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At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Identification and properties of molecular systems of potential use in solar-pumped lasers

The concepts and computational tools of theortical chemistry are used to investigate molecular properties needed in direct solar-pumped lasers. Compounds of the type RR'CXY, with R and R' organic groups, and X and Y halide atoms were identified as likely candidates because of their highly enhanced absorption coefficients over compounds with a single halide atom. The use of a combination of vibrational excitation followed by electronic excitation to enhance quantum yields at certain wavelengths is indicated. A self-consistent eikonal approximation to state-to-state transitions was tested for CH3I and is useful for other problems involving electronic energy and charge transfer. An approach to calculate potential energy surfaces and transition dipoles was developed which is based on the generation of eigenstates of the nonrelativisitc Hamiltonian followed by incorporation of the spin-orbit coupling by configuration interaction.

Micha, D. A.↗
NASA NTRS1985

Phenomena Simulation for Heavy Doping and Surface Recombination Velocity

The theoretical models now available that characterize heavily doped (highly conducting) regions in silicon are survyed. Analytical and numerical approaches that determine the influence of such regions on the conversion efficiency of solar cells are examined. Although dilutely doped silicon is well characterized except for some disagreement about optical absorption coefficients, what exists now for heavily doped silicon and its interplay with adjoining regions is an incomplete theory in which not all contributers to transport, recombination, generation, and trapping are defined. Further, the parameters relating to these mechanisms and their values as determined by experiment are subject to various interpretations. The characterization of heavily doped silicon is treated not as a theory but rather as an imperfectly articulated and incompletely formalized body of experience. This view is intended to help point the way toward the attainment of a more complete of heavily doped silicon and thereby toward more informed designs of solar cells. Because computer programs constitute tools both for design and for estimating performance limits, the review includes some remarks pertinent to existing and developing programs.

Lindholm, F. A.↗
NASA NTRS1983

Analysis of 12-700 micron reflectance spectra of three optical black samples

Normal incidence, specular reflectance spectra of three samples of optical black coatings have been measured in 10 filter passbands at effective wavelengths between 12 and 700 microns. Strong absorption, due to amorphous silicate material in the coatings, is found in the 15-50 micron region of each spectrum. Reflecting-layer model calculations are fitted by a nonlinear least-squares routine to the spectra at wavelengths beyond the absorption band to determine far-infrared optical parameters. It is found that, with a similar wavelength dependence, the absorption coefficient of a new black coating (ECP 2200) made by the Minnesota Mining and Manufacturing Company (3M) is less than 1/10 that of the discontinued coating, 3M Black Velvet Nextel. It is also shown that the extinction effect of a very rough substrate is negligible compared with the effects of increased upper surface roughness and coating thickness attendant upon fully covering a very rough substrate.

Smith, S. M.↗
NASA NTRS1985

Far-infrared spectrum of IRC + 10216

Far-infrared observations of IRC + 10216 in the wavelength range 20-160 microns are presented. The observations were performed simultaneously in four bands with effective wavelengths of 21, 42, 73, and 135 microns, respectively. The scan profile across the source at 21 microns is found to be wider than that for a point source. Interpreting the far-infrared spectrum on the basis of a model in which circumstellar grains are heated by a central source, the radial density dependence is r exp -2, and the emissivity dependence is lambda exp -n, it is found that n = 1-1.2. Time variations of a smaller magnitude at longer wavelengths as compared to the variation at near-infrared wavelengths can also be understood on the basis of this model. Using the mass-loss rate derived from CO observations, the mass absorption coefficient of the grains at 100 microns is found to be not less than 40/sq cm g.

Rengarajan, T. N.↗
NASA NTRS1985

Laboratory infrared spectra of predicted condensates in carbon-rich stars

Laboratory spectra and mass absorption coefficients of MgS, CaS, FeS, SiS2, FeS2, Fe3C, and a commercial iron carbide are presented over the wavelength range 125-15 microns. These spectra confirm that MgS is the most likely source of the unidentified 30-micron emission in carbon-rich sources and that FeS, Fe3C, and 'iron carbide' cannot be responsible for this feature although they could contribute to the continuum in this region. CaS and FeS2 may contribute to the 30-micron feature; however, both higher resolution and higher precision astronomical observations are needed before their presence can be established. SiS2 has a peak near 22 microns and therefore cannot be a significant component of the dust in such regions.

Nuth, J. A.↗
NASA NTRS1985

A theory for the 2f(p) radiation upstream of the earth's bow shock

The mechanism responsible for the radiation observed near the earth bow shock at twice the plasma frequency f(p) is investigated theoretically. A model comprising two three-wave steps and involving Langmuir (L), ion-sound (S), and EM (t) waves is proposed: L + or - S yields L-prime; L + L-prime yields t. This model is shown to be consistent with observations of low-frequency S-like waves (Anderson et al., 1981), and further observational tests are suggested. A critical examination of the theory of Fung et al. (1982) is included, and it is found that an important term in the absorption coefficient was neglected. Correcting this error leads to an intrinsic theoretical brightness-temperature limit of 3 x 10 to the 9th K, well below the observed brightness temperature of the 2 f(p) radiation, about 10 to the 11th K.

Cairns, I. H.↗
NASA NTRS1985

Bremsstrahlung in the scattering of low-energy electrons by neutral atomic systems

By elementary methods, the cross section for electron-atom and electron-molecule bremsstrahlung is computed in the limit when the incident electron energy is much less than Ry. The procedure employs the classical soft-photon emission probability formula for general (h/2pi)(omega), yielding a simple expression for the bremsstrahlung cross section in terms of the total elastic scattering cross section. The validity of the method is discussed, and results are compared with more elaborate and accurate calculations. Comparison is made with ('free-free') opacity calculations for the associated process at the temperature (6300 K) of the solar atmosphere. For chi sub omega = (h/2pi)(omega)/kT = 1, the computed absorption coefficient is within 2, 7, and 12 percent of accurate calculations for scatterings by H, He, and H2, respectively. The general dependence of the opacity on chi sub omega is described well by the simple formula, although the error is larger for higher chi sub omega; it is suggested that the inaccuracy at high frequencies is due to the failure of the soft-photon approximation.

Gould, R. J.↗
NASA NTRS1984

A simple method of obtaining concentration depth-profiles from X-ray diffraction

The construction of composition profiles from X-ray intensity bands was investigated. The intensity band-to-composition profile transformation utilizes a solution which can be easily evaluated. The technique can be applied to thin films and thick speciments for which the variation of lattice parameters, linear absorption coefficient, and reflectivity with composition are known. A deconvolution scheme with corrections for the instrumental broadening and ak-alfadoublet is discussed.

Wiedemann, K. E.↗
NASA NTRS1986

Radiative coupled nonequilibrium flow fields associated with aeroassisted orbital transfer

Development of an algorithm which will allow nonequilibrium flow field codes to be coupled to radiative transfer codes (currently limited to equilibrium applications) was initiated. The algorithm consists of an equation for the prediction of electronic state population fractions (electronic state temperature) and equations for the computation of spectral absorption coefficients and source functions. These expressions represent a thorough treatment in the context of the bandless model which in the past has proven adequate for equilibrium radiative transfer predictions. Perhaps the approach is more than adequate as the current algorithm requires four temperatures for each transition. Clearly, a more sophisticated model can be developed; however, it would require more information, such as rotational temperatures of the electronic levels.

Horton, T. E.↗
NASA NTRS1985

Modeling of pressure-induced far-infrared absorption spectra Molecular hydrogen pairs

Meyer et al. (1985) have calculated the accurate induced dipole moment function of H2-H2 from first principles, using highly correlated wave functions for the first time in such work. The present paper is concerned with the collision-induced translational-rotational absorption coefficient for molecular hydrogen pairs, taking into account computations on the basis of the fundamental theory considered by Meyer et al. Data have been obtained for temperatures in the range from 40 to 300 K. Criteria are developed for choosing among various model line shapes. It is found that certain models are capable of approximating the quantum profiles closely, with rms errors of only a few percent.

Borysow, J.↗
NASA NTRS1986

He-Ne and CW CO2 laser long-path systems for gas detection

This paper describes the design and testing of a laboratory prototype dual He-Ne laser system for the detection of methane leaks from underground pipelines and solid-waste landfill sites using differential absorption of radiation backscattered from topographic targets. A laboratory-prototype dual CW carbon dioxide laser system also using topographic backscatter is discussed, and measurement results for methanol are given. With both systems, it was observed that the time-varying differential absorption signal was useful in indicating the presence of a gas coming from a nearby source. Limitations to measurement sensitivity, especially the role of speckle and atmospheric turbulence, are described. The speckle results for hard targets are contrasted with those from atmospheric aerosols. The appendix gives appropriate laser lines and values of absorption coefficients for the hydrazine fuel gases.

Grant, W. B.↗
NASA NTRS1985

Mass fluxes and magnetic structures in the chromosphere and the transition region - Canopies

Preliminary results of applying a model of canopy-type magnetic lines to account for observed mass fluxes in the chromosphere and transiton region are presented. A set of center-to-limb data obtained in H-alpha and C IV, and to which the model is applied, is reported. The C IV line is assumed to form everywhere at the same height, and the H-alpha formation height is derived by assuming that the absorption coefficient is proportional to the local density. The density ratio between H-alpha and C IV levels is taken to be 100. From the results, it is concluded that the model accounts for the low ratio of radial velocities C IV/H-alpha at r = 0, the increase of H-alpha velocity near the limb, and the general center-to-limb behavior in both lines.

Mein, P.↗
NASA NTRS1986

Detection of NO sub x,C2H4 concentrations by using CO and CO2 lasers

A laser, especially the infrared line tunable laser, opens up a new way to monitor the atmospheric environment, and already has gotten effective practical application. One of the most serious problems in open path remote measurement at atmospheric pressure is the broadening effect which leads to increased linewidths, spectral interferences, and, as a result, tends to reduce detection sensitivity, so measuring laser wavelengths should be selected carefully, and interaction between the measuring wavelength and gas to be measured must be known very well. Therefore, N2O, No, NO2, CH4, NH3 and C2H4 absorption properties at some lines of CO and CO2 line tunable lasers were studied. The absorption coefficients of NO, NO2, and C2H4; some results on detection of NO sub x, C2H4 concentrations in both laboratory and field; and selection of measuring wavelengths and error analysis are discussed.

Gengchen, W.↗
NASA NTRS1987

Documentation of the space station/aircraft acoustic apparatus

This paper documents the design and construction of the Space Station/Aircraft Acoustic Apparatus (SS/AAA). Its capabilities both as a space station acoustic simulator and as an aircraft acoustic simulator are described. Also indicated are the considerations which ultimately resulted in man-rating the SS/AAA. In addition, the results of noise surveys and reverberation time and absorption coefficient measurements are included.

Clevenson, Sherman A.↗
NASA NTRS1987

Calculations of the displacement damage and short-circuit current degradation in proton irradiated (AlGa)As-GaAs solar cells

A theoretical model for computing the displacement damage defect density and the short-circuit current (I sub sc) degradation in proton-irradiated (AlGa)As-GaAs p-n junction solar cells is presented. Assumptions were made with justification that the radiation induced displacement defects form an effective recombination center which controls the electron and hole lifetimes in the junction space charge region and in the n-GaAs active layer of the irradiated GaAs p-n junction cells. The degradation of I sub sc in the (AlGa)As layer was found to be negligible compared to the total degradation. In order to determine the I sub sc degradation, the displacement defect density, path length, range, reduced energy after penetrating a distance x, and the average number of displacements formed by one proton scattering event were first calculated. The I sub sc degradation was calculated by using the electron capture cross section in the p-diffused layer and the hole capture cross section in the n-base layer as well as the wavelength dependent absorption coefficients. Excellent agreement was found between the researchers calculated values and the measured I sub sc in the proton irradiated GaAs solar cells for proton energies of 100 KeV to 10 MeV and fluences from 10 to the 10th power p/square cm to 10 to the 12th power p/square cm.

Yeh, C. S.↗
NASA NTRS1986

R Coronae Borealis stars and planetary nebulae

IRAS observations of R Coronae Borealis type stars (R CrB's) suggests that a subset of these is inside planetary nebulae (PNs). In most cases, the PN is confirmed by the finding of a visible nebula around the star. These nebular R CrB's are identified as being the results of a final helium shell flash on the central star of old PNs. The majority of the R CrB's formed after the coalescence of a binary consisting of CO and He white dwarfs. Also presented in this paper are the results of a survey of 52 R CrB's. The normal R CrB's have power-law spectra which imply that the grain absorption coefficient varies linearly with frequency. It is estimated that R CrB's eject about 300 clouds per year, each of which subtend an angle of about 30 sq deg.

Schaefer, B. E.↗
NASA NTRS1985

Use of a corrugated surface to enhance radiation tolerance in a GaAs solar cell

The use of a corrugated surface on a GaAs solar cell and its effects on radiation resistance were studied. A compute code was developed to determine the performance of the cell for various geometric parameters. The large optical absorption coefficient of GaAs allows grooves to be only 4-5 micrometers deep. Using accepted material parameters for GaAs solar cells the theoretical performances were compared for various corrugated cells before and after minority carrier diffusion length degradation. The total power output was maximized for both n(+)/p and p(+)/n cells. Optimum values of 1.0-1.5 and 5.0 micrometers for groove and ridge widths respectively were determined.

Leon, Rosa P.↗