some of the nanocomposite films. The most effective organoclay was found to have a CEC of 0.70 meq/g. Nanocomposite films prepared with 3-8 wt% of this organoclay were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and thin-film tensile testing. High levels of clay dispersion could be achieved even at the higher clay loadings. Results from mechanical testing revealed that while the moduli of the nanocomposites increased with increasing clay loadings, both strength and elongation decreased.

Delozier, D. M.↗
NASA NTRS2011

NASA Tech Briefs, May 2011

Topics covered include: 1) Method to Estimate the Dissolved Air Content in Hydraulic Fluid; 2) Method for Measuring Collimator-Pointing Sensitivity to Temperature Changes; 3) High-Temperature Thermometer Using Cr-Doped GdAlO3 Broadband Luminescence; 4)Metrology Arrangement for Measuring the Positions of Mirrors of a Submillimeter Telescope; 5) On-Wafer S-Parameter Measurements in the 325-508-GHz Band; 6) Reconfigurable Microwave Phase Delay Element for Frequency Reference and Phase-Shifter Applications; 7) High-Speed Isolation Board for Flight Hardware Testing; 8) High-Throughput, Adaptive FFT Architecture for FPGA-Based Spaceborne Data Processors; 9) 3D Orbit Visualization for Earth-Observing Missions; 10) MaROS: Web Visualization of Mars Orbiting and Landed Assets; 11) RAPID: Collaborative Commanding and Monitoring of Lunar Assets; 12) Image Segmentation, Registration, Compression, and Matching; 13) Image Calibration; 14) Rapid ISS Power Availability Simulator; 15) A Method of Strengthening Composite/Metal Joints; 16) Pre-Finishing of SiC for Optical Applications; 17) Optimization of Indium Bump Morphology for Improved Flip Chip Devices; 18) Measuring Moisture Levels in Graphite Epoxy Composite Sandwich Structures; 19) Marshall Convergent Spray Formulation Improvement for High Temperatures; 20) Real-Time Deposition Monitor for Ultrathin Conductive Films; 21) Optimized Li-Ion Electrolytes Containing Triphenyl Phosphate as a Flame-Retardant Additive; 22) Radiation-Resistant Hybrid Lotus Effect for Achieving Photoelectrocatalytic Self-Cleaning Anticontamination Coatings; 23) Improved, Low-Stress Economical Submerged Pipeline; 24) Optical Fiber Array Assemblies for Space Flight on the Lunar Reconnaissance Orbiter; 25) Local Leak Detection and Health Monitoring of Pressurized Tanks; 26) Dielectric Covered Planar Antennas at Submillimeter Wavelengths for Terahertz Imaging; 27) Automated Cryocooler Monitor and Control System; 28) Broadband Achromatic Phase Shifter for a Nulling Interferometer; 29) Super Dwarf Wheat for Growth in Confined Spaces; 30) Fine Guidance Sensing for Coronagraphic Observatories; 31) Single-Antenna Temperature- and Humidity-Sounding Microwave Receiver; 32) Multi-Wavelength, Multi-Beam, and Polarization-Sensitive Laser Transmitter for Surface Mapping; 33) Optical Communications Link to Airborne Transceiver; 34) Ascent Heating Thermal Analysis on Spacecraft Adaptor Fairings; 35) Entanglement in Self-Supervised Dynamics; 36) Prioritized LT Codes; 37) Fast Image Texture Classification Using Decision Trees; 38) Constraint Embedding Technique for Multibody System Dynamics; 39) Improved Systematic Pointing Error Model for the DSN Antennas; 40) Observability and Estimation of Distributed Space Systems via Local Information-Exchange Networks; 41) More-Accurate Model of Flows in Rocket Injectors; 42) In-Orbit Instrument-Pointing Calibration Using the Moon as a Target; 43) Reliability of Ceramic Column Grid Array Interconnect Packages Under Extreme Temperatures; 44) Six Degrees-of-Freedom Ascent Control for Small-Body Touch and Go; and 45) Optical-Path-Difference Linear Mechanism for the Panchromatic Fourier Transform Spectrometer.

Source record↗
NASA NTRS1991

Theoretical studies of molecular collisions

The following subject areas are covered: (1) total integral reactive cross sections and vibrationally resolved reaction probabilities for F + H2 = HF + H; (2) a theoretical study of inelastic O + N2 collisions; (3) body frame close coupling wave packet approach to gas phase atom-rigit rotor inelastic collisions; (4) wave packet study of gas phase atom-rigit motor scattering; (5) the application of optical potentials for reactive scattering; (6) time dependent, three dimensional body frame quantal wave packet treatment of the H + H2 exchange reaction; (7) a time dependent wave packet approach to atom-diatom reactive collision probabilities; (8) time dependent wave packet for the complete determination of s-matrix elements for reactive molecular collisions in three dimensions; (9) a comparison of three time dependent wave packet methods for calculating electron-atom elastic scattering cross sections; and (10) a numerically exact full wave packet approach to molecule-surface scattering.

Kouri, Donald J.↗
NASA NTRS1995

Radiative flux opens new window on climate research

For several decades, global satellite observations have been made of the rate at which electromagnetic energy (radiative flux) is emerging from the top of the atmosphere of our planet in the spectral range of about 0.2-50.0 microns. At the same time, models have been developed to infer the radiative flux at the surface from the values observed by the satellites at the upper boundary. The balance of incoming and outgoing radiative flux (radiation budget) at both boundaries, determines the net gain or loss of the radiative energy within an atmospheric column. Climate researchers can use the radiative flux as a tool to validate climate models, separate the radiative impact of clouds from surface and atmosphere contributions, and to understand the global hydrological cycle. When applied to physical processes occurring at the surface, information on the radiative flux has the potential to substantially advance our understanding of the transport of heat, moisture, and momentum across the surface/atmosphere interface. Geophysicists of many disciplines stand to benefit from efforts to improve the use of this latter untapped resource. Oceanographers can improve the representation of the selective absorption of radiation in the oceans; biologists and ecologists can improve their models for carbon dioxide exchange and biological heating in oceans; agronomists can model more realistically biomass and crop yields; and environmentalists can obtain better assessment of natural resources of radiation.

Pinker, R. T.↗
NASA NTRS1993

Ferric sulfate montmorillonites as Mars soil analogs

Spectroscopic analyses have shown that Fe(3+)-doped smectites prepared in the laboratory exhibit important similarities to the soils on Mars. Ferrihydrite in these smectites has features in the visible to near-infrared region that resemble the energies and band-strengths of features in reflectance spectra observed for several bright regions on Mars. Ferric - sulfate - montmorillonite samples have been prepared more recently because they are a good compositional match with the surface material on Mars as measured by Viking. Reflectance spectra of montmorillonite doped with ferric sulfate in the interlayer regions include a strong 3 micron band that persists under dry conditions. This is in contrast to spectra of similarly prepared ferric-doped montmorillonites, which exhibit a relatively weaker 3 micron band under comparable dry environmental conditions. Presented here are reflectance spectra of a suite of ferric-sulfate exchanged montmorillonites prepared with variable ferric sulfate concentrations and variable pH conditions.

Bishop, J. L.↗
NASA NTRS1995

MP2 Studies of Relativistic Effects on the Linear Stationary Points of the H+Cl2 Yields HCl+Cl and Cl+HCl Yields ClH+Cl Reactions

The influence of relativistic effects on the linear stationary points of the potential energy surfaces of the ClHCl and HCl2 systems is studied. Scalar relativistic effects have little influence on the geometries and the energies of these points. Spin-orbit effects have no influence on the barrier of the forward reaction of H with Cl2, but increase the reaction energy. The total relativistic effect is an increase of the reaction energy by 2.3 kJ /mol. The barrier for the iso-energetic exchange reaction of HCl with Cl is decreased by 0.5 kJ /mol due to the scalar relativistic effects. This small decrease is cancelled by the larger increase of 2.5 kJ /mol due to spin-orbit effects, giving a total relativistic effect of 2.0 kJ /mol.

Visscher, L.↗
NASA NTRS2005

Closed-Cycle Engine Program Used to Study Brayton Power Conversion

One form of power conversion under consideration in NASA Glenn Research Center's Thermal Energy Conversion Branch is the closed-Brayton-cycle engine. In the tens-of-kilowatts to multimegawatt class, the Brayton engine lends itself to potential space nuclear power applications such as electric propulsion or surface power. The Thermal Energy Conversion Branch has most recently concentrated its Brayton studies on electric propulsion for Prometheus. One piece of software used for evaluating such designs over a limited tradeoff space has been the Closed Cycle Engine Program (CCEP). The CCEP originated in the mid-1980s from a Fortran aircraft engine code known as the Navy/NASA Engine Program (NNEP). Components such as a solar collector, heat exchangers, ducting, a pumped-loop radiator, a nuclear heat source, and radial turbomachinery were added to NNEP, transforming it into a high-fidelity design and performance tool for closed-Brayton-cycle power conversion and heat rejection. CCEP was used in the 1990s in conjunction with the Solar Dynamic Ground Test Demonstration conducted at Glenn. Over the past year, updates were made to CCEP to adapt it for an electric propulsion application. The pumped-loop radiator coolant can now be n-heptane, water, or sodium-potassium (NaK); liquid-metal pump design tables were added to accommodate the NaK fluid. For the reactor and shield, a user can now elect to calculate a higher fidelity mass estimate. In addition, helium-xenon working-fluid properties were recalculated and updated.

Johnson, Paul K.↗
NASA NTRS1973

Survey on effect of surface winds on aircraft design and operation and recommendations for needed wind research

A survey of the effect of environmental surface winds and gusts on aircraft design and operation is presented. A listing of the very large number of problems that are encountered is given. Attention is called to the many studies that have been made on surface winds and gusts, but development in the engineering application of these results to aeronautical problems is pointed out to be still in the embryonic stage. Control of the aircraft is of paramount concern. Mathematical models and their application in simulation studies of airplane operation and control are discussed, and an attempt is made to identify their main gaps or deficiencies. Key reference material is cited. The need for better exchange between the meteorologist and the aeronautical engineer is discussed. Suggestions for improvements in the wind and gust models are made.

Houbolt, J. C.↗
NASA NTRS1981

Weather and climate needs for lidar observations from space and concepts for their realization

The spectrum of weather and climate needs for lidar observations from space is discussed. This paper focuses mainly on the requirements for winds, temperature, moisture, and pressure. Special emphasis is given to the need for wind observations, and it is shown that winds are required to depict realistically all atmospheric scales in the tropics and the smaller scales at higher latitudes, where both temperature and wind profiles are necessary. The need for means to estimate air-sea exchanges of sensible and latent heat also is noted. Lidar can aid here by measurement of the slope of the boundary layer. Recent theoretical feasibility studies concerning the profiling of temperature, pressure, and humidity by differential absorption lidar (DIAL) from space and expected accuracies are reviewed. Initial ground-based trials provide support for these approaches and also indicate their direct applicability to path-average temperature measurements near the surface. An alternative approach to Doppler lidar wind measurements also is presented. The concept involves the measurement of the displacement of the aerosol backscatter pattern, at constant height, between two successive scans of the same area, one ahead of the spacecraft and the other behind it, a few minutes later. Finally, an integrated space lidar system capable of measuring temperature, pressure, humidity, and winds which combines the DIAL methods with the aerosol pattern displacement concept is described briefly.

Atlas, D.↗
NASA NTRS1996

Feeding Frequency Affects Cultured Rat Pituitary Cells in Low Gravity

In this report, we describe the results of a rat pituitary cell culture experiment done on STS-65 in which the effect of cell feeding on the release of the six anterior pituitary hormones was studied. We found complex microgravity related interactions between the frequency of cell feeding and the quantity and quality (i.e. biological activity) of some of the six hormones released in flight. Analyses of growth hormone (GH) released from cells into culture media on different mission days using gel filtration and ion exchange chromatography yielded qualitatively similar results between ground and flight samples. Lack of cell feeding resulted in extensive cell clumping in flight (but not ground) cultures. Vigorous fibroblast growth occurred in both ground and flight cultures fed 4 times. These results are interpreted within the context of autocrine and or paracrine feedback interactions. Finally the payload specialist successfully prepared a fresh trypsin solution in microgravity, detached the cells from their surface and reinserted them back into the culture chamber. These cells reattached and continued to release hormone in microgravity. In summary, this experiment shows that pituitary cells are microgravity sensitive and that coupled operations routinely associated with laboratory cel1 culture can also be accomplished in low gravity.

Hymer, W. C.↗
NASA NTRS1999

Preliminary Findings: Issues in Surface Movement

The final report for the grant is presented. The recent goals for this project have been: (1) To identify common surface movement challenges which affect the airlines and Air Traffic Control; (2) To map out possible solutions to these challenges; (3) To start generalizing about the information we are receiving so that major, abstract categories of challenges and potential solutions will begin to emerge. In particular, there are several areas of opportunity which are beginning to emerge from the data, dealing with the need for: (1) Tools to support information exchange regarding priorities (both within an individual airline and between the ATC tower and airlines). Such priorities include both concerns affecting departure throughput as well as the ordering of departures to accommodate other airline considerations; (2) Planning tools to help ATC and airline Ramp staff deal with information about priorities; (3) Implementation of strategies to enable greater flexibility in queueing flights for departures; (4) Tools to provide better coordination and situation awareness during taxiing (within an airline as well as between airlines and between the airlines); (5) Tools to support planning and to deal with the interactions between departures and arrivals. Thus far, the initial interviews and observations at three airlines and two ATC facilities have been completed.

Smith, Philip J.↗
NASA NTRS2001

Determination of Interannual to Decadal Changes in Ice Sheet Mass Balance from Satellite Altimetry

A major uncertainty in predicting sea level rise is the sensitivity of ice sheet mass balance to climate change, as well as the uncertainty in present mass balance. Since the annual water exchange is about 8 mm of global sea level equivalent, the +/- 25% uncertainty in current mass balance corresponds to +/- 2 mm/yr in sea level change. Furthermore, estimates of the sensitivity of the mass balance to temperature change range from perhaps as much as - 10% to + 10% per K. Although the overall ice mass balance and seasonal and inter-annual variations can be derived from time-series of ice surface elevations from satellite altimetry, satellite radar altimeters have been limited in spatial coverage and elevation accuracy. Nevertheless, new data analysis shows mixed patterns of ice elevation increases and decreases that are significant in terms of regional-scale mass balances. In addition, observed seasonal and interannual variations in elevation demonstrate the potential for relating the variability in mass balance to changes in precipitation, temperature, and melting. From 2001, NASA's ICESat laser altimeter mission will provide significantly better elevation accuracy and spatial coverage to 86 deg latitude and to the margins of the ice sheets. During 3 to 5 years of ICESat-1 operation, an estimate of the overall ice sheet mass balance and sea level contribution will be obtained. The importance of continued ice monitoring after the first ICESat is illustrated by the variability in the area of Greenland surface melt observed over 17-years and its correlation with temperature. In addition, measurement of ice sheet changes, along with measurements of sea level change by a series of ocean altimeters, should enable direct detection of ice level and global sea level correlations.

Zwally, H. Jay↗
NASA NTRSDate not supplied

The Mineralogy and Cation Exchange of Sediments in Don Juan Pond, Antarctica Dry Valley: Implications for Mars

Located in the McMurdo Dry Valleys of Antarctica (MDV) is among of the saltiest bodies of water of Earth, Don Juan Pond (DJP)[1]. DJP pond waters are unique in that they contain nearly 40% salt by weight including 95% CaCl2 [1-5] and they never evaporate or freeze entirely due to the high hygroscopicity and low eutectic temperature of the CaCl2 brine (-52 ̊C) [6]. The source of DJP water is suggested to be due to groundwater upwelling through a weathered dolerite aquifer and/or near-surface runoff, including salt deliquescence in the pond’s watershed [7,8], however the source of water is still a topic of study. During the 2017-2018 field season, we collected soil samples and altered sediments on hillslopes and drainage basins near the pond (Fig. 1). Two drill bores were also acquired in Don Juan Pond sediments in a episodically flooded area of the pond basin. This study's objectives were to characterize the mineralogy of these soils and sediments to determine if there are mineralogical indicators and/or controls for the delivery of salts to DJP and understand the role of salts on Mars on these analog studies.

V M Tu↗
NASA NTRS2015

The Transit-Time Distribution from the Northern Hemisphere Midlatitude Surface

The distribution of transit times from the Northern Hemisphere (NH) midlatitude surface is a fundamental property of tropospheric transport. Here we present an analysis of the transit time distribution (TTD) since air last contacted the northern midlatitude surface layer, as simulated by the NASA Global Modeling Initiative Chemistry Transport Model. We find that throughout the troposphere the TTD is characterized by long flat tails that reflect the recirculation of old air from the Southern Hemisphere and results in mean ages that are significantly larger than the modal age. Key aspects of the TTD -- its mode, mean and spectral width -- are interpreted in terms of tropospheric dynamics, including seasonal shifts in the location and strength of tropical convection and variations in quasi-isentropic transport out of the northern midlatitude surface layer. Our results indicate that current diagnostics of tropospheric transport are insufficient for comparing model transport and that the full distribution of transit times is a more appropriate constraint.

model transport↗
NASA NTRS2004

Understanding Sea Level Changes

Today more than 100 million people worldwide live on coastlines within one meter of mean sea level; any short-term or long-term sea level change relative to vertical ground motion is of great societal and economic concern. As palm-environment and historical data have clearly indicated the existence and prevalence of such changes in the past, new scientific information regarding to the nature and causes and a prediction capability are of utmost importance for the future. The 10-20 cm global sea-level rise recorded over the last century has been broadly attributed to two effects: (1) the steric effect (thermal expansion and salinity-density compensation of sea water) following global climate; (2) mass-budget changes due to a number of competing geophysical and hydrological processes in the Earth-atmosphere-hydrosphere-cryosphere system, including water exchange from polar ice sheets and mountain glaciers to the ocean, atmospheric water vapor and land hydrological variations, and anthropogenic effects such as water impoundment in artificial reservoirs and extraction of groundwater, all superimposed on the vertical motions of solid Earth due to tectonics, rebound of the mantle from past and present deglaciation, and other local ground motions. As remote-sensing tools, a number of space geodetic measurements of sea surface topography (e.g., TOPEX/Poseidon, Jason), ice mass (e.g., ICESat), time-variable gravity (e.g. GRACE), and ground motions (SLR, VLBI, GPS, InSAR, Laser altimetry, etc.) become directly relevant. Understanding sea level changes "anywhere, anytime" in a well-defined terrestrial reference frame in terms of climate change and interactions among ice masses, oceans, and the solid Earth, and being able to predict them, emerge as one of the scientific challenges in the Solid Earth Science Working Group (SESWG, 2003) conclusions.

Chao, Benjamin F.↗
NASA NTRS2020

Returning Samples from Enceladus for Life Detection

Evidence suggests that Saturn’s icy moon Enceladus has a subsurface ocean that sources plumes of water vapor and ice vented to space from its south pole. In situ analyses of this material by the Cassini spacecraft have shown that the ocean contains key ingredients for life (elements H, C, N, O and possibly S; simple and complex organic compounds; chemical disequilibria at water-rock interfaces; clement temperature, pressure, and pH). The Cassini discoveries make Enceladus’ interior a prime locale for life detection beyond Earth. Scant material exchange with the inner Solar System makes it likely that such life would have emerged independently of life on Earth. Thus, its discovery would illuminate life’s universal characteristics. The alternative result of an upper bound on a detectable biosphere in an otherwise habitable environment would likewise considerably advance our understanding of the prevalence of life beyond Earth. Here we outline the rationale for returning vented ocean samples, accessible from Enceladus’ surface or low altitudes, to Earth for life detection. Returning samples allows analyses using laboratory instruments that cannot be flown, with decades or more to adapt and repeat analyses. We describe an example set of measurements to estimate the amount of sample to be returned and discuss possible mission architectures and collection approaches. We then turn to the challenges of preserving sample integrity and implementing planetary protection policy. We conclude by placing such a mission in the broader context of Solar System exploration.

Enceladus↗
NASA NTRS1987

Evaluation of surface energy and radiation balance systems on the Konza Prairie

Four Surface Energy and Radiation Balance Systems (SERBS) were installed and operated for two weeks in Kansas during July of 1986. Surface energy and radiation balances were investigated on six sites on the Konza Prairie about 3 km south of Manhattan, Kansas. Measurements were made to allow the computation of these radiation components: total solar and diffuse radiation, reflected solar radiation, net radiation, and longwave radiation upward and downward. Measurements were made to allow the computation of the sensible and latent heat fluxes by the Bowen ratio method using differential psychrometers on automatic exchange mechanisms. The report includes a description of the experimental sites, data acquisition systems and sensors, data acquisitions system operating instructions, and software used for data acquisition and analysis. In addition, data listings and plots of the energy balance components for all days and systems are given.

Fritschen, Leo J.↗
NASA NTRS1991

Convective flows around sunspot-like objects

Calculations of convective flows around objects in the outer layers of the sun that have characteristics similar to those of sunspots are presented. It is assumed that these objects are allowed to radiatively exchange heat with their surroundings, but convective motions and exchange are absent. The flow structure around the object, and the question of the overall balance or redistribution of the emerging heat flux as suggested by earlier empirical models are discussed. In all the cases studied, there was a significant increase in the kinetic energy flux and thus the lateral transport of the energy flux surrounding the object. This mainly occurred below the object to allow the heat to appear at the surface, with some time delay. The percentage reduction in the specific intensity agrees well with the observed deficits for pores or small sunspot-type regions. The diverted heat flow was not totally blocked by the object. Because the sunspot-like object is magnetic and the convective flow closely surrounds it, some conversion between internal, kinetic, and magnetic energy is likely.

Fox, Peter A.↗