Synthesis and Characterization of Anion-Exchange Membranes Using Semicrystalline Triblock Copolymers in Ordered and Disordered States
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99 GENERAL AND MISCELLANEOUS↗
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Photoinduced Dirac semimetal in ZrTe5
Abstract Novel phases of matter with unique properties that emerge from quantum and topological protection present an important thrust of modern research. Of particular interest is to engineer these phases on demand using ultrafast external stimuli, such as photoexcitation, which offers prospects of their integration into future devices compatible with optical communication and information technology. Here, we use MeV Ultrafast Electron Diffraction (UED) to show how a transient three-dimensional (3D) Dirac semimetal state can be induced by a femtosecond laser pulse in a topological insulator ZrTe 5 . We observe marked changes in Bragg diffraction, which are characteristic of bond distortions in the photoinduced state. Using the atomic positions refined from the UED, we perform density functional theory (DFT) analysis of the electronic band structure. Our results reveal that the equilibrium state of ZrTe 5 is a topological insulator with a small band gap of ~ 25 meV, consistent with angle-resolved photoemission (ARPES) experiments. However, the gap is closed in the presence of strong spin-orbit coupling (SOC) in the photoinduced transient state, where massless Dirac fermions emerge in the chiral band structure. The time scale of the relaxation dynamics to the transient Dirac semimetal state is remarkably long, τ ~ 160 ps, which is two orders of magnitude longer than the conventional phonon-driven structural relaxation. The long relaxation is consistent with the vanishing density of states in Dirac spectrum and slow spin-repolarization of the SOC-controlled band structure accompanying the emergence of Dirac fermions.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Towards an understanding of the resolution dependence of Core-Collapse Supernova simulations
ABSTRACT Using our new state-of-the-art core-collapse supernova (CCSN) code Fornax, we explore the dependence upon spatial resolution of the outcome and character of three-dimensional (3D) supernova simulations. For the same 19 M⊙ progenitor star, energy and radial binning, neutrino microphysics, and nuclear equation of state, changing only the number of angular bins in the θ and ϕ directions, we witness that our lowest resolution 3D simulation does not explode. However, when jumping progressively up in resolution by factors of two in each angular direction on our spherical-polar grid, models then explode, and explode slightly more vigorously with increasing resolution. This suggests that there can be a qualitative dependence of the outcome of 3D CCSN simulations upon spatial resolution. The critical aspect of higher spatial resolution is the adequate capturing of the physics of neutrino-driven turbulence, in particular its Reynolds stress. The greater numerical viscosity of lower resolution simulations results in greater drag on the turbulent eddies that embody turbulent stress, and, hence, in a diminution of their vigor. Turbulent stress not only pushes the temporarily stalled shock further out, but bootstraps a concomitant increase in the deposited neutrino power. Both effects together lie at the core of the resolution dependence we observe.
79 ASTRONOMY AND ASTROPHYSICS↗
Mean-field limit of a hybrid system for multi-lane car-truck traffic
In the present work we model multi-lane traffic flow in presence of two population of vehicles: cars and trucks. We first develop a finite-dimensional hybrid system which rely on continuous Bando-Follow-the-Leader dynamics coupled with discrete events motivated by the lane-change maneuvers. Then we rigorously prove that the mean-field limit is given by a system of Vlasov-type PDE with source terms generated by the lane-change maneuvers of the human-driven vehicles.
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
Stratospheric hydroxyl radical concentrations - New limitations suggested by observations of gaseous and particulate sulfur
A one-dimensional aerosol model is employed in investigating the sensitivity of the stratospheric distributions of gaseous sulfur compounds and sulfate aerosol particles to changes in OH and CS2 concentrations, in eddy diffusion coefficients, and in important chemical rate constants. By comparing model predictions with recent observational data for SO2, OCS, and particulates, it is found that, with regard to atmospheric sulfur, CS2 is only a secondary source of sulfur for the stratosphere relative to OCS and that background tropospheric CS2 concentrations by volume are likely to be less than 70 parts per trillion. It is also established that under stratospheric conditions the rate coefficients for the reactions of OH with OCS and CS2 may be substantially smaller than the room temperature laboratory values of Kurylo (1978).
Turco, R. P.↗
Ion current in a magnetic neutral region - Generation of an incipient magnetopause
The current contributed by ions trapped in the vicinity of a magnetic X line is calculated. The three dimensional configuration of the neutral region is found to be critical in determining the current in that the escape mechanism and trapping times depend on the three-dimensional aspects. A trapping criterion is defined. In the neutral region the ions can gain substantial kinetic energy, and the current will change the X line configuration in such a way that there will be a positive feedback effect, rapidly forming an extended magnetopauselike structure for even very small incident plasma densities.
Whipple, E. C.↗
Stability of absorption phenomena in laser-thermal propulsion
The mean flow and stability characteristics of laser absorption phenomena in a choked converging-diverging nozzle are considered. Calculations are presented for a given nozzle geometry and a series of laser intensities. Gas absorptivities corresponding to a hydrogen-cesium mixture are used with different initial temperatures being selected to investigate the effects of changes in the shape of the k-T curve. Both stability and mean flow calculations are limited to the one-dimensional case. The mean flow results show a decrease in mass flow as laser power is increased, along with increasingly steep temperature profiles. Calculations span regions of partial and complete absorption. One region is found where multiple solutions exist. Local stability results indicate the u-c characteristic is the only unstable mode in the unheated case. Laser heat addition makes this mode more unstable and also destabilizes the u-characteristic. Numerical calculations of disturbance propagation show that the instability of the u-c disturbances is counteracted by their reflection to u + c disturbances at the upstream end. The growth of the u-disturbances is localized in regions where the temperature profile is steep and they are damped in other regions. The increasing destabilization that is observed with increased laser power is probably the reason for difficulty in obtaining converged mean flow solutions at high laser intensities.
Merkle, C. L.↗
Plasma instability in the presence of negative ions
Ion density fluctuations are studied in a diffusion-controlled argon plasma containing, as a dilutant, two electron-attaching species, carbon dioxide and sulfur hexafluoride. It is found that the system becomes increasingly unstable as the concentration of the electron-attaching species is increased. Nonlinear mode-mode couplings have been identified and the coupling coefficients for these interactions have been computed. Turbulent fluctuations are observed to have pronounced three-dimensionality with distinct axial and azimuthal behaviors. The power spectra of these fluctuations are composed of many discrete modes. The importance of changes in the total discharge pressure is dependent on the electron-attachment cross section of the dilutant species. From these results it is shown that the ionization instability is probably responsible for the observed phenomenon.
Johnson, J. A., III↗
Overview of numerical codes developed for predicted electrothermal deicing of aircraft blades
An overview of the deicing computer codes that have been developed at the University of Toledo under sponsorship of the NASA-Lewis Research Center is presented. These codes simulate the transient heat conduction and phase change occurring in an electrothermal deicier pad that has an arbitrary accreted ice shape on its surface. The codes are one-dimensional rectangular, two-dimensional rectangular, and two-dimensional with a coordinate transformation to model the true blade geometry. All modifications relating to the thermal physics of the deicing problem that have been incorporated into the codes will be discussed. Recent results of reformulating the codes using different numerical methods to increase program efficiency are described. In particular, this reformulation has enabled a more comprehensive two-dimensional code to run in much less CPU time than the original version. The code predictions are compared with experimental data obtained in the NASA-Lewis Icing Research Tunnel with a UH1H blade fitted with a B. F. Goodrich electrothermal deicer pad. Both continuous and cyclic heater firing cases are considered. The major objective in this comparison is to illustrate which codes give acceptable results in different regions of the airfoil for different heater firing sequences.
Keith, Theo G.↗
The Effect of the Angle of Afterbody Keel on the Water Performance of a Flying-Boat Hull Model
NACA model 11-C was tested according to the general method with the angle of afterbody keel set at five different angles from 2-1/2 degrees to 9 degrees, but without changing other features of the hull. The results of the tests are expressed in curves of test data and of non-dimensional coefficients. At the depth of step used in the tests, 3.3 percent beam, the smaller angles of afterbody keel give greater load-resistance ratios at the hump speed and smaller at high speed than the larger angles of afterbody keel. Comparisons are made of the load-resistance ratios at several other points in the speed range. The effect of variation of the angle of afterbody keel upon the take-off performance of a hypothetical flying boat of 15,000 pounds gross weight having a hull of model 11-C lines is calculated, and the calculations show that the craft with the largest of the angles of afterbody keel tested, 9 degrees, takes off in the least time and distance.
Allison, John M.↗
Relationship between ozone and temperature trends in the lower stratosphere: Latitude and seasonal dependences
A one-dimensional radiative transfer model with fixed dynamical heating is used to calculate the approximate latitude and seasonal dependences of lower stratospheric temperature changes associated with observed ozone trends. The spatial and temporal distribution of ozone profile trends in the lower stratosphere is estimated from a combination of Nimbus 7 Solar Backscattered Ultraviolet (SBUV) global measurements of the ozone column below 32 mbar for the period 1979-1990 and balloon ozonesonde profile trends at northern middle latitudes. The calculated temperature trends near 100 mbar compare favorably with those recently derived by Randel and Cobb (1994) using data from Channel 4 of the Microwave Sounding Unit (MSU) on the NOAA operational satellites, although a number of quantitative differences are found. An independent analysis reported here of 100 mbar temperatures derived from northern hemisphere radiosonde data at the Free University of Berlin (FUB) supports the validity of the satellite-derived lower stratospheric temperature trends. These results are therefore generally consistent with the hypothesis that observed lower stratospheric cooling trends are predominantly determined by reductions in radiative heating associated with stratospheric ozone depletion.
Mccormack, John P.↗
Model Deformation Measurements at NASA Langley Research Center
Only recently have large amounts of model deformation data been acquired in NASA wind tunnels. This acquisition of model deformation data was made possible by the development of an automated video photogrammetric system to measure the changes in wing twist and bending under aerodynamic load. The measurement technique is based upon a single view photogrammetric determination of two dimensional coordinates of wing targets with a fixed third dimensional coordinate, namely the spanwise location. A major consideration in the development of the measurement system was that use of the technique must not appreciably reduce wind tunnel productivity. The measurement technique has been used successfully for a number of tests at four large production wind tunnels at NASA and a dedicated system is nearing completion for a fifth facility. These facilities are the National Transonic Facility, the Transonic Dynamics Tunnel, and the Unitary Plan Wind Tunnel at NASA Langley, and the 12-FT Pressure Tunnel at NASA Ames. A dedicated system for the Langley 16-Foot Transonic Tunnel is scheduled to be used for the first time for a test in September. The advantages, limitations, and strategy of the technique as currently used in NASA wind tunnels are presented. Model deformation data are presented which illustrate the value of these measurements. Plans for further enhancements to the technique are presented.
Burner, A. W.↗
Combined Effect of Contraction Ratio and Chamber Pressure on the Performance of a Gaseous Hydrogen-Liquid-Oxygen Combustor for a Given Propellant Weight Flow and Oxidant-Fuel Ratio
The effect of contraction ratio and chamber pressure on the combustion performance of a gaseous-hydrogen-liquid-oxygen combustor was investigated analytically and experimentally. The experiment was conducted with a "two-dimensional" gaseous-hydrogen-liquid-oxygen engine of about 150-pound thrust. The contraction ratio was varied from 1.5 to 6 by changing the nozzle throat area. This variation resulted in a chamber pressure variation of about 25 to 120 pounds per square inch. The experimental results were corrected for heat transfer to the engine walls and momentum pressure losses. The experimental performance, as evaluated in terms of characteristic exhaust velocity, was 98 percent of theoretical at contraction ratios greater than 3 but decreased very rapidly at smaller contraction ratios. The heat-transfer rate increased with increasing contraction ratio and chamber pressure; it was about 1 Btu per square inch per second at a contraction ratio of 1.5 and increased to about 3 at a contraction ratio of 6. The combined effects of contraction-ratio and chamber-pressure changes on performance were investigated analytically with a mixing model and a vaporization model. The mixing model predicted very poor mixing at contraction ratios below 3 and almost perfect mixing at higher contraction ratios. The performance predicted by the vaporization model was very close to 100 percent for all contraction ratios. From these results, it was concluded that the performance was limited by poor mixing at low contraction ratios and chamber pressures.
Hersch, Martin↗
Overview of NASA Multi-dimensional Stirling Convertor Code Development and Validation Effort
A NASA grant has been awarded to Cleveland State University (CSU) to develop a multi-dimensional (multi-D) Stirling computer code with the goals of improving loss predictions and identifying component areas for improvements. The University of Minnesota (UMN) and Gedeon Associates are teamed with CSU. Development of test rigs at UMN and CSU and validation of the code against test data are part of the effort. The one-dimensional (1-D) Stirling codes used for design and performance prediction do not rigorously model regions of the working space where abrupt changes in flow area occur (such as manifolds and other transitions between components). Certain hardware experiences have demonstrated large performance gains by varying manifolds and heat exchanger designs to improve flow distributions in the heat exchangers. 1-D codes were not able to predict these performance gains. An accurate multi-D code should improve understanding of the effects of area changes along the main flow axis, sensitivity of performance to slight changes in internal geometry, and, in general, the understanding of various internal thermodynamic losses. The commercial CFD-ACE code has been chosen for development of the multi-D code. This 2-D/3-D code has highly developed pre- and post-processors, and moving boundary capability. Preliminary attempts at validation of CFD-ACE models of MIT gas spring and "two space" test rigs were encouraging. Also, CSU's simulations of the UMN oscillating-flow fig compare well with flow visualization results from UMN. A complementary Department of Energy (DOE) Regenerator Research effort is aiding in development of regenerator matrix models that will be used in the multi-D Stirling code. This paper reports on the progress and challenges of this
Tew, Roy C.↗
The Surface Water and Ocean Topography Satellite Mission - An Assessment of Swath Altimetry Measurements of River Hydrodynamics
The Surface Water and Ocean Topography (SWOT) satellite mission, scheduled for launch in 2020 with development commencing in 2015, will provide a step-change improvement in the measurement of terrestrial surface water storage and dynamics. In particular, it will provide the first, routine two-dimensional measurements of water surface elevations, which will allow for the estimation of river and floodplain flows via the water surface slope. In this paper, we characterize the measurements which may be obtained from SWOT and illustrate how they may be used to derive estimates of river discharge. In particular, we show (i) the spatia-temporal sampling scheme of SWOT, (ii) the errors which maybe expected in swath altimetry measurements of the terrestrial surface water, and (iii) the impacts such errors may have on estimates of water surface slope and river discharge, We illustrate this through a "virtual mission" study for a approximately 300 km reach of the central Amazon river, using a hydraulic model to provide water surface elevations according to the SWOT spatia-temporal sampling scheme (orbit with 78 degree inclination, 22 day repeat and 140 km swath width) to which errors were added based on a two-dimension height error spectrum derived from the SWOT design requirements. Water surface elevation measurements for the Amazon mainstem as may be observed by SWOT were thereby obtained. Using these measurements, estimates of river slope and discharge were derived and compared to those which may be obtained without error, and those obtained directly from the hydraulic model. It was found that discharge can be reproduced highly accurately from the water height, without knowledge of the detailed channel bathymetry using a modified Manning's equation, if friction, depth, width and slope are known. Increasing reach length was found to be an effective method to reduce systematic height error in SWOT measurements.
Wilson, Matthew D.↗
TEMHD Effects on Solidification Under Microgravity Conditions
An unexplored potential exists to control microstructure evolution through the use of external DC magnetic fields. Thermoelectric currents form during solidification and interact with this external field to drive microscopic fluid dynamics within the inter-dendritic region. The convective heat and mass transport can lead to profound changes on the dendritic structure. In this paper the effect of high magnetic fields is demonstrated through the use of both 3-dimensional and 2-dimensional numerical models. The results show that the application of a magnetic field causes significant disruption to the dendritic morphology. Investigation into the underlying mechanism gives initial indicators of how external magnetic fields can either lead to unexpected growth behaviour, or alternatively can be used to control the evolution of microstructure in undercooled melts as encountered in levitated droplet solidification.
Kao, Andrew↗
The Gmao Hybrid 4d-Envar Observing System Simulation Experiment Framework.
This work describes the extension of the Global Modeling and Assimilation Office (GMAO) Observing System Simulation Experiment (OSSE) framework to use a hybrid 4D-EnVar scheme instead of 3D-Var. The original 3D-Var and hybrid 4D-EnVar OSSEs use the same version of the data assimilation system (DAS) so that a direct comparison is possible in terms of the validation with respect to their corresponding real cases. Rather than quantifying the differences between the two data assimilation methodologies, a short inter-comparison of upgrading from a 3D- to a 4D-OSSE is provided to highlight aspects where this change matters to the OSSE community and to identify features of data assimilation that can only be explored in a four-dimensional OSSE framework. A short validation of the hybrid 4D-EnVar OSSE shows that conclusions from previous assessments of the 3D-Var OSSE in its ability to mimic the behavior of the real system still hold with the same caveats. Furthermore, some aspects of the ensemble configuration and behavior are discussed along with forecast sensitivity to observation impacts (FSOI). Estimates of error standard deviations are shown to be smaller in the hybrid 4D-EnVar OSSE but with little impact on the character of the error. A discussion on future work directions focuses on exploring the four-dimensional aspect such as the error distribution within the assimilation window or four-dimensional handling of high-temporal density observations.
Data assimilation↗
Impact of Design Factors for ESA CCI Satellite Soil Moisture Data Assimilation over Europe
In this study, soil moisture retrievals of the combined active–passive ESA Climate Change Initiative (CCI) soil moisture product are assimilated into the Noah-MP land surface model over Europe using a one-dimensional ensemble Kalman filter and an 18-yr study period. The performance of the data assimilation (DA) system is evaluated by comparing it with a model-only experiment (at in situ sites) and by assessing statistics of innovations and increments as DA diagnostics (over the entire domain). For both assessments, we explore the impact of three design choices, resulting in the following insights. 1) The magnitude of the assumed observation errors strongly affects the skill improvements evaluated against in situ stations and internal diagnostics. 2) Choosing between climatological or monthly cumulative distribution function matching as the observation bias correction method only has a marginal effect on the in situ skill of the DA system. However, the internal diagnostics suggest a more robust system parameterization if the observations are rescaled monthly. 3) The choice of atmospheric reanalysis dataset to force the land surface model affects the model-only skill and the DA skill improvements. The model-only skill is higher with input from the MERRA-2 than with input from the ERA5 reanalysis, resulting in larger DA skill improvements for the latter. Additionally, we show that the added value of the DA strongly depends on the quality of the satellite retrievals and land cover, with the most substantial soil moisture skill improvements occurring over croplands and skill degradation occurring over densely forested areas.
Soil moisture↗