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At least 1,099 records · Page 61

The Lunar Orbital Prospector

The establishment of lunar bases will not end the need for remote sensing of the lunar surface by orbiting platforms. Human and robotic surface exploration will necessarily be limited to some proximate distance from the support base. Near real-time, high-resolution, global characterization of the lunar surface by orbiting sensing systems will continue to be essential to the understanding of the Moon's geophysical structure and the location of exploitable minerals and deposits of raw materials. The Lunar Orbital Prospector (LOP) is an orbiting sensing platform capable of supporting a variety of modular sensing packages. Serviced by a lunar-based shuttle, the LOP will permit the exchange of instrument packages to meet evolving mission needs. The ability to recover, modify, and rotate sensing packages allows their reuse in varying combinations. Combining this flexibility with robust orbit modification capabilities and near real-time telemetry links provides considerable system responsiveness. Maintenance and modification of the LOP orbit are accomplished through use of an onboard propulsion system that burns lunar-supplied oxygen and aluminum. The relatively low performance of such a system is more than compensated for by the elimination of the need for Earth-supplied propellants. The LOP concept envisions a continuous expansion of capability through the incorporation of new instrument technologies and the addition of platforms.

Redd, Frank J.↗

Simulating fluxes from heterogeneous land surfaces: Explicit subgrid method employing the biosphere-atmosphere transfer scheme (BATS)

A vectorized version of the biosphere-atmosphere transfer scheme (VBATS) is used to study moisture, energy, and momentum fluxes from heterogeneous land surfaces st the scale of an atmospheric model (AM) grid cells. To incorporate subgrid scale inhomogeneity, VBATS includes two important features: (1) characterization of the land surface (vegetation and soil parameters) at N subgrid points within an AM grid cell and (2) explicit distribution of climate forcing (precipitation, clouds, etc.) over the subgrid. In this study, VBATS is used in stand-alone mode to simulate a single AM grid cell and to evaluate the effects of subgrid scale vegetation and climate specification on the surface fluxes and hydrology. It is found that the partitioning of energy can be affected by up to 30%, runoff by 50%, and surface stress in excess of 60%. Distributing climate forcing over the AM grid cell increases the Bowen ratio, as a result of enhanced sensible heat flux and reduced latent heat flux. The combined effect of heterogeneous vegetation and distribution of climate is found to be dependent on the dominat vegetation class in the AM grid cell. Development of this method is part of a larger program to explore the importance of subgrid scale processes in regional and global climate simulations.

Seth, Anji↗

Simulation of Urban Heat Island Mitigation Strategies in Atlanta, GA Using High-Resolution Land Use/Land Cover Data Set to Enhance Meteorological Modeling

The specification of land use/land cover (LULC) and associated land surface parameters in meteorological models at all scales has a major influence on modeled surface energy fluxes and boundary layer states. In urban areas, accurate representation of the land surface may be even more important than in undeveloped regions due to the large heterogeneity within the urban area. Deficiencies in the characterization of the land surface related to the spatial or temporal resolution of the data, the number of LULC classes defined, the accuracy with which they are defined, or the degree of heterogeneity of the land surface properties within each class may degrade the performance of the models. In this study, an experiment was conducted to test a new high-resolution LULC data set for meteorological simulations for the Atlanta, Georgia metropolitan area using a mesoscale meteorological model and to evaluate the effects of urban heat island (UHI) mitigation strategies on modeled meteorology for 2030. Simulation results showed that use of the new LULC data set reduced a major deficiency of the land use data used previously, specifically the poor representation of urban and suburban land use. Performance of the meteorological model improved substantially, with the overall daytime cold bias reduced by over 30%. UHI mitigation strategies were projected to offset much of a predicted urban warming between 2000 and 2030. In fact, for the urban core, the cooling due to UHI mitigation strategies was slightly greater than the warming associated with urbanization over this period. For the larger metropolitan area, cooling only partially offset the projected warming trend.

Crosson, William L.↗

Sources of Uncertainty in Predicting Land Surface Fluxes Using Diverse Data and Models

In the domain of predicting land surface fluxes, models are used to bring data from large observation networks and satellite remote sensing together to make predictions about present and future states of the Earth. Characterizing the uncertainty about such predictions is a complex process and one that is not yet fully understood. Uncertainty exists about initialization, measurement and interpolation of input variables; model parameters; model structure; and mixed spatial and temporal supports. Multiple models or structures often exist to describe the same processes. Uncertainty about structure is currently addressed by running an ensemble of different models and examining the distribution of model outputs. To illustrate structural uncertainty, a multi-model ensemble experiment we have been conducting using the Terrestrial Observation and Prediction System (TOPS) will be discussed. TOPS uses public versions of process-based ecosystem models that use satellite-derived inputs along with surface climate data and land surface characterization to produce predictions of ecosystem fluxes including gross and net primary production and net ecosystem exchange. Using the TOPS framework, we have explored the uncertainty arising from the application of models with different assumptions, structures, parameters, and variable definitions. With a small number of models, this only begins to capture the range of possible spatial fields of ecosystem fluxes. Few attempts have been made to systematically address the components of uncertainty in such a framework. We discuss the characterization of uncertainty for this approach including both quantifiable and poorly known aspects.

Dungan, Jennifer L.↗

WHONDRS Surface Water Dissolved Organic Carbon and FTICR-MS across Glacial Features in Svalbard 2022

This dataset supports a broader study examining climatic forcing of terrestrial greenhouse gas emission through permafrost and glaciers in Svalbard. The dataset provides geochemistry and organic matter characterization data generated from surface water collected from 11 sites across central Svalbard. Data were also collected in 2021 and can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/1888571. Additional related data were collected and will be published separately in collaboration with Yde and Kleber.This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) dissolved organic carbon (DOC; measured as non-purgeable organic carbon; NPOC); (5) surface water sampling protocol; (6) readme; (7) methods codes; (8) international geo-sample number (IGSN) mapping file; (9) a folder of field photos; and (10) folder of high resolution characterization of organic matter via 7 Tesla Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) generated through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The FTICR folder contains two subfolders, one containing the .xml data files and the other containing instructions for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. All files are .csv, .pdf, .R, .ref, or .xml.

54 ENVIRONMENTAL SCIENCES↗

Assessing Confidence in Pliocene Sea Surface Temperatures to Evaluate Predictive Models

In light of mounting empirical evidence that planetary warming is well underway, the climate research community looks to palaeoclimate research for a ground-truthing measure with which to test the accuracy of future climate simulations. Model experiments that attempt to simulate climates of the past serve to identify both similarities and differences between two climate states and, when compared with simulations run by other models and with geological data, to identify model-specific biases. Uncertainties associated with both the data and the models must be considered in such an exercise. The most recent period of sustained global warmth similar to what is projected for the near future occurred about 3.33.0 million years ago, during the Pliocene epoch. Here, we present Pliocene sea surface temperature data, newly characterized in terms of level of confidence, along with initial experimental results from four climate models. We conclude that, in terms of sea surface temperature, models are in good agreement with estimates of Pliocene sea surface temperature in most regions except the North Atlantic. Our analysis indicates that the discrepancy between the Pliocene proxy data and model simulations in the mid-latitudes of the North Atlantic, where models underestimate warming shown by our highest-confidence data, may provide a new perspective and insight into the predictive abilities of these models in simulating a past warm interval in Earth history.This is important because the Pliocene has a number of parallels to present predictions of late twenty-first century climate.

simulation↗

Towards Improved Snow Water Equivalent Estimation via GRACE Assimilation

Passive microwave (e.g. AMSR-E) and visible spectrum (e.g. MODIS) measurements of snow states have been used in conjunction with land surface models to better characterize snow pack states, most notably snow water equivalent (SWE). However, both types of measurements have limitations. AMSR-E, for example, suffers a loss of information in deep/wet snow packs. Similarly, MODIS suffers a loss of temporal correlation information beyond the initial accumulation and final ablation phases of the snow season. Gravimetric measurements, on the other hand, do not suffer from these limitations. In this study, gravimetric measurements from the Gravity Recovery and Climate Experiment (GRACE) mission are used in a land surface model data assimilation (DA) framework to better characterize SWE in the Mackenzie River basin located in northern Canada. Comparisons are made against independent, ground-based SWE observations, state-of-the-art modeled SWE estimates, and independent, ground-based river discharge observations. Preliminary results suggest improved SWE estimates, including improved timing of the subsequent ablation and runoff of the snow pack. Additionally, use of the DA procedure can add vertical and horizontal resolution to the coarse-scale GRACE measurements as well as effectively downscale the measurements in time. Such findings offer the potential for better understanding of the hydrologic cycle in snow-dominated basins located in remote regions of the globe where ground-based observation collection if difficult, if not impossible. This information could ultimately lead to improved freshwater resource management in communities dependent on snow melt as well as a reduction in the uncertainty of river discharge into the Arctic Ocean.

Forman, Bart↗

InSAR Monitoring to Evaluate Surface Changes with CO 2 Storage in a Depleted Oil Field in Northern Michigan

Battelle evaluated the potential use of Interferometric Synthetic Aperture Radar (InSAR) for monitoring the outcome of injected CO 2 at the Dover 33 reef near Gaylord, Michigan. InSAR is a satellite-based technology that provides high-precision information on the movement of ground surface in areas with high radar coherence (e.g., roads, buildings, bare soils). Depending on the setting, this technique may provide a useful tool for characterizing reservoirs by measuring surface deformations from activities such as brine water disposal; production of water, oil, and/or gas; and carbon capture, utilization, and storage (CCUS).

47 OTHER INSTRUMENTATION↗

InSAR Monitoring to Evaluate Surface Changes with CO 2 Storage in a Depleted Oil Field in Northern Michigan (Volume II.E)

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. This report describes the effort under MRCP to evaluate the potential use of Interferometric Synthetic Aperture Radar (InSAR) for monitoring the outcome of injected CO 2 at the Dover 33 reef near Gaylord, Michigan. InSAR is a satellite-based technology that provides high-precision information on the movement of ground surface in areas with high radar coherence (e.g., roads, buildings, bare soils). Depending on the setting, this technique may provide a useful tool for characterizing reservoirs by measuring surface deformations from activities such as brine water disposal; production of water, oil, and/or gas; and carbon capture, utilization, and storage (CCUS).

54 ENVIRONMENTAL SCIENCES↗

The Mars Environmental Dynamics Analyzer, MEDA. A Suite of Environmental Sensors for the Mars 2020 Mission

NASA’s Mars 2020 (M2020) rover mission includes a suite of sensors to monitor current environmental conditions near the surface of Mars and to constrain bulk aerosol properties from changes in atmospheric radiation at the surface. The Mars Environmental Dynamics Analyzer (MEDA) consists of a set of meteorological sensors including wind sensor, a barometer, a relative humidity sensor, a set of 5 thermocouples to measure atmospheric temperature at ∼1.5 m and ∼0.5 m above the surface, a set of thermopiles to characterize the thermal IR brightness temperatures of the surface and the lower atmosphere. MEDA adds a radiation and dust sensor to monitor the optical atmospheric properties that can be used to infer bulk aerosol physical properties such as particle size distribution, non-sphericity, and concentration. The MEDA package and its scientific purpose are described in this document as well as how it responded to the calibration tests and how it helps prepare for the human exploration of Mars. A comparison is also presented to previous environmental monitoring payloads landed on Mars on the Viking, Pathfinder, Phoenix, MSL, and InSight spacecraft.

J. A. Rodriguez-Manfredi↗

WHONDRS Surface Water and Sediment Non-Purgeable Organic Carbon and FTICR-MS across Glacial Features in Svalbard 2021 (v3)

This dataset supports a broader study examining land-atmosphere gas exchange associated with permafrost and glaciers in Svalbard. The dataset provides geochemistry and organic matter characterization data generated from surface water and sediment. Samples were collected from 8 spatially diverse sites across central Svalbard and also from a more comprehensive temporal and spatial study within one glacial catchment area throughout one summer melt season. Related data were collected and will be published separately in collaboration with Yde and Kleber.This data package was originally published in September 2022. It was updated in March 2023 (v2; new and modified files), and July 2025 (v3; modified files). See the change history section in the readme for details.For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) dissolved organic carbon (DOC; measure as non-purgeable organic carbon; NPOC); (5) surface water sampling protocol; (6) sediment extraction protocol; (7) readme; (8) methods codes; (9) international generic sample number (IGSN) mapping file; and (10) folder of high resolution characterization of organic matter via 7 and 12 Tesla (7T and 12T) Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) generated through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The FTICR folder contains two subfolders containing the 7T and 12T .xml data files and another subfolder containing instructions for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. All files are .csv, .pdf, .R, .ref, or .xml.

54 ENVIRONMENTAL SCIENCES↗

The size and shape of equilibrium capillary surfaces

The classical theory of capillary is concerned largely with size and shape estimates in symmetric asymptotic configurations. Recent developments leading to global results for all symmetric cases, and to qualitative information on asymptotic properties are discussed. Additional stability criteria are described. Asymmetric situations leading to behavior that differs strikingly from the symmetric case are discussed. When gravity vanishes, capillary surfaces in the accustomed sense may not appear. The question of characterizing those tubes in which surfaces can be found has partially been settled. Progress toward determining the effects of contact angle hysteresis in cases of particular interest is reported.

Finn, R.↗

Results From Mars Show Electrostatic Charging of the Mars Pathfinder Sojourner Rover

Indirect evidence (dust accumulation) has been obtained indicating that the Mars Pathfinder rover, Sojourner, experienced electrostatic charging on Mars. Lander camera images of the Sojourner rover provide distinctive evidence of dust accumulation on rover wheels during traverses, turns, and crabbing maneuvers. The sol 22 (22nd Martian "day" after Pathfinder landed) end-of-day image clearly shows fine red dust concentrated around the wheel edges with additional accumulation in the wheel hubs. A sol 41 image of the rover near the rock "Wedge" (see the next image) shows a more uniform coating of dust on the wheel drive surfaces with accumulation in the hubs similar to that in the previous image. In the sol 41 image, note particularly the loss of black-white contrast on the Wheel Abrasion Experiment strips (center wheel). This loss of contrast was also seen when dust accumulated on test wheels in the laboratory. We believe that this accumulation occurred because the Martian surface dust consists of clay-sized particles, similar to those detected by Viking, which have become electrically charged. By adhering to the wheels, the charged dust carries a net nonzero charge to the rover, raising its electrical potential relative to its surroundings. Similar charging behavior was routinely observed in an experimental facility at the NASA Lewis Research Center, where a Sojourner wheel was driven in a simulated Martian surface environment. There, as the wheel moved and accumulated dust (see the following image), electrical potentials in excess of 100 V (relative to the chamber ground) were detected by a capacitively coupled electrostatic probe located 4 mm from the wheel surface. The measured wheel capacitance was approximately 80 picofarads (pF), and the calculated charge, 8 x 10(exp -9) coulombs (C). Voltage differences of 100 V and greater are believed sufficient to produce Paschen electrical discharge in the Martian atmosphere. With an accumulated net charge of 8 x 10(exp -9) C, and average arc time of 1 msec, arcs can also occur with estimated arc currents approaching 10 milliamperes (mA). Discharges of this magnitude could interfere with the operation of sensitive electrical or electronic elements and logic circuits. Sojourner rover wheel tested in laboratory before launch to Mars. Before launch, we believed that the dust would become triboelectrically charged as it was moved about and compacted by the rover wheels. In all cases observed in the laboratory, the test wheel charged positively, and the wheel tracks charged negatively. Dust samples removed from the laboratory wheel averaged a few ones to tens of micrometers in size (clay size). Coarser grains were left behind in the wheel track. On Mars, grain size estimates of 2 to 10 mm were derived for the Martian surface materials from the Viking Gas Exchange Experiment. These size estimates approximately match the laboratory samples. Our tentative conclusion for the Sojourner observations is that fine clay-sized particles acquired an electrostatic charge during rover traverses and adhered to the rover wheels, carrying electrical charge to the rover. Since the Sojourner rover carried no instruments to measure this mission's onboard electrical charge, confirmatory measurements from future rover missions on Mars are desirable so that the physical and electrical properties of the Martian surface dust can be characterized. Sojourner was protected by discharge points, and Faraday cages were placed around sensitive electronics. But larger systems than Sojourner are being contemplated for missions to the Martian surface in the foreseeable future. The design of such systems will require a detailed knowledge of how they will interact with their environment. Validated environmental interaction models and guidelines for the Martian surface must be developed so that design engineers can test new ideas prior to cutting hardware. These models and guidelines cannot be validated without actual flighata. Electrical charging of vehicles and, one day, astronauts moving across the Martian surface may have moderate to severe consequences if large potential differences develop. The observations from Sojourner point to just such a possibility. It is desirable to quantify these results. The various lander/rover missions being planned for the upcoming decade provide the means for doing so. They should, therefore, carry instruments that will not only measure vehicle charging but characterize all the natural and induced electrical phenomena occurring in the environment and assess their impact on future missions.

Kolecki, Joseph C.↗

Nanocomposite Materials for Radionuclide Sequestration from Groundwater Environments

The half-lives of radionuclides range from fractions of a second to billions of years. Since no practical method of altering radioactive decay exists, and since exposure to either the energy emitted from radioactive decay or chemical properties of radionuclides poses dire health risks, radioactive materials must be segregated and controlled. The capture, treatment, and disposition of radioactive materials remain an extraordinary challenge. In here, we focus our attention on the synthesis and characterization of a unique class of nanocomposite materials that have potential for removal of radionuclide contamination. Specifically, we report a simple approach to decorate the surface of iron-based (Fe/FexOy) material with various nano-catalysts. Specifically, copper (Cu), tin (Sn), and silver (Ag) nanoparticles were prepared through two different reduction approaches, namely, citrate and cetyltrimethylammonium bromide (CTAB) methods, on the iron-based material surface. All samples were characterized by a variety of analytical tools, which included scanning electron microscopy (SEM), electron-dispersive X-ray microanalysis (EDS), and EDS mapping to elucidate materials’ morphology as well as nano-catalysts’ loading and location on the iron-based structures.

Hunyadi Murph, Simona E.↗

Failure Analysis of a New Polyamide-Based Fluoropolymer-Free Backsheet After Combined-Accelerated Stress Testing

The viability of novel coextruded, fluoropolymer-free backsheets for photovoltaic (PV) modules has been questioned as a result of a large number of early-life backsheet failures in PV installations containing one of the earliest co-extruded polyamide (PA)-based backsheet to reach the market, “AAA.” New PV reliability testing protocols have been recently developed and applied to backsheets to reproduce failures observed in the field and evaluate the durability of novel backsheet materials and designs prior to commercialization. A new co-extruded PA-based backsheet was tested using combined-accelerated stress testing (C-AST) and demonstrated a greater lifetime than AAA, and some other fluoropolymer-based backsheets such as polyvinylidene fluoride. The improved PA-based backsheet also eventually failed by through-thickness cracking. Using surface and bulk material characterization techniques, we performed a comprehensive study of material properties before and after the stress testing. Aging of the backsheet resulted in an increase of surface roughness by erosion of the outer PA layer. However the failure is more likely related to an increase in crystallinity of the polyolefin core layer reducing the backsheet tearing energy. The analysis can ultimately inform on the specific weaknesses of the materials so that the manufacturer can improve the backsheet design to extend its lifetime.

14 SOLAR ENERGY↗

Analysis of Experimental Ice Accretion Data and Assessment of a Thermodynamic Model During Ice Crystal Icing

This paper evaluates a thermodynamic ice crystal icing model that has been previously presented to describe the possible mechanisms of icing within the core of a turbofan jet engine. The model functions between two distinct ice accretions based on a surface energy balance: freeze-dominated icing and melt-dominated icing. Freeze-dominated icing occurs when liquid water (from melted ice crystals) freezes and accretes on a surface along with the existing ice of the impinging water and ice mass. This freeze-dominated icing is characterized as having strong adhesion to the surface. The amount of ice accretion is partially dictated by a freeze fraction, which is the fraction of impinging liquid water that freezes. Melt-dominated icing occurs as unmelted ice on a surface accumulates. This melt-dominated icing is characterized by weakly bonded surface adhesion. The amount of ice accumulation is partially dictated by a melt fraction, which is the fraction of impinging ice crystals that melts. Experimentally observed ice growth rates suggest that only a small fraction of the impinging ice remains on the surface, implying a mass loss mechanism such as splash, runback, bounce, or erosion. The fraction of mass loss must be determined in conjunction with the fraction of freezing liquid water or fraction of melting ice on an icing surface for a given ice growth rate. This mass loss parameter, however, along with the freeze fraction and melt fraction, are the only experimental parameters that are currently not measured directly. Using icing growth rates from ice crystal icing experiments, a methodology that has been previously proposed is used to determine these unknown parameters. This work takes ice accretion data from tests conducted by the National Aeronautics and Space Administration (NASA) at the Glenn Research Center in 2018 that examined the fundamental physics of ice crystal icing. This paper continues evaluation of the thermodynamic model from a previous effort, with additions to the model that account for sub-freezing temperatures that have been observed at the leading edge of the airfoil during icing. The predicted temperatures were generally in good agreement with measured temperatures. Other key findings include the total wet-bulb temperature being a good first order indicator of whether icing is freeze-dominated (sub-freezing values) or melt-dominated (above freezing). Maximum sticking efficiency values, the fraction of impinging mass that adheres to a surface, was calculated to be about 0.2, and retained this maximum value for a range of melt ratios (0.3 to 0.65 and possibly higher), which is defined as the ratio of liquid water content to total water content. Higher air velocities reduced the maximum sticking efficiency and shifted the icing regime to higher melt ratio values. Finally, the leading edge ice accretion angle was found to be related to ice growth (lower growth rates for smaller angles) and melt ratio (smaller melt ratios resulted in smaller angles, likely due to erosion effects).

Ice-Crystal Icing↗

Degrade-Repair Cycle of a Fuel-Forming Photoelectrode

Artificial leaves that produce fuels using sunlight hold promise for sustainably powering the planet, but they require advance- ments in energetic efficiency, cost effectiveness, and operational durability. Herein, we showcase the application of combined surface- sensitive spectroscopic techniques to durability studies that characterize structural changes accompanying functional degradation and go beyond just observing changes in function over time. Further, the photoelectrodes used in this work feature a polymeric surface coating functionalized with molecular complexes that catalyze the hydrogen evolution reaction. Using a polymeric layer to interface the light-harvesting component with catalytic sites enables reassembly of catalysts that detach during operation, establishing a degrade-repair cycle.

14 SOLAR ENERGY↗

Simulations of Ground and Space-Based Oxygen Atom Experiments

Fast, pulsed atomic oxygen sources are a key tool in ground-based investigations of spacecraft contamination and surface erosion effects. These technically challenging ground-based studies provide a before and after picture of materials under low-earth-orbit (LEO) conditions. It would be of great interest to track in real time the pulsed flux from the source to the surface sample target and beyond in order to characterize the population of atoms and molecules that actually impact the surface and those that make it downstream to any coincident detectors. We have performed simulations in order to provide such detailed descriptions of these ground-based measurements and to provide an assessment of their correspondence to the actual LEO environment. Where possible we also make comparisons to measured fluxes and erosion yields. To perform the calculations we use a detailed description of a measurement beam and surface geometry based on the W, pulsed apparatus at Montana State University. In this system, a short pulse (on the order of 10 microseconds) of an O/O2 beam impacts a flat sample about 40 cm downstream and slightly displaced &om the beam s central axis. Past this target, at the end of the beam axis is a quadrupole mass spectrometer that measures the relative in situ flux of 0102 to give an overall normalized erosion yield. In our simulations we use the Direct Simulation Monte Carlo (DSMC) method, and track individual atoms within the atomic oxygen pulse. DSMC techniques are typically used to model rarefied (few collision) gas-flows which occur at altitudes above approximately 110 kilometers. These techniques are well suited for the conditions here, and multi-collision effects that can only be treated by this or a similar technique are included. This simulation includes collisions with the surface and among gas atoms that have scattered from the surface. The simulation also includes descriptions of the velocity spread and spatial profiles of the O/O2 beam obtained from separate measurements. These computations use basic engineering models for the gas-gas and gas-surface scattering and focus on the influence of multi-collision effects. These simulations characterize many important quantities of interest including the actual flux of atoms that reach the surface, the energy distribution of this flux, as well as the direction of the velocity of the flux that strikes the surface. These quantities are important in characterizing the conditions which give rise to measured surface erosion. The calculations also yield time- snapshots of the pulse as it impacts and flows around the surface. These snapshots reveal the local environment of gas near the surface for the duration of the pulse. We are also able to compute the flux of molecules that travel downstream and reach the spectrometer, and we characterize their velocity distribution. The number of atoms that reach the spectrometer can in fact be influenced by the presence of the surface due to gas-gas collisions from atoms scattered h m the surface, and it will generally be less than that with the surface absent. This amounts to an overall normalization factor in computing erosion yields. We discuss these quantities and their relationship to the gas-surf$ce interaction parameters. We have also performed similar calculations corresponding to conditions (number densities, temperatures, and velocities) of low-earth orbit. The steady-state nature and lower overall flux of the actual space environment give rise to differences in the nature of the gas-impacts on the surface from those of the ground-based measurements using a pulsed source.

Minton, T. K.↗