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At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

On-Demand Designing of Cathode Internal Surface Architecture for Dramatic Enhancement of SOFC Performance and Durability

This project is aimed to design and modify the internal surfaces of porous composite cathode from currently commercially viable Solid Oxide Fuel Cells (SOFCs), using additive manufacturing process of Atomic Layer Deposition (ALD). The material systems being investigated are commercial composite electrodes complex three-dimensional topographies. In term of the chemistry of the ALD layer applied on the internal surface of the porous cathode, this project has employed commercially relevant electrolyte, electrocatalyst and noble metal materials set. Such materials are fully compatible with the commercial fuel cells, and this project has developed special nanostructure on the surface of the commercial composite cathodes. The formation of the designed nanoarchitecture on the surface of SOFC cathode has been achieved through precise control of ALD parameters and their effect on overall cell performance and resultant electrochemical reaction mechanism of cathodes has been investigated through full cell electrochemical performance testing and nanostructure characterization by transmission electron microscopy (TEM). Under the support of this award, following has been achieved: (1). For cathode materials in solid oxide fuel cells (SOFCs), such as perovskite mixed conductor La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-x (LSCF), cation surface segregation and consequently losing conductivity and active sites for the oxygen reduction reaction (ORR) are problematic. To mitigate the cation segregation and enhance SOFC durability, further decorating the internal backbone surface using the desired electrocatalysts could be a promoting approach. Commonly, the cation segregation such as Sr is very volatile, so the effective surface decoration is ideally conformal. Nevertheless, the conformal surface coating would inevitably alter the ORR pathways that initially take place on the surface of the backbone. To reveal the impact of the conformal coating on both the catalytic activity and the conductivity of the cathode, the unary electrocatalyst of Pt or CoO x , was applied to the LSCF/SDC composite electrode of inherently functional SOFCs, respectively. Both ALD coating layers evolve strong interaction with the LSCF composite cathode. Upon operations, the Pt coating layer remains conformal on LSCF grain surfaces but turns into discrete particles on SDC grain surfaces. Meanwhile, CoO x conformal coating grows to be the discrete nanograins on both the LSCF and SDC grains. ALD coating of the cathode alone reduces the ohmic resistance up to 28 % for the entire cells. The increased conductivity induced by the ALD coating of Pt or CoO x is ascribed to different mechanisms. For the inherent functional SOFCs, the present study presents a novel and feasible approach to apply a conformal, dense coating layer on the surface of a mixed conductor, simultaneously increasing the conductivity and durability of the SOFC cathode. (2). High resistance of the oxygen electrode still significantly hinders the state-of-the-art Solid Oxide Fuel Cells (SOFCs). In particular, for an oxygen electrode consisting of mixed electronic and ionic conductors, such as perovskite lanthanum strontium cobalt ferrite (LSCF), it deteriorates due to its low chemical stability of the grain surface. Such degradation is often associated with the segregation of cations. To prevent the cation surface segregation and its resultant perovskite phase decomposition, we demonstrate a conformal ultra-thin (7-10 nm) surface heterogeneous coating layer consisting of subjacent discrete Pt nanoparticles capped with a superjacent fully dense conformal CoO x layer. The performance studies indicate the ALD coating reduces the cell series resistance by up to 40 %. The conformal CoO x layer consists of randomly orientated but single-layered nanograins, with high-density intergranular and surface grain boundaries serving as the electrochemical reaction sites and facilitating mass transport. The conformal coating layer appears to have successfully suppressed the Sr outward diffusion and confined the Sr enriched layer to a ~ 2 nm interface perovskite phase between the coating layer and the LSCF grain surface. Moreover, this ultra-thin Sr enriched perovskite layer presumably possesses high oxygen vacancy and high ionic conductivity and further imposes tensile strain to the LSCF grain surfaces. With the combination of a conformal CoO x nanoionics, Sr enriched layer, and its strained interface, the ALD coating induced surface layer is estimated to have a conductivity of ~ 1.27x10 4 S/cm, which is over two orders magnitude of that from LSCF at 750 ºC.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2024

Methodological guidelines on concrete degradation based on predictive models and the release of MOSAIC for industry use

In light-water reactors (LWRs), the concrete biological shield (CBS) designates the concrete structure directly facing the reactor pressure vessel (RPV). The primary function of the CBS is to protect equipment and personnel from the neutron and gamma radiation exiting the RPV. Most CBSs in operation in the United States also provide structural support to the RPV. Based on a long-term structural analysis, the structural integrity of the CBS to transfer the in-service passive load to the foundation, dynamic loading during an earthquake, and thermal loading during a loss-of-coolant accident (LOCA) must be maintained. Based on test reactor data for accelerated conditions, the mechanical properties of irradiated concrete are affected when exposed to neutron fluence higher than ≈ 10 19 n.cm -2 (E > 0.1 MeV). At 80 years of operation, the fluence estimates at the surface of the CBS range between 1×10 19 and 7×10 19 n.cm -2 (E > 0.1 MeV): the fluence value depends mostly on the design. Although fluence attenuates through the CBS by virtue of the shielding properties of concrete, about 5% to 10% of the CBS wall depth is affected by high fluence. The main degradation mechanism is the so-called radiation-induced volumetric expansion (RIVE) caused by the amorphization of aggregate-forming minerals. RIVE causes large deformation of up to 18% in pure quartz, and it also reduces the structural properties of concrete. The structural effects of long-term exposure to fast neutron irradiation in LWRs was studied in the report entitled “Assessment of the Effect of the Irradiation-Induced Degradation on the In-Service Structural Performance of the Concrete Biological Shields” (M3LW-23OR0403013). This report illustrates that (1) irradiation-induced damage expands further than the region subject to a cumulative fluence of 10 19 n.cm -2 (E > 0.1 MeV) to reach the steel reinforcement location, and (2) the irradiation-induced damage region shows no substantial residual bearing capacity and should not be accounted for in the integrity assessment of the CBS.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2023

CERESMIP: a climate modeling protocol to investigate recent trends in the Earth's Energy Imbalance

The Clouds and the Earth's Radiant Energy System (CERES) project has now produced over two decades of observed data on the Earth's Energy Imbalance (EEI) and has revealed substantive trends in both the reflected shortwave and outgoing longwave top-of-atmosphere radiation components. Available climate model simulations suggest that these trends are incompatible with purely internal variability, but that the full magnitude and breakdown of the trends are outside of the model ranges. Unfortunately, the Coupled Model Intercomparison Project (Phase 6) (CMIP6) protocol only uses observed forcings to 2014 (and Shared Socioeconomic Pathways (SSP) projections thereafter), and furthermore, many of the ‘observed' drivers have been updated substantially since the CMIP6 inputs were defined. Most notably, the sea surface temperature (SST) estimates have been revised and now show up to 50% greater trends since 1979, particularly in the southern hemisphere. Additionally, estimates of short-lived aerosol and gas-phase emissions have been substantially updated. These revisions will likely have material impacts on the model-simulated EEI. We therefore propose a new, relatively low-cost, model intercomparison, CERESMIP, that would target the CERES period (2000-present), with updated forcings to at least the end of 2021. The focus will be on atmosphere-only simulations, using updated SST, forcings and emissions from 1990 to 2021. The key metrics of interest will be the EEI and atmospheric feedbacks, and so the analysis will benefit from output from satellite cloud observation simulators. The Tier 1 request would consist only of an ensemble of AMIP-style simulations, while the Tier 2 request would encompass uncertainties in the applied forcing, atmospheric composition, single and all-but-one forcing responses. We present some preliminary results and invite participation from a wide group of models.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Self-contamination and environment of an orbiting spacecraft

The flux of molecules emitted by a spacecraft and subsequently reflected to its surface was investigated. The reflection occurs upon collision of the outgassed molecules with ambient molecules. Evaluation of the flux was based on a knowledge of the spacecraft outgassing rate, the spacecraft dimensions, and the orbit parameters. Condensation rates and adsorption layers on critical surfaces were calculated from the knowledge of this flux and the nature and temperature of the gas and the surface. Based on estimated and measured emission rates, calculation of these parameters was performed for a number of spacecraft. The relationships and graphs developed allow an estimate of several important parameters for an orbiting spacecraft to be made. The pressures and densities at various distances from the spacecraft, as produced by the surrounding ambient molecules and by the spacecraft's own outgassing, are presented. The pressure and density produced by the outgassing can be obtained as a function of time if the behavior of the outgassing with time is known. The number of desorbed molecules ionized by impact with ambient charged particles and the effect of the spacecraft's electric field on polarized desorbed molecules were considered.

Scialdone, J. J.↗
NASA NTRS1972

Information from Jupiter's decametric radiation

Radiation associated with decametric bursts are observed from about 39.5 MHz downwards, and its occurrence probability depends partly on the central meridian longitude of Jupiter. Three central meridian longitude regions of emission are designated as Sources A, B, and C. Emissions from B and C regions are also dependent on Io's phase. The frequency band of noise storms drifts slowly up or down the spectrum. Pulses with durations of 20 microseconds display drifts at the rate of 1000 MHz/sec. Decametric data are used to estimate Jupiter's surface magnetic field strength to be 10 gauss; however, if the maximum emission, about 10 MHz, is the electron gyrofrequency at Io's orbit, the surface field strength would be about 800 gauss. A model of the emission beam control exercised by Io is summarized. Data are presented which indicate that the width of source A emissions results from the changes in the angle of Jovicentric declination of the earth. One of two recent theories places the plasmapause at least 50 Jupiter radii from the surface on the sunward side, and the other places it within Io's orbit.

Carr, T. D.↗
NASA NTRS1972

Transient variation of martian ground-atmosphere thermal boundary layer structure.

Results of a numerical simulation of the diurnal redistribution of temperature by radiative and molecular-conductive processes in the Martian soil-atmosphere system. An attempt is made to assess the importance of atmospheric molecular conduction near the surface and to estimate the characteristic depth of the diurnal temperature wave. The computational results are found to indicate a dual structure in the diurnal temperature wave propagation pattern, with a diffusive-type wave in the lowest 150 m superimposed on a radiatively induced disturbance with a characteristic scale of 1.8 km. Atmospheric molecular thermal conduction typically accounts for about 15% of the total heating/cooling in the lowest 25 m. Thermal conduction in both the soil and atmosphere appears to be an important factor in the thermal coupling of these subsystems. A free-convection regime in the conduction layer is predicted by the model for about five hours of the Martian day.

Pallmann, A. J.↗
NASA NTRS1976

Comparisons of cloud cover evaluated from LANDSAT imagery and meteorological stations across the British Isles

The author has identified the following significant results. This stage of the study has confirmed the initial supposition that LANDSAT data could be analyzed to provide useful data on cloud amount, and that useful light would be thrown thereby on the performance of the ground observer of this aspect of the state of the sky. This study, in comparison with previous studies of a similar nature using data from meteorological satellites, has benefited greatly from the much higher resolution data provided by LANDSAT. This has permitted consideration of not only the overall performance of the surface observer in estimating total cloud cover, but also his performance under different sky conditions.

Barrett, E. C.↗
NASA NTRS1977

A feasibility analysis of the employment of satellite imagery to monitor and inspect surface mining operations in western Kentucky, volume 1

The author has identified the following significant results. Surface mining violation estimates were scaled by scores assigned by ten inspectors from western Kentucky to each violation. A sensitivity analysis was made by varying the violation costs; costs were varied by using three different average durations. These durations were: (1) best estimated duration; (2) longest possible duration as restricted by the one year permit renewal and bond release regulations, and (3) shortest possible duration when inspections were made. If a social cost cannot be reduced, then the value of the social cost is irrelevant. Indications from the increased inspection rate of 1975 were that the total amount of fines collected per year remains constant independent of the increased detection rate.

Fish, B. R.↗
NASA NTRS1978

Estimate of Orbiter static aeroelasticity properties via FLEXSTAB

The theory underlying the use of rigid-model experimental data in FLEXSTAB aeroelasticity calculations is summarized. A description is given of the aerodynamic and structural models used in the calculation of Space Shuttle Orbiter aeroelasticity properties during the re-entry phase. Experience gained with the use of pressure, nonlinear force and moment, and area-ratio correction methods in the Orbiter application is described and typical program output data are included. The inability of the program to correctly estimate differential control surface pressures and to accept external corrections for these terms is shown to be a major limitation in the Orbiter application.

Cavin, R. K., III↗
NASA NTRS1979

Study of advanced sunflower precision deployable antenna

The maximum deployed diameter stowable in shuttle was determined for the original concept and for new more efficient concepts. Estimates of weight, surface accuracy and cost were made for the various configurations. Five critical technologies were identified which would be required to manufacture large solid deployable reflectors. These technologies are concerned with surface accuracy improvement and verification.

Giebler, M. M.↗
NASA NTRS1981

Effects of meteoric debris on stratospheric aerosols and gases

Characterizations of meteoric dust height and size distributions are obtained using Hunten's calculations of meteor ablation and recondensation rates. The contribution of meteor residues to aerosol composition, the role of meteoric dust as condensation nuclei, and the effects of meteor debris on aerosol size distributions are quantified, and particle surface areas are estimated. The potential importance of heterogeneous chemistry for stratospheric trace gases is discussed. The interaction between H2SO4 vapor and meteor metal vapors is investigated. It is concluded that meteoric particles may dominate the natural stratospheric aerosols at small (less than .01 micron radius) and large (greater than 1 micron radius) sizes under normal conditions.

Turco, R. P.↗
NASA NTRS1981

Viking bistatic radar experiment - Summary of first-order results emphasizing north polar data

Initial results of bistatic radar observations of Mars made by the Viking Orbiter spacecraft are presented with particular emphasis on the previously unstudied polar regions. Bistatic radar scattering experiments were performed in near-equatorial regions by the Viking Orbiter 1, while other regions of the planet were observed by the polar-orbiting Orbiter 2, with scattered signals received by stations of the NASA Deep Space Network. In the equatorial region, the bistatic radar estimates of rms surface slope are found to be in qualitative agreement with results obtained using earth-based transmitter-receivers, showing a nearly 2:1 decrease in rms surface roughness between 20 and 22 deg N with no appreciable change in dielectric constant. Data in the north polar region reveal variations in surface roughness from 1 to 6 deg, with areas of smooth material generally located within rougher environs, surface roughness decreasing along Vastitas Borealis in the direction of the north pole, and north polar cap rms roughnesses on the order of 2.5-3.0 deg. Trends in radar reflectivity suggest a decreasing surface density with increasing latitude, consistent with a layer of seasonal CO2 or H2O snow increasing in depth as the pole is approached.

Simpson, R. A.↗
NASA NTRS1981

Satellite-derived ice data sets no. 1: Antarctic monthly average microwave brightness temperatures and sea-ice concentrations, 1973 - 1976

A summary data set concerning 4 years of Antarctic sea-ice conditions was created and is available on magnetic tape. The data were derived from electrically scanning microwave radiometer brightness temperatures and were mapped into a polar stereographic grid enclosing the 50 deg S latitude circle. The grid size varies from about 32 by 32 sq km at the poles to about 28 by 28 sq km at 50 deg S. The microwave brightness temperatures of Antarctic sea ice are predominantly characteristic of first-year ice with an emissivity of 0.92 at 19 GHz frequency. Sea ice concentrations were calculated from the brightness temperature data for each grid element with an algorithm that uses an emissivity value of 0.92 and an ice physical temperature estimate from climatological surface air temperatures. Monthly, multiyear monthly, and yearly maps of brightness temperatures and sea ice concentrations were created for the 4 years, except for 7 months for which useable data were insufficient.

Zwally, H. J.↗
NASA NTRS1982

Mars' atmospheric behavior from Viking infra-red thermal mapper measurements

Data from the 15 micron band of CO2 readings with the two Viking IR thermal mappers are discussed. Contrasts were observed to be strong between clear and dusty conditions, with a latitudinal gradient and a diurnal amplitude variation in the winter southern hemisphere. Consistency was found in zonal mean temperatures in the absence of dust, with a peak temperature of 180 K at the poles and a diurnal amplitude of 15 K at the equator. Large temperature increases occur in dusty conditions, with global dust storms being present in the northern, but not southern, hemisphere. Estimations of the surface and atmospheric temperatures are calculated in order to derive optical depths from the IR measurements of atmospheric opacity. The optical depth around the whole planet is found to be relatively uniform at any given moment. Finally, the diurnal behavior of the brightness temperature is outlined for 1.4 Mars years.

Martin, T. Z.↗
NASA NTRS1983

Determination of the Io heat flow. 1: Eclipse observations

The thermal emission from Io during eclipse by Jupiter yields data from which the total thermal flux from the volcanoes on the satellite surface can be estimated. Thermal infrared observations in spectral bands between 3.5 and 30 microns of five Io eclipse reappearances and one eclipse disappearance are reported and discussed. The thermal emission of the volcanoes which occurs almost all of the time was determined from the Io heat flux data. The thermal observations of Io are discussed with respect to previous thermophysical theories.

Sinton, W. M.↗