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At least 1,099 records · Page 61
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NASA NTRS1977

Stratospheric aerosols - Undissolved granules and physical state

The physical state of stratospheric aerosol particles was studied along with the nature of included undissolved granules. It was found that: (1) undissolved granules are present in only a third of the aerosol particles and are not always associated with a slurry matrix, (2) those undissolved particles usually contain only sulfur and sodium or undetectable light elements, (3) all stratospheric aerosols have a similar appearance: a volatile slurry mixture of crystalline-like material in a liquid matrix, and (4) variations in the relative amounts of liquid and crystalline materials at different times cause variations in particle spreading.

Farlow, N. H.↗
NASA NTRS1977

The HF:HCl ratio in the 14-38 km region of the stratosphere

A balloon-borne high resolution Michelson interferometer recorded near infrared absorption spectra of the 1-0 fundamental vibration bands of HF and HCl in the stratosphere over Australia in March 1977. The ratio of the number density of HF to that of HCl as a function of stratospheric height was deduced from the measurements. Within estimated experimental error, the ratio is constant, its mean value being 0.1.

Farmer, C. B.↗
NASA NTRS1977

The vertical distribution of HCl in the stratosphere

The vertical distribution of HCl in the stratosphere has been measured from infrared solar absorption spectra recorded with a balloon-borne interferometer. The flights were made in September, 1975, and May, 1976 at float altitudes of 40 km and 37 km, respectively, near Palestine, Texas. Concentration profiles derived from the data show an increase from 0.6 ppbv at 20 km to 1.7 plus or minus .5 ppbv in the region of 37 km. Above 37 km, the data permit only the total abundance to be determined; this value is found to be equivalent to 1.6 plus or minus .6 ppbv if the gas were uniformly mixed. The results from the two flights are closely similar, and no significant seasonal variation in the HCl concentrations can be discerned. The balloon data are consistent with the profile in the 14-21 km altitude region of the stratosphere reported earlier from U-2 observations.

Raper, O. F.↗
NASA NTRS1978

Temporal and latitudinal variations of stratospheric trace gases - A critical comparison between theory and experiment

Global calculations of stratospheric HOx, Clx, and NOx are presented which include the effects of planetary albedo and diurnal and seasonal variations of the insolation. Comparisons are made with a wide range of atmospheric measurements at different latitudes and altitudes. Agreement between theory and observations is generally within a factor of 2. The theory appears to explain adequately the major features of latitude and seasonal distributions of NO2 and HNO3. The results indicate that mesospheric OH makes an appreciable contribution to the total OH column abundance and strongly suggest that nitrogen oxides exist principally in the form of HNO3 at high latitudes in winter. There are difficulties in reconciling OH, ClO, and O3 observations in the upper stratosphere.

Wofsy, S. C.↗
NASA NTRS1978

Lower stratosphere measurements of variation with latitude of CF2Cl2, CFCl3, CCl4, and N2O profiles in the northern hemisphere

Measurements were made from a U-2 aircraft of profiles of CF2Cl2, CFCl3, CCl4 and N2O in the lower stratosphere in a meridional survey at a longitude of 159 deg W during the period October 1 to November 14, 1976. The latitude distributions obtained show a marked decrease in mixing ratio with increasing latitude from about 7 deg N in the Intertropical Convergence Zone to about 79 deg N. The results suggest the importance of meridional transport and mixing in the stratosphere in accounting, at least in part, for the observed profile variation with latitude. The contaminants C2F4Cl2, C2F3Cl3, CHCCl3 and SF6 were also detected but their mixing ratios were small and no accurate standards were prepared for them.

Vedder, J. F.↗
NASA NTRS1978

Ozone profiles and chemical loss rates in the tropical stratosphere deduced from backscatter ultraviolet measurements

Analysis of data obtained by the backscatter ultraviolet (BUV) experiment on the Atmosphere Explorer E satellite has provided equatorial ozone mixing ratio profiles for equinox and solstice conditions. The combination of these results with a pure oxygen chemical model yields the rate of odd oxygen loss due to the sum of the odd hydrogen, nitrogen, and chlorine cycles. Use of recent mid-latitude stratospheric measurements of HO(x), NO(x), and ClO(x) with the BUV data provides an independent calculation of the catalytic loss. Below 45 km the agreement between the two sets of loss rates is satisfactory. At higher altitudes the odd hydrogen cycle provides far more O(x) loss than can be tolerated by the BUV measurements if the photodissociation of O2 is the only source and has the currently accepted magnitude. The results suggest either a tropical HO(x) concentration smaller than is now believed or the presence of a very large source of odd oxygen in the upper stratosphere and lower mesosphere.

Frederick, J. E.↗
NASA NTRS1978

Limb Infrared Monitor of the Stratosphere /LIMS/ experiment

The Limb Infrared Monitor of the Stratosphere (LIMS) radiometer is a satellite-borne six-channel multispectral scanning radiometer using a two-stage methane and ammonia solid-cryogen cooler to cool the (Hg, Cd)Te focal plane to 65 K. The LIMS experiment employs thermal IR limb sounding to provide vertical-profile measurement of temperature and of concentrations of O3, NO3, and H2O in the stratosphere on a global scale. The goals of the experiment and the expected accuracies of the measurements are outlined, and the radiance measured by the radiometer is analyzed. A program of correlative measurements designed for verification and augmentation of the LIMS data is discussed. Detailed descriptions are given of the LIMS components and optics, the detector capsule assembly, the solid-cryogen cooler, the four operational modes of the LIMS system, and the data-processor electronics. It is noted that prelaunch acceptance testing thus far completed indicates that the LIMS specification design requirements have been met, and the experiment's performance goals can be achieved.

Drozewski, R. W.↗
NASA NTRS1978

Geographical variations of NO and O3 in the lower stratosphere

Nitric oxide and ozone concentrations in the lower stratosphere have been measured from a high-altitude research aircraft using in situ measuring techniques. Results of several geographical surveys are presented along with predictions of two two-dimensional stratospheric models. Meridional and zonal data were obtained in June 1974 and in June, July, and August 1975. At longitudes 122-158 deg W the meridional data taken between 5 and 80 deg N latitude show an increasing NO concentration with latitude, by a factor of 4 at 21-km altitude and a less marked increase at 18 km. The minimum NO concentration at 21 km is observed at 5 deg N latitude and is about 6 x 10 to the 8th power/cu cm. Zonal data at latitudes 22-38 deg N taken from 55 to 176 deg N longitude show little variation of the NO and O3 concentrations with longitude.

Loewenstein, M.↗
NASA NTRS1978

Radiative equilibrium temperatures in the stratosphere and mesosphere - A comparison for the stellar occultation and BUV ozone data

Recently published ozone densities in the equatorial stratosphere and mesosphere from satellite stellar occultation measurements are appreciably larger than previous independent midlatitude measurements and ozone densities predicted by photochemical theory. Radiative equilibrium temperature profiles with a stratosphere-mesosphere optimized model have been calculated for each of these ozone profiles; it is found that the stellar occultation studies cannot be discounted on energy balance grounds.

Kuhn, W. R.↗
NASA NTRS1978

Balloon-borne photoionization mass spectrometer for measurement of stratospheric gases

A balloon-borne photoionization mass spectrometer used to measure stratospheric trace gases is described. Ions are created with photons from high-intensity krypton discharge lamps and a quadrupole mass analyzer is employed for ion identification. Differential pumping is achieved with liquid helium cryopumping. To insure measurement of unperturbed stratospheric air, the entire system is contained in a sealed gondola and the atmospheric sample is taken some distance away during descent. The photoionization technique allows the detection of a low ionization potential constituent, such as nitric oxide, at less than a part in one billion in the presence of the major atmospheric gases and their isotopes. Operation of the mass spectrometer system was demonstrated during a daytime flight from Palestine, Texas on 26 April 1977. The sensitivity achieved and the unique selectivity afforded by this technique offer a capability for trace constituent measurement not possible with the more conventional electron impact ionization approach.

Aikin, A. C.↗
NASA NTRS1978

A steady-state stratospheric aerosol model

This paper deals with the development of a one-dimensional steady-state stratospheric aerosol model and the subsequent perturbations caused by including the expected Space Shuttle particulate effluents in the model. Two approaches to the basic modeling effort have been made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other, very few simplifications were made and a computer technique was used to solve the equations. The most complete form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. The results indicate that the model is capable of describing many aspects of the stratospheric aerosol layer, such as size distribution and the vertical profile of particles greater than 0.3 micron diameter.

Rosen, J. M.↗
NASA NTRS1978

The uncertainty in ozone calculations by a stratospheric photochemistry model

At present, there is an apparent conflict between one-dimensional stratospheric photochemistry models used in predicting ozone depletion and average data for stratospheric ozone. This conflict is in three particulars - column density of O3 and ozone density in the regions around 30 km and 50 km altitude. A study of the sensitivity of one such model to the values of reaction rates, boundary conditions, solar intensities, photolysis cross sections, and O(1D) yield parameters reveals that even at the 2-sigma uncertainty limit due to these input parameters, the model does not overlap the data for O3 density at 30 km and 50 km. The data is outside the 1-sigma model uncertainty limit for O3 column density. The study also shows the relative contribution of the various parameters studied to the imprecision in these model results.

Butler, D. M.↗
NASA NTRS1978

The response of the zonally averaged circulation to stratospheric ozone reductions

The effects of various ozone density reductions of the zonally averaged circulation are evaluated with a numerical quasi-geostrophic model. If the ozone perturbations are confined to the polar regions and are minuscule on a global basis as was characteristic of the August 1972 solar proton event, then the calculations indicate a negligible effect on the mean circulation. For global ozone perturbations by predicted halocarbon pollution, about 10% reduction in the zonal jet strength and less than a 5% change in global mean stratospheric temperature are calculated. Large, uniform ozone reductions (above 50%) produce significant effects on the mean circulation: a substantial collapse of the stratosphere due to cooler temperatures, and a weak polar night jet. The reflection and transmission of quasi-stationary planetary waves in the middle atmosphere are computed to be insensitive to solar activity as extreme as the August 1972 solar proton event. It thus seems improbable that planetary waves are a viable mechanism for solar-weather interactions that involve perturbations of the zonally averaged circulation by ozone density reductions.

Schoeberl, M. R.↗
NASA NTRS1978

A vortex model for transport in the polar stratosphere

A semi-empirical model based on a Gaussian vorticity distribution was developed for determining eddy diffusivity and wind transport distributions in the polar stratosphere. The model uses as input data pressure surface heights measured at periods of the year when the stratospheric polar vortex exhibits nearly circular patterns around the pole. The components of the polar wind velocities that result from a Prandtl eddy viscosity distribution are found to be in general agreement with those obtained by other investigators.

Eberstein, I. J.↗
NASA NTRS1977

A stratospheric aerosol model with perturbations induced by the space shuttle particulate effluents

A one dimensional steady state stratospheric aerosol model is developed that considers the subsequent perturbations caused by including the expected space shuttle particulate effluents. Two approaches to the basic modeling effort were made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other approach very few simplifications were made and a computer technique was used to solve the equations. The most complex form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. Results of the perturbation calculations show that there will probably be an immeasurably small increase in the stratospheric aerosol concentration for particles larger than about 0.15 micrometer radius.

Rosen, J. M.↗
NASA NTRS1979

Lidar backscattering measurements of background stratospheric aerosols

A comparative lidar-dustsonde experiment was conducted in San Angelo, Texas, in May 1974 in order to estimate the uncertainties in stratospheric-aerosol backscatter for the NASA Langley 48-inch lidar system. The lidar calibration and data-analysis procedures are discussed. Results from the Texas experiment indicate random and systematic uncertainties of 35 and 63 percent, respectively, in backscatter from a background stratospheric-aerosol layer at 20 km.

Remsberg, E. E.↗
NASA NTRS1978

Stratospheric ozone measurement with an infrared heterodyne spectrometer

A stratospheric ozone absorption line in the 10 micron band was measured and resolved completely, using an infrared heterodyne spectrometer with a spectral resolution of 5 MHz. The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectra line profile. The absolute total column density was 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) - (7,1,7) O3 line center frequency was found to be 1043.1772 plus or minus 0.00033 cm/1 or 420 plus or minus 10 MHz higher than the P(24) CO2 laser line frequency.

Abbas, M. M.↗
NASA NTRS1978

The sensitivity of a model of the ambient stratosphere to empirical inputs

The usefulness of a general application of sensitivity studies to the modeling of the ambient stratosphere using the GSFC steady-state photochemistry model is examined. The comparison of theoretical model results with field measurements of trace species is used to assess the applicability of the model to the stratosphere, to help determine the eddy diffusion profile, and to validate mechanisms within the photochemistry of the model. Specific examples of each are discussed and the results of a comprehensive sensitivity study used to elucidate certain points about the comparison are analyzed.

Butler, D. M.↗