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NASA NTRSDate not supplied

Ground Segment Operations Concept for the Orion Artemis-2 Optical Communications System

The ACCESS Project (formerly Space Network) will implement an optical communications ground segment to support the Orion Artemis II Optical Communications (O2O) demonstration as part of the next manned human spaceflight mission to the moon, Artemis II. O2O implements laser communication (lasercomm) technology for operational use on the Orion series of spacecraft, as a development test objective (DTO), in order to demonstrate the feasibility and operational utility of lasercomm for human spaceflight missions. O2O consists of three segments: Space Segment, Ground Segment, and Operations Segment. The Space Segment consists of the Space Terminal Element and the Orion spacecraft. The Space Terminal Element effort is managed by the GSFC Laser-Enhanced Mission Communications Navigation and Operational Services (LEMNOS) project in collaboration with MIT Lincoln Laboratory. The Ground Segment consists of an optical ground terminal (GT) at the White Sands Complex (WSC), which is being developed in collaboration with MIT Lincoln Laboratory, the Ground Segment Operations and Analysis (GSOA) element and Ground Data Element (GDE), and a second optical GT in the Optical Communications Telescope Laboratory (OCTL) at the JPL Table Mountain Facility. The Operations Segment consists of the Artemis II Mission Control Center (MCC), the Lasercomm Space Terminal Console (LSTC), and the Lasercomm Link Planning & Analysis Center (LPAC), all located at the Johnson Space Center (JSC). O2O utilizes pulse-position modulation (PPM) direct-to-earth services resulting in an 80 Mbps downlink data rate from lunar orbit. The O2O concept of operations is to provide optical services for a minimum of 1 hour per day for each day of the Artemis II mission. O2O will utilize a 10-20 Mbps uplink data rate and 40-260 Mbps downlink data rate, depending on the Artemis II mission phase. The ACCESS project will also provide a centralized mission data interface for user data distribution and storage to the MCC and perform planning and scheduling of services in coordination with the Operations Segment for the O2O Ground Segment. The O2O Ground Segment will support the following O2O mission phases: Pre-Mission Planning; Daily Operations Planning; Event Execution; and Post-Pass Reporting. O2O will be used to exchange data files between Orion and the MCC and to distribute real-time video through the optical downlink service to the MCC; which would not be possible without the high-bandwidth link that O2O will provide to Orion. In this paper, I will discuss the O2O Ground Segment development approach and how it will support these critical O2O functions: plan and schedule the contact; acquire and track the optical link; flow information bidirectionally; distribute information; and control and accommodate the system.

optical communications↗
DOE OSTI2021

Multi-fluid and kinetic models of partially ionized magnetic reconnection

Magnetic reconnection in partially ionized plasmas is a ubiquitous and important phenomenon in both laboratory and astrophysical systems. Here, simulations of partially ionized magnetic reconnection with well-matched initial conditions are performed using both multi-fluid and fully-kinetic approaches. Despite similar initial conditions, the time-dependent evolution differs between the two models. In multi-fluid models, the reconnection rate locally obeys either a decoupled Sweet–Parker scaling, where neutrals are unimportant, or a fully coupled Sweet–Parker scaling, where neutrals and ions are strongly coupled, depending on the resistivity. In contrast, kinetic models show a faster reconnection rate that is proportional to the fully-coupled, bulk Alfvén speed, $v^*_A$. In this work, these differences are interpreted as the result of operating in different collisional regimes. Multi-fluid simulations are found to maintain $ν_{ni}L/v^*_A$ ≳1, where $ν_{ni}$ is the neutral–ion collision frequency and L is the time-dependent current sheet half-length. This strongly couples neutrals to the reconnection outflow, while kinetic simulations evolve to allow $ν_{ni}L/v^*_A$ <1, decoupling neutrals from the reconnection outflow. Differences in the way reconnection is triggered may explain these discrepancies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1984

Report of the Panel on Propulsion

Propulsion, while conventionally included on the list of important aeronautical disciplines along with aerodynamics, structures, etc., is in itself a systems endeavor, analogous to the engineering of the entire vehicle; indeed propulsion encompasses important aspects of all the other disciplines. In recognition of this fact, the panel focused its discussion on those aspects of the key disciplines that are especially or uniquely important to propulsion. From the initial development of the airplane, the propulsion system has been recognized as one of the pacing technologies. It is perhaps because of the technological disparity between the reciprocating engine and the primitive airframe that the two remained relatively and separate, were developed somewhat independently, usually by different organizations. In recent years, the maturing of the gas turbine power plant and the advance in high-speed airframes have rendered this separation somewhat artificial. The power plant and the airframe now share common structural and aerodynamic elements; as the flight Mach number rises, the degree of interaction increases. By the year 2000, this interdependence will have increased in many respects to a point where independent design may not be practical or possible. During the period since the initiation of the aircraft gas turbine, the solid propellant rocket and the liquid propellant rocket, a vast array of other novel engines have been studied, covering the full spectrum of flight conditions from low subsonic to hypersonic and transatmospheric flight. In each instance, performance limits have been investigated under the assumption that current technology or reasonably foreseeable technology would be available for their development. Among the extensive list of advanced, high-performance concepts and cycles examined are the hypersonic ramjet, the variable cycle, runway-to-orbit airbreathing engine, the ram rocket (airbreathing and rich solid propellant rocket), and the air turborocket. At various times, these systems have come relatively close to meriting development and application. In many instances, limitations of materials and technologies curtailed development. As important and with almost equal frequency, the lack of commercial or military utility of the concept precluded the necessary funding. It is instructive to note that two former items on this list, the turbofan (bypass engine) and the high-speed turboprop, are respectively a mainstay engine and a promising development. In the case of the turbofan, its full potential could not be realized until turbine cooling technology had been developed and new materials developed to permit the construction of transonic fans. In the case of the highspeed turbopropeller engine, not only were the material and turbine technologies needed, but, in addition, the rise in fuel costs provided the impetus to take advantage of its favorable fuel consumption characteristic. As the basic technologies progress and as new missions become attractive, the engines in the foregoing list become candidates for new feasibility studies and further technology development. At the present time, the ram rocket is the prime contender to augment the range of small missiles. Of interest also is the hypersonic ram jet and its logical extension, the runway-to-orbit airbreathing engine. Much of this report deals with the development of current or near-future power plant concepts. First, the motivating factors for aeronautical propulsion research are reviewed as a reminder of the importance of continued effort in a field that has often been characterized as mature. Next, technical areas are discussed in which the panel feels additional research effort is warranted and would lead to the realization of the technological potentials between now and the year 2000. Under these guidelines, new cycles (e.g., isothermal energy exchange) were not considered by the panel. Finally, although facility requirements were not a prime consideration in the current projections, the panel believes that the increasing complexity of propulsion systems; the need for more refined interaction between propulsion system, airframe, and controls; and increasing operation in adverse weather will require test capabilities beyond those now available (see appendix). Enhanced test capability is needed in the areas of propulsion airframe integration and in largescale icing research with proper concurrent treatment of altitude, temperature, and speed.

Kerrebrock, Jack L.↗
DOE OSTI2019

Equation of state of boron nitride combining computation, modeling, and experiment

The equation of state (EOS) of materials at warm dense conditions poses significant challenges to both theory and experiment. We report a combined computational, modeling, and experimental investigation leveraging new theoretical and experimental capabilities to investigate warm-dense boron nitride (BN). The simulation methodologies include path integral Monte Carlo (PIMC), several density functional theory (DFT) molecular dynamics methods [plane-wave pseudopotential, Fermi operator expansion (FOE), and spectral quadrature (SQ)], activity expansion (actex), and all-electron Green's function Korringa-Kohn-Rostoker (mecca), and compute the pressure and internal energy of BN over a broad range of densities and temperatures. Our experiments were conducted at the Omega laser facility and the Hugoniot response of BN to unprecedented pressures (1200–2650 GPa). The EOSs computed using different methods cross validate one another in the warm-dense matter regime, and the experimental Hugoniot data are in good agreement with our theoretical predictions. By comparing the EOS results from different methods, we assess that the largest discrepancies between theoretical predictions are ≲ 4% in pressure and ≲ 3% in energy and occur at 10 6 K, slightly below the peak compression that corresponds to the K -shell ionization regime. At these conditions, we find remarkable consistency between the EOS from DFT calculations performed on different platforms and using different exchange-correlation functionals and those from PIMC using free-particle nodes. This provides strong evidence for the accuracy of both PIMC and DFT in the high-pressure, high-temperature regime. Moreover, the recently developed SQ and FOE methods produce EOS data that have significantly smaller statistical error bars than PIMC, and so represent significant advances for efficient computation at high temperatures. The shock Hugoniot predicted by PIMC, actex, and mecca shows a maximum compression ratio of 4.55 ± 0.05 for an initial density of 2.26 g/cm 3 , higher than the Thomas-Fermi predictions by about 5%. In addition, we construct tabular EOS models that are consistent with the first-principles simulations and the experimental data. Our findings clarify the ionic and electronic structure of BN over a broad range of temperatures and densities and quantify their roles in the EOS and properties of this material. The tabular models may be utilized for future simulations of laser-driven experiments that include BN as a candidate ablator material.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Estimating CO 2 fluxes through integrating spatial and temporal input layers via deep learning algorithms

Background Accurate estimation of net ecosystem exchange of CO 2 fluxes (Fc) is essential for understanding carbon cycle processes and assessing ecosystem carbon budgets. However, conventional modeling approaches often emphasize temporal dynamics while overlooking the pronounced spatial heterogeneity within the footprint of eddy covariance (EC) towers, potentially limiting predictive accuracy and interpretability of Fc estimates. To address this challenge, we developed a spatiotemporal model that integrates high-resolution footprint-weighted spatial information with sequential environmental drivers. Results The integrated model combines a deeper graph convolutional network to characterize fine-scale spatial variability within EC footprints and a gated recurrent unit network to capture temporal dependencies in biophysical conditions. Using multi-year flux tower observations, remote sensing vegetation indices and footprint modeling, we evaluate the proposed method across three land cover types. This spatiotemporal model consistently outperforms temporal-only and spatial-only baselines, achieving the highest overall accuracy (R 2 = 0.9569) and the lowest RMSE (1.8128 μmol m −2 s −1 ) and MAE (1.1939 μmol m −2 s −1 ). Performance gains are particularly evident in ecosystems with strong vegetation heterogeneity, where spatial structure substantially modulates Fc variability. Conclusions This study demonstrates the importance of joint modeling spatial heterogeneity and temporal dynamics for improving Fc estimation and provides a robust method for advancing footprint-based Fc estimates across diverse ecosystems, supporting refined assessments of terrestrial carbon fluxes, and enhancing scientific foundations for carbon studies.

CO2 flux estimate↗
NASA NTRS2020

ATD-2 Benefits Mechanism

NASA has been developing and demonstrating a suite of decision support capabilities for integrated arrival, departure, and surface (IADS) operations in a metroplex environment. The effort is being made in three phases, under NASA’s Airspace Technology Demonstration 2 (ATD-2) sub-project, through a close partnership with the Federal Aviation Administration (FAA), air carriers, airport, and general aviation community. The Phase 1 Baseline IADS capabilities provide enhanced operational efficiency and predictability of flight operations through data exchange and integration, tactical surface metering, and automated coordination of release time of controlled flights for overhead stream insertion. The Phase 2 Fused IADS capabilities include the fusion of strategic and tactical surface metering, Atlanta Center airspace tactical scheduling, Electronic Flight Data (EFD) integration, Terminal Flight Data Manager (TFDM) Terminal Publication (TTP) prototype, and Mobile App for General Aviation (GA) community. In the Phase 2 field evaluation, strategic surface metering provides advance notice of metering and additional stability to the assigned gate holds. The users of the IADS system in Phases 1 and 2 include the personnel at Charlotte Douglas International Airport (CLT) air traffic control tower, American Airlines ramp tower, CLT terminal radar approach control (TRACON), and Washington and Atlanta Center. This document describes the ATD-2 benefits mechanism used to assess the Phases 1 and 2 IADS capabilities and field evaluation conducted at CLT since September 2017. The ATD-2 benefits mechanism mainly consists of surface metering and overhead stream insertion. This document provides detailed calculation methods of major benefit metrics, such as fuel savings, gas emissions savings, and engine runtime reduction, which can be obtained through surface metering, gate hold of Approval Request (APREQ) flights prior to pushback, and the renegotiation of release time while taxiing. As of March 31, 2020, it is estimated that 5,075,981 pounds of fuel savings and 15,634,022 pounds of CO2 emission reduction have been achieved so far, with a reduction of 3,832 hours in total engine runtime. The amount of CO2 savings is estimated to be equivalent to planting 116,254 urban trees. The pre- and post-metering comparison results using FAA’s Aviation System Performance Metrics (ASPM) data have also shown that the surface metering had no negative impact on the on-time arrival performance of both outbound and inbound flights at CLT.

ATD-2↗
NASA NTRS2020

ATD-2 Benefits Mechanism

NASA has been developing and demonstrating a suite of decision support capabilities for integrated arrival, departure, and surface (IADS) operations in a metroplex environment. The effort is being made in three phases, under NASA’s Airspace Technology Demonstration 2 (ATD-2) sub-project, through a close partnership with the Federal Aviation Administration (FAA), air carriers, airport, and general aviation community. The Phase 1 Baseline IADS capabilities provide enhanced operational efficiency and predictability of flight operations through data exchange and integration, tactical surface metering, and automated coordination of release time of controlled flights for overhead stream insertion. The Phase 2 Fused IADS capabilities include the fusion of strategic and tactical surface metering, Atlanta Center airspace tactical scheduling, Electronic Flight Data (EFD) integration, Terminal Flight Data Manager (TFDM) Terminal Publication (TTP) prototype, and Mobile App for General Aviation (GA) community. In the Phase 2 field evaluation, strategic surface metering provides advance notice of metering and additional stability to the assigned gate holds. The users of the IADS system in Phases 1 and 2 include the personnel at Charlotte Douglas International Airport (CLT) air traffic control tower, American Airlines ramp tower, CLT terminal radar approach control (TRACON), and Washington and Atlanta Center. This document describes the ATD-2 benefits mechanism used to assess the Phases 1 and 2 IADS capabilities and field evaluation conducted at CLT since September 2017. The ATD-2 benefits mechanism mainly consists of surface metering and overhead stream insertion. This document provides detailed calculation methods of major benefit metrics, such as fuel savings, gas emissions savings, and engine runtime reduction, which can be obtained through surface metering, gate hold of Approval Request (APREQ) flights prior to pushback, and the renegotiation of release time while taxiing. As of April 30, 2020, it is estimated that 5,097,173 pounds of fuel savings and 15,699,292 pounds of CO2 emission reduction have been achieved so far, with a reduction of 3,831 hours in total engine runtime. The amount of CO2 savings is estimated to be equivalent to planting 116,739 urban trees. The pre- and post-metering comparison results using FAA’s Aviation System Performance Metrics (ASPM) data have also shown that the surface metering had no negative impact on the on-time arrival performance of both outbound and inbound flights at CLT.

ATD-2↗
DOE OSTI2026

Aligning NASA Earth Science Data Stewardship with FAIR Principles: Outcomes, Recommendations, and Future Directions

The FAIR Principles—Findable, Accessible, Interoperable, and Reusable—offer a widely accepted framework for improving the sharing and reuse of digital scientific data by both human and machine users. Following these principles is critical for effective scientific data stewardship, broader scientific collaboration, and compliance with federal and agency data policies. This paper, based on the work of NASA’s Open, Free, and FAIR Working Group (O’FAIR WG) under the Earth Science Data Systems Program, presents an overview of how FAIR is being applied within NASA’s Earth science data landscape. It highlights ongoing progress and challenges, identifies FAIR-enabling resources, and offers recommendations and strategic actions to enhance the FAIRness of NASA-funded open and free Earth science data products. The FAIR-enabling resources identified underscore the vital role of NASA's existing enterprise processes, standards, tools, and infrastructures in supporting FAIR implementation. Our findings show strong performance in making NASA Earth science data more findable and accessible. However, further work is needed—especially in enhancing interoperability, so that different systems and tools can better understand and exchange data. This is especially important for enabling machine-driven discovery and analysis. We emphasize the importance of a balanced strategy that combines a centralized, top-down approach—focused on building enterprise-level capabilities and processes—with a decentralized, bottom-up approach driven by discipline-specific needs and community practices. We advocate for coordinated efforts to enhance (meta)data interoperability to facilitate seamless data and information sharing and exchange of Earth science data both within NASA and across other agencies managing Earth science data.

Data Product↗
DOE OSTI2014

Optimizations of spin-exchange relaxation-free magnetometer based on potassium and rubidium hybrid optical pumping

The hybrid optical pumping atomic magnetometers have not realized its theoretical sensitivity, the optimization is critical for optimal performance. The optimizations proposed in this paper are suitable for hybrid optical pumping atomic magnetometer, which contains two alkali species. To optimize the parameters, the dynamic equations of spin evolution with two alkali species were solved, whose steady-state solution is used to optimize the parameters. The demand of the power of the pump beam is large for hybrid optical pumping. Moreover, the sensitivity of the hybrid optical pumping magnetometer increases with the increase of the power density of the pump beam. The density ratio between the two alkali species is especially important for hybrid optical pumping magnetometer. A simple expression for optimizing the density ratio is proposed in this paper, which can help to determine the mole faction of the alkali atoms in fabricating the hybrid cell before the cell is sealed. The spin-exchange rate between the two alkali species is proportional to the saturated density of the alkali vapor, which is highly dependent on the temperature of the cell. Consequently, the sensitivity of the hybrid optical pumping magnetometer is dependent on the temperature of the cell. We proposed the thermal optimization of the hybrid cell for a hybrid optical pumping magnetometer, which can improve the sensitivity especially when the power of the pump beam is low. With these optimizations, a sensitivity of approximately 5 fT/Hz{sup 1/2} is achieved with gradiometer arrangement.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2026

Collapse of Nuclear Collectivity along the 𝑁 = 𝑍 Line

The lifetime of the 𝐽 𝜋 = 2 + state in the self-conjugate 88 Ru nucleus has been determined in an experiment performed using rare-isotope beams provided by the new Facility for Rare Isotope Beams. This is the heaviest 𝑁 = 𝑍 nucleus for which such a measurement has been achieved. 88 Ru was populated by both one-neutron knockout and charge-exchange reactions, and the lifetime of 14.3$^{+2.5}_{−3.4}$ ps was determined using the triple-foil plunger technique. The extracted electromagnetic transition strength shows that the quadrupole collectivity has dropped significantly compared with the highly deformed 𝑁 = 𝑍 region around 𝐴 ∼ 80. These results are compared with state-of-the-art large-scale shell-model and discrete nonorthogonal shell-model calculations. The theoretical calculations indicate a moderate triaxial deformation and suggest that low-lying states in this nucleus are no longer dominated by strong many-particle many-hole excitations, unlike the lighter, highly deformed 𝑁 = 𝑍 nuclei nearby.

59 ≤ A ≤ 89↗
DOE OSTI2018

Cementation of Nuclear Wastes: From Past to Future in a Sustainable Approach - 18266

Cementation of nuclear wastes is a widespread technology due to several factors such as excellent feedback from past experience, simplicity of implementation and versatility. Indeed, as nuclear wastes come in many physical states (bulk wastes, powders, sludges), cementation is the immobilisation process that can easily accommodate this large range of wastes provided the appropriate mixing technology is used: heterogenous cementation (grouting of bulky wastes) or homogenous cementation (intermixing process between the powder or the sludge and the cementitious material). However, nuclear wastes equally present an important chemical variability. This is especially true as New Areva's range of nuclear activities covers the entire fuel cycle: mining, conversion, enrichment and recycling and dismantling and decommissioning. The chemical interactions between the waste and the cement matrix are carefully studied by New Areva's R and D teams in order to provide comprehensive solutions by developing cement formulations which are adapted to wastes characteristics. The aim of the studies is to obtain cement waste-forms that meet the waste acceptance criteria, the final product being thus in perfect adequacy with the disposal requirements. For over 30 years New Areva has been developing cement formulations adapted to the physical and chemical specificities of the wastes accounting for constrains imposed by waste characteristics. The overall approach includes the definition of the appropriate cement composition at laboratory scale, engineering design, equipment manufacturing, testing and commissioning of the cementation facilities. With this strong technical background, a specific methodology has been developed by New Areva teams in order to allow a rapid screening of possible solutions for a given waste (in terms of cement chemistry adapted to the waste) in a learn-fast approach that is based on theoretical analysis and small-scale tests. The methodology was applied for wastes presenting a complex nature (such as reactive metals, ion exchange resins, oils and solvents, mercury, etc), known to interact with Portland cement from a chemical point of view and leading to durability issues of the wasteform (swelling, strength reduction, leaching) and thus reducing the final waste loading. Once the screening process is over, the main drivers for choosing the most appropriate solution to be further developed at pilot scale are: reducing the overall volume and the impact of the final waste package, ensure the waste package performance as defined by the disposal requirements and control the long-term behaviour in final disposal. Moreover, a modelling approach is addressed, aiming to develop a thermo-chemo-mechanical (THM) concrete models that are able to predict the behaviour of the structure (waste form) in time. The aim of the present paper is to describe the main principles within the developed methodology and illustrate it by using a few specific examples. Several distinct cement formulations are developed for complex wastes, limiting the chemical interaction between the cement matrix and the given wastes, obtaining better waste loadings and better overall durability behaviour which facilitates long term behaviour demonstration. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Collaborative Research: Vlasov-Maxwell Simulations to Resolve Electron Heating and Dissipation, in Quasi-Perpendicular Shocks (Final Report)

Collisionless shocks are a grand challenge problem in plasma physics and have been the subject of study for more than six decades. Shocks are ubiquitous phenomena in the universe and are responsible for transforming high energy and momentum flows into thermal energy and energetic particles. Understanding how shocks operate is of primary importance to understand the sun-earth coupling, protecting manned missions and spacecrafts from high energy particles, inertial confinement fusion, and radiation observed from astrophysical plasmas, such as supernova remnants and astrophysical jets. A major unanswered question on this frontier is, how does a collisionless plasma transform flow energy and momentum into electron thermal energy? Many potential mechanisms have been proposed to perform the conversion between flow and thermal energy in a collisionless plasma, but the answer has been elusive. To solve the mystery, non-relativistic perpendicular and quasi-perpendicular shocks are studied via a coordinated approach employing cutting-edge numerical simulations with the continuum kinetic code Gkeyll and spacecraft observations supplied by NASA's Magnetospheric Multiscale (MMS) mission. In both sets of data, we employ novel techniques to identify how and where energy is exchanged between electromagnetic fields and plasma particles. By combining cutting-edge spacecraft data and numerical simulations with these diagnostics, we have been able to identify some of the primary mechanisms responsible electron heating and dissipation in heliospheric shocks. In addition to electron dynamics, we have complete access to proton simulation and in situ data, enabling us to characterize proton heating and acceleration in quasi-perpendicular shocks. Many astrophysical quasi-perpendicular shocks have similar parameters to those in this study, including supernova remnants and shocks in galaxy clusters. Additionally, the simulation code, Gkeyll, and associated analysis scripts are openly available for community use. This award has supported a collaborative effort between Princeton University, the University of Arizona - Tucson, and the University of Maryland - College Park. The award funded three early career scientists, including the funding and training of one female postdoctoral researcher, who was involved in all aspects of the MMS data analysis and some portions of the simulation analysis.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Study of Compatibility of Stainless Steel Weld Joints with Liquid Sodium-Potassium Coolants for Fission Surface Power Reactors for Lunar and Space Applications

To make a manned mission to the surface of the moon or to Mars with any significant residence time, the power requirements will make a nuclear reactor the most feasible source of energy. To prepare for such a mission, NASA has teamed with the DOE to develop Fission Surface Power technology with the goal of developing viable options. The Fission Surface Power System (FSPS) recommended as the initial baseline design includes a liquid metal reactor and primary coolant system that transfers heat to two intermediate liquid metal heat transfer loops. Each intermediate loop transfers heat to two Stirling heat exchangers that each power two Stirling converters. Both the primary and the intermediate loops will use sodium-potassium (NaK) as the liquid metal coolant, and the primary loop will operate at temperatures exceeding 600°C. The alloy selected for the heat exchangers and piping is AISI Type 316L stainless steel. The extensive experience with NaK in breeder reactor programs and with earlier space reactors for unmanned missions lends considerable confidence in using NaK as a coolant in contact with stainless steel alloys. However, the microstructure, chemical segregation, and stress state of a weld leads to the potential for corrosion and cracking. Such failures have been experienced in NaK systems that have operated for times less than the eight year goal for the FSPS. For this reason, it was necessary to evaluate candidate weld techniques and expose welds to high-temperature, flowing NaK in a closed, closely controlled system. The goal of this project was to determine the optimum weld configuration for a NaK system that will withstand service for eight years under FSPS conditions. Since the most difficult weld to make and to evaluate is the tube to tube sheet weld in the intermediate heat exchangers, it was the focus of this research. A pumped loop of flowing NaK was fabricated for exposure of candidate weld specimens at temperatures of 600°C, the expected temperature within the intermediate heat exchangers. Since metal transfer from a high-temperature region to a cooler region is a predominant mode of corrosion in liquid metal systems, specimens were placed at zones in the loop at the above temperature to evaluate the effects of both alloy component leaching and metal deposition. Microstructural analysis was performed to evaluate weld performance on control weld specimens. The research was coordinated with Oak Ridge National Laboratory (ORNL) where most of the weld samples were prepared. In addition, ORNL participated in the loop operation to assist in keeping the testing relevant to the project and to take advantage of the extensive experience in liquid metal research at ORNL.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2024

Synthesis, Processing, and Use of Isotopically Enriched Epitaxial Oxide Thin Films

Isotopic engineering has emerged as a key approach to study the nucleation, diffusion, phase transitions, and reactions of materials at an atomic level. It aims to uncover mass transport pathways, kinetics, and operational and failure mechanisms of functional materials and devices. Understanding these phenomena leads to deeper insights into important physical processes, such as the transport of ions in energy conversion and storage devices and the role of active sites and supports during heterogeneous catalytic reactions. Likewise, isotopic engineering is being pursued as a means of modifying functionality to enable future technological applications. In this Account, we summarize our recent work employing isotope labeling (e.g., 18 O 2 and 57 Fe) during thin film synthesis and postgrowth processing to reveal growth mechanisms, defect chemistry, and elemental diffusion under working and extreme conditions. Isotope-resolved analysis techniques with nanometer-scale spatial resolution, such as time-of-flight secondary ion mass spectrometry and atom probe tomography, facilitate the accurate quantification of isotopic placement and concentration in our well-defined heterostructures with precisely positioned, isotope-enriched layers. By measuring the nanometer-scale redistribution between natural abundance and isotopically enriched oxygen layers during the deposition of Fe 2 O 3 and Cr 2 O 3 by molecular beam epitaxy, we identified intermixing processes driven by surface adatoms occurring both at the film growth surface and within the first few layers below the surface. Further insights into synthesis mechanisms were gained by studying the tungsten oxide thin films grown by evaporating WO 3 powder in the presence of background 18 O 2 , revealing minimal incorporation of background oxygen during the film formation process. Thermal and radiation-enhanced diffusion in epitaxial Fe and Cr oxides were precisely tracked using 18 O and 57 Fe tracer layers incorporated into model epitaxial oxide thin films. This approach has allowed us to access thermal diffusion behavior at lower temperatures than previously measured, revealing a potential changeover in diffusion mechanism. Understanding radiation-enhanced diffusion in model oxides that represent the surface layers on the structural components of nuclear reactors informs our understanding of their corrosion behavior under irradiation. Isotopic labeling can also provide unique insights into the surface exchange reactions and defect chemistry of electrocatalysts. For instance, tracking the change in 18 O concentration at the surface of an epitaxial LaNiO 3 thin film after the electrocatalytic oxygen evolution reaction revealed the participation of lattice oxygen, confirming a hypothesis that had been proposed previously. Lastly, we highlight a new direction wherein we perform in situ processing studies utilizing isotopic tracers in conjunction with model epitaxial thin films within the atom probe tomography instrument. Additionally, this Account illustrates the great potential of isotopic engineering to enable fundamental mechanistic insights into physical processes and engineer functional properties in epitaxial films, heterostructures, and superlattices.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Management of Risk and Uncertainty Through Optimized Co-Operation of Transmission Systems and Microgrids With Responsive Loads (Final Report)

The evolution of the power system to the reliable, efficient and sustainable system of the future will involve development of both demand- and supply-side technology and operations. Ambitious national and state-level goals around the decarbonization of electricity relies on the integration of very high levels of renewable resources, most of which are variable and intermittent. The use of demand response is an ideal approach to counterbalance the intermittency of renewable generation and brings the consumer into the spotlight. Though individual consumers are interconnected at the low-voltage distribution system, these resources are typically modeled as variables at the transmission network level. Demand-side participation cannot be leveraged effectively without explicitly including the distribution system dynamics in the optimization-based wholesale market operations. This project grew from a vision for co-optimized interaction of distribution systems, or microgrids, with the high-voltage transmission system. In this framework, microgrids encompass consumers, distributed renewables and storage. The energy management system of the lower voltage system (distribution or microgrid) can also sell (buy) excess (necessary) energy from the transmission system. Until recently, very little research had been conducted on the co-optimization of these two systems due to computational limitations. However, advances in computational capabilities, and the judicious use of decomposition methods and innovative approximation methods for high-dimension dynamic programming made this goal a viable objective for this project, leading to a fundamental shift in the ability to integrate and fully utilize demand-side resources. To this end, the modeling framework developed introduces a novel co-optimization framework, to include the operations of both the transmission and distribution systems (or microgrids) in operational decision making. This framework was used to analyze renewable and distributed generation along with responsive demand and to compare the capability of co-optimized systems to perform with higher levels of variable renewables. An ideal microgrid is defined as an electric entity capable of operating in both interconnected (with the high-voltage grid) and islanded mode. As such, the microgrid should incorporate generating units (traditional units and intermittent) and if needed, exchange power with the high-voltage grid. The interplay between the microgrid and high-voltage grid motivated the development of the co-optimization approach to ensure efficient performance of the interconnected network. Results show that the use of a bi-level optimization approach is an appropriate structure, capable of co-optimizing a transmission system with multiple distribution systems and microgrids. While increasing the number of connected systems provides increasing flexibility for renewables integration this can also the economic benefits to the low-voltage subsystems with each additional system connected. Comparison of a traditional single-level decision structure with the co-optimization approach illustrates a reduction in overall system cost under co-optimization, while specific cost allocations to transmission and distribution systems are changed.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2019

High Performance Anion Exchange Membrane Fuel Cells Enabled by Fluoropoly(olefin) Membranes

Abstract Although the peak power density of anion exchange membrane fuel cells (AEMFCs) has been raised from ≈0.1 to ≈1.4 W cm −2 over the last decade, a majority of AEMFCs reported in the literature have not been demonstrated to achieve consistently high performance and steady‐state operation. Poly(olefin)‐based AEMs with fluorine substitution on the aromatic comonomer show considerably higher dimensional stability compared to samples that do not contain fluorine. More importantly, fluorinated poly(olefin)‐based AEMs exhibit high hydroxide conductivity without excessive hydration due to a new proposed mechanism where the fluorinated dipolar monomer facilitates increased hydroxide dissociation and transport. Using this new generation of AEMs, a stable, high‐performance AEMFC is operated for 120 h. When the fuel cell configuration is subjected to a constant current density of 600 mA cm −2 under H 2 /O 2 flow, the cell voltage declines only 11% (from 0.75 to 0.67 V) for the first 20 h during break‐in and the cell voltage loss is low (0.2 mV h −1 ) over the subsequent 100 h of cell testing. The ease of synthesis, potential for low‐cost commercialization, and remarkable ex situ properties and in situ performance of fluoropoly(olefin)‐based AEM renders this material a benchmark membrane for practical AEMFC applications.

Zhu, Liang↗
DOE OSTI2023

Advanced Reactor Cyber Analysis and Development Environment (ARCADE) for System-Level Design Analysis

Cybersecurity is a persistent concern to the safety and security of Nuclear Power Plants (NPPs), but has lacked data-driven, evidence-based research. Rigorous cybersecurity analysis is critical for the licensing of advanced reactors using a performance-based approach. One tool that enables cybersecurity analysis is modeling and simulation. The nuclear industry makes extensive use of modeling and simulation throughout the decision process but lacks a method to incorporate cybersecurity analysis with existing models. To meet this need, the Advanced Reactor Cyber Analysis and Development Environment (ARCADE) was developed. ARCADE is a suite of publicly available tools that can be used to develop emulations of industrial control system devices and networks and integrate those emulations with physics simulators. This integration of cyber emulations and physics models enables rigorous cyber-physical analysis of cyber-attacks on NPP systems. This report provides an overview of key considerations for using ARCADE with existing physics models and demonstrates ARCADE’s capabilities for cybersecurity analysis. Using a model of the Small Modular Advanced High Temperature Reactor (SmAHTR), ARCADE was able to determine the sensitivity of the primary heat exchangers (PHX) to coordinated cyber-attacks. The analysis determined that while the PHX’s failures cause disruption to the reactor, they did not cause any safety limits to be exceeded because of the plant design, including passive safety features. Further development of ARCADE will enable rigorous, repeatable, and automated cyber-physical analysis of advanced reactor control systems. These efforts will also help reduce regulatory uncertainty by presenting similar types of cybersecurity analyses in a common format, driving standard approaches and reporting.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗