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At least 1,117 records · Page 62

Internet Based, GIS Catalog of Non-Traditional Sources of Cooling Water for Use at America's Coal-Fired Power Plants

In recent years, rising populations and regional droughts have caused coal-fired power plants to temporarily curtail or cease production due to a lack of available water for cooling. In addition, concerns about the availability of adequate supplies of cooling water have resulted in cancellation of plans to build much-needed new power plants. These issues, coupled with concern over the possible impacts of global climate change, have caused industry and community planners to seek alternate sources of water to supplement or replace existing supplies. The Department of Energy, through the National Energy Technology Laboratory (NETL) is researching ways to reduce the water demands of coal-fired power plants. As part of the NETL Program, ALL Consulting developed an internet-based Catalog of potential alternative sources of cooling water. The Catalog identifies alternative sources of water, such as mine discharge water, oil and gas produced water, saline aquifers, and publicly owned treatment works (POTWs), which could be used to supplement or replace existing surface water sources. This report provides an overview of the Catalog, and examines the benefits and challenges of using these alternative water sources for cooling water.

20 FOSSIL-FUELED POWER PLANTS↗

Fire Retardant/Heat Resistant Paint, Primer, Insulation and Other Construction Materials

The objective of this project, by BNL and PVI, is to develop fire retardant additive for paint, primer, insulation, other construction materials, as well as to draperies, window coverings, and carpets. With these additives, paint, primer, insulation and other construction materials become fire retardant. With additives manufactured in Russia, material cost increase is minimal, while labor construction cost are unchanged. Hence, the economic incentive: fireproof homes at insignificant additional cost.

99 GENERAL AND MISCELLANEOUS↗

Membrane Process to Capture CO 2 from Coal-Fired Power Plant Flue Gas

This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO 2 ) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO 2 in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO 2 capture process.

20 FOSSIL-FUELED POWER PLANTS↗

Site Characterization for CO 2 Storage from Coal-fired Power Facilities in the Black Warrior Basin of Alabama

Coal-fired power plants produce large quantities of carbon dioxide. In order to mitigate the greenhouse gas emissions from these power plants, it is necessary to separate and store the carbon dioxide. Saline formations provide a potential sink for carbon dioxide and delineating the capacity of the various known saline formations is a key part of building a storage inventory. As part of this effort, a project was undertaken to access the storage capacity of saline reservoirs in the Black Warrior Basin of Alabama. This basin has been a productive oil and gas reservoir that is well characterized to the west of the two major coal-fired power plants that are north of Birmingham. The saline zones were thought to extend as far east as the Sequatchie Anticline which is just east of the power plants. There is no oil or gas production in the area surrounding the power plants so little is known about the formations in that area. A geologic characterization well was drilled on the Gorgas Power Plant site, which is the farthest west of two power plants in the area. The well was planned to be drilled to approximately 8,000 feet, but drilling was halted at approximately 5,000 feet when a prolific freshwater zone was penetrated. During drilling, a complete set of cores through all of the potential injection zones and the seals above these zones were acquired. A complete set of openhole logs were run along with a vertical seismic profile (VSP). Before drilling started two approximately perpendicular seismic lines were run and later correlated with the VSP. While the zones that were expected were found at approximately the predicted depths, the zones that are typically saline through the reservoir were found to be saturated with a light crude oil. Unfortunately, both the porosity and permeability of these zones were small enough that no meaningful hydrocarbon production would be expected even with carbon dioxide flooding. While this part of the basin was found to be unsuitable for carbon dioxide injection, there is still a large storage capacity in the basin to the west of the power plants. It will, however, require pipeline construction to transport the carbon dioxide to the injection sites.

20 FOSSIL-FUELED POWER PLANTS↗

Optimized Solvent for Energy-Efficient, Environmentally-Friendly Capture of CO{sub 2} at Coal-Fired Power Plants

The overall goal of this project, as originally proposed, was to optimize the formulation of a novel solvent as a critical enabler for the cost-effective, energy-efficient, environmentally-friendly capture of CO{sub 2} at coal-fired utility plants. Aqueous blends of concentrated piperazine (PZ) with other compounds had been shown to exhibit high rates of CO{sub 2} absorption, low regeneration energy, and other desirable performance characteristics during an earlier 5-year development program conducted by B&W. The specific objective of this project was to identify PZ-based solvent formulations that globally optimize the performance of coal-fired power plants equipped with CO{sub 2} scrubbing systems. While previous solvent development studies have tended to focus on energy consumption and absorber size, important issues to be sure, the current work seeks to explore, understand, and optimize solvent formulation across the full gamut of issues related to commercial application of the technology: capital and operating costs, operability, reliability, environmental, health and safety (EH&S), etc. Work on the project was intended to be performed under four budget periods. The objective of the work in the first budget period has been to identify several candidate formulations of a concentrated PZ-based solvent for detailed characterization and evaluation. Work in the second budget period would generate reliable and comprehensive property and performance data for the identified formulations. Work in the third budget period would quantify the expected performance of the selected formulations in a commercial CO{sub 2} scrubbing process. Finally, work in the fourth budget period would provide a final technology feasibility study and a preliminary technology EH&S assessment. Due to other business priorities, however, B&W has requested that this project be terminated at the end of the first budget period. This document therefore serves as the final report for this project. It is the first volume of the two-volume final report and summarizes Budget Period 1 accomplishments under Tasks 1-5 of the project, including the selection of four solvent formulations for further study.

20 FOSSIL-FUELED POWER PLANTS↗

Subtask 4.27 - Evaluation of the Multielement Sorbent Trap (MEST) Method at an Illinois Coal-Fired Plant

Owners of fossil fuel-fired power plants face the challenge of measuring stack emissions of trace metals and acid gases at much lower levels than in the past as a result of increasingly stringent regulations. In the United States, the current reference methods for trace metals and halogens are wet-chemistry methods, U.S. Environmental Protection Agency (EPA) Methods 29 and 26 or 26A, respectively. As a possible alternative to the EPA methods, the Energy & Environmental Research Center (EERC) has developed a novel multielement sorbent trap (MEST) method to be used to sample for trace elements and/or halogens. Sorbent traps offer a potentially advantageous alternative to the existing sampling methods, as they are simpler to use and do not require expensive, breakable glassware or handling and shipping of hazardous reagents. Field tests comparing two sorbent trap applications (MEST-H for hydrochloric acid and MEST-M for trace metals) with the reference methods were conducted at two power plant units fueled by Illinois Basin bituminous coal. For hydrochloric acid, MEST measured concentrations comparable to EPA Method 26A at two power plant units, one with and one without a wet flue gas desulfurization scrubber. MEST-H provided lower detection limits for hydrochloric acid than the reference method. Results from a dry stack unit had better comparability between methods than results from a wet stack unit. This result was attributed to the very low emissions in the latter unit, as well as the difficulty of sampling in a saturated flue gas. Based on these results, the MEST-H sorbent traps appear to be a good candidate to serve as an alternative to Method 26A (or 26). For metals, the MEST trap gave lower detection limits compared to EPA Method 29 and produced comparable data for antimony, arsenic, beryllium, cobalt, manganese, selenium, and mercury for most test runs. However, the sorbent material produced elevated blanks for cadmium, nickel, lead, and chromium at levels that would interfere with accurate measurement at U.S. hazardous air pollutant emission limits for existing coal-fired power plant units. Longer sampling times employed during this test program did appear to improve comparative results for these metals. Although the sorbent contribution to the sample was reduced through improved trap design, additional research is still needed to explore lower-background materials before the MEST-M application can be considered as a potential alternative method for all of the trace metals. This subtask was funded through the EERC–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Electric Power Research Institute, the Illinois Clean Coal Institute, Southern Illinois Power Company, and the Center for Air Toxic Metals Affiliates Program.

Pavlish, John↗

Low Cost, High Capacity Regenerable Sorbent for Carbon Dioxide Capture from Existing Coal-fired Power Plants

In this project TDA Research, Inc (TDA) has developed a new post combustion carbon capture technology based on a vacuum swing adsorption system that uses a steam purge and demonstrated its technical feasibility and economic viability in laboratory-scale tests and tests in actual coal derived flue gas. TDA uses an advanced physical adsorbent to selectively remove CO 2 from the flue gas. The sorbent exhibits a much higher affinity for CO 2 than N 2 , H 2 O or O 2 , enabling effective CO 2 separation from the flue gas. We also carried out a detailed process design and analysis of the new system as part of both sub-critical and super-critical pulverized coal fired power plants. The new technology uses a low cost, high capacity adsorbent that selectively removes CO 2 in the presence of moisture at the flue gas temperature without a need for significant cooling of the flue gas or moisture removal. The sorbent is based on a TDA proprietary mesoporous carbon that consists of surface functionalized groups that remove CO 2 via physical adsorption. The high surface area and favorable porosity of the sorbent also provides a unique platform to introduce additional functionality, such as active groups to remove trace metals (e.g., Hg, As). In collaboration with the Advanced Power and Energy Program of the University of California, Irvine (UCI), TDA developed system simulation models using Aspen PlusTM simulation software to assess the economic viability of TDA’s VSA-based post-combustion carbon capture technology. The levelized cost of electricity including the TS&M costs for CO 2 is calculated as $116.71/MWh and $113.76/MWh for TDA system integrated with sub-critical and super-critical pulverized coal fired power plants; much lower than the $153.03/MWhand $147.44/MWh calculated for the corresponding amine based systems. The cost of CO 2 captured for TDA’s VSA based system is $38.90 and $39.71 per tonne compared to $65.46 and $66.56 per tonne for amine based system on 2011 $ basis, providing 40% lower cost of CO 2 captured. In this analysis we have used a sorbent life of 4 years. If a longer sorbent life can be maintained (which is not unreasonable for fixed bed commercial PSA systems), this would lower the cost of CO 2 captured by $0.05 per tonne (e.g., to $38.85 and $39.66 per tonne at 5 years sorbent replacement). These system analysis results suggest that TDA’s VSA-based post-combustion capture technology can substantially improve the power plant’s thermal performance while achieving near zero emissions, including greater than 90% carbon capture. The higher net plant efficiency and lower capital and operating costs results in a substantial reduction in the cost of carbon capture and cost of electricity for the power plant equipped with TDA’s technology.

20 FOSSIL-FUELED POWER PLANTS↗

Multi-Function Gas Fired Heat Pump

The aim of this project was to design a residential fuel fired heat pump and further improve efficiency in collaboration with an industry partner – Southwest Gas, the developer of the Nextaire commercial rooftop fuel-fired heat pump. Work started in late 2010. After extensive search for suitable engines, one manufactured by Marathon was selected. Several prototypes were designed and built over the following four years. Design changes were focused on lowering the cost of components and the cost of manufacturing. The design evolved to a final one that yielded the lowest cost. The final design also incorporates noise and vibration reduction measures that were verified to be effective through a customer survey. ETL certification is currently (as of November 2015) underway. Southwest Gas is currently in talks with GTI to reach an agreement through which GTI will assess the commercial viability and potential of the heat pump. Southwest Gas is searching for investors to manufacture the heat pump and introduce it to the market.

42 ENGINEERING↗

Novel Functionally Graded Thermal Barrier Coatings in Coal-Fired Power Plant Turbines

This project presents a detailed investigation of a novel functionally graded coating material, pyrochlore oxide, for thermal barrier coating (TBC) in gas turbines used in coal-fired power plants. Thermal barrier coatings are refractory materials deposited on gas turbine components, which provide thermal protection for metallic components at operating conditions. The ultimate goal of this research is to develop a manufacturing process to produce the novel low thermal conductivity and high thermal stability pyrochlore oxide based coatings with improved high-temperature durability. The current standard TBC, yttria stabilized zirconia (YSZ), has service temperatures limited to <1200°C, due to sintering and phase transition at higher temperatures. In contrast, pyrochlore oxide, e.g., lanthanum zirconate (La 2 Zr 2 O 7 , LZ), has demonstrated lower thermal conductivity and better thermal stability, which are crucial to high temperature applications, such as gas turbines used in coal-fired power plants. Indiana University – Purdue University Indianapolis (IUPUI) has collaborated with Praxair Surface Technologies (PST), and Changwon National University in South Korea to perform the proposed research. The research findings are critical to the extension of current TBCs to a broader range of high-temperature materials and applications. Several tasks were originally proposed and accomplished, with additional new opportunities identified during the course of the project. In this report, a description of the project tasks, the main findings and conclusions are given. A list of publications and presentations resulted from this research is listed in the Appendix at the end of the report.

20 FOSSIL-FUELED POWER PLANTS↗

Using Probability of Exceedance to Compare the Resource Risk of Renewable and Gas-Fired Generation

Of the myriad risks surrounding long-term investments in power plants, resource risk is one of the most difficult to mitigate, and is also perhaps the risk that most-clearly distinguishes renewable generation from natural gas-fired generation. For renewable generators like wind and solar projects, resource risk manifests as a quantity risk—i.e., the risk that the quantity of wind and insolation will be less than expected.i For gas-fired generators (i.e., a combined-cycle gas turbine or “CCGT”), resource risk manifests primarily as a price risk—i.e., the risk that natural gas will cost more than expected. Most often, resource risk—and natural gas price risk in particular—falls disproportionately on utility ratepayers, who are typically not well-equipped to manage this risk. As such, it is incumbent upon utilities, regulators, and policymakers to ensure that resource risk is taken into consideration when making or approving resource decisions, or enacting policies that influence the development of the electricity sector more broadly.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Large Pilot Scale Testing of Linde/BASF Post-Combustion CO 2 Capture Technology at the Abbott Coal-Fired Power Plant

The work summarized in this report is the first step towards a project that will re-train and create jobs for personnel in the coal industry and continue regional economic development to benefit regions impacted by previous downturns. The larger project is aimed at capturing ~300 tons/day (272 metric tonnes/day) CO 2 at a 90% capture rate from existing coal- fired boilers at the Abbott Power Plant on the campus of University of Illinois (UI). It will employ the Linde-BASF novel amine-based advanced CO 2 capture technology, which has already shown the potential to be cost-effective, energy efficient and compact at the 0.5-1.5 MWe pilot scales. The overall objective of the project is to design and install a scaled-up system of nominal 15 MWe size, integrate it with the Abbott Power Plant flue gas, steam and other utility systems, and demonstrate the viability of continuous operation under realistic conditions with high efficiency and capacity. The project will also begin to build a workforce that understands how to operate and maintain the capture plants by including students from regional community colleges and universities in the operation and evaluation of the capture system. This project will also lay the groundwork for follow-on projects that pilot utilization of the captured CO 2 from coal-fired power plants. The net impact will be to demonstrate a replicable means to (1) use a standardized procedure to evaluate power plants for their ability to be retrofitted with a pilot capture unit; (2) design and construct reliable capture systems based on the Linde-BASF technology; (3) operate and maintain these systems; (4) implement training programs with local community colleges and universities to establish a workforce to operate and maintain the systems; and (5) prepare to evaluate at the large pilot scale level various methods to utilize the resulting captured CO 2 . Towards the larger project goal, the UI-led team, together with Linde, has completed a preliminary design for the carbon capture pilot plant with basic engineering and cost estimates, established permitting needs, identified approaches to address Environmental, Health, and Safety concerns related to pilot plant installation and operation, developed approaches for long-term use of the captured carbon, and established strategies for workforce development and job creation that will re-train coal operators to operate carbon capture plants. This report describes Phase I accomplishments and demonstrates that the project team is well-prepared for full implementation of Phase 2, to design, build, and operate the carbon capture pilot plant.

01 COAL, LIGNITE, AND PEAT↗

LA-UR-14-27684, Analysis of Wildland Fire Hazard to the TWF at Los Alamos National Labs

Wildfires represent an Anticipated Natural Phenomena Hazard for LANL and the surrounding area. The TWF facility is located in a cleared area and is surrounded on three sides by roadway pavement. Therefore, direct propagation of flames to the facility is not considered the most credible means of ignition. Rather, fires started by airborne transport of burning brands constitute the most significant wildland fire threat to the TWF. The purpose of this document is to update LA-UR-13-24529, Airborne Projection of Burning Embers – Planning and Controls for Los Alamos National Laboratory Facilities, to be specific to the TWF site and operations.

54 ENVIRONMENTAL SCIENCES↗

Response of Nuclear Power Plant Instrumentation Cables Exposed to Fire Conditions.

This report presents the results of instrumentation cable tests sponsored by the US Nuclear Regulatory Commission (NRC) Office of Nuclear Regulatory Research and performed at Sandia National Laboratories (SNL). The goal of the tests was to assess thermal and electrical response behavior under fire-exposure conditions for instrumentation cables and circuits. The test objective was to assess how severe radiant heating conditions surrounding an instrumentation cable affect current or voltage signals in an instrumentation circuit. A total of thirty-nine small-scale tests were conducted. Ten different instrumentation cables were tested, ranging from one conductor to eight-twisted pairs. Because the focus of the tests was thermoset (TS) cables, only two of the ten cables had thermoplastic (TP) insulation and jacket material and the remaining eight cables were one of three different TS insulation and jacket material. Two instrumentation cables from previous cable fire testing were included, one TS and one TP. Three test circuits were used to simulate instrumentation circuits present in nuclear power plants: a 4–20 mA current loop, a 10–50 mA current loop and a 1–5 VDC voltage loop. A regression analysis was conducted to determine key variables affecting signal leakage time.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Healthy forests depend on balancing fire and water

Fire at first might seem exclusively destructive. According to the National Interagency Fire Center, in 2018 more than 50,000 wildfires scorched more than 8.5 million acres across the United States alone. Verisk’s 2017 Wildfire Risk Analysis reported losses from wildfires exceeded $5 billion during the past 10 years.

54 ENVIRONMENTAL SCIENCES↗

Project: Enabling Technologies for Oxy-fired Pressurized Fluidized Bed Combustor Systems (Final Project)

GTI and team members CanmetENERGY and Linde worked on developing technologies at the pilot-scale to significantly improve the performance and economics of current oxy-fired pressurized fluidized bed combustor systems and reduce scale up risk. The technologies include: an In-bed Supercritical CO 2 (SCO 2 ) Heat Exchanger, the objective being to quantify SCO 2 heat transfer coefficients and pressure drop in an Oxygen-fired pressurized fluidized bed combustor (Oxy-PFBC) environment to anchor design rules for scale up; Staged Coal Combustion, the objective being to develop design rules for placement of staged coal combustion injectors to appropriately distribute heat throughout the bed to maintain an oxidizing environment and avoid slagging; and an Isothermal Deoxidation Reactor, the objective being to define operational limits on flue gas O 2 concentration for an isothermal catalyst bed and demonstrate heat recovery from this deoxidation unit. In-bed SCO 2 heat exchanger manifolds were successfully manufactured and installed in the combustor at CanmetENERGY. Staged fuel injectors were designed and fabricated. A task to test an oxygen carrier in the fluidized bed was also planned. A Quasi-Isothermal Deoxidation Reactor (Q-IDR) concept was developed and fabricated, consisting of two adiabatic catalytic reactors with a single inter-stage cooler with SCO 2 as the coolant. The project was stopped prior to testing these technologies due to damage to the hardware on the related Oxy-PFBC Phase II project (DE-FE0009448).

20 FOSSIL-FUELED POWER PLANTS↗

Ensuring Reliable Natural Gas-Fired Power Generation with Fuel Contracts and Storage

This report finds that natural gas-fired power plants purchase fuel both on the spot market and through firm supply contracts; there do not appear to be clear drivers propelling power plants toward one or the other type. Most natural gas-fired power generators are located near major natural gas transmission pipelines, and most natural gas contracts are currently procured on the spot market. Although there is some regional variation in the type of contract used, a strong regional pattern does not emerge. Whether gas prices are higher with spot or firm contracts varies by both region and year.

20 FOSSIL-FUELED POWER PLANTS↗

Modeling the dynamical coupling between fires and atmospheric hydrodynamics [Slides]

The role of physic process-based modeling in wildfire behavior research : Fire experiments and field observations; Process-based fire behavior modeling; Models can help test our understanding; Models can assist in the development of hypotheses, which can be tested with observations; Models can allow scenario and sensitivity explorations when observations are difficult; It is important to keep in mind the assumptions/approximations of model formulations (only partial physics).

58 GEOSCIENCES↗

Criticality Control Overpack Fire Testing (Phase III)

This report will describe the one test conducted during phase III of the Pipe Overpack Container (POC) test campaign, present preliminary results from these tests, and discuss implications for the Criticality Control Overpack (CCO). The goal of this test was to see if aerosol surrogate material inside the Criticality Control Container (CCC) gets released when the drum lid of the CCO comes off during a thirty-minute long, fully-engulfing, fire test. As expected from POC tests conducted in Phase I and II of this test campaign, the CCO drum lid is ejected about one minute after the drum is exposed to fully-engulfing flames. The remaining pressure inside the drum is high enough to eject the top plywood dunnage a considerable distance from the drum. Subsequently, most of the bottom plywood dunnage supporting the CCC burns off during and after the fire. High pressure buildup inside the CCC and inside two primary containers holding the surrogate powder also results in damage to the filter media of the CCC and the filter-house, thread attachment of the primary canisters. No discernable release of surrogate powder material was detected from the two primary containers when pre- and post-test average mass were compared. However, when the average masses are corrected to account for possible uncertainties in mass measurements, error overlap does not preclude the possibility that some surrogate powder mass may have been lost from these primary canisters. Still, post-test conditions of the secondary canisters enclosing these two primary canisters suggest it is very unlikely this mass loss would have escaped into the CCC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗