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At least 1,117 records · Page 62

Magnetic leverage effects in amorphous SmCo/CoAlZr heterostructures

Although magnetic heterostructures are the basis of many magnetic technologies, the mechanisms involved in magnetization reversals in such structures are not fully understood, especially in amorphous multilayers. Here, we report on the SmCo/CoAlZr system and exploit resonant magnetic x-ray scattering to probe the element specific magnetization reversals. When combined into a tri-layer structure, two different switching fields and reversal mechanisms are observed for the Sm and Co sub-lattices. We argue that the decoupling of the sub-lattices arises from the local distribution of atomic species within the amorphous matrix leading to a strong magnetic leverage effect and exchange pinning. The decoupling arises due to strong interactions between regions of high Co density which span the interface. The relatively sparse interactions between Sm and Co induce a localized pinning of the Co-rich areas, resulting in an exchange bias in minor loops and an enhanced coercivity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA- g -PS with High Molecular Weight Using Miniemulsion Polymerization

For this study, comb and centipede multigraft copolymers, poly(n-butyl acrylate)-g-polystyrene (PnBA-g-PS) with PnBA backbones and PS side chains, were synthesized via high-vacuum anionic polymerization and miniemulsion polymerization. Single-tailed and double-tailed PS macromonomers were synthesized by anionic polymerization and Steglich esterification. Subsequently, the copolymerization of each macromonomer and nBA was carried out in miniemulsion, and multigraft copolymers were obtained. The latex particles of multigraft copolymers were characterized using dynamic light scattering. The molecular weights of macromonomers and multigraft copolymers were analyzed by size exclusion chromatography. Moreover, the molecular weights and structures of macromonomers were investigated by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and 1H nuclear magnetic resonance spectroscopy. The weight contents of PS in comb and centipede multigraft copolymers were calculated by 1H nuclear magnetic resonance spectroscopy. The thermal properties of multigraft copolymers were characterized by thermogravimetric analysis and differential scanning calorimetry. The microphase separation of multigraft copolymers was observed by atomic force microscopy and transmission electronic microscopy. Rheological measurements showed that comb and centipede multigraft copolymers have elastic properties when the weight content of PS side chains is 26–32 wt %. Centipede multigraft copolymers possess better elastic properties than comb multigraft copolymers with the similar weight content of PS. In conclusion, these findings are similar to previous results on poly(isoprene-g-polystyrene) comb and centipede copolymers made by anionic polymerization.

36 MATERIALS SCIENCE↗

Microwave and THz sensing using slab-pair-based metamaterials

Here in this work the sensing capability of an artificial magnetic metamaterial based on pairs of metal slabs is demonstrated, both theoretically and experimentally, in the microwave regime. The demonstration is based on transmission measurements and simulations monitoring the shift of the magnetic resonance frequency as one changes a thin dielectric layer placed between the slabs of the pairs. Strong dependence of the magnetic resonance frequency on both the permittivity and the thickness of the dielectric layer under detection was observed. The sensitivity to the dielectrics' permittivity (ε) is larger for dielectrics of low ε values, which makes the approach suitable for sensing organic materials also in the THz regime. Finally, the capability of our approach for THz sensing is also demonstrated through simulations.

36 MATERIALS SCIENCE↗

A novel electron gun for inline MRI-linac configurations

Purpose: This work introduces a new electron gun geometry capable of robust functioning in the presence of a high strength external magnetic field for axisymmetric magnetic resonance imaging (MRI)-linac configurations. This allows an inline MRI-linac to operate without the need to isolate the linear accelerator (linac) using a magnetic shield. This MRI-linac integration approach not only leaves the magnet homogeneity unchanged but also provides the linac flexibility to move along the magnet axis of symmetry if the source to target distance needs to be adjusted. Methods: Simple electron gun geometry modifications of a Varian 600C electron gun are considered and solved in the presence of an external magnetic field in order to determine a set of design principles for the new geometry. Based on these results, a new gun geometry is proposed and optimized in the fringe field of a 0.5 T open bore MRI magnet (GE Signa SP). A computer model for the 6 MeV Varian 600C linac is used to determine the capture efficiency of the new electron gun-linac system in the presence of the fringe field of the same MRI scanner. The behavior of the new electron gun plus the linac system is also studied in the fringe fields of two other magnets, a 1.0 T prototype open bore magnet and a 1.5 T GE Conquest scanner. Results: Simple geometrical modifications of the original electron gun geometry do not provide feasible solutions. However, these tests show that a smaller transverse cathode diameter with a flat surface and a slightly larger anode diameter could alleviate the current loss due to beam interactions with the anode in the presence of magnetic fields. Based on these findings, an initial geometry resembling a parallel plate capacitor with a hole in the anode is proposed. The optimization procedure finds a cathode-anode distance of 5 mm, a focusing electrode angle of 5°, and an anode drift tube length of 17.1 mm. Also, the linac can be displaced with ±15 cm along the axis of the 0.5 T magnet without capture efficiency reduction below the experimental value in zero field. In this range of linac displacements, the electron beam generated by the new gun geometry is more effectively injected into the linac in the presence of an external magnetic field, resulting in approximately 20% increase of the target current compared to the original gun geometry behavior at zero field. The new gun geometry can generate and accelerate electron beams in external magnetic fields without current loss for fields higher than 0.11 T. The new electron-gun geometry is robust enough to function in the fringe fields of the other two magnets with a target current loss of no more than 16% with respect to the current obtained with no external magnetic fields. Conclusions: In this work, a specially designed electron gun was presented which can operate in the presence of axisymmetric strong magnetic fringe fields of MRI magnets. Computer simulations show that the electron gun can produce high quality beams which can be injected into a straight through linac such as Varian 600C and accelerated with more efficiency in the presence of the external magnetic fields. Also, the new configuration allows linac displacements along the magnet axis in a range equal to the diameter of the imaging spherical volume of the magnet under consideration. The new electron gun-linac system can function in the fringe field of a MRI magnet if the field strength at the cathode position is higher than 0.11 T. The capture efficiency of the linac depends on the magnetic field strength and the field gradient. The higher the gradient the better the capture efficiency. The capture efficiency does not degrade more than 16%.

43 PARTICLE ACCELERATORS↗

New Window into the Human Body

Michael Vannier, MD, a former NASA engineer, recognized the similarity between NASA's computerized image processing technology and nuclear magnetic resonance. With technical assistance from Kennedy Space Center, he developed a computer program for Mallinckrodt Institute of Radiology enabling Nuclear Magnetic Resonance (NMR) to scan body tissue for earlier diagnoses. Dr. Vannier feels that "satellite imaging" has opened a new window into the human body.

Source record↗

The suppression effect of external magnetic field on the high-power microwave window multipactor phenomenon

To suppress the surface multipactor phenomenon and improve the transmitting power of the high-power microwave window, the application of external magnetic fields is theoretically analyzed and simulated. A Monte Carlo algorithm is used to track the secondary electron trajectories and study the multipactor scenario on the surface of a cylinder window. It is confirmed that over-resonant magnetic fields (an external magnetic field whose magnitude is slightly greater than that of a resonant magnetic field) will generate a compensating trajectory and collision, which can suppress the secondary electron avalanche. The optimal value of this external magnetic field that will avoid the multipactor phenomenon on cylinder windows is discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Estradiol associations with brain functional connectivity in postmenopausal women

Abstract Objective Previous studies have found that estrogens play a role in functional connectivity in the brain; however, little research has been done regarding how estradiol is associated with functional connectivity in postmenopausal women. The purpose of this study was to examine the relationship between estradiol and functional connectivity in postmenopausal women. Methods Structural and blood oxygenation level–dependent resting-state magnetic resonance imaging scans of 88 cognitively healthy postmenopausal individuals were obtained along with blood samples collected the same day as the magnetic resonance imaging to assess hormone levels. We generated connectivity values in CONN toolbox version 20.b, an SPM-based software. Results A regression analysis was run using estradiol level and regions of interest (ROI), including the hippocampus, parahippocampus, dorsolateral prefrontal cortex, and precuneus. Estradiol level was found to enhance parahippocampal gyrus anterior division left functional connectivity during ROI-to-ROI regression analysis. Estradiol enhanced functional connectivity between the parahippocampal gyrus anterior division left and the precuneus as well as the parahippocampal gyrus anterior division left and parahippocampal gyrus posterior division right. An exploratory analysis showed that years since the final menstrual period was related to enhanced connectivity between regions within the frontoparietal network. Conclusions These results illustrated the relationship between estradiol level and functional connectivity in postmenopausal women. They have implications for understanding how the functioning of the brain changes for individuals after menopause that may eventually lead to changes in cognition and behavior in older ages.

Obstetrics & Gynecology↗

Effect of magnetic perturbations on turbulence-flow dynamics at the L-H transition on DIII-D

Detailed 2D turbulence measurements from the DIII-D tokamak provide an explanation for how resonant magnetic perturbations (RMPs) raise the L-H power threshold P LH [P. Gohil et al. , Nucl. Fusion 51 , 103020 (2011)] in ITER-relevant, low rotation, ITER-similar-shape plasmas with favorable ion ∇ B direction. RMPs simultaneously raise the turbulence decorrelation rate Δ ω D and reduce the flow shear rate ω shear in the stationary L-mode state preceding the L-H transition, thereby disrupting the turbulence shear suppression mechanism. RMPs also reduce the Reynolds stress drive for poloidal flow, contributing to the reduction of ω shear . On the ~100 μ s timescale of the L-H transition, RMPs reduce Reynolds-stress-driven energy transfer from turbulence to flows by an order of magnitude, challenging the energy depletion theory for the L-H trigger mechanism. In contrast, non-resonant magnetic perturbations, which do not significantly affect P LH , do not affect Δ ω D and only slightly reduce ω shear and Reynolds-stress-driven energy transfer.<

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Open-Access, Low-Magnetic-Field MRI System for Lung Research

An open-access magnetic resonance imaging (MRI) system is being developed for use in research on orientational/gravitational effects on lung physiology and function. The open-access geometry enables study of human subjects in diverse orientations. This system operates at a magnetic flux density, considerably smaller than the flux densities of typical other MRI systems, that can be generated by resistive electromagnet coils (instead of the more-expensive superconducting coils of the other systems). The human subject inhales air containing He-3 or Xe-129 atoms, the nuclear spins of which have been polarized by use of a laser beam to obtain a magnetic resonance that enables high-resolution gas space imaging at the low applied magnetic field. The system includes a bi-planar, constant-current, four-coil electromagnet assembly and associated electronic circuitry to apply a static magnetic field of 6.5 mT throughout the lung volume; planar coils and associated circuitry to apply a pulsed magnetic-field-gradient for each spatial dimension; a single, detachable radio-frequency coil and associated circuitry for inducing and detecting MRI signals; a table for supporting a horizontal subject; and electromagnetic shielding surrounding the electromagnet coils.

Mair, Ross W.↗

MR-Guided Focused Ultrasound for the Treatment of Uterine Fibroids

Magnetic resonance imaging-guided focused ultrasound (MRgFUS) ablation of uterine fibroids provides a minimally invasive outpatient technique for targeting and treating symptomatic uterine fibroids. Magnetic resonance imaging provides a guidance platform that has high temporal and spatial resolution for guiding, as well as thermal monitoring of the procedure. The high-intensity focused ultrasound provides a mechanism for delivering large amounts of energy directly into the fibroid without causing detrimental effects to the nontarget tissues. Early and intermediate follow-up of patients treated with MRgFUS provided promising results on the efficacy of the technique for providing symptom relief to patients. As more long-term follow-up data are published, the efficacy of this technique can be compared to more invasive surgical and minimally invasive catheter treatments.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Thermo-physical and structural studies of sodium zinc borovanadate glasses in the region of high concentration of modifier oxides

Highlights: ► Highly modified sodium zinc borovanadate glasses. ► Structural model for borovanadate glasses. ► Network forming tendency of ZnO in borovanadate glasses. ► Fragility can be limited to NBO concentration in borovanadate glasses. -- Abstract: This paper reports investigation of Na{sub 2}O and ZnO modified borovanadate glasses in the highly modified regime of compositions. These glasses have been prepared by microwave route. Ultraviolet (UV) and visible, infrared (IR), Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR) and Electron Paramagnetic Resonance (EPR) spectroscopies have been used to characterize the speciation in the glasses. Together with the variation of properties such as molar volume and glass transition temperatures, spectroscopic data indicate that at high levels of modification, ZnO tends to behave like network former. It is proposed that the observed variation of all the properties can be reasonably well understood with a structural model. The model considers that the modification and speciation in glasses are strongly determined by the hierarchy of group electronegativities. Further, it is proposed that the width of the transitions of glasses obtained under same condition reflects the fragility of the glasses. An empirical expression has been suggested to quantify fragility on the basis of width of the transition regions.

36 MATERIALS SCIENCE↗

Resolving Chemical and Spatial Heterogeneities at Complex Electrochemical Interfaces in Li-Ion Batteries

The high specific capacities of Ni-rich transition metal oxides have garnered immense interest for improving the energy density of Li-ion batteries (LIBs). Despite the potential of these materials, Ni-rich cathodes suffer from interfacial instabilities that lead to crystallographic rearrangement of the active material surface as well as the formation of a cathode electrolyte interphase (CEI) layer on the composite during electrochemical cycling. While changes in crystallographic structure can be detected with diffraction-based methods, probing the chemistry of the disordered, heterogeneous CEI layer is challenging. In this work, we use a combination of ex situ solid-state nuclear magnetic resonance (SSNMR) spectroscopy and X-ray photoemission electron microscopy (XPEEM) to provide chemical and spatial information, on the nanometer length scale, on the CEI deposited on LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) composite cathode films. XPEEM elemental maps offer insight into the lateral arrangement of the electrolyte decomposition products that comprise the CEI and paramagnetic interactions (assessed with electron paramagnetic resonance (EPR) and relaxation measurements) in 13 C SSNMR provide information on the radial arrangement of the CEI from the NMC811 particles outward. Using this approach, here we find that LiF, Li 2 CO 3 , and carboxy-containing structures are directly appended to NMC811 active particles, whereas soluble species detected during in situ 1 H and 19 F solution NMR experiments (e.g., alkyl carbonates, HF, and vinyl compounds) are randomly deposited on the composite surface. We show that the combined approach of ex situ SSNMR and XPEEM, in conjunction with in situ solution NMR, allows spatially-resolved, molecular-level characterization of paramagnetic surfaces and new insights into electrolyte oxidation mechanisms in porous electrode films.

36 MATERIALS SCIENCE↗

Using 3D Measurements from MRI to Improve VVUQ

Magnetic resonance velocimetry (MRV) is a diagnostic that can measure 3D, three-component turbulent velocity fields in arbitrarily complex flow configurations. The approach uses magnetic resonance imaging (MRI), which is a system commonly available in radiology departments or medical research centers. MRV acquires signal from hydrogen protons in water channel flows. Despite the obvious utility of the measurements for investigating a variety of flows, comparisons with computational fluid dynamic (CFD) simulations largely retain traditional metrics, comparing velocity profiles and planes at discrete regions within the flow rather than using the 3D nature of the measured field. In this effort, MRV was conducted in a simple water channel with six spanwise-centered periodic obstacles roughly shaped as cubes. At a fully turbulent Reynolds number of 15,000, the channel includes two flows: a main streamwise flow and, in the wake of the second obstacle, an injected flow oriented perpendicular to the streamwise flow. The flow geometry includes partial obstacles on the side walls and is inherently 3D because of the interaction of the two streams and the wake features, making the flow challenging to completely measure with traditional optical techniques. Aside from line profiles and planar comparisons, two 3D metrics are used to compare the data with a steady Reynolds-averaged Navier–Stokes (RANS) simulation result. A brief discussion about the comparison is provided, including comments about uncertainty.

Benson, Mike [ORNL] (ORCID:000000023210116X)↗

Quasi-mode evolution in a stochastic magnetic field

Abstract We present a multi-scale model of quasi-mode evolution in a stochastic magnetic field. The similarity between a quasi-mode and a ballooning mode enables us to address the challenges arising from the disparate geometries in the theories of ballooning modes in the presence of resonant magnetic perturbations. We obtain useful insights into our understanding of ballooning mode dynamics in a stochastic background. To maintain quasi-neutrality at all scales, the beat between the quasi-mode and the stochastic magnetic field drives microturbulence, which drives the turbulent background that promotes mixing and damps the quasi-mode. As a result of the broad mode structure of the quasi-mode, the turbulent viscosity and the turbulent diffusivity produced by the microturbulence are larger than those in our related study on resistive interchange modes. The stochastic magnetic field can also enhance the effective plasma inertia and reduce the effective drive, thereby slowing the mode growth. A nontrivial correlation between the microturbulence and the magnetic perturbations is shown to develop. This could account for the reduction in the Jensen–Shannon complexity of pedestal turbulence in the Resonant Magnetic Perturbation Edge-Localized Mode suppression phase observed in recent experiments. Directions for future experimental and theoretical studies are suggested.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dipole Approximation to Predict the Resonances of Dimers Composed of Dielectric Resonators for Directional Emission: Dielectric Dimers Dipole Approximation

In this paper we develop a fully-retarded, dipole approximation model to estimate the effective polarizabilities of a dimer made of dielectric resonators. They are computed from the polarizabilities of the two resonators composing the dimer. We analyze the situation of full-cubes as well as split-cubes, which have been shown to exhibit overlapping electric and magnetic resonances. We compare the effective dimer polarizabilities to ones retrieved via full-wave simulations as well as ones computed via a quasi-static, dipole approximation. We observe good agreement between the fully-retarded solution and the full-wave results, whereas the quasi-static approximation is less accurate for the problem at hand. The developed model can be used to predict the electric and magnetic resonances of a dimer under parallel or orthogonal (to the dimer axis) excitation. This is particularly helpful when interested in locating frequencies at which the dimer will emit directional radiation.

42 ENGINEERING↗

Sensitivity of Proposed Search for Axion-induced Magnetic Field using Optically Pumped Magnetometers

We investigate the sensitivity of a search for the oscillating current induced by axion dark matter in an external magnetic field using optically pumped magnetometers. This experiment is based upon the LC circuit (circuit with inductor and capacitor) axion detection concept of Sikivie et al. [Phys. Rev. Lett. 112, 131301 (2014)]. The modification of Maxwell’s equations caused by the axion-photon coupling results in a minute magnetic field oscillating at a frequency equal to the axion mass, in the presence of an external magnetic field. The axion-induced magnetic field could be searched for using a LC circuit amplifier with an optically pumped magnetometer, the most sensitive cryogen-free magnetic-field sensor, in a room-temperature experiment, avoiding the need for a complicated and expensive cryogenic system. Here, we discuss how an existing magnetic resonance imaging experiment can be modified to search for axions in a previously unexplored part of the parameter space. Our existing detection setup, optimized for magnetic resonance imagining, is already sensitive to an axion-photon coupling of 10 -7 GeV -1 for an axion mass near 3 × 10 -10 eV, which is already limited by astrophysical processes and solar axion searches. We show that realistic modifications, and optimization of the experiment for axion detection, can probe the axion-photon coupling up to 4 orders of magnitude beyond the current best limit, for axion masses between 10 -1 and 10 -7 eV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Low‐Field Borehole NMR Applications in the Near‐Surface Environment

Core Ideas Low‐field borehole NMR characterizes subsurface heterogeneities from pore to macro scales. Borehole NMR is sensitive to biogeochemical processes and conversions in the subsurface. Development of borehole NMR benefits hydrogeology, soil management, and engineering. The inherent heterogeneity of the near subsurface (<200 m below the ground surface) presents challenges for agricultural water management, hydrogeologic characterization, and engineering, among other fields. Borehole nuclear magnetic resonance (NMR) has the potential not only to describe this heterogeneity in space nondestructively but also to monitor physical and chemical changes in the subsurface with time. Nuclear magnetic resonance is sensitive to parameters of interest like porosity and permeability, saturation, fluid viscosity, and formation mineralogy. Borehole NMR tools have been used to measure soil moisture in model soils, and recent advances in low‐field borehole NMR instrumentation allow estimation of hydraulic properties of unconsolidated aquifers. We also demonstrate the potential for low‐field borehole NMR tools to monitor field‐relevant biogeochemical processes like biofilm accumulation and microbially induced calcite precipitation at laboratory and field scales. Finally, we address some remaining challenges and areas of future research, as well as other possible applications where borehole NMR could provide valuable complementary data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗