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At least 1,117 records · Page 62

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NASA NTRS1983

Compressive behavior of unidirectional fibrous composites

The longitudinal compressive behavior of unidirectional fiber composites was investigated by using the Illinois Institute of Technology Research Institute (IITRI) test method with thick and thin test specimens. The test data obtained are interpreted by means of stress/strain curves from back-to-back strain gages, examination of fracture surfaces by scanning electron microscope, and predictive equations for distinct failure modes including fiber compression failure. Euler buckling, delamination, and flexure. The results show that longitudinal compressive fracture is induced by a combination of delamination, flexure, and fiber tier breaks. No distinct fracture surface characteristics can be associated with unique failure modes. An equation is described that can be used to extract the longitudinal compressive strength from the longitudinal tensile and flexural strengths of the same composite system.

Sinclair, J. H.↗

NASA NTRS1984

Investigation of Toughened Neat Resins and Their Relations to Advanced Composite Mechanical Properties

Four epoxies (Hercules 3502, Hercules 2220-1 and 2220-3, and Ciba-Geigy Fibredux 914 epoxy) were evaluated to judge their merits within the ACEE program and also to provide material property input for a micromechanics finite element program. A casting procedure was developed for the four matrix systems mentioned and mechanical properties were studied at three test temperatures and two moisture contents. A scanning electron microscope study was performed to catalogue fracture surfaces for the unreinforced (neat) epoxies. In addition, tension testing, shear testing, a limited amount of fracture toughness testing, and thermal expansion coefficient and moisture expansion coefficient testing were carried out. Mechanical material properties were generated for input into a micromechanics program and to characterize these four matrix systems.

R. S. Zimmerman↗

NASA NTRS1984

Shock-induced CO2 loss from CaCO3: Implications for early planetary atmospheres

Recovered samples from shock recovery experiments on single crystal calcite were subjected to thermogravimetric analysis to determine the amount of post-shock CO2, the decarbonization interval and the activation energy, for the removal of remaining CO2 in shock-loaded calcite. Comparison of post-shock CO2 with that initially present determines shock-induced CO2 loss as a function of shock pressure. Incipient to complete CO2 loss occurs over a pressure range of approximately 10 to approximately 70 GPa. Optical and scanning electron microscopy reveal structural changes, which are related to the shock-loading. The occurrence of dark, diffuse areas, which can be resolved as highly vesicular areas as observed with a scanning electron microscope are interpreted as representing quenched partial melts, into which shock-released CO2 was injected. The experimental results are used to constrain models of shock-produced, primary CO2 atmospheres on the accreting terrestrial planets.

Lange, M. A.↗

NASA NTRS1984

Chondrule rims and interchondrule matrix in UOC

Opaque rims around chondrules and clasts were distinguished from opaque, interchondrule matrix apparently unrelated spatially to chondrules and clasts. Microprobe and electron microscope techniques were used. The mean chemical composition for dark rim and matrix in Bishunpur and Tieschitz are similar to the opaque matrix of Huss, et al. However, the mean dark rim compositions in Bishunpur have significantly higher Fe, and lower Na, K, Al and Si than opaque interchondrule matrix. The opaque matrix of Huss, et al, essentially lies between these compositions. In Tieschitz only rim material was observed. In Tieschitz the rims are Si-poor and dominated by normative olivine (Fo50). Again there is an Na, K, Al component but is often nepheline normative rather than albitic. It too is probably present as glass, Ashworth (pers.comm.). In Bishunpur rims as well as the silicate-FeS, FeNi layering described by Allen, et al, discontinuous layering was observed within the silicate portion. This is apparently due to variations in the proportions of the components, particularly in the glassy phase. In Bishunpur there is a strong genetic link between matrix and rims, although rims seem to have formed under different, possibly more oxidizing, conditions. Also the presence of the same component in rims, matrix chondrules, and clasts suggests a common source.

Alexander, C.↗

NASA NTRS1985

Lunar sample analysis

Recent results on the antarctic meteorite ALPHA 77003 which contribute to understanding the alteration processes which produced matrix in unequilibrated chondrites are presented. Also included are additional scanning electron microscope results confirming that the matrix in Allende was formed by in situ alteration.

Housley, R. M.↗

NASA NTRS1985

Characterization-curing-property studies of HBRF 55A resin formulations

Characterization curing property investigations on HBRF 55A resin formulations are reported. The initial studies on as received cured samples cut from a full-size FWC are reviewed. Inadequacies of as-received and aged samples are pointed out and additional electron microscopic evidence is offered. Characterization of as-received ingredients of HBRF 55A formulation is described. Specifically, Epon 826, Epon 828, EpiRez 5022, RD-2 and various amines, including Tonox and Tonox 60.40, were characterized. Cure kinetics of various formulations are investigated. Changes in physical/thermal properties (viscosity, specific heat, thermal conductivity and density) during cure are described.

Pearce, E. M.↗

NASA NTRS1985

Mechanical protection of DLC films on fused silica slides

Measurements were made with a new test for improved quantitative estimation of the mechanical protection of thin films on optical materials. The mechanical damage was induced by a sand blasting system using spherical glass beads. Development of the surface damage was measured by the changes in the specular transmission and reflection, and by inspection using a surface profilometer and a scanning electron microscope. The changes in the transmittance versus the duration of sand blasting was measured for uncoated fused silica slides and coated ones. It was determined that the diamond like carbon films double the useful optical lifetime of the fused silica. Theoretical expressions were developed to describe the stages in surface deterioration. Conclusions were obtained for the SiO2 surface mechanism and for the film removal mechanism.

Nir, D.↗

NASA NTRS1984

Spherical microglass particle impingement studies of thermoplastic materials at normal incidence

Light optical and scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluoroethylene (PTFE) and ultra-high-molecular-weight-polyethylene (UHMWPE). Erosion was caused by a jet of spherical micro-glass beads at normal impact. During the initial stages of damage, the surfaces of these materials were studied using a profilometer. Material buildup above the original surface was observed on PC and PMMA. As erosion progressed, this buildup disappeared as the pit became deeper. Little or no buildup was observed on PTFE and on UHMWPE. UHMWPE and PTFE are the most resistant materials and PMMA the least. Favorable properties for high erosion resistance seem to be high values of ultimate elongation, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibit incubation, acceleration and steady state periods. A continuously increasing erosion rate period was observed however for PMMA instead of a steady state period. At early stages of damage and at low impact pressure material removal mechanisms appear to be similar to those for metallic materials.

Veerabhadra Rao, P.↗

NASA NTRS1985

The determination of minority carrier lifetimes in direct band-gap semiconductors by monitoring intensity-modulated luminescence radiation

When an extrinsic, direct band-gap semiconductor sample is irradiated by photons of an energy higher than the energy of the band gap between valence and conduction bands, excess electron-hole pairs are generated which, while diffusing through the sample, produce luminescence via radiative recombination. If, furthermore, the intensity of the impinging beam of photons is modulated sinusoidally, the luminescence radiation escaping from the sample will be phase shifted with respect to the original photon beam in a characteristic way. It will be shown that by measuring the phase shift at different modulation frequencies, the Shockley-Read-Hall lifetime of minority carriers may be ascertained. The method is nondestructive inasmuch as there is no need to fabricate p-n junctions or Ohmic contacts, nor is it necessary to remove already existing Ohmic contacts of angle lap the surface, etc., procedures often needed when determining lifetimes with the scanning electron microscope (in which case a p-n junction must be present).

Von Roos, O.↗

NASA NTRS1985

Hydrated interplanetary dust particle linked with carbonaceous chondrites?

The results of transmission electron microscope observations of a hydrated interplanetary dust particle (IDP) containing Fe-, Mg-rich smectite or mica as a major phase are reported. The sheet silicate appears to have formed by alteration of anhydrous silicates. Fassaite, a Ca, Al clinopyroxene, also occurs in this particle, and one of the crystals exhibits solar-flare tracks, clearly indicating that it is extraterrestrial. Fassaite is a major constituent of the Ca-, Al-rich refractory inclusions found in the carbonaceous chondrites, so its presence in this particle suggests that there may be a link between hydrated IDPs and carbonaceous chondrites in the early history of the solar system.

Tomeoka, K.↗

NASA NTRS1984

Recombination-active defects in silicon ribbon and polycrystalline solar cells

This paper reports results from a study of recombination-active structural defects in silicon ribbon and polycrystalline solar cells using the electron beam induced current (EBIC) technique in a scanning electron microscope. It is demonstrated that low temperature EBIC measurements can reveal a range of defects that are not observable at room temperature, including slip dislocations in silicon dendritic web ribbons as well as decorated twin boundaries and dislocation complexes in cast polycrystalline silicon solar cell materials.

Cheng, L. J.↗

NASA NTRS1985

Lunar sample 14425 - Corrected analysis

A polished section of lunar sample 14425, an 8 mm glass bead, was studied using a scanning electron microscope and energy-dispersive X-ray analyzer. The silicon, aluminum, iron, magnesium, calcium, sodium, potassium, titanium, and chromium contents of the glass were determined. Two types of glass are visible in the polished section. One is clear and almost devoid of metallic spherules, while the other is cloudy and contains numerous metallic spherules, some less than one micron in size. Both glass types are homogeneous and identical in composition. This composition closely matches that of some Apollo 14 breccias or glass found in the breccias. The apparent similarity in composition between lunar sample 14425 and the high-magnesium microtektites found in a previous study was probably due to charging effects during analyses in which the sample was uncoated.

Glass, B. P.↗

NASA NTRS1986

Mapping the Structure of Heterogeneous Materials

Image-processing microdensitometer/Fourier analyzer yields statistics of subcomponent distribution. Nondestructive method for studying structure heterogeneous materials uses energy-dispersive X-ray analysis in scanning electron microscope. Scanning microdensitometer/Fourier analyzer (SMFA) is applied to SEM images to obtain statistics about sample structure. Method originally developed for studying effect on combustion of fine structure of composite solid propellants.

Strand, L. D.↗

NASA NTRS1985

Effects of real-time thermal aging on graphite/polyimide composites

As part of a program to evaluate high-temperature advanced composites for use on supersonic cruise transport aircraft, two graphite/polyimide composites have been aged at elevated temperatures for times up to 5.7 years. Work on the first, HT-S/710 graphite/polyimide, was started in 1974. Evaluation of the second polyimide, Celion 6000/LARC-160, began in 1980. Baseline properties are presented, including unnotched and notched tensile data as a function of temperature, compression, flexure, shear, and constant-amplitude fatigue data at R = 0.1 and R = -1. Tensile specimens were aged in ovens where pressure and aging temperatures were controlled for various times up to and including 50,000 hours. Changes in tensile strength were determined and plotted as a function of aging time. The HT-S/710 composite aged at 450 F and 550 F if compared to the Celion 6000/LARC-160 composite aged at 350 F and 450 F. After tensile testing, many of the thermal aging specimens were examined using a scanning electron microscope. Results of these studies are presented, and changes in properties and degradation mechanisms during high-temperature aging are discussed and illustrated using metallographic techniques.

Haskins, J. F.↗

NASA NTRS1985

Mechanical properties testing of candidate polymer matrix materials for use in high performance composites

The mechanical properties of four candidate neat resin systems for use in graphite/epoxy composites are characterized. This includes tensile and shear stiffnesses and strengths, coefficients of thermal and moisture expansion, and fracture toughness. Tests are conducted on specimens in the dry state and moisture-saturated, at temperatures of 23C, 82C and 121C. The neat resins tested are Hexcel HX-1504, Narmco 5245-C, American Cyanamid CYCOM 907, and Union Carbide ERX-4901A (MDA). Results are compared with those obtained for four other epoxy resins tested in a prior program, i.e., Hercules 3502, 2220-1, and 2220-3, and Ciba-Geigy Fibredux 914, as well as with available Hercules 3501-6 data. Scanning electron microscopic examination of fracture surfaces is performed to permit the correlation of observed failure modes with the environmental test conditions. A finite element micromechanics analysis is used to predict unidirectional composite response under various test conditions, using the measured neat resin properties as input data.

Zimmerman, R. S.↗

NASA NTRS1985

Fracture morphology of 2-D carbon-carbon composition

Out-of-plane tensile tests of a woven fabric carbon-carbon composite were performed in a scanning electron microscope equipped with a tensile stage and a videotape recording system. The composite was prepared from T-300 8-harness satin graphite fabric and a phenolic resin. The (0/90/0/90/0 sub 1/2) sub 2 laminate, with a Theta describing the orientation of the warp fibers of the fabric, was cured at 160 C and pyrolized at 871 C. This was followed by four cycles of resin impregnation, curing, and pyrolysis. A micrograph of the cross section of the composite is presented. Inspection of the specimen fracture surface revealed that the filaments had no residual matrix bonded to them. Further inspection revealed that the fracture was interlaminar in nature. Failure occurred where filaments of adjacent plies had the same orientation. Thus it is postulated that improvement in transverse tensile strength of 2-D carbon-carbon depends on the improvement of the filament-matrix bond strength.

Avery, W. B.↗

NASA NTRS1986

Surface film effects on drop tube undercooling studies

The effects of various gaseous atmospheric constituents on drop-tube solidified samples of elemental metals were examined from a microstructural standpoint. All specimens were prepared from the purest available elements, so effects of impurities should not account for the observed effects. The drop-tube gas has a definite effect on the sample microstructure. Most dramatically, the sample cooling rate is effected. Some samples receive sufficient cooling to solidify in free fall while others do not, splating at the end of the drop tube in the sample catcher. Gases are selectively absorbed into the sample. Upon solidification gas can become less soluble and as a result forms voids within the sample. The general oxidation/reduction characteristics of the gas also affect sample microstructures. In general, under the more favorable experimental conditions including reducing atmospheric conditions and superheatings, examination of sample microstructures indicates that nucleation has been suppressed. This is indicated by underlying uniform dendrite spacings throughout the sample and with a single dendrite orientation through most of the sample. The samples were annealed yielding a few large grains and single or bi-crystal samples were commonly formed. This was especially true of samples that were inadvertently greatly superheated. This is in contrast with results from a previous study in which surface oxides were stable and contained numerous sites of nucleation. The number of nucleation events depends upon the surface state of the specimen as determined by the atmosphere and is consistent with theoretical expectations based upon the thermodynamic stability of surface oxide films. Oxide-free specimens are characterized by shiny surfaces, with no observable features under the scanning electron microscope at 5000X.

Ethridge, E. C.↗

NASA NTRS1984

Volcanic impact on stratospheric aerosol chemistry

Samples collected by the National Center for Atmospheric Research (NCAR) using the multiple-filter sampler on the U-2 were analyzed. The sampler is capable of exposing a number of 110 mm filters in sequence to ram air flow. Two types of filters, IPC cellulose and polystrene, were used, both of which have high blank levels for the trace elements determined. The levels of most trace elements in the stratosphere are so low under normal circumstances that none can be seen. Results from the eruption of Mt. St. Helens, a mystery cloud (probably volcanic in origin) in 1982, and the El Chichonal eruption in 1983 are discussed. To improve the collection of particles for chemical analysis, a new sampling system was developed for use on the U-2. The sampler consisted of an electrostatic collection of particles between 1 and 0.001 micron diameter dierectly onto electron microscopic grids, followed by a thermal precipitation for the smaller particles. The system was built and tested in the laboratory, but never flown on the U-2.

Zoller, W. H.↗