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At least 1,117 records · Page 62

The Influence of Sound Cues on the Maintenance of Temporal Organization in the Sprague-Dawley Rat

Temporal organization is a fundamental property of living matter. From single cells to complex animals including man, most physiological systems undergo daily periodic changes in concert with environmental cues (e.g., light, temperature etc.). It is known that pulsed Environmental synchronizers, zeitgebers, (e.g. light) can modify rhythm parameters. Rhythm stability is a necessary requirement for most animal experiments. The extent to which sound can influence the circadian system of laboratory rats is poorly understood. This has implications to animal habitats in the novel environments of the Space-Laboratory or Space Station. A series of three white noise (88+/-0.82 db) zeitgeber experiments were conducted (n=6/experiment).The sound cue was introduced in the circadian free-running phase (DD-NQ) and in one additional case sound was added to the usual photoperiod (12L:12D) to determine masking effects. Circadian rhythm parameters of drinking frequency, feeding frequency, and gross locomotor activity were continuously monitored. Data analysis for these studies included macroscopic and microscopic methods. Raster plots to visually detect entrainment versus free-running period, were plotted for each animal, for all three parameters, during all sound perturbation tested. These data were processed through a series of detrending (robust locally weighted regression analyses) and complex demodulation analyses. In summary, these findings show that periodic "white" noise "influences" the rats circadian system but does not "entrain" the feeding, drinking or locomotor activity rhythms.

Winget, C. M.↗

An Improved Formulation for Calorimetric Emittance Testing of Spacecraft Thermal Control Coatings

Spacecraft often really heavily on passive thermal control to maintain operating temperature. An important parameter in the spacecraft heat balance equation is the emittance of thermal control coatings as a function of coating temperature. One method for determining the emittance of spacecraft thermal control from elevated temperature to cryogenic temperatures relies on a calorimetric technique. The fundamental equation governing this test method can be found in numerous places in the literature and although it generally provides reasonable results, its formulation is based on a conceptual flaw that only becomes apparent when the sample temperature approaches the wall temperature during testing. This paper investigates the cause for this error and develops the correct formulation for calorimetric emittance testing. Experimental data will also be presented that illustrates the difference between the two formulations and the resulting difference in the calculated emittance.

Kauder, Lonny R.↗

Tapping the Brake for Entry, Descent, and Landing

A matrix of simulations of hypersonic flow over blunt entry vehicles with steady and pulsing retropropulsion jets is presented. Retropropulsion in the supersonic domain is primarily designed to reduce vehicle velocity directly with thrust. Retropropulsion in the hypersonic domain may enable significant pressure recovery through unsteady, oblique shocks while providing a buffer of reactant gases with relatively low total temperature. Improved pressure recovery, a function of Mach number squared and oblique shock angle, could potentially serve to increase aerodynamic drag in this domain. Pulsing jets are studied to include an additional degree of freedom to search for resonances in an already unsteady flow domain with an objective to maximize the time-averaged drag coefficient. In this paradigm, small jets with minimal footprints of the nozzle exit on the vehicle forebody may be capable of delivering the requisite perturbations to the flow. Simulations are executed assuming inviscid, symmetric flow of a perfect gas to enable a rapid assessment of the parameter space (nozzle geometry, plenum conditions, jet pulse frequency). The pulsed-jet configuration produces moderately larger drag than the constant jet configuration but smaller drag than the jet-off case in this preliminary examination of a single design point. The fundamentals of a new algorithm for this challenging application with time dependent, interacting discontinuities using the feature detection capabilities of Walsh functions are introduced.

Gnoffo, Peter A.↗

Quantifying Uncertainty in Ice Particle Velocity–Dimension Relationships Using MC3E Observations

Abstract Ice particle terminal fall velocity ( V t ) is fundamental for determining microphysical processes, yet remains extremely challenging to measure. Current theoretical best estimates of V t are functions of Reynolds number. The Reynolds number is related to the Best number, which is a function of ice particle mass, area ratio ( A r ), and maximum dimension ( D max ). These estimates are not conducive for use in most models since model parameterizations often take the form , where ( α , β ) depend on habit and D max . A previously developed framework is used to determine surfaces of equally plausible ( α , β ) coefficients whereby ice particle size/shape distributions are combined with V t best estimates to determine mass- ( V M ) or reflectivity-weighted ( V Z ) velocities that closely match parameterized V M ,SD or V Z ,SD calculated using the ( α , β ) coefficients using two approaches. The first uses surfaces of equally plausible ( a , b ) coefficients describing mass ( M )–dimension relationships (i.e., ) to calculate mass- or reflectivity-weighted velocity from size/shape distributions that are then used to determine ( α , β ) coefficients. The second investigates how uncertainties in A r , D max , and size distribution N ( D ) affect V M or V Z . For seven of nine flight legs flown on 20 and 23 May 2011 during the Mesoscale Continental Convective Clouds Experiment (MC3E), uncertainty from natural parameter variability—namely, the variability in ice particle parameters in similar meteorological conditions—exceeds uncertainties arising from different A r assumptions or D max estimates. The combined uncertainty between A r , D max , and N ( D ) produced smaller variability in ( α , β ) compared to varying M ( D ), demonstrating M ( D ) must be accurately quantified for model fall velocities. Primary sources of uncertainty vary considerably depending on environmental conditions. Significance Statement Ice particle fall velocity is fundamental for numerous processes within clouds, and hence is a critical property that must be accurately represented in weather and climate models. Using aircraft observations of ice particle shapes and sizes obtained in clouds behind midlatitude thunderstorms, this work develops a new framework for estimating ice particle fall velocities and their uncertainty, including quantifying the importance of different uncertainty sources from cloud microphysics measurements. Natural parameter variability contributes the most uncertainty in ice particle fall velocity estimates, although other sources can also be important contributors to uncertainty in certain conditions. Additional work examining ice particle data is needed to further understand how dependent uncertainty in certain ice particle properties are to local environmental conditions.

Meteorology & Atmospheric Sciences↗

Pressure-induced phase transition in barium hydride studied with neutron scattering

Barium hydride can undergo a structural phase transition from an orthorhombic phase to a hexagonal phase induced by high temperature or high pressure. This transition causes an immediate increase in the hydrogen diffusion rates by over an order of magnitude, and therefore, understanding the origin and details of such transition is of great interest not only for fundamental reasons but also for improving materials for future applications. In this work, the pressure evolution of the crystal structure was characterized using neutron powder diffraction up to a maximum pressure of 11.3 GPa. The pressure dependence of the unit cell volumes, lattice parameters, atomic sites, and compressibilities were determined for both phases. A structural phase transition occurred over a wide pressure range of P = 1.3 GPa–4.9 GPa. The transition to the higher density hexagonal phase reduced the volume per formula unit of BaD 2 by 13.6%, hence increasing the volumetric storage density. In addition, we investigated the hydrogen diffusion process using high pressure quasi-elastic neutron scattering up to 7.1 GPa. Our results show that the hydrogen mobility increases with pressure in the hexagonal phase. This work sheds light on the structural and dynamical aspects of barium hydride caused by the application of high pressure. Finally, the results may aid in the development of advanced metal hydride systems with increased hydrogen dynamics.

36 MATERIALS SCIENCE↗

Cooperative effects in thin dielectric layers: Long-range Dicke superradiance

The realization and control of collective quantum effects so far have predominantly focused on cold atomic ensembles. Quantum photonic platforms, with their engineered Green's functions and integration capability of advanced solid-state quantum emitters, provide opportunities to explore regimes of light-matter interaction beyond the scope of atomic systems. In this work, we demonstrate that embedding quantum emitters within a thin dielectric layer fundamentally alters their collective radiative behavior. The optical modes in the dielectric layer mediate long-range dipole-dipole interactions between emitters, enabling both total and directional superradiance between emitters separated by several wavelengths. Crucially, this mechanism supports Dicke superradiance even in parameter regimes where standard settings fail to support an interaction, unveiling a dimensionality-driven enhancement of cooperative effects. By bridging many-body quantum optics and photonic engineering, our work reveals a distinct interplay between surrounding dimensionality and collective quantum dynamics. Experimental realization of these predictions, readily achievable in solid-state quantum optics platforms, paves the way for scalable, directional quantum light sources and frontiers in many-body quantum optics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Simulating Turbulence-aided Neutrino-driven Core-collapse Supernova Explosions in One Dimension

The core-collapse supernova (CCSN) mechanism is fundamentally 3D, with instabilities, convection, and turbulence playing crucial roles in aiding neutrino-driven explosions. Simulations of CCNSe including accurate treatments of neutrino transport and sufficient resolution to capture key instabilities remain among the most expensive numerical simulations in astrophysics, prohibiting large parameter studies in 2D and 3D. Studies spanning a large swath of the incredibly varied initial conditions of CCSNe are possible in 1D, though such simulations must be artificially driven to explode. We present a new method for including the most important effects of convection and turbulence in 1D simulations of neutrino-driven CCSNe, called Supernova Turbulence In Reduced-dimensionality, or STIR. Our new approach includes crucial terms resulting from the turbulent and convective motions of the flow. We estimate the strength of convection and turbulence using a modified mixinglength theory approach, introducing a few free parameters to the model that are fit to the results of 3D simulations. For sufficiently large values of the mixing-length parameter, turbulence-aided neutrino-driven explosions are obtained. We compare the results of STIR to high-fidelity 3D simulations and perform a parameter study of CCSN explosion using 200 solar-metallicity progenitor models from 9 to 120 M ⊙ . We find that STIR is a better predictor of which models will explode in multidimensional simulations than other methods of driving explosions in 1D. We also present a preliminary investigation of predicted observable characteristics of the CCSN population from STIR, such as the distributions of explosion energies and remnant masses.

79 ASTRONOMY AND ASTROPHYSICS↗

The evolution of large-scale structure in a universe dominated by cold dark matter

The results of numerical simulations of nonlinear gravitational clustering in universes dominated by weakly interacting, 'cold' dark matter are presented. The numerical methods used and the way in which initial conditions were generated are described, and the simulations performed are catalogued. The evolution of the fundamental statistical properties of the models is described and their comparability with observation is discussed. Graphical comparisons of these open models with the observed galaxy distribution in a large redshift survey are made. It is concluded that a model with a cosmological density parameter omega equal to one is quite unacceptable if galaxies trace the mass distribution, and that models with omega of roughly two, while better, still do not provide a fully acceptable match with observation. Finally, a situation in which galaxy formation is suppressed except in sufficiently dense regions is modelled which leads to models which can agree with observation quite well even for omega equal to one.

Davis, M.↗

Liquid-Vapor Equilibrium of Multicomponent Cryogenic Systems

Liquid-vapor and solid-vapor equilibria at low to moderate pressures and low temperatures are important in many solar system environments, including the surface and clouds of Titan, the clouds of Uranus and Neptune, and the surfaces of Mars and Triton. The familiar cases of ideal behavior are limiting cases of a general thermodynamic representation for the vapor pressure of each component in a homogeneous multicomponent system. The fundamental connections of laboratory measurements to thermodynamic models are through the Gibbs-Duhem relation and the Gibbs-Helmholtz relation. Using laboratory measurements of the total pressure, temperature, and compositions of the liquid and vapor phases at equilibrium, the values of these parameters can be determined. The resulting model for vapor-liquid equilibrium can then conveniently and accurately be used to calculate pressures, compositions, condensation altitudes, and their dependencies on changing climatic conditions. A specific system being investigated is CH4-C2H6-N2, at conditions relevant to Titan's surface and atmosphere. Discussed are: the modeling of existing data on CH4-N2, with applications to the composition of Titan's condensate clouds; some new measurements on the CH4-C2H6 binary, using a high-precision static/volumetric system, and on the C2H6-N2 binary, using the volumetric system and a sensitive cryogenic flow calorimeter; and describe a new cryogenic phase-equilibrium vessel with which we are beginning a detailed, systematic study of the three constituent binaries and the ternary CH4-C2H6-N2 system at temperatures ranging from 80 to 105 K and pressures from 0.1 to 7 bar.

Thompson, W. Reid↗

Fluorescence Imaging of Underexpanded Jets and Comparison with CFD

An experimental study of underexpanded and highly underexpanded axisymmetric nitrogen free jets seeded with 0.5% nitric oxide (NO) and issuing from a sonic orifice was conducted at NASA Langley Research Center. Reynolds numbers based on nozzle exit conditions ranged from 770 to 35,700, and nozzle exit-to-ambient jet pressure ratios ranged from 2 to 35. These flows were non-intrusively visualized with a spatial resolution of approximately 0.14 mm x 0.14 mm x 1 mm thick and a temporal resolution of 1 s using planar laser-induced fluorescence (PLIF) of NO, with the laser tuned to the strongly-fluorescing UV absorption bands of the Q1 band head near 226.256 nm. Three laminar cases were selected for comparison with computational fluid dynamics (CFD). The cases were run using GASP (General Aerodynamic Simulation Program) Version 4. Comparisons of the fundamental wavelength of the jet flow showed good agreement between CFD and experiment for all three test cases, while comparisons of Mach disk location and Mach disk diameter showed good agreement at lower jet pressure ratios, with a tendency to slightly underpredict these parameters with increasing jet pressure ratio.

Wilkes, Jennifer A.↗

Structural and chemical complexity of minerals: An update

The complexities of chemical composition and crystal structure are fundamental characteristics of minerals that have high relevance to the understanding of their stability, occurrence and evolution. This review summarises recent developments in the field of mineral complexity and outlines possible directions for its future elaboration. The database of structural and chemical complexity parameters of minerals is updated by H-correction of structures with unknown H positions and the inclusion of new data. The revised average complexity values (arithmetic means) for all minerals are 3.54(2) bits/atom and 345(10) bits/cell (based upon 4443 structure reports). The distributions of atomic information amounts, chemIG and strIG, versus the number of mineral species fit the normal modes, whereas the distributions of total complexities, chemIG,total and strIG,total, along with numbers of atoms per formula and per unit cell are log normal. The three most complex mineral species known today are ewingite, morrisonite and ilmajokite, all either discovered or structurally characterised within the last five years. The most important complexity-generating mechanisms in minerals are: (1) the presence of isolated large clusters; (2) the presence of large clusters linked together to form three-dimensional frameworks; (3) formation of complex three-dimensional modular frameworks; (4) formation of complex modular layers; (5) high hydration state in salts with complex heteropolyhedral units; and (6) formation of ordered superstructures of relatively simple structure types. The relations between symmetry and complexity are considered. The analysis of temporal dynamics of mineralogical discoveries since 1875 with the step of 25 years show the increasing chemical and structural complexities of human knowledge of the mineral kingdom in the history of mineralogy. In the Earth’s history, both diversity and complexity of minerals experience dramatic increases associated with the formation of Earth’s continental crust, initiation of plate tectonics and the Great Oxidation event.

complexity↗

Elucidating the Radiation-Induced Redox Chemistry of Plutonium Under Used Nuclear Fuel Reprocessing Conditions

Plutonium plays a critical role in the development of sustainable nuclear fuel cycles, and yet, our fundamental understanding of this element’s inherent radiation-induced redox chemistry and associated impacts on nuclear fuel cycle technologies is limited. Unanticipated changes in oxidation state distribution can influence the speciation and transport of plutonium in a given process. Control of these parameters is especially important for used nuclear fuel reprocessing technologies, wherein the separation and recovery of plutonium is typically achieved by the selective formation, maintenance, and complexation of specific oxidation states. Furthermore, plutonium’s inherent radiation-induced redox chemistry has the capacity to influence the radiolytic behavior of its complexes, the longevity of which are critical in the design of efficient and cost-effective advanced reprocessing technologies. These radiation-induced processes are unavoidable under fuel cycle conditions owing to the inherency of ionizing radiation fields to the decay of plutonium’s isotopes and to the various other radioisotopes generated by nuclear fission and neutron-capture process and the subsequent radioactive decay of their products. As such, mechanistically understanding the response of plutonium’s multiple oxidation states to multi-component ionizing radiation fields is essential for predicting the behavior of this critical element under used nuclear fuel reprocessing conditions. Here, through a combination of time-resolved (electron pulse) and steady-state (alpha and gamma) irradiation experiments complemented by quantitative, multiscale modeling calculations, we present advances in our understanding of radiation-induced plutonium redox chemistry!

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Basic Energy Sciences Roundtable: Foundational Science to Accelerate Nuclear Energy Innovation

Energy security, availability, and reliability are among the greatest challenges facing the nation and the planet. An abundant potential source of energy resides in the fundamental atomic building blocks of the universe in the form of nuclear fission and fusion reactions. In fact, energy from nuclear fission currently provides the majority of the world’s zero-carbon electricity, and future fusion energy systems offer great promise; carbon-free nuclear energy technologies can be key to the world’s decarbonized energy future. Although contemporary fission systems use well-established technologies to supply safe and efficient baseload power, they could be more fuel efficient and less costly. Moving beyond massive light-water fission reactors to a variety of advanced nuclear systems—which will vary in size and operate in extremes of temperature, corrosivity, and other parameters—will place stringent conditions on materials and chemical systems. New demands will be placed on the coolants and solvents, the materials, and the monitoring tools used in these reactors. Fusion-based nuclear energy will require superior materials to withstand extremely high temperatures, plasma exposure, radiation damage, and implanted gases. The advantages associated with these new fission and fusion technologies will be realized only through continued advancements in the fundamental science underpinning our knowledge of the physics and chemistry of nuclear systems gained via improved experimental and computational methods. In July 2022, the U.S. Department of Energy’s Office of Basic Energy Sciences—in coordination with the Offices of Nuclear Energy, Fusion Energy Sciences, and Advanced Scientific Computing Research—held a virtual roundtable titled “Foundational Science to Accelerate Nuclear Energy Innovation” to discuss the scientific and technical barriers for advanced nuclear energy systems. Five priority research opportunities were identified to address these scientific and technical challenges and to accelerate progress toward the realization of next-generation fusion and fission energy systems. The foundational science gaps inhibiting the advancement of nuclear energy technologies are identified and tackled in five priority research opportunities. These opportunities pave the way to accelerate the development and ultimately the adoption of new nuclear energy systems. They include the fundamental aspects of ion-electron interactions; novel properties of next-generation coolants and solvents; interfacial dynamics, not only in solids, but in other aspects of nuclear reactors; novel operando and in situ monitoring and sensing; and artificial intelligence to accelerate condensed phases discovery. Building on the foundation established by previous Basic Energy Sciences workshops, these opportunities encompass recent advances in fundamental knowledge and focus on the experimental and computational methods needed to resolve major technical challenges for nuclear energy technologies. Through developing fundamental scientific insight as well as pushing the frontiers of modeling complex systems and probing the operation of materials and chemical systems in extreme environments, research motivated by the priorities identified here will further develop the promise, potential, and utilization of nuclear energy for a clean energy future.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Precision tests of fundamental physics with η and η ' mesons

Decays of the neutral and long-lived $\eta$ and $\eta'$ mesons provide a unique, flavor-conserving laboratory to test low-energy Quantum Chromodynamics and search for new physics beyond the Standard Model. They have drawn world-wide attention in recent years and have inspired broad experimental programs in different high-intensity-frontier centers. Additionally, new experimental data will offer critical inputs to precisely determine the light quark mass ratios, $\eta$-$\eta'$ mixing parameters, and hadronic contributions to the anomalous magnetic moment of the muon. At the same time, it will provide a sensitive probe to test potential new physics. This includes searches for hidden photons, light Higgs scalars, and axion-like particles that are complementary to worldwide efforts to detect new light particles below the GeV mass scale, as well as tests of discrete symmetry violation. In this review, we give an update on theoretical developments, discuss the experimental opportunities, and identify future research needed in this field.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

IntraShuffler: A Privacy Preserving Framework for Heterogeneous DP Federated Learning

Heterogeneous Differential Privacy (HDP) in Federated Learning (FL) allows clients to select individual privacy budgets () according to institutional policies and data sensitivity. In practice, many HDP-FL systems employ -aware server aggregation to improve model utility by re-weighting client updates according to their declared privacy budgets. However, gradient updates in FL retain structural patterns induced by non-independent and identically-distributed (non-IID) data, and these additional signals exposed by -aware aggregation create new opportunities for inference by an honest-but-curious server. In this work, we first show that a server equipped with gradient denoising and surrogate modeling can mount a Privacy Inference Attack that infers distributional attributes of clients and links updates from the same client across training rounds, measured via surrogate inference accuracy and linkage success, under realistic knowledge constraints. The Shuffle-Model has been widely studied as a defense against such inference risks by anonymizing update sources, but it is fundamentally incompatible with HDP-FL -aware aggregation. To address this challenge, we propose IntraShuffler, a middleware defense framework designed for HDP-FL systems. IntraShuffler introduces a privacy-aware shuffling mechanism that groups clients into privacy-compatible buckets and performs parameter-level shuffling within each bucket to disrupt persistent gradient structure while preserving -aware aggregation. Experiments across four different datasets show that IntraShuffler reduces gradient recoverability by over 60% and decreases surrogate inference accuracy from 0.78 to 0.33 while maintaining comparable model utility across multiple FL aggregation rules.

Riya, Farhin Farhad [ORNL]↗

A fast reduced model for a shell-and-tube based latent heat thermal energy storage heat exchanger and its application for cost optimal design by nonlinear programming

Numerical simulation of latent heat thermal energy storage (LHTES) systems plays a fundamental role in studying the physical process and guiding the engineering design. Discretization of the PDEs describing the nonlinear solidification/melting process of phase change materials (PCMs) leads to a large-scale complex dynamics system, where the system behavior depends on a set of parameters. In a design setting, repeated model evaluations are required over the set of parameters results in significant computational burden. In this paper, an explicit analytic solution was built for the propagation of the solidification front in a cylindrical coordinate. The analytic solution approach is further employed to develop a low computational reduced model (RM) as a module for a shell-and-tube based LHTES heat exchanger. The levelized Cost of Energy (LCOE) is used as a design metric and the RM model is used to apply system-level constraints in the nonlinear programming formulation that facilitates efficient global optimal design of the PCM properties, flow conditions and tube geometries. The use of LCOE as the design metric prevents over design of the heat transfer rate and also establishes a fair ground for evaluation of different thermal storage technologies and their integrated applications with other systems. Optimal results showed that a higher effectiveness results in a higher LCOE; the velocity of the HTF and the length of the channel are highly correlated with each other; both larger PCM latent energy and conductivity result in lower LCOE.

25 ENERGY STORAGE↗

Effect of negative triangularity on tearing mode stability in tokamak plasmas

Abstract The influence of negative triangularity (NT) of the plasma shape on the n = 1 (n is the toroidal mode number) tearing mode (TM) stability has been numerically investigated, with results compared to that of the positive triangularity (PT) counterpart. By matching the safety factor profile for a series of toroidal equilibria, several important plasma parameters, including the triangularity, the plasma equilibrium pressure, the plasma resistivity as well as the toroidal rotation, have been varied. The TM localized near the plasma edge is found to be more unstable in the NT plasmas as compared to the PT counterpart. The fundamental reason for this difference is the lack of favorable average curvature stabilization in NT configurations. Direct comparison of the Mercier index corroborates this conclusion. For the core-localized mode, where the difference in the local triangularity between NT and PT becomes small and the curvature stabilization is significantly reduced, larger Shafranov shift in the plasma core associated with the NT configuration results in more stable TM. The plasma toroidal flow generally stabilizes the TM in plasmas with both NTs and PTs. The flow stabilization is however weaker in the case of negative triangularity with finite plasma pressure.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Learning Many-Body Hamiltonians with Heisenberg-Limited Scaling

Learning a many-body Hamiltonian from its dynamics is a fundamental problem in physics. Here, in this Letter, we propose the first algorithm to achieve the Heisenberg limit for learning an interacting N-qubit local Hamiltonian. After a total evolution time of $\mathscr{O}$⁡(ε –1 ), the proposed algorithm can efficiently estimate any parameter in the N-qubit Hamiltonian to ε error with high probability. Our algorithm uses ideas from quantum simulation to decouple the unknown N-qubit Hamiltonian H into noninteracting patches and learns H using a quantum-enhanced divide-and-conquer approach. The proposed algorithm is robust against state preparation and measurement error, does not require eigenstates or thermal states, and only uses polylog⁡(ε –1 ) experiments. In contrast, the best existing algorithms require $\mathscr{O}$⁡⁡(ε –2 ) experiments and total evolution time. We prove a matching lower bound to establish the asymptotic optimality of our algorithm.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗