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At least 1,117 records · Page 62

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NASA NTRS1980

Temperature and moisture analysis in composites

Advanced fiber-reinforced polymeric matric composites have emerged as strong candidate materials for airframe applications. Favorable aspects include high strength, stiffness, and low density. Temperature and Moisture Analysis in Composites (TMAC) program was developed to study effect of variations in diffusion coefficients, surface properties, panel tilt, ground reflection, and geographical location on moisture-concentration profiles and average moisture contents of composite laminates.

Tenney, D. R.↗

NASA NTRS1980

Scratch encourages selective doping

Dislocations induced by scratching produce deep narrow spikes of zinc diffused in gallium arsenide. Density of defects formed locally increases zinc diffusion coefficient. Enhancements by factor of 6 have been observed. Technique works for other dopants than zinc and for other semiconductors besides GaAs.

Hawrylo, F. Z.↗

NASA NTRS1979

Mathematical model for steady state, simple ampholyte isoelectric focusing: Development, computer simulation and implementation

The elimination of Ampholine from the system by establishing the pH gradient with simple ampholytes is proposed. A mathematical model was exercised at the level of the two-component system by using values for mobilities, diffusion coefficients, and dissociation constants representative of glutamic acid and histidine. The constants assumed in the calculations are reported. The predictions of the model and computer simulation of isoelectric focusing experiments are in direct importance to obtain Ampholine-free, stable pH gradients.

Palusinski, O. A.↗

NASA NTRS1979

Mathematical model investigation of long-term transport of ocean-dumped sewage sludge related to remote sensing

An existing, three-dimensional, Eulerian-Lagrangian finite-difference model was modified and used to examine the transport processes of dumped sewage sludge in the New York Bight. Both in situ and laboratory data were utilized in an attempt to approximate model inputs such as mean current speed, horizontal diffusion coefficients, particle size distributions, and specific gravities. The results presented are a quantitative description of the fate of a negatively buoyant sewage sludge plume resulting from continuous and instantaneous barge releases. Concentrations of the sludge near the surface were compared qualitatively with those remotely sensed. Laboratory study was performed to investigate the behavior of sewage sludge dumping in various ambient density conditions.

Kuo, C. Y.↗

NASA NTRS1979

Decay of the zincate concentration gradient at an alkaline zinc cathode after charging

The transport of the zincate ion to the alkaline zinc cathode was studied by observing the decay of the zincate concentration gradient at a horizontal zinc cathode after charging. This decay was found to approximate first order kinetics as expected from a proposed boundary layer model. The concentrations were calculated from polarization voltages. The decay half life was shown to be a linear function of the thickness of porous zinc deposit on the cathode indicating a very rapid transport of zincate through porous zinc metal. The rapid transport is attributed to an electrochemical mechanism. From the linear dependence of the half life on the thickness the boundary layer thickness was found to be about 0.010 cm when the cathode was at the bottom of the cell. No significant dependence of the boundary layer thickness on the viscosity of electrolyte was observed. The data also indicated a relatively sharp transition between the diffusion and convection transport regions. When the cathode was at the top of the cell, the boundary layer thickness was found to be roughly 0.080 cm. The diffusion of zincate ion through asbestos submerged in alkaline electrolyte was shown to be comparable with that predicted from the bulk diffusion coefficient of the zincate ion in alkali.

Kautz, H. E.↗

NASA NTRS1979

The NASA-Ames Research Center stratospheric aerosol model. 2. Sensitivity studies and comparison with observatories

Sensitivity tests were performed on a one-dimensional, physical-chemical model of the unperturbed stratospheric aerosols, and model calculations were compared with observations. The tests and comparisons suggest that coagulation controls the particle number mixing ratio, although the number of condensation nuclei at the tropopause and the diffusion coefficient at high altitudes are also important. The sulfur gas source strength and the aerosol residence time are much more important than the supply of condensation nuclei in establishing mass and large particle concentrations. The particle size is also controlled mainly by gas supply and residence time. In situ observations of the aerosols and laboratory measurements of aerosols, parameters that can provide further information about the physics and chemistry of the stratosphere and the aerosols found there are provided.

Toon, O. B.↗

NASA NTRS1979

Numerical methods of solving a system of multi-dimensional nonlinear equations of the diffusion type

The principles of conservation and stability of difference schemes achieved using the iteration control method were examined. For the schemes obtained of the predictor-corrector type, the conversion was proved for the control sequences of approximate solutions to the precise solutions in the Sobolev metrics. Algorithms were developed for reducing the differential problem to integral relationships, whose solution methods are known, were designed. The algorithms for the problem solution are classified depending on the non-linearity of the diffusion coefficients, and practical recommendations for their effective use are given.

Agapov, A. V.↗

NASA NTRS1979

Moisture diffusion parameter characteristics for epoxy composites and neat resins

The moisture absorption characteristics of two graphite/epoxy composites and their corresponding cured neat resins were studied in high humidity and water immersion environments at elevated temperatures. Moisture absorption parameters, such as equilibrium moisture content and diffusion coefficient derived from data taken on samples exposed to high humidity and water soak environments, were compared. Composite swelling in a water immersion environment was measured. Tensile strengths of cured neat resin were measured as a function of their equilibrium moisture content after exposure to different moisture environments. The effects of intermittent moderate tensile loads on the moisture absorption parameters of composite and cured neat resin samples were determined.

Long, E. R., Jr.↗

NASA NTRS1978

Non-thermal hydrogen in the Venus exosphere - The ionospheric source and the hydrogen budget

A nonthermal, or 'hot', Venus corona of H atoms has been observed by Mariners 5 and 10 and Venera 9. Of the sources investigated, reaction of H2 with ionospheric O(+) is still the strongest. It can explain the smaller densities but falls somewhat short of the largest (from Mariner 5). The subsequent recombination of OH(+), supplemented by solar-wind processes, may give an escape flux of 10 million atoms per sq cm/s. The low density of thermal H atoms on the day side has previously been attributed to either a large eddy diffusion coefficient or an escape flux tenfold greater than this. An alternative mechanism, suggested by Hartle and Mayr (1977) is supported: the hydrogen is swept to the night side by strong thermospheric winds. This process is analogous to the 'Johnson pump' for the terrestrial winter helium bulge. Large nightside bulges of H and H2 are predicted; the night/day density ratio is estimated to be as large as 100 for each.

Kumar, S.↗

NASA NTRS1978

Closure of a kinetic model of plasma in strong turbulence by relaxation

A Fokker-Planck kinetic equation for a turbulent plasma is derived by a repeated cascade decomposition. Calculation of the propagator and the kinetic equation determine the transport coefficients (diffusivity and turbulent viscosity) by means of a closure based on a relaxation procedure governing the approach to equilibrium. The k to the minus third power spectral law is obtained, which governs the coupling between the velocity and the electrostatic field fluctuations.

Tchen, C. M.↗

NASA NTRS1979

Further observational support for the lossy radial diffusion model of the inner Jovian magnetosphere

A mathematical model describing radial diffusion, with violation of the third adiabatic invariant and with local losses, is applied to the Pioneer 10 and 11 observations of omnidirectional integral intensities of electrons with energy exceeding 21 MeV. Local losses outside L = 3 are much stronger than synchrotron losses but weaker than the losses one would expect for strong pitch angle diffusion. If radial diffusion is driven by ionospheric winds, as was suggested by Brice and McDonough (1973), it is found that the theoretical solution which best fits the data requires that the radial diffusion coefficient equals 3 x 10 to the -9th L-cubed/s and the lifetime against local losses is approximately a few million seconds.

Goertz, C. K.↗

NASA NTRS1979

Acceleration and transport of galactic cosmic rays

A recently proposed cosmic-ray acceleration mechanism is combined with a model of transport and loss from the Galaxy to construct a model for galactic cosmic rays. Various aspects of the cosmic-ray spectrum, including the secondary-to-primary ratio as a function of energy, are found to fit naturally into the overall picture. A solution to the dynamical-halo model with energy-dependent diffusion coefficient (kappa) is presented. This model is consistent with the observed spectra if kappa is proportional to the square root of the kinetic energy. The observed flattening of the secondary-to-primary ratio below about 1-2 GeV per nucleon is shown to be a natural consequence of the model. Similarly, the primary electron spectrum is predicted to flatten below about 1-2 GeV, which is consistent with deconvolution of the local nonthermal radio spectrum, although the flattening is not quite as much as indicated by the observations.

Jokipii, J. R.↗

NASA NTRS1979

The Galilean satellites as a source of CO in the Jovian upper atmosphere

Material from the Galilean satellites of Jupiter ejected by energetic particles in the Jovian magnetosphere may provide large sources of oxygen to the parent planet. Formation of a CO molecule is the ultimate fate of an oxygen atom in the upper Jovian atmosphere. This high-altitude source of CO supports Beer and Taylor's (1978) observations and analysis, provided that the globally averaged O atom input flux is about 10 million per sq cm/sec and the eddy diffusion coefficient at the tropopause is around 1000 sq cm/sec. Implications for the possible presence of other atoms and molecules derived from the satellites are discussed.

Strobel, D. F.↗

NASA NTRS1979

The role of thermophysics in the design, optimization and understanding of semiconductor crystal growth in space

The compound semiconductor material PbSnTe has been investigated by NASA Langley Research Center as part of the Material Processing in Space (MPS) experiment in the framework of the Space Shuttle program. The long-range goal of the research is the improving of the performance of infrared detectors for use in remote sensing experiments. Three distinct techniques will be used in the low-g environment of space: two techniques involving bulk growth from melt and a vapor growth technique. In order to establish realistic estimates of the required time for experiments and to determine the thermal gradients that will be required to avoid constitutional supercooling, the diffusion coefficients must be accurately measured, however more data especially in the vapor-solid phase relations are needed.

Crouch, R. K.↗

NASA NTRS1979

On solar cosmic rays

The report summarizes the major results obtained over the last four years in the following areas: (1) transport in interplanetary space which includes solar particle observations combined with theoretical efforts to develop models which simulate the dynamics of the event; (2) transport in the solar corona and release of particles in the interplanetary medium; and (3) characteristics of source spectra and acceleration models. Modelling the propagation of solar cosmic rays through interplanetary space and establishing the magnitude and the radial and energy dependence of the diffusion coefficient K are considered. An important result due to statistical observation is that the coronal propagation must be independent of or weakly dependent on both rigidity and energy. Increasing evidence is found for prolonged injection at the sun.

Van Hollebeke, M. A. I.↗

NASA NTRS1979

An interpretation of the Voyager measurement of Jovian electron density profiles

Electron-density profiles measured for the daytime and nighttime Jovian ionosphere by the Voyager 1 radio-science experiment are analyzed. It is found that the measured profiles can be reproduced by using a model appropriate for an exospheric temperature of 1300 K with temperature varying above the homopause and with an eddy diffusion coefficient of 100,000 to 300,000 sq cm/s at the homopause. An overall rate constant of 4.3 x 10 to the -16th cu cm/s is estimated for the reaction H(+) + H2 (v-prime at least 4) yields H2(+) + H.

Atreya, S. K.↗

NASA NTRS1980

A study on the electrolysis of sulfur dioxide and water for the sulfur cycle hydrogen production process

Experimental electrolysis cells using various platinum catalyzed carbon electrodes were tested. When operated at 200 mA/sq cm current density using 50 w/o acid at 50 C and 1 atm, a reference cell required 1.22 volts and degraded rapidly. After several improvements were incorporated into electrodes and the test cell configuration, a later cell required only 0.77 volts under identical operating conditions. At a lower current density, 100 mA/sq cm, the cell required only 0.63 volts. Kinetic studies on metal electrodes, measurements of temperature effects on electrode kinetics, investigations of electrocatalytic activities of metal electrodes over a wide range of acid concentrations, cyclic voltametric studies and evaluation of alternate catalysts were also conducted. From diffusivity experiments, a cation exchange membrane material, P-4010, exhibited an excellent diffusion coefficient, more than two orders of magnitude lower than that of rubber. Ionic resistivity measurements of eight materials showed that microporous rubber had the lowest resistivity.

Source record↗

NASA NTRS1979

Solar-wind interactions with the moon - Role of oxygen ions

The role of oxygen ions in the solar-wind interactions with the lunar surface due to tenuous atmosphere and magnetic field is examined. The interaction results in an absorption of the solar-wind corpuscles producing no upstream bowshock but a cavity downstream, and the oxygen ionic species undergo a set of reactions with the lunar minerals and the solar-wind derived trapped gases. The oxygen concentrations in the lunar surface material and the solar-wind species flux are discussed, noting that for the contributions of oxygen from the lunar surface grains to the atmosphere, the diffusion coefficients of oxygen atom and molecules should be known. The coefficients are calculated by using the apparent lifetimes of oxygen in the lunar material, and the atmospheric concentration of oxygen atoms and molecules near the lunar surface were compared with the Apollo 17 lunar orbital data.

Mukherjee, N. R.↗