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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Method development for thermal analyses testing on Reillex HPQ resin using the advanced reactive system screening tool (ARSST)

Reillex™ HPQ resin was developed by Los Alamos Laboratory and Reilly Industries Inc. in an effort to increase safety and process efficiency during the recovery and purification of plutonium. Ionac™ A-641, another strong base macroporous anion exchange resin used in the nuclear industry, was known to undergo a runaway reaction in hot nitric acid solutions. Because of this, an extensive amount of thermal analyses testing on the Reillex™ HPQ resin in SRNL was performed in 1999-2001 prior to use. A report on the thermal stability qualification of the Reillex™ HPQ resin in 8M (35%) and 12M (53%) HNO 3 was reported in 2000. In 2001, the reactivity of Reillex™ HPQ resin in 14.4M (64%) HNO 3 was evaluated. In January of 2001, thermal stability scoping tests were performed on irradiated Reillex™ HPQ resin in 14.4M (64%) HNO 3 (as a worst case scenario) and the results sent to Fauske and Associates to calculate a rupture disk size for the HB-Line resin column. A technical report by Fauske and Associates was issued in February 2001 recommending a 2.0” vent line with a rupture disk set pressure of 60 psig. This calculation was based on ARSST thermal analyses scoping tests at SRNL in which 4 grams of dried resin and 6.0 grams of 64% nitric acid in a 10 gram test cell, produced a maximum pressure rate (dP/dt) of 720 psi/min (12 psi/sec) and a maximum temperature of 250 °C. In 2015, a new batch of Reillex™ HPQ resin was manufactured by Vertellus Industries. A test sample of the resin was sent to SRNL to perform acceptance and qualification thermal stability testing using the ARSST. During these tests, method development was performed to ensure that a representative resin to acid ratios were used while running the tests in the ARSST. Fauske and Associates recommended to either use a full test cell representative of the HB-Line column or a 10 gram sample in the test cell that was representative of the ratios of resin to nitric acid in the actual HB-Line column. An observation was made during method development testing that the 4 grams of resin to 6 grams of 64% acid ratio used in 2001 to determine the rupture disk size did not entirely wet the resin and was not representative of the actual HB-Line column. The results of this study raised questions as to whether the ratio of 4 grams of resin to 6 grams of 64% nitric acid recommended by Fauske and Associates in 2001 was the correct ratio.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Adaptive RAS/SPS System Settings for Improving Grid Reliability and Asset Utilization through Predictive Simulation and Controls

Remedial Action Schemes (RAS) or Special Protection Schemes (SPS) are used throughout the bulk transmission system as a non-wires method of increasing transmission transfer capability. However, as the population grows within the Western Interconnection, more power needs to be transferred with less ability to build lines. This leads to a greater number of RAS, and the subsequent interaction between these disparate schemes can have unintended consequences. While the large number of RAS within the Western Electricity Coordinating Council (WECC) protect for different things, which can range from the violation of thermal limitations to transient stability issues, they can be described by common methods of operation. In order to understand these methods, a survey was sent out to members of the WECC Modeling & Validation Working Group (MVWG). The response received provides a necessary base in which to understand and build models that can be used within WECC. This report provides information on the survey results regarding RAS/SPS modeling practices for planning and operational studies within the WECC footprint, which is foundational for on-going and future work on RAS. Pacific Northwest National Laboratory (PNNL) and its industry partners are developing innovative methods for adaptively setting RAS parameters based on realistic and near real-time operational conditions to improve power grid reliability and grid asset utilization.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2018

Impact of Molecular Weight on the Thermal Stability and the Miscibility of Poly(ε-caprolactone)/Polystyrene Binary Blends

Poly(ε-caprolactone) (PCL) and two different molecular weight (6K and 650K) of polystyrene (PS) were mixed in solution to prepare binary blends of PCL/PS with various compositions. The impact of the molecular weight of PS in the blends was studied on thermal stability and miscibility by the thermogravimetric analysis (TGA) and the differential scanning calorimetry (DSC) method. The TGA results under dynamic conditions in an inert atmosphere show that the thermal stability of the blends depends on the length of PS molecules. The increase of the low molecular weight PS into the PCL/PS blend reduces the thermal stability while the high molecular weight PS improves the thermal stability. The crystallization peak temperature, enthalpy, and crystallinity of the blends are found molecular weight dependent; these parameters with blend compositions deviate from linearity of additive law for low molecular weight PS, while they do follow the additive law for high molecular weight PS. A significant melting point depression of PCL crystals with composition was observed for the blends with the incorporation of the low molecular weight PS, while the no significant melting temperature depression was observed for the high molecular weight PS. The experimental results clearly indicate that in the PCL/PS blends, the thermal stability and the interaction between the neat components strongly depend on the molecular weight of the PS.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Small-Signal Stability of Grid-Forming Converters Under Fault Conditions

Threshold virtual impedance (TVI)-based current limiting for grid-forming converters (GFMs) has gained great interest due to its ability to maintain voltage source behaviour during faults. However, sequence component extraction (SCE) and negative-sequence control (NSC) are often overlooked in small-signal stability assessments during faults. This paper develops small-signal sequence impedance models for GFMs under four well-known SCE methods based on TVI current limiting control during symmetrical fault conditions. Using the developed impedance models, the impacts of SCE and NSC, and the voltage and current control loop bandwidths, on system stability during faults are investigated. Additionally, since negative-sequence TVI (TVI-) is typically added along with its positive-sequence counterpart, which is often inductive, inductive and resistive TVI- are examined. The findings suggest that a higher voltage or current control loop bandwidth has a negative impact on system stability, while SCE and NSC largely reduce the stable range for voltage and current control loop bandwidth during faults, and that the severity of such impacts is determined by the particular SCE method. Furthermore, it is observed that inductive TVI- significantly degrades system stability, while resistive TVI- can enhance stability when suitable SCE methods are appropriately selected and designed. Matlab/Simulink electromagnetic transient simulations validate these analytical results.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Direct observation of the formation and stabilization of metallic nanoparticles on carbon supports

Direct formation of ultra-small nanoparticles on carbon supports by rapid high temperature synthesis method offers new opportunities for scalable nanomanufacturing and the synthesis of stable multi-elemental nanoparticles. However, the underlying mechanisms affecting the dispersion and stability of nanoparticles on the supports during high temperature processing remain enigmatic. In this work, we report the observation of metallic nanoparticles formation and stabilization on carbon supports through in situ Joule heating method. We find that the formation of metallic nanoparticles is associated with the simultaneous phase transition of amorphous carbon to a highly defective turbostratic graphite (T-graphite). Molecular dynamic (MD) simulations suggest that the defective T-graphite provide numerous nucleation sites for the nanoparticles to form. Furthermore, the nanoparticles partially intercalate and take root on edge planes, leading to high binding energy on support. This interaction between nanoparticles and T-graphite substrate strengthens the anchoring and provides excellent thermal stability to the nanoparticles. These findings provide mechanistic understanding of rapid high temperature synthesis of metal nanoparticles on carbon supports and the origin of their stability.

36 MATERIALS SCIENCE↗
DOE OSTI2015

SU-E-T-156: Can Sr-90 Check Sources Replace Co-60 Measurements for Monitoring of Reference Chamber Stability?

Purpose: To determine the ultimate precision of a system for monitoring reference-class ion chamber stability using a commercial Sr-90 check source. Methods: A detailed investigation of a commercial Sr-90 check source (PTW48002) was carried out using a series of Farmer-type ionization chambers. Investigations included: positioning repeatability (angular variation as chamber is rotated in source, variation in ionization current with vertical alignment); chamber settling; short and long term repeatability Results: i) Measurement precision – the ionization current was typically 10 pA, and therefore a high-precision electrometer is required to prevent electrometer noise/resolution/leakage biaising the results. ii) Chamber settling - the chamber response stabilizes after approximately 10 minutes, which is longer than reported for linac beams and is likely due to the low doserate of the source.iii) The measured response depended at the 1 % level on the orientation of the chamber with respect to the source. However, consistent positioning resulted in repeatability at the 0.05 % level. Care was also required to ensure that the chamber was consistently positioned vertically with respect to the source. The sensitivity to vertical position was found to be > 1 % per mm.iv)With a uniform procedure the long-term (> 6 month) repeatability was found to be better than 0.1 % for multiple chamber types and potentially a precision of 0.05 % is achievable. Conclusion: A Sr-90 check source is easy to use and is a viable alternative to Co-60 for monitoring reference chamber stability.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Passivity-Short-based Stability Analysis on Electricity Market Trading System Considering Negative Price

This paper deals with a distributed decision method for determining the electricity price considering the negative price in the market trading. In addition, we analyze the stability and convergence properties for the market trading system using the concept of passivity-short. At first, mathematical models of market participants' behavior which maximize their own profits are discussed. Then, we construct a trading system based on dynamic pricing considering plug and play operation that each market participant intermittently participates in market trading. As for the optimal electricity price, even if the optimal price might be negative, we indicate the stability of the system can be guaranteed by using passivity-short which is a relaxed concept of passivity. Finally, numerical simulation results illustrate that each value decided by the market trading converges to the optimal value.

Muto, Keita↗
DOE OSTI2019

Role of the ocean in climate stabilization

The ocean has absorbed over 90% of the heat from recent anthropogenic greenhouse warming. This chapter reviews a variety of ocean-related methods for slowing down and eventually halting this warming. “Blue carbon” reservoirs store more carbon than terrestrial equivalents, although are still limited compared with global negative emissions needs. Oceanic carbon uptake could be augmented via iron fertilization, although this method presents challenges. Algal-based biomass energy with carbon capture and storage (ABECCS) offers opportunities for carbon-neutral fuel alternatives as well as for negative emissions. Total carbon dioxide removal potential is estimated at 15–33 Pg CO 2 /year by mid-century and 33–95 Pg CO 2 /year by the end of the century, which could offset current and projected CO 2 emissions. ABECCS can also coproduce high-protein feed for aquaculture and reduce demand for agricultural land. Furthermore, combined with effective ocean blue carbon management and terrestrial methods, ocean-based carbon removal can play a critical role in climate stabilization.

bioenergy carbon capture and storage↗
DOE OSTI2017

Effective strategies for stabilizing sulfur for advanced lithium–sulfur batteries

The lithium-ion battery, with a relatively small energy density of similar to 250 W h kg(-1), has dominantly powered many devices requiring small energy demands. However, there remains a need for a cheaper and smaller type of battery with higher energy density for energy-intensive storage purposes in the automotive, aircraft, and household energy sectors. With its higher specific capacity (1675 mA h g(-1)) and lower costs, the lithium-sulfur (Li-S) battery represents the most promising next generation battery. The main focus of scientific inquiry surrounding Li-S batteries lies at the cathode, where sulfur chemically bonds to lithium. Current challenges pertaining to the high performance cathode such as the dissolution of sulfur into the electrolyte and electrode volume changes are highlighted. This review focuses on recent developments in the last three years of various sulfur integration methods at the cathode that result in improved electrochemical performance, increased energy density, cyclic stability, and a higher capacity over the mainstream lithium-ion battery. In particular, the most recent approaches were systematically examined and compared including the use of carbon and non-carbon composites to stabilize sulfur. Ideal material hosts for sulfur atoms in the cathode for outstanding Li-S batteries were outlined and thoroughly discussed. Critical understanding and relevant knowledge were summarized aiming to provide general guidance for rational design of high-performance cathodes for advanced Li-S batteries.

Ogoke, Ogechi↗
DOE OSTI2014

On the use of the double floating probe method to infer the difference between the electron and the heavy particles temperatures in an atmospheric pressure, vortex-stabilized nitrogen plasma jet

Sweeping double probe measurements in an atmospheric pressure direct current vortex-stabilized plasma jet are reported (plasma conditions: 100 A discharge current, N{sub 2} gas flow rate of 25 Nl/min, thoriated tungsten rod-type cathode, copper anode with 5 mm inner diameter). The interpretation of the double probe characteristic was based on a generalization of the standard double floating probe formulae for non-uniform plasmas coupled to a non-equilibrium plasma composition model. Perturbations caused by the current to the probe together with collisional and thermal processes inside the probe perturbed region were taken into account. Radial values of the average electron and heavy particle temperatures as well as the electron density were obtained. The calculation of the temperature values did not require any specific assumption about a temperature relationship between different particle species. An electron temperature of 10 900 ± 900 K, a heavy particle temperature of 9300 ± 900 K, and an electron density of about 3.5 × 10{sup 22} m{sup −3} were found at the jet centre at 3.5 mm downstream from the torch exit. Large deviations from kinetic equilibrium were found toward the outer border of the plasma jet. These results showed good agreement with those previously reported by the authors by using a single probe technique. The calculations have shown that this method is particularly useful for studying spraying-type plasma torches operated at power levels of about 15 kW.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Crystal Structure and Preparation of Li7La3Zr2O12 (LLZO) Solid-State Electrolyte and Doping Impacts on the Conductivity: An Overview

As an essential part of solid-state lithium-ion batteries, solid electrolytes are receiving increasing interest. Among all solid electrolytes, garnet-type Li7La3Zr2O12 (LLZO) has proven to be one of the most promising electrolytes because of its high ionic conductivity at room temperature, low activation energy, good chemical and electrochemical stability, and wide potential window. Since the first report of LLZO, extensive research has been done in both experimental investigations and theoretical simulations aiming to improve its performance and make LLZO a feasible solid electrolyte. These include developing different methods for the synthesis of LLZO, using different crucibles and different sintering temperatures to stabilize the crystal structure, and adopting different methods of cation doping to achieve more stable LLZO with a higher ionic conductivity and lower activation energy. It also includes intensive efforts made to reveal the mechanism of Li ion movement and understand its determination of the ionic conductivity of the material through molecular dynamic simulations. Nonetheless, more insightful study is expected in order to obtain LLZO with a higher ionic conductivity at room temperature and further improve chemical and electrochemical stability, while optimal multiple doping is thought to be a feasible and promising route. This review summarizes recent progress in the investigations of crystal structure and preparation of LLZO, and the impacts of doping on the lithium ionic conductivity of LLZO.

Raju, Md Mozammal (ORCID:0000000319040523)↗
DOE OSTI2026

Control Parameter Sensitivity Study for Inverter-Based-Resource Dominated Grids: A Small Signal Stability Approach and Framework

The growing adoption of renewable energy is driving the prevalence of inverter-based resources (IBRs) within power grids. Future power grids will integrate both grid-following IBRs (GFM-IBRs) and grid-forming IBRs (GFL-IBRs) alongside synchronous generators. Therefore, it is crucial to perform stability studies that account for all components and especially control interactions related to IBRs. Extensive research has performed to study the IBR-related stability, however, the sensitivity study of IBRs' control parameters on system stability has not been adequately studied yet, especially from a systematic way. Therefore, this paper conducts a small signal stability analysis for a generic grid with multiple types of resources and develops an analytical framework for assessing the sensitivity of control parameters affecting stability margins. To achieve that, the non-autonomous reduced-order non-linear dynamic model is developed for a generic power system with multiple synchronous generator-based resources (SGBRs), GFM-IBRs, and GFL-IBRs. Based on the analytic model, a systematic framework for parametric sensitivity on systems' asymptotic stability is developed. A parameter sensitivity analysis based on eigenvalue methods is proposed. The impact of the droop controllers of GFM-IBRs, PQ-dispatch and the PLL controller of GFL-IBR on the system asymptotic stability is discussed. This sensitivity study is aiming to provide deep insights on control parameters' impact on system stability, and gives direction for parameter tuning in case of instability.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2015

Enhanced capacity and stability for the separation of cesium in electrically switched ion exchange

Electrically switched ion exchange (ESIX) can be used to separate ionic contaminants from industrial wastewater, including that generated by the nuclear industry. The ESIX method involves sequential application of reduction and oxidation potentials to an ion exchange film to induce the respective loading and unloading of cesium. This technology is superior to conventional methods (e.g electrodialysis reversal or reverse osmosis) as it requires very little energy for ionic separation. In previous studies, ESIX films have demonstrated relatively low ion exchange capacities and limited film stabilities over repeated potential applications. In this study, the methodology for the deposition of electro-active films (nickel hexacyanoferrate) on nickel electrodes was modified to improve the ion exchange capacity for cesium removal using ESIX. Cyclic voltammetry was used to investigate the ion exchange capacity and stability. Scanning electron microscopy (SEM) was used to characterize the modified film surfaces. Additionally, the films were examined for the separation of cesium ions. This modified film preparation technique enhanced the ion exchange capacity and improves the film stability compared to previous methods for the deposition of ESIX films. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Stability of liquid-nitrogen-jet laser-plasma targets

Microscopic jets of cryogenic substances such as liquid nitrogen are important regenerative high-density targets for high-repetition rate, high-brightness laser-plasma soft x-ray sources. When operated in vacuum such liquid jets exhibit several non-classical instabilities that negatively influence the x-ray source's spatial and temporal stability, yield, and brightness, parameters that all are important for applications such as water-window microscopy. In the present paper, we investigate liquid-nitrogen jets with a flash-illumination imaging system that allows for a quantitative stability analysis with high spatial and temporal resolution. Direct and indirect consequences of evaporation are identified as the key reasons for the observed instabilities. Operating the jets in an approximately 100 mbar ambient atmosphere counteracts the effects of evaporation and produces highly stable liquid nitrogen jets. For operation in vacuum, which is necessary for the laser plasmas, we improve the stability by introducing an external radiative heating element. The method significantly extends the distance from the nozzle that can be used for liquid-jet laser plasmas, which is of importance for high-average-power applications. Finally, we show that laser-plasma operation with the heating-element-stabilized jet shows improved short-term and long-term temporal stability in its water-window x-ray emission.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Frequency Stability Enhancement in a Fully Solar Power Grid: A Case Study on the Saudi Model

Recently, renewable energy sources (RES) such as solar photovoltaic (PV) have been recognized for their significant potential. Several studies have explored the issue of frequency stability with high RES penetration. A significant observation related to this issue is the decline in the weighted short circuit ratio (WSCR), which has the potential to adversely affect system stability. This research uniquely focuses on the gradual transition of the Saudi Electricity Company (SEC) system to a fully integrated solar PV grid, offering insight and methodology that can be adapted for other power systems. While a variety of mitigation methods are available, synchronous condensers (SC) were used in this study to stabilize grid frequency, and their implementation has been shown to improve the overall performance of the system. In response to the observed decline in WSCR, a comprehensive short circuit analysis was applied across all regions in the Saudi power grid model to evaluate the reduction in short circuit power and highlight areas requiring enhancement. Finally, scenarios illustrating frequency response with a gradual increase in SCR were analyzed, with the objective of establishing a stable, fully solar PV power system that is resilient to sudden power grid disturbances.

14 SOLAR ENERGY↗
DOE OSTI2017

New adaptive optics control strategy for petawatt-class laser chains

A new generation of ultra-high intensity femtosecond petawatt- and above-class lasers requires new approaches to wavefront corrections. New challenges for adaptive optics consist in overcoming the constraints of potentially bigger diameters, larger amplitude aberrations, faster optics, higher risk of damaging optical components and faster and easier maintenance. Here we present a new technology of a mechanical deformable mirror, which has a large stroke, high temporal stability, low hysteresis, no print-through effect, easy, safe and fast maintenance and an operating frequency up to 10 Hz. We propose the full correction of the final focal spot in the target chamber by a combination of a standard adaptive optics system, a simple focal plane camera and a phase retrieval correction process. We test the reliability of the correction system in terms of intensity variation and wavefront stability. We further verify correction robustness of the method on a large spectral bandwidth and finally perform a focal spot correction on a terawatt laser system in both low and high-power regimes. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

A Vitrimer Acts as a Compatibilizer for Polyethylene and Polypropylene Blends

Abstract Polymer compatibilization plays a critical role in achieving polymer blends with favorable mechanical properties and enabling efficient recycling of mixed plastic wastes. Nonetheless, traditional compatibilization methods often require tailored designs based on the specific chemical compositions of the blends. In this study, we propose a new approach for compatibilizing polymer blends using a dynamically crosslinked polymer network, known as vitrimers. By adding a relatively small amount (1–5 w/w%) of a vitrimer made of siloxane‐crosslinked high‐density polyethylene (HDPE), we successfully compatibilized unmodified HDPE and isotactic polypropylene (iPP). The vitrimer‐compatibilized blend exhibited enhanced elongation at break (120 %) and smaller iPP domain sizes (0.4 μm) compared to the control blend (22 % elongation at break, 0.9 μm iPP droplet size). Moreover, the vitrimer‐compatibilized blend showed significantly improved microphase stability during annealing at 180 °C. This straightforward method shows promise for applications across various polymer blend systems.

Yokoyama, Kosuke↗
DOE OSTI2024

A Vitrimer Acts as a Compatibilizer for Polyethylene and Polypropylene Blends

Polymer compatibilization plays a critical role in achieving polymer blends with favorable mechanical properties and enabling efficient recycling of mixed plastic wastes. Nonetheless, traditional compatibilization methods often require tailored designs based on the specific chemical compositions of the blends. In this study, we propose a new approach for compatibilizing polymer blends using a dynamically crosslinked polymer network, known as vitrimers. By adding a relatively small amount (1–5 w/w%) of a vitrimer made of siloxane‐crosslinked high‐density polyethylene (HDPE), we successfully compatibilized unmodified HDPE and isotactic polypropylene (iPP). The vitrimer‐compatibilized blend exhibited enhanced elongation at break (120 %) and smaller iPP domain sizes (0.4 μm) compared to the control blend (22 % elongation at break, 0.9 μm iPP droplet size). Moreover, the vitrimer‐compatibilized blend showed significantly improved microphase stability during annealing at 180 °C. This straightforward method shows promise for applications across various polymer blend systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗