Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Spectrum Accountability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Modification of conventional peak shapes to accurately represent spectral asymmetry: High-Resolution X-ray photoelectron spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] ionic liquids

X-ray photoelectron spectroscopy (XPS) is one of the most widely used techniques for surface characterization. Analysis of XPS data is challenging and requires the analyst to fit the data with synthetic line shapes to reach physically meaningful interpretations. Experimental spectral envelopes, however, are complex and display asymmetric features that are often ignored or attributed to additional chemical components. The high-resolution XPS spectra of [C 4 C 1 Pyrr][NTf 2 ] and [C 8 C 1 Im][NTf 2 ] all exhibit a degree of asymmetry which is systematically observed at the higher binding energy side of photoemission envelopes. Here, we present the development of a refined fitting procedure for XPS spectra of these ionic liquid-based systems which include (a) Shirley background offset necessary to account for the insulator-like region and (b) spectral asymmetry in C 1s and N 1s regions. Further, Shirley and trapezoid components are applied to compensate for inelastic scattering taking place during electron transitions as high as 7.8 eV above the start of the fitting region in C 1s high-resolution spectrum. To demonstrate the fitness of this model, we present an analysis of a 2:1 mixture of [C 4 C 1 Pyrr][NTf 2 ]: [C 8 C 1 Im][NTf 2 ].

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Impact of the Langdon effect on crossed-beam energy transfer

The prediction that laser plasma heating distorts the electron distribution function away from Maxwellian and towards a super-Gaussian distribution dates back four decades. In conditions relevant to inertial confinement fusion, yet, no direct evidence of this so-called “Langdon effect” has previously been observed. Here, measurements of the spatially and temporally resolved Thomson scattering spectrum indicate the presence of super-Gaussian electron distribution functions that are consistent with existing theory. In such plasmas, ion acoustic wave frequencies increase monotonically with the super-Gaussian exponent. Our findings show that the measured power transfer between crossed laser beams mediated by ion acoustic waves requires a model that accounts for the non-Maxwellian electron distribution function, whereas the standard Maxwellian calculations overpredict power transfer over a wide region of parameter space. Including this effect is expected to improve the predictive capability of crossed-beam energy transfer modeling at the National Ignition Facility and may restore a larger operable design space for inertial confinement fusion experiments. Furthermore, this is expected to motivate further inquiry in other areas impacted by non-Maxwellian electron distribution functions, such as laser absorption, heat transport, and x-ray spectroscopy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2015

Planck intermediate results: XXV. The Andromeda galaxy as seen by Planck

The Andromeda galaxy (M 31) is one of a few galaxies that has sufficient angular size on the sky to be resolved by the Planck satellite. Planck has detected M 31 in all of its frequency bands, and has mapped out the dust emission with the High Frequency Instrument, clearly resolving multiple spiralarms and sub-features. In this paper, we examine the morphology of this long-wavelength dust emission as seen by Planck, including a study of its outermost spiral arms, and investigate the dust heating mechanism across M 31. We find that dust dominating the longer wavelength emission (≳0.3 mm) is heated by the diffuse stellar population (as traced by 3.6 μm emission), with the dust dominating the shorter wavelength emission heated by a mix of the old stellar population and star-forming regions (as traced by 24 μm emission). We also fit spectral energy distributions for individual 5' pixels and quantify the dust properties across the galaxy, taking into account these different heating mechanisms, finding that there is a linear decrease in temperature with galactocentric distance for dust heated by the old stellar population, as would be expected, with temperatures ranging from around 22 K in the nucleus to 14 K outside of the 10 kpc ring. Finally, we measure the integrated spectrum of the whole galaxy, which we find to be well-fitted with a global dust temperature of (18.2 ± 1.0) K with a spectral index of 1.62 ± 0.11 (assuming a single modified blackbody), and a significant amount of free-free emission at intermediate frequencies of 20–60 GHz, which corresponds to a star formation rate of around 0.12 M ⊙ yr -1 . Finally, we find a 2.3σ detection of the presence of spinning dust emission, with a 30 GHz amplitude of 0.7 ± 0.3 Jy, which is in line with expectations from our Galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Comparison between Gaussian-type orbitals and plane wave ab initio density functional theory modeling of layer silicates: Talc [Mg{sub 3}Si{sub 4}O{sub 10}(OH){sub 2}] as model system

The quantum chemical characterization of solid state systems is conducted with many different approaches, among which the adoption of periodic boundary conditions to deal with three-dimensional infinite condensed systems. This method, coupled to the Density Functional Theory (DFT), has been proved successful in simulating a huge variety of solids. Only in relatively recent years this ab initio quantum-mechanic approach has been used for the investigation of layer silicate structures and minerals. In the present work, a systematic comparison of different DFT functionals (GGA-PBEsol and hybrid B3LYP) and basis sets (plane waves and all-electron Gaussian-type orbitals) on the geometry, energy, and phonon properties of a model layer silicate, talc [Mg{sub 3}Si{sub 4}O{sub 10}(OH){sub 2}], is presented. Long range dispersion is taken into account by DFT+D method. Results are in agreement with experimental data reported in literature, with minimal deviation given by the GTO/B3LYP-D* method regarding both axial lattice parameters and interaction energy and by PW/PBE-D for the unit-cell volume and angular values. All the considered methods adequately describe the experimental talc infrared spectrum.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

GENERATION OF HIGH-ENERGY PHOTONS AT ULTRA-RELATIVISTIC SHOCK BREAKOUT IN SUPERNOVAE

We present theoretical expectations for non-thermal emission due to the bulk Comptonization at the ultra-relativistic shock breakout. We calculate the transfer of photons emitted from the shocked matter with a Monte Carlo code fully taking into account special relativity. As a hydrodynamical model, we use the self-similar solution of Nakayama and Shigeyama. Our calculations reveal that the spectral shape exhibits a double peak or a single peak depending on the shock temperature at breakout; if it is significantly smaller than the rest energy of an electron, the spectrum has a double peak. We also include a few sample light curves, and estimate the total radiation energy. In comparison with observations of γ-ray bursts, a part of the higher energy component in the spectra and the total energy can be reproduced by some parameter sets. Meanwhile, the lower energy counterpart in the Band function is not reproduced by our results and the duration seems too short to represent an entire γ-ray burst. Therefore the subsequent phase will constitute the lower energy part of the spectrum.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Inhomogeneous dark energy

We modify Einstein General Relativity by adding non-dynamical scalar fields to account simultaneously for both dark matter and dark energy. The dark energy in this case can be distributed in-homogeneously even within horizon scales. Its inhomogeneities can contribute to the late time integrated Sachs-Wolfe effect, possibly removing some of the low multipole anomalies in the temperature fluctuations of the CMB spectrum. The presence of the inhomogeneous dark matter also influences structure formation in the universe.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Non-perturbative production of fermionic dark matter from fast preheating

We investigate non-perturbative production of fermionic dark matter in the early universe. We study analytically the gravitational production mechanism accompanied by the coupling of fermions to the background inflaton field. The latter leads to the variation of effective fermion mass during preheating and makes the resulting spectrum and abundance sensitive to its parameters. Assuming fast preheating that completes in less than the inflationary Hubble time and no oscillations of the inflaton field after inflation, we find an abundant production of particles with energies ranging from the inflationary Hubble rate to the inverse duration of preheating. The produced fermions can account for all observed dark matter in a broad range of parameters. As an application of our analysis, we study non-perturbative production of fermionic dark matter in the model of Palatini Higgs inflation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

Ingredients for the electronic nematic phase in FeSe revealed by its anisotropic optical response

The origin of the anisotropy in physical quantities related to a symmetry-broken (nematic) electronic state is still very much debated in high-temperature superconductors. FeSe at ambient pressure undergoes a structural, tetragonal-to-orthorhombic phase transition at T s ≃ 90 K without any magnetic ordering on further cooling, which leads to an ideal electronic nematicity. Our unprecedented optical results provide evidence that the low-energy excitation spectrum in the nematic phase is shaped by an important interplay of the anisotropic Drude weight and scattering rate. In the zero-frequency limit though, the temperature dependence of the anisotropic scattering rate plays the dominant role and, combined with the nematic order parameter as evinced from the high energy optical response, accounts for the anisotropic dc resistivity. In conclusion, this favors the scattering by anisotropic spin fluctuations as the prominent candidate in governing the properties of the nematic phase.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Primordial black hole dark matter from single field inflation

We propose a model of inflation capable of generating a population of light black holes (about 10 –16 –10 –14 solar masses) that might account for a significant fraction of the dark matter in the Universe. The effective potential of the model features an approximate inflection point arising from two-loop order logarithmic corrections in well-motivated and perturbative particle physics examples. This feature decelerates the inflaton before the end of inflation, enhancing the primordial spectrum of scalar fluctuations and triggering efficient black hole production with a peaked mass distribution. At larger field values, inflation occurs thanks to a generic small coupling between the inflaton and the curvature of spacetime. We compute accurately the peak mass and abundance of the primordial black holes using the Press-Schechter and Mukhanov-Sasaki formalisms, showing that the slow-roll approximation fails to reproduce the correct results by orders of magnitude. We study as well a qualitatively similar implementation of the idea, where the approximate inflection point is due to competing terms in a generic polynomial potential. In both models, requiring a significant part of the dark matter abundance to be in the form of black holes implies a small blue scalar tilt with a sizable negative running and a tensor spectrum that may be detected by the next-generation probes of the cosmic microwave background. We also comment on previous works on the topic.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Gluon radiation from a classical point particle: recoil effects

Abstract The gluon radiation spectrum of a classical particle struck by a sheet of colored glass, is a key ingredient in understanding the distribution of energy and baryon density in the fragmentation region, particularly in the initial stages of heavy ion collisions. However, the currently known classical spectrum has a troublesome high-momentum tail (Kajantie et al. in Phys. Rev. D 100(5):054011, 2019; Phys Rev D 101(5):054012, 2020). By comparing tree-level bremsstrahlung of a spin-less quark to the above-mentioned known result, we propose an interpolating formula that takes into account the recoil of the struck particle, and therefore produces the correct perturbative behaviour at high momentum of the radiated gluon.

Physics↗
NASA NTRS1976

Repeated-cascade theory of strong turbulence in a magnetized plasma

A two-dimensional Navier-Stokes equation of vorticity in fluid turbulence is used to model drift turbulence in a plasma with a strong constant magnetic field and a constant mean density gradient. The nonlinear eddy diffusivity is described by a time-integrated Lagrangian correlation of velocities, and the repeated-cascade method is employed to choose the rank accounting for nearest-neighbor interactions, to calculate the Lagrangian correlation, and to close the correlation hierarchy. As a result, the diffusivity becomes dependent on the plasma's induced diffusion and is represented by a memory chain that is cut off by similarity and inertial randomization. Spectral laws relating the kinetic-energy spectrum to the -5, -5/2, -3, and -11 powers of wavenumber are derived for the velocity subranges of production, approach to inertia, inertia, and dissipation, respectively. It is found that the diffusivity is proportional to some inverse power of the magnetic field, that power being 1, 2/3, 5/6, and 2, respectively, for the four velocity subranges.

Tchen, C. M.↗
NASA NTRS1983

The optical identification content of the Einstein Observatory deep X-ray survey of a region in Pavo

Results are presented from the Einstein deep X-ray survey in Pavo, with correlated optical and radio observations of a complete sample of candidate identifications. There are 16 X-ray sources detected with positional accuracy better than 10 arcsec, of which five are identified, with a further seven (and a maximum nine) probable identifications. Of the identified sources, four are QSOs with J-magnitude about 20 (one is an inverted spectrum radio source) and one is associated with extended emission from a pair or cluster of galaxies. Of the probable identifications, one is a galaxy and the rest are a subset of a yellow stellar object population which may also be QSOs. Identifications with QSOs and QSO candidates with J less than 24 account for 60-80 percent of the detected sources.

Griffiths, R. E.↗
NASA NTRS1989

The evolution of energetic particles and the emitted radiation in solar flares

The evolution of accelerated particle distributions in a magnetized plasma and the resulting radiation are calculated, and the results are applied to solar flares. To study the radiation on timescales of order the particle lifetimes, the evolution of the particle distribution is determined by the use of the Fokker-Planck equation including Coulomb collisions and magnetic mirroring. Analytic solution to the equations are obtained for limiting cases such as homogeneous injection in a homogeneous plasma, and for small pitch angle. These analytic solutions are then used to place constraints on flare parameters such as density, loop length, and the injection timescale for very short implusive solar flares. For general particle distributions in arbitrary magnetic field and background density, the equation is solved numerically. The relative timing of microwaves and X-rays during individual flares is investigated. A number of possible sources for excessive microwave flux are discussed including a flattening in the electron spectrum above hard X-ray energies, thermal synchrotron emission, and trapping of electron by converging magnetic fields. Over shorter timescales, the Fokker-Planck equation is solved numerically to calculate the temporal evolution of microwaves and X-rays from nonthermal thick target models. It is shown that magnetic trapping will not account for the observed correlation of microwaves of approximately 0.15 seconds behind X-rays in flares with rapid time variation, and thus higher energy electrons must be accelerated later than lower energy electrons.

Lu, Edward Tsang↗
NASA NTRS1989

The Li-7 and Be-7 deexcitation lines: Probes for accelerated particle transport models in solar flares

The photon energy spectrum of a spectral feature composed of the 429 and 478 keV gamma-ray lines from Li-7 and Be-7 (produced by interactions of flare-accelerated alpha particles with ambient He in the solar atmosphere) depends on the angular distribution of the interacting accelerated particles. This spectrum is calculated for limb and disc-centered flares using a loop model for the transport of the ions. In this model, the flux tube magnetic field is constant in the corona and converges in the chromosphere to the photosphere. Magnetic mirroring and MHD pitch-angle scattering are both taken into account. Comparison of these results with data from other experiments is presented.

Murphy, Ronald J.↗
NASA NTRS1991

Continuum radiation in planetary magnetospheres

With the completion of the Voyager tour of the outer planets, radio and plasma wave instruments have executed the first survey of the wave spectra of Earth, Jupiter, Saturn, Uranus, and Neptune. One of the most notable conclusions of this survey is that there is a great deal of qualitative similarity in both the plasma wave and radio wave spectra from one magnetosphere to the next. In particular, in spite of detailed differences, most of the radio emissions at each of the planets have been tentatively classified into two primary categories. First, the most intense emissions are generally associated with the cyclotron maser instability. Second, a class of weaker emissions can be found at each of the magnetospheres which appears to be the result of conversion from intense electrostatic emissions at the upper hybrid resonance frequency into (primarily) ordinary mode radio emission. It is this second category, often referred to as nonthermal continuum radiation, which we will discuss in this review. We review the characteristics of the continuum spectrum at each of the planets, discuss the source region and direct observations of the generation of the emissions where available, and briefly describe the theories for the generation of the emissions. Over the past few years evidence has increased that the linear mode conversion of electrostatic waves into the ordinary mode can account for at least some of the continuum radiation observed. There is no definitive evidence which precludes the possibility that a nonlinear mechanism may also be important.

Kurth, W. S.↗
NASA NTRS1991

Si II emission line diagnostics

The present study compares ratios of Si II UV emission lines in a variety of objects with computations based on recently published collisional data of Dufton and Kingston (1991). A high-quality spectrum of Alpha Tau (K5 III) obtained by Carpenter et al. (1991) is analyzed using the G270M mode of the GHRS on the HST, in addition to high-dispersion data from Skylab and IUE. Agreement between observation and theory is satisfactory for most lines. A blend with a line of Ni II accounts partially for the discrepancies and solves a problem with semiforbidden S II emission measures. Disagreement exists between certain observed flux ratios and computed values using recent atomic data for the intersystem lines. The discrepancy is most significant for Alpha Tau. The computed atomic collision strengths within the intersystem multiplet itself are argued as a possible cause of the discrepancy.

Judge, P. G.↗
NASA NTRS2000

A Passive Method for Detecting Vegetation Stress from Orbit: Chlorophyll Fluorescence Spectra from Fraunhofer Lines

Solar-stimulated chlorophyll fluorescence measured with the Fraunhofer line depth method has correlated well with vegetation stress in previous studies. However, the instruments used in those studies were limited to a single solar absorption line (e.g. 656.3 nm), obviating the red/far-red ratio (R/FR) method. Optics and detector technology have reached the level whereby multiple, very narrow Fraunhofer lines are resolvable. Thirteen such lines span the visible spectrum in the red to far-red region where chlorophyll fluorescence occurs. Fluorescence intensities at the 13 Fraunhofer line wavelengths were used to model emission spectra. The source data were collected for summer and fall bean crops (Phaseolus vulgaris L.) subjected to various levels of nitrogen fertilization. The intensities were adjusted to account for Fraunhofer line depth and atmospheric transmittance. Multiple R/FR fluorescence ratios, calculated from the modeled fluorescence spectra, correlated strongly with leaf chlorophyll concentration and well with applied nitrogen. The ratio yielding the best correlation with chlorophyll utilized red fluorescence at the 694.5 nm Fraunhofer line and farred fluorescence at the 755.6 nm Fraunhofer line. Twenty R/FR ratios, each evaluated for the maximum differential between low and high (optimal) nitrogen treatments, ranked higher in some cases and lower in others, possibly related to the time of year the crops were grown and the stage of growth of the crops. Ratios with 728.9 nm and 738.9 nm in the denominator consistently ranked in the lowest and next lowest quartile, respectively. Ratios of the 656.3 nm Fraunhofer line and the 755.6 nm line consistently ranked highest for the summer crop. Ratios with 755.6 nm in the denominator ranked in the upper quartile for 10 out of 12 measurement dates. Differences in ratio ranking indicate that physiological conditions may be estimated using selected ratios of Fraunhofer lines within the context of R/FR analysis. A passive instrument designed to monitor R/FR chlorophyll fluorescence (i.e. vegetation stress) from orbit could be built today.

Theisen, Arnold F.↗