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NASA NTRS1993

Seasonal variation of surface and atmospheric cloud radiative forcing over the globe derived from satellite data

Global distributions of surface and atmospheric cloud radiative forcing parameters have been derived using parameterized radiation models with satellite meteorological data from the International Satellite Cloud Climatology Project, and directly measured top-of-atmosphere radiative fluxes from the Earth Radiation Budget Experiment. Specifically, shortwave, longwave, and total cloud forcing at the surface, and column-averaged values of longwave cloud forcing of the atmosphere were derived for the midseasonal months of April, July, and October 1985 and January 1986, covering a complete annual cycle. Seasonal variability is illustrated by comparing the results for July 1985 and January 1986, which represent the seasonal extremes. Surface shortwave cloud forcing is always negative, representing a cooling of the surface, with strongest cooling (-120 to -180 W/sq m) occurring over midlatitude storm tracks of the summer hemisphere. Surface longwave cloud forcing is always positive, representing a warming of the surface, with strongest warming (60 to 75 W/sq m) occurring over storm tracks of the winter hemisphere. Zonal averages show the entire summer hemisphere dominated by shortwave cooling, the middle and high latitudes of the winter hemisphere dominated by longwave warming, and a broad zone of transition in between. The globally averaged total cloud forcing amounts to a cooling throughout the year, ranging from a low of about -12 W/sq m for July 1985 to a high of about -25 W/sq m for January 1986. The longwave cloud forcing of the atmosphere shows a strong warming over deep convective regions in the tropics and a moderate cooling outside the tropics, amounting to a weak cooling (-2 to -5 W/sq m) in the global average. Comparisons of the results with general circulation model simulations show broad qualitative agreement regarding the locations of prominent warming and cooling regions. Quantitative comparisons, on the other hand, show significant differences between the magnitudes of warming and cooling in these regions. Most of the larger differences can be attributed to known deficiences of the general circulation model simulations. Comparisons with satellite-derived results of other investigators show much better agreement.

Gupta, Shashi K.↗
NASA NTRS1995

The fate of atmospheric phosgene and the stratospheric chlorine loadings of its parent compounds: CCl4, C2Cl4, C2HCL3, CH3CCl3, and CHCl3

A study of the tropospheric and stratospheric cycles of phosgene is carried out to determine its fate and ultimate role in controlling the ozone depletion potentials of its parent compounds. Tropospheric phosgene is produced from the OH-initiated oxidation of C2Cl4, CH3CCl3, CHCl3, and C2HCl3. Simulations using a two-dimensional model indicate that these processes produce about 90 pptv/yr of tropospheric phosgene with an average concentration of about 18 pptv, in reasonable agreement with observations. We estimate a residence time of about 70 days for tropospheric phosgene, with the vast majority being removed by hydrolysis in cloudwater. Only about 0.4% of the phosgene produced in the troposphere avoids wet removal and is transported to the stratosphere, where its chlorine can be released to participate in the catalytic destruction of ozone. Stratospheric phosgene is produced from the photochemical degradation of CCl4, C2Cl4, CHCl3, and CH3CCl3 and is removed by photolysis and downward transport to the troposphere. Model calculations, in good agreement with observations, indicate that these processes produce a peak stratospheric concentration of about 25-30 pptv at an altitude of about 25 km. In contrast to tropospheric phosgene, stratospheric phosgene is found to have a lifetime against photochemical removal of the order of years. As a result, a significant portion of the phosgene that is produced in the stratosphere is ultimately returned to the troposphere, where it is rapidly removed by clouds. This phenomenon effectively decreases the amount of reactive chlorine injected into the stratosphere and available for ozone depletion from phosgene's parent compounds. A similar phenomenon due to the downward transport of stratospheric COFCl produced from CFC-11 is estimated to cause a 7% decrease in the amount of reactive chlorine injected into the stratosphere from this compound. Our results are potentially sensitive to a variety of parameters, most notably the rate of reaction of phosgene with sulfate aerosols. However, on the basis of the observed vertical distribution of COCl2, we estimate that the reaction of COCl2 with sulfate aerosol most likely has a gamma less than 5 x 10(exp -5) and, as a result, has a negligible impact on the stratospheric chlorine loadings of the phosgene parent compounds.

Kindler, T. P.↗
NASA NTRS1994

Observations of stratospheric hydrogen fluoride by halogen occultation experiment (HALOE)

The Halogen Occultation Experiment (HALOE) Hydrogen Fluoride (HF) channel on the Upper Atmospheric Research Satellite (UARS) is providing the first global measurements of stratospheric HF, the dominant flourine reservoir in the atmosphere. This paper describes the latitudinal and seasonal variations of HALOE-observed HF in terms of vertical profiles, altitude/latitude cross sections, and column abundances. The HF global distribution shows a 'tracerlike' structure and its column amount increases with latitude, in agreement with previous aircraft measurements of the HF column amount. A comparison between the HALOE HF column above 20 km and the ATMOS 1985 measurements is used to estimate the annual rate of increase of stratospheric HF. Exponential rates of 4.9-6.6%/yr and linear growth rates of 6-8.6%/yr in 1985 and 4.3-5.5%/yr in 1992-1993 are found. HALOE HF measurements during the 1993 Antarctic spring are briefly described. This species behaves like a conserved tracer and its distribution shows an area of enhanced mixing ratios correlated with the polar vortex that has a clear latitude boundary. Finally, simulated HF distributions by the National Center for Atmospheric Research (NCAR) two-dimensional model are used to compare with HALOE observations of HF. Reasonable agreements in the global structure and the absolute amount of HF are found. The differences between the model and the observed results indicate the need for improving treatment of atmospheric dynamics and fluorine-related chemical parameters in the model simulations.

Luo, M.↗
NASA NTRS1995

Gas-phase chemistry in dense interstellar clouds including grain surface molecular depletion and desorption

We present time-dependent models of the chemical evolution of molecular clouds which include depletion of atoms and molecules onto grain surfaces and desorption, as well as gas-phase interactions. We have included three mechanisms to remove species from the grain mantles: thermal evaporation, cosmic-ray-induced heating, and photodesorption. A wide range of parameter space has been explored to examine the abundance of species present both on the grain mantles and in the gas phase as a function of both position in the cloud (visual extinction) and of evolutionary state (time). The dominant mechanism that removes molecules from the grain mantles is cosmic-ray desorption. At times greater than the depletion timescale, the abundances of some simple species agree with abundances observed in the cold dark cloud TMC-1. Even though cosmic-ray desorption preserves the gas-phase chemistry at late times, molecules do show significant depletions from the gas phase. Examination of the dependence of depletion as a function of density shows that when the density increases from 10(exp 3)/cc to 10(exp 5)/cc several species including HCO(+), HCN, and CN show gas-phase abundance reductions of over an order of magnitude. The CO: H2O ratio in the grain mantles for our standard model is on the order of 10:1, in reasonable agreement with observations of nonpolar CO ice features in rho Ophiuchus and Serpens. We have also examined the interdependence of CO depletion with the space density of molecular hydrogen and binding energy to the grain surface. We find that the observed depletion of CO in Taurus in inconsistent with CO bonding in an H2O rich mantle, in agreement with observations. We suggest that if interstellar grains consist of an outer layer of CO ice, then the binding energies for many species to the grain mantle may be lower than commonly used, and a significant portion of molecular material may be maintained in the gas phase.

Bergin, E. A.↗
NASA NTRS1995

One-dimensional hybrid satellite track model for the Dynamics Explorer 2 (DE 2) satellite

A one-dimensional hybrid satellite track model has been developed to calculate the high-latitude thermospheric/ionospheric structure below the satellite altitude using Dynamics Explorer 2 (DE 2) satellite measurements and theory. This model is based on Emery et al. (1985) satellite track code but also includes elements of Roble et al. (1987b) global mean thermosphere/ionosphere model. A number of parameterizations and data handling techniques are used to input satellite data from several DE 2 instruments into this model. Profiles of neutral atmospheric densities are determined from the Mass Spectrometer Incoherent Scatter 1990 (MSIS-90) model and measured neutral temperatures. Measured electron precipitation spectra are used in an auroral model to calculate particle impact ionization rates below the satellite. These rates are combined with a solar ionization rate profile and used to solve the O(+) diffusion equation, with the measured electron density as an upper boundary condition. The calculated O(+) density distribution, as well as the ionization profiles, are then used in a photochemical equilibrium model to calculate the electron and molecular ion densities. The electron temperature is also calculated by solving the electron energy equation with an upper boundary condition determined by the DE 2 measurement. The model enables calculations of altitude profiles of conductivity and Joule heating rate along and below the satellite track. In a first application of the new model, a study is made of thermospheric and ionospheric structure below the DE 2 satellite for a single orbit which occurred on October 25, 1981. The field-aligned Poynting flux, which is independently obtained for this orbit, is compared with the model predictions of the height-integrated energy conversion rate. Good quantitative agreement between these two estimates has been reached. In addition, measurements taken at the incoherent scatter radar site at Chatanika (65.1 deg N, 147.4 deg W) during a DE 2 overflight are compared with the model calculations. A good agreement was found in lower thermospheric conductivities and Joule heating rate.

Deng, Wei↗
NASA NTRS1993

A comparison of in situ measurements of vector-E and - vector-V x vector-B from Dynamics Explorer 2

Dynamics Explorer-2 provided the first opportunity to make a direct comparison of in situ measurements of the high-latitude convection electric field by two distinctly different techniques. The vector electric field instrument (VEFI) used antennae to measure the intrinsic electric fields and the ion drift meter (IDM) and retarding potential analyzer (RPA) measured the ion drift velocity vector, from which the convection electric field can be deduced. The data from three orbits having large electric fields at high latitude are presented, one at high, one at medium, and one at low altitudes. The general agreement between the two measurements of electric field is very good, with typical differences at high latitudes of the order of a few millivolts per meter, but there are some regions where the particle fluxes are extremely large (e.g., the cusp) and the disagreement is worse, probably because of IDM difficulties. The auroral zone potential patterns derived from the two devices are in excellent agreement for two of the cases, but not in the third, where bad attitude data may be the problem. At low latitudes there are persistent differences in the measurements of a few millivolts per meter, though these differences are quite constant from orbit to orbit. This problem seems to arise from some shortcoming in the VEFI measurments. Overall, however, these measurements confirm the concept of `frozen-in' plasma that drifts with velocity vector-E x vector-B/B(exp 2) within the measurement errors of the two techniques.

Hanson, W. B.↗
NASA NTRS1993

Absorption by H2O and H2O-N2 mixtures at 153 GHz

New experimental data on and a theoretical analysis of the absorption coefficient at 153 GHz are presented for pure water vapor and water vapor-nitrogen mixtures. This frequency is 30 GHz lower than the resonant frequency of the nearest strong water line (183 GHz) and complements our previous measurements at 213 GHz. The pressure dependence is observed to be quadratic in the case of pure water vapor, while in the case of mixtures there are both linear and quadratic density components. By fitting our experimental data taken at several temperatures we have obtained the temperature dependence of the absorption. Our experimental data are compared to several theoretical models with and without a continuum contribution, and we find that none of the models is in very good agreement with the data; in the case of pure water vapor, the continuum contribution calculated using the recent theoretical absorption gives the best results. In general, the agreement between the data and the various models is less satisfactory than found previously in the high-frequency wing. The anisotropy in the observed absorption differs from that currently used in atmospheric models.

Bauer, A.↗
NASA NTRS1994

Hot gas in the cold dark matter scenario: X-ray clusters from a high-resolution numerical simulation

A new, three-dimensional, shock-capturing hydrodynamic code is utilized to determine the distribution of hot gas in a standard cold dark matter (CDM) model of the universe. Periodic boundary conditions are assumed: a box with size 85 h(exp -1) Mpc having cell size 0.31 h(exp -1) Mpc is followed in a simulation with 270(exp 3) = 10(exp 7.3) cells. Adopting standard parameters determined from COBE and light-element nucleosynthesis, sigma(sub 8) = 1.05, omega(sub b) = 0.06, and assuming h = 0.5, we find the X-ray-emitting clusters and compute the luminosity function at several wavelengths, the temperature distribution, and estimated sizes, as well as the evolution of these quantities with redshift. We find that most of the total X-ray emissivity in our box originates in a relatively small number of identifiable clusters which occupy approximately 10(exp -3) of the box volume. This standard CDM model, normalized to COBE, produces approximately 5 times too much emission from clusters having L(sub x) is greater than 10(exp 43) ergs/s, a not-unexpected result. If all other parameters were unchanged, we would expect adequate agreement for sigma(sub 8) = 0.6. This provides a new and independent argument for lower small-scale power than standard CDM at the 8 h(exp -1) Mpc scale. The background radiation field at 1 keV due to clusters in this model is approximately one-third of the observed background, which, after correction for numerical effects, again indicates approximately 5 times too much emission and the appropriateness of sigma(sub 8) = 0.6. If we have used the observed ratio of gas to total mass in clusters, rather than basing the mean density on light-element nucleosynthesis, then the computed luminosity of each cluster would have increased still further, by a factor of approximately 10. The number density of clusters increases to z approximately 1, but the luminosity per typical cluster decreases, with the result that evolution in the number density of bright clusters is moderate in this redshift range, showing a broad peak near z = 0.7, and then a rapid decline above redshift z = 3. Detailed computations of the luminosity functions in the range L(sub x) = 10(exp 40) - 10(exp 44) ergs/s in various energy bands are presented for both cluster central regions and total luminosities to be used in comparison with ROSAT and other observational data sets. The quantitative results found disagree significantly with those found by other investigators using semianalytic techniques. We find little dependence of core radius on cluster luminosity and a dependence of temperature on luminosity given by log kT(sub x) = A + B log L(sub x), which is slightly steeper (B = 0.38) than is indicated by observations. Computed temperatures are somewhat higher than observed, as expected, in that COBE-normalized CDM has too much power on the relevant scales. A modest average temperature gradient is found, with temperatures dropping to 90% of central values at 0.4 h(exp -1) Mpc and 70% of central values at 0.9 h(exp -1) Mpc. Examining the ratio of gas to total mass in the clusters normalized to Omega(sub B) h(exp 2) = 0.015, and comparing with observations, we conclude, in agreement with White (1991), that the cluster observations argue for an open universe.

Kang, Hyesung↗
NASA NTRS1994

Oscillator strengths of selected resonance transitions in neutral sulfur

Mean lives and branching ratios for the 4s (3)S(sup 0 sub 1) and 4s(double prime) (3)P(sup 0 sub 1, 2) levels of neutral sulfur were determined at the Toledo Heavy Ion Accelerator using beam-foil spectroscopic techniques. The mean lives obtained for the 4s (3)S(sup 0 sub 1) 4s(double prime) (3)P(sup 0 sub 1), and (3)P(sup 0 sub 2) levels, 1.875 +/- 0.094 ns, 2.034 +/- 0.102 ns, and 2.146 +/- 0.129 ns, respectively, represent the most accurate results available to date. Oscillator strengths for the transitions 3p(sup 4)(3)P(sub 2, 1, 0)-4s (3)S(sup 0 sub 1) and 3p(sup 4)(3)P(sub 2, 1, 0)-4s(double prime) (3)P(sup 0 sub 1, 2) were derived from these mean lives together with the measured branching ratios. For comparison with published results which present only multiplet f-values, such f-values were computed from the measured individual line oscillator strengths. The value obtained for the 3p(sup 4)(3)P-4s(sup 3)S(sup 0) multiplet at 1814 A is 0.088 +/- 0.005, in good agreement with the mean of previous experimental measurements and theoretical calculations. With the mean life for the 4s(double prime) 3P(sup 0 sub 0) level set equal to the mean of our determination for the other two 4s(double prime) (3)P(sup 0) levels (a valid assumption for LS coupling conditions, and consistent with the observed equality of the mean lives within the accuracy of our measurement), an oscillator strength for the 1299 A multiplet of 0.121 +/- 0.004 was found. Both results are in good agreement with recent large-scale theoretical calculations that incorporate the effects of configuration interaction.

Beideck, D. J.↗
NASA NTRS1995

Equatorial Kelvin wave variability during 1992 and 1993

Temperature and ozone data from the Microwave Limb Sounder (MLS) instrument on Upper Atmosphere Research Satellite (UARS) are used to analyze the variability of Kelvin wave activity during the first two years of the UARS mission. The analysis is carried out using the asynoptic mapping technique. Time frequency plots for zonal wavenumbers 1 and 2, at two heights representing the middle stratosphere and the stratopause, respectively, are used to analyze the temporal variability of the waves, and its possible relationship to the equatorial quasi-biennial oscillation (QBO) and semiannual oscillation (SAO). Kelvin wave activity reaches a maximum during the solstice seasons and almost disappears during the equinoxes, in agreement with previous studies. Eastward propagating variance is estimated for wave periods from 4 to 20 days, at all UARS pressure surfaces currently available for MLS. The semiannual modulation of variance is observed to extend down to the lower limits of the height ranges of the temperature and ozone retrievals. Furthermore, a superposed QBO modulation is detected up to the stratopause. Comparison between the variance in eastward propagating waves and the mean zonal wind shows a possible participation of kelvin waves in the forcing of the QBO. At the stratopause the role of Kelvin waves in forcing the SAO appears to be limited, in agreement with previous results. Between the 21-hPa and 4.6-hPa surfaces there appears to be a transition zone where there is no clear relationship between Kelvin wave activity and mean zonal flow acceleration.

Canziani, Pablo O.↗
NASA NTRS1993

An intercomparison of aircraft instrumentation for tropospheric measurements of carbonyl sulfide, hydrogen sulfide, and carbon disulfide

This paper reports results of NASA's Chemical Instrumentation and Test Evaluation (CITE 3) during which airborne measurements for carbonyl sulfide (COS), hydrogen sulfide (H2S), and carbon disulfide (CS2) were intercompared. Instrumentation included a gas chromatograph using flame photometric detection (COS, H2S, and CS2), a gas chromatograph using mass spectrometric detection (COS) and CS2), a gas chromatograph using fluorination and subsequent SF6 detection via electron capture (COS and CS2), and the Natusch technique (H2S). The measurements were made over the Atlantic Ocean east of North and South America during flights from NASA's Wallops Flight Center, Virginia, and Natal, Brazil, in August/September 1989. Most of the intercomparisons for H2S and CS2 were at mixing ratios less than 25 pptv and less than 10 pptv, respectively, with a maximum mixing ratio of about 100 pptv and 50 pptv, respectively. Carbonyl sulfide intercomparisons were at mixing ratios between 400 and 600 pptv. Measurements were intercompared from data bases constructed from time periods of simultaneous or overlapping measurements. Agreement among the COS techniques averaged about 5%, and individual measurements were generally within 10%. For H2S and at mixing ratio greater than 25 pptv, the instruments agreed on average to about 15%. At mixing ratios less than 25 pptv the agreement was about 5 pptv. For CS2 (mixing ratios less than 50 pptv), two techniques agreed on average to about 4 pptv, and the third exhibited a bias (relative to the other two) that varied in the range of 3-7 pptv. CS2 mixing ratios over the ocean east of Natal as measured by the gas chromatograph-mass spectrometer technique were only a few pptv and were below the detection limits of the other two techniques. The CITE 3 data are used to estimate the current uncertainty associated with aircraft measurements of COS, H2S, and CS2 in the remote troposphere.

Gregory, Gerald L.↗
NASA NTRS1993

Comparison of ISCCP and other cloud amounts

A new 8-year global cloud climatology has been produced by the International Satellite Cloud Climatology Project (ISCCP) that provides information every 3 h at 280-km spatial resolution covering the period from July 1983 through June 1991. If cloud detection errors and differences in area sampling are neglected, individual ISCCP cloud amounts agree with individual surface observations to within 15% rms with biases of only a few percent. When measurements of small-scale, broken clouds are isolated in the comparison, the rms differences between satellite and surface cloud amounts are about 25%, similar to the rms difference between ISCCP and Landsat determinations of cloud amount. For broken clouds, the average ISCCP cloud amounts are about 5% smaller than estimated by surface observers (difference between earth cover and sky cover), but about 5% larger than estimated from very high spatial resolution satellite observations (overestimate due to low spatial resolution offset by underestimate due to finite radiance thresholds). Detection errors caused by errors in the ISCCP clear-sky radiances or incorrect radiance threshold magnitudes, are the dominant source of error in monthly average cloud amounts. The ISCCP cloud amounts appear to be too low over land by about 10%, somewhat less in summer and somewhat more in winter, and about right (maybe slightly low) over oceans. In polar regions, ISCCP cloud amounts are probably too low by about 15%-25% in summer and 5%-10% in winter. Comparison of the ISCCP climatology to three other cloud climatologies shows excellent agreement in the geographic distribution and seasonal variation of cloud amounts; there is little agreement about day/night contrasts in cloud amount. Notable results from ISCCP are that the gobal annual mean cloud amount is about 63%, being about 23% higher over oceans than over land, that it varies by less than 1% rms from month to month, and that it has varied by about 4% on a time scale approximately equal to 2-4 years. The magnitude of interannual variations of local (280-km scale) monthly mean cloud amounts is about 7%-9%. Longitudinal contrasts in cloud amount are just as large as latitudinal contrasts. The largest seasonal variation of cloud amount occurs in the tropics, being larger in summer than in winter; the seasonal variation in the middle latitudes has the opposite phase. Polar regions may have little seasonable variability in cloud amount. The ISCCP results show slightly more nightime than daytime cloud amount over oceans and more daytime than nightime cloud amount over land.

Rossow, William B.↗
NASA NTRS1994

Observations of water vapor by ground-based microwave radiometers and Raman lidar

In November to December 1991, a substantial number of remote sensors and in situ instruments were operated together in Coffeyville, Kansas, during the climate experiment First ISCCP Regional Experiment Phase 2 (FIRE 2). Includede in the suite of instruments were (1) the NOAA Environmental Technology Laboratory (ETL) three-channel microwave radiometer, (2) the NASA GSFC Raman lidar, (3) ETL radio acoustic sounding system (RASS), and (4) frequent, research-quality radiosondes. The Raman lidar operated only at night and the focus of this portion of the experiment concentrated on clear conditions. The lidar data, together with frequent radiosondes and measurements of temperature profiles (every 15 min) by RASS allowed profiles of temperature and absolute humidity to be estimated every minute. We compared 20 min measurements of brightness temperature (T(sub b) with calculations of T(sub b) that were based on the Liebe and Layton (1987) and Liebe et al. (1993) microwave propagation models, as well as the Waters (1976) model. The comparisons showed the best agreement at 20.6 GHz with the Waters model, with the Liebe et al. (1993) model being best at 31.65 GHz. The results at 90 GHz gave about equal success with the Liebe and Layton (1987) and Liebe et al. (1993) models. Comparisons of precipitable water vapor derived independently from the two instruments also showed excellent agreement, even for averages as short as 2 min. The rms difference between Raman and radiometric determinations of precipitable water vapor was 0.03 cm which is roughly 2%. The experiments clearly demonstrate the potential of simultaneous operation of radiometers and Raman lidars for fundamental physical studies of water vapor.

Han, Yong↗
NASA NTRS1994

Northern middle-latitude ozone profile features and trends observed by SBUV and Umkehr, 1979-1990

A comparison of Umkehr ozone profile data with the reprocessed solar backscatter ultraviolet (SBUV) ozone data in the northern middle-latitude region, 30 deg to 50 deg N, is reported. Although significant biases exist between the two types of observations, the long-term variations and least squares linear regression trends agree remarkably well over the comparison period of 1979 to 1990. The ozone trend in the upper stratosphere is of the order of -0.9%/yr. Near 25 km, little if any trend appears, but a larger negative trend is seen in the lower stratosphere near 15 km. Comparisons show that the average annual ozone cycles in the profiles also agree well. The upper stratospheric ozone results are consistent with photochemical model predictions of ozone depletion near 40 km that are due to the release of anthropogenically produced chlorofluorocarbons. The lower stratospheric ozone trend results are in reasonable agreement with published ozonesonde data trends. It is shown that the ozone trends in the lower stratospheric layers impact significantly on the total ozone trend of the order of -0.47%/yr. The good agreement now seen between the two types of observations suggest that the combined ground-based and satellite approach could provide a valuable database for long-term monitoring of stratospheric ozone for trends and extraordinary variations.

Deluisi, J. J.↗
NASA NTRS1994

The chemical and radiative effects of the Mount Pinatubo eruption

To clarify the mechanisms leading to effects on stratospheric ozone, time-dependent stratospheric aerosol and gas experiment II (SAGE II) and cryogenic limb array elaton spectrometer (CLAES) aerosol optical extinction data and SAGE II surface area density are used as parameters in a two-dimensional (2-D) zonally averaged chemical radiative transport model. The model was integrated with time from before the eruption through December 1993. The modeled impact on global ozone results from increased rates of heterogeneous reactions on sulfate aerosols and from the increased radiative heating and scattering caused by these aerosols. When the aerosol heating is allowed to modify the temperature distribution, the maximum change calculated in equatorial column ozone is -1.6%. The calculated equatorial temperature change and peak local ozone change in October 1991 are +6K and -4%, respectively. When aerosol heating perturbs the circulation in the model, the maximum change in equatorial column ozone is -6%. Increased heterogeneous processing on sulfate aerosols is calculated to have changed equatorial column ozone in late 1991 by -1.5%. Global column ozone in the model in 1992 and 1993 changed by -2.8% and -2.4%, respectively. The relationship of ozone-controlling processes in the lower stratosphere is altered as well; HO(x) becomes the most important catalytic cycle, followed by ClO(x) and NO(x). This is driven by significant changes in trace gas concentrations. In October 1991, lower stratospheric, equatorial NO(x) decreased by 40%, ClO(x) increased by 60%, and HO(x) increased by 25%. When the effect of heterogeneous chemical processing on sulfate aerosols is combined with aerosol heating, modifying either circulation or temperature, dramatically different ozone fingerprints with time and latitude are predicted. Model-derived changes in the equatorial region in column ozone best represented the observed data when perturbed circulation was combined with heterogeneous chemical effects. However, at high latitudes, the increased ozone production from the strengthening of the mean circulation tends to cancel the heterogeneous reduction of ozone. This is not in good agreement with observed data, especially in 1992 and 1993. When the circulation is held fixed and the temperature allowed to change, and heterogeneous chemical effects are included, the equatorial ozone decrease predicted was too small for 1991. However, the mid- to high-latitude decrease in 1992 and 1993 is in better agreement with observed data.

Kinneson, Douglas E.↗
NASA NTRS1994

Substorm recurrence during steady and variable solar wind driving: Evidence for a normal mode in the unloading dynamics of the magnetosphere

Farrugia et al (1993) have recently studied substorm activity driven by the passage of an interplanetary magnetic cloud during which the interplanetary magnetic field turned southward for approximately 18 hours. It was shown that both the epsilon and the VB(sub s) parameters varied slowly on the timescale of a substorm but changed considerably over the interval as a whole. The substorm occurrence rate did not reflect the variation in magnetospheric energy loading rate as measured by these parameters but, rather, remained roughly constant with a 50-min average period. Klimas et al. (1992) showed that the Faraday loop analog model of geomagnetic activity predicts this single unloading rate under various constant loading rates. However, various model parameters were adjusted to yield a 1-hour unloading period in agreement with the Bargatze et al. (1985) linear prediction filters and in approximate agreement with the Farrugia et al. (1993) results. It has since been found necessary to add a slow relaxation mechanism to the Faraday loop model to allow for its approach to a ground state during long periods of inactivity. It is proposed that the relaxation mechanism is provided by slow convection of magnetic flux out of the magnetotail to the dayside magnetosphere. In addition, a rudimentary representation of magnetotail-ionosphere coupling has been added to enable comparison of model output to measured AL. The present study is of the modified Faraday loop model response to solar wind input from the Bargatze et al. data set with comparison of its output to concurrent AL. This study has removed the degree of freedom in parameter choice that had earlier allowed adjustments toward the 1-hour unloading period and has, instead, yielded the 1-hour unloading period under various constant loading rates. It is demonstrated that the second peak of the bimodal Bargatze et al. linear prediction filters at approximately equal 1-hour lag and the approximately constant substorm recurrence rate observed by Farrugia et al. can be interpreted as both being due to the existence of a normal unloading recurrence period in the dynamics of the magnetosphere.

Klimas, A. J.↗
NASA NTRS1994

F2 peak electron density at Millstone Hill and Hobart: Comparsion of theory and measurement at solar maximum

This paper compares the observed behavior of the (F2) layer of the ionosphere at Millstone Hill and Hobart with calculations from the field line interhemispheric plasma (FLIP) model for solar maximum, solstice conditions in 1990. During the study period the daily F(sub 10.7) index varied by more than a factor of 2 (123 to 280), but the 81-day mean F(sub 10.7) (F(sub 10.7 A)) was almost constant near 190. Calculations were performed with and without the effects of vibrationally excited N2 (N(sup *)(sub 2) which affects the loss rate of atomic oxygen ions. In the case without N(sup *)(sub 2) there is generally good agreement between the model and measurement for the daytime, peak density of the F region (NmF2). Both the model and the measurement show a strong seasonal anomaly with the winter noon densities a factor of 3 to 4 greater than the summer noon densities at Millstone Hill and a factor of 2 greater at Hobart. The seasonal anomaly in the model is caused by changes in the neutral composition as given by the mass spectrometer and incoherent scatter (MSIS) 86 neutral density model. There is generally little or no increase in the observed noon NmF2 as a function of daily F(sub 10.7) except at Millstone Hill in winter. In contrast to the generally good agreement between model and data at noon, the model badly underestimates the density at night at Millstone Hill at all seasons. At Hobart the model reproduces the nighttime density variations well in both winter and summer. The international reference ionosphere (IRI) model generally provides a good representation of the average behavior of noon NmF2 and hmF2 but because the data show a lot of day-to-day variability, there are often large differences. The FLIP model is able to reproduce this variability when hmF2 is specified. The IRI model peak densities are better than the FLIP densities at night, but the IRI model does not represent the Millstone Hill summer data very well at night in 1990.

Richards, P. G.↗
NASA NTRS1995

Analysis of a 170-GHz frequency doubler with an array of planar diodes

Analysis of a planar diode multiplier from 85-170 GHz is described. The doubler uses a waveguide mount with two series pairs of diodes in a balanced structure. Because of the difficulties in conventional scale model measurements, numerical electromagnetic simulation based on the finite element method was chosen for the analysis, using a commercial program. To optimize the diode design, the de-embedded diode terminal impedance was studied, as well as the power balance between the diodes. The analysis showed that the matching of the diode impedance to that of the waveguide is quite sensitive to the diode substrate thickness. Thicknesses from 25-100 micron in GaAs were studied as well as 100-micron-thick quartz. The accuracy of the theoretical analysis was verified by careful measurements using a slotted line to determine the diode terminal impedance under large signal pump, for frequencies between 80 and 90 GHz. Good agreement between the measured and simulated diode terminal impedance was observed, although full agreement requires the addition of an empirical loss term. Several options are considered for the source of this loss.

DIODE MULTIPLIER↗