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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Chemisorption of CO on Pd particles supported on mica

A UHV technique is presented for evaluating the adsorption-desorption properties of UHV vapor-deposited metal particles supported on insulating substrates. Desorption studies of CO from particulate and continuous Pd films supported on mica were performed. The desorption results indicate that: the CO desorption energies from the deposited metals are much lower than those from bulk single crystals; two desorption states exist for the vapor-deposited films; and the lower energy desorption peak of the vapor-deposited films is coverage dependent. Possible reasons for the difference between previously reported CO desorption studies on bulk substrates and the present results are discussed.

Thomas, M.↗
NASA NTRS1977

Shock glass veins in some lunar and meteoritic samples - Their nature and possible origin

Glassy veinlets, 15 microns to 1 mm thick and now in part devitrified, cut through breccias 67915, 67936, and 67955 from Outhouse Rock, and similar veins have been found in several other lunar samples and in meteorites. The veins have features suggesting injection of extremely hot material, possibly at several thousands degrees of superheat, presumably from an impact event. The vein compositions are very similar but not identical to the bulk compositions of the host rocks. Two mechanisms of injection are considered feasible-injection of hot liquid and injection of hot particulate matter (resembling a 'fluidized bed'), but neither mechanism fully explains all details of the occurrences.

Roedder, E.↗
NASA NTRS1978

Controlled vapor growth of small particles of Pd and Fe on thin Al2O3 substrates

An exploratory study, dealing with the preparation of well-defined particulate metal deposits that can be used in model studies of catalytic reactions, was performed. Small metal particles of Fe and Pd were grown in situ in an electron microscope by vapor deposition onto different phase of electron transparent alumina substrates. The results show that characteristic properties of the deposits, such as particle density, size distribution, habit, and orientation, are strongly dependent on the cleanliness, phase, and crystallographic orientation of the alumina substrate; also, the deposition conditions can be chosen in such a way as to reproducibly manipulate the overall deposit structure.

Poppa, H.↗
NASA NTRS1978

A steady-state stratospheric aerosol model

This paper deals with the development of a one-dimensional steady-state stratospheric aerosol model and the subsequent perturbations caused by including the expected Space Shuttle particulate effluents in the model. Two approaches to the basic modeling effort have been made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other, very few simplifications were made and a computer technique was used to solve the equations. The most complete form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. The results indicate that the model is capable of describing many aspects of the stratospheric aerosol layer, such as size distribution and the vertical profile of particles greater than 0.3 micron diameter.

Rosen, J. M.↗
NASA NTRS1978

Carbon suboxide polymer, an explanation for the wave of darkening on Mars

The carbon suboxide thermal polymer or its irradiated product is affected by water vapor. The polymerized carbon suboxide simulates the Martian wave of darkening on the inner wall of a glass tube when humidified by passage of water vapor through the tube. The polymer was visibly darkened by the advancing vapor front. With increasing polymer thickness and/or water vapor concentration the wave of darkening similarly intensifies simulating the dark fringe in the Martian circumpolar areas. Surfaces are lightened constantly being renewed by particulate material settling from the atmosphere. It is hypothesized that light and dark areas have polymer coatings, but light areas have small particles which scatter white light more effectively and appear brighter on the surface of Mars.

Oyama, V. I.↗
NASA NTRS1978

Forwardscattering corrections for optical extinction measurements in aerosol media. II - Polydispersions

The paper presents a parametric study of the forwardscattering corrections for experimentally measured optical extinction coefficients in polydisperse particulate media, since some forward scattered light invariably enters, along with the direct beam, into the finite aperture of the detector. Forwardscattering corrections are computed by two methods: (1) using the exact Mie theory, and (2) the approximate Rayleigh diffraction formula for spherical particles. A parametric study of the dependence of the corrections on mode radii, real and imaginary parts of the complex refractive index, and half-angle of the detector's view cone has been carried out for three different size distribution functions of the modified gamma type. In addition, a study has been carried out to investigate the range of these parameters in which the approximate formulation is valid. The agreement is especially good for small-view cone angles and large particles, which improves significantly for slightly absorbing aerosol particles. Also discussed is the dependence of these corrections on the experimental design of the transmissometer systems.

Deepak, A.↗
NASA NTRS1976

Energy Conservation Alternatives Study (ECAS): Conceptual Design and Implementation Assessment of a Utility Steam Plant with Conventional Furnace and Wet Lime Stack Gas Scrubbers

A study was performed to estimate the technical/economic characteristics of a steam power plant (3500 pounds per square inch gauge, 1000 degrees Fahrenheit / 1000 degrees Fahrenheit) with a coal-burning radiant furnace and a wet lime stack gas scrubber to control sulfur emissions. Particulate emissions were controlled by an electrostatic precipitator operating at 300 degrees Fahrenheit. The stack gas from the scrubber was reheated from 125 degrees Fahrenheit to 250 degrees Fahrenheit as a base case, and from 125 degrees Fahrenheit to 175 degrees Fahrenheit as an alternate case. The study was performed on a basis consistent with the General Electric ECAS Phase II evaluation of advanced energy conversion systems for electric utility baseload applications using coal or coal-derived fuels. A conceptual design of the power plant was developed, including the on-site calcination of limestone to lime and the provision of sludge ponds to store the products of flue gas scrubbing. From this design, estimates were derived for power plant efficiency, capital cost, environmental intrusion characteristics, natural resource requirements, and cost of electricity at an assumed capacity factor of 65 percent. An implementation assessment was performed where factors affecting applicability of the conceptual design power plant in electric utility generation systems were appraised. At 250 degrees Fahrenheit and 175 degrees Fahrenheit stack gas temperatures respectively, the plants showed a cost of electricity of 39.8 and 37.0 mills per kilowatt-hours and overall plant efficiencies of 32 percent and 34 percent.

Brown, Dale H.↗
NASA NTRS1979

Controlled metal-film deposition on alumina substrates

Report describes results of investigation of preparation, nucleation and controlled growth of particulate deposits (palladium and iron) on electron-transparent alumina substrates. Results indicate that characteristic properties of metal deposits are strongly dependent on cleanliness, phase, and crystallographic orientation of substrate.

Lee, E. H.↗
NASA NTRS1978

Studies of satellite and planetary surfaces and atmospheres

Completed or published research supported by NASA is summarized. Topics cover limb darkening and the structure of the Jovian atmosphere; the application of generalized inverse theory to the recovery of temperature profiles; models for the reflection spectrum of Jupiter's North Equatorial Belt; isotropic scattering layer models for the red chromosphore on Titan; radiative-convective equilibrium models of the Titan atmosphere; temperature structure and emergent flux of the Jovian planets; occultation of epsilon Geminorum by Mars and the structure and extinction of the Martian upper atmosphere; lunar occultation of Saturn; astrometric results and the normal reflectances of Rhea, Titan, and Iapetus; near limb darkening of solids of planetary interest; scattering light scattering from particulate surfaces; comparing the surface of 10 to laboratory samples; and matching the spectrum of 10: variations in the photometric properties of sulfur-containing mixtures.

Sagan, C.↗
NASA NTRS1979

Launch vehicle effluent measurements during the May 12, 1977, Titan 3 launch at Air Force Eastern Test Range

Airborne effluent measurements and cloud physical behavior for the May 21, 1977, Titan 3 launch from the Air Force Eastern Test Range, Fla. are presented. The monitoring program included airborne effluent measurements in situ in the launch cloud, visible and infrared photography of cloud growth and physical behavior, and limited surface collection of rain samples. Airborne effluent measurements included concentrations of HCl, NO, NOx, and aerosols as a function of time in the exhaust cloud. For the first time in situ particulate mass concentration and aerosol number density were measured as a function of time and size in the size range of 0.05 to 25 micro meters diameter. Measurement results were similar to those of earlier launch monitorings. Maximum HCl and NOx concentrations ranged from 10 ppm and 500 ppb, respectively, several minutes after launch to about 1 ppm and 100 ppb at 45 minutes after launch.

Gregory, G. L.↗
NASA NTRS1979

Launch vehicle effluent measurements during the August 20, 1977, Titan 3 launch at Air Force Eastern Test Range

Airborne effluent measurements within the launch cloud and visible and infrared measurements of cloud physical behavior are discussed. Airborne effluent measurements include concentrations of HCl, Cl2, NO, NOX, and particulates as a function of time during each sampling pass through the exhaust cloud. The particle size distribution was measured for each pass through the cloud. Mass concentration as a function of particle diameter was measured over the size range of 0.05- to 25 micron diameter, and particle number density was measured as a function of diameter over a size range of 0.5 to 7.5 micron. Effluent concentrations in the cloud ranged from about 30 ppm several minutes after launch to about 1 to 2 ppm at 100 minutes. Maximum Cl2 concentrations were about 40 to 55 ppb and by 20 minutes were less than 1.0 ppb. A tabulated listing of the airborne data is given in the appendix. Usable cloud imaging data were limited to the first 16 minutes after launch.

Woods, D. C.↗
NASA NTRS1978

Optical effects module

The possible degradation of optical samples exposed to the effluent gases and particulate matter emanating from the payload of the space transportation system during orbital operations may be determined by measuring two optical parameters for five samples exposed to this environment, namely transmittance and diffuse reflectance. Any changes detected in these parameters as a function of time during the mission are then attributable to surface contamination or to increased material absorption. These basic functions are attained in the optical effects module by virtue of the following subsystems which are described: module enclosure; light source with collimator and modulator; sample wheel with holders and rotary drive; photomultipliers for radiation detection; processing and sequencing electronic circuitry; and power conditioning interfaces. The functions of these subsystems are reviewed and specified.

Source record↗
NASA NTRS1979

Building penetration analysis

The airborne exposure to carbon fibers experienced within a building may be substantially less than that outside the building. By their very nature, buildings provide a barrier to the free flow of airborne particulate contaminants through the air space they occupy. The objective of this report is an evaluation of the degree to which buildings and other structures will attenuate potential exposures to carbon fibers. Most if not all types of buildings, and all phenomena which may influence the extent to which fibers in outdoor air can penetrate structures are addressed.

Source record↗
NASA NTRS1977

Airborne particle monitoring by electrostatic precipitation

For qualitative analysis of atmospheric particulates by microscopy, the sampling device should preserve the particles in the state existing at the moment of capture. A collector is described that uses electrostatic precipitation to capture and disperse specimens on various substrates for direct insertion into microscopes. Sampling runs in various atmospheres are described. Micrographs are presented to show particle morphology and distribution on the substrates. Chemical identification by X-ray energy probe and electron diffraction is illustrated.

Robinson, J. C.↗
NASA NTRS1979

Development of a model and computer code to describe solar grade silicon production processes

Mathematical models, and computer codes based on these models were developed which allow prediction of the product distribution in chemical reactors in which gaseous silicon compounds are converted to condensed phase silicon. The reactors to be modeled are flow reactors in which silane or one of the halogenated silanes is thermally decomposed or reacted with an alkali metal, H2 or H atoms. Because the product of interest is particulate silicon, processes which must be modeled, in addition to mixing and reaction of gas-phase reactants, include the nucleation and growth of condensed Si via coagulation, condensation, and heterogeneous reaction.

Srivastava, R.↗
NASA NTRS1979

Electron Spectroscopy for Chemical Analysis (ESCA) study of atmospheric particles

The results of analyses by ESCA (Electron Spectroscopy for Chemical Analysis) on several Nuclepore filters which were exposed during air pollution studies are presented along with correlative measurements by Neutron Activation Analysis and Scanning Electron Microscopy. Samples were exposed during air pollution studies at Norfolk, Virginia and the NASA Kennedy Space Center (KSC). It was demonstrated that with the ESCA technique it was possible to identify the chemical (bonding) state of elements contained in the atmospheric particulate matter collected on Nuclepore filters. Sulfur, nitrogen, mercury, chlorine, alkali, and alkaline earth metal species were identified in the Norfolk samples. ESCA binding energy data for aluminum indicated that three chemically different types of aluminum are present in the launch and background samples from NASA-KSC.

Dillard, J. G.↗
NASA NTRS1978

The Texaco coal gasification process for manufacture of medium BTU gas

The development of the Texaco coal gasification process is discussed with particular emphasis on its close relationship to the fully commercialized Texaco synthesis gas generation process for residual oil gasification. The end uses of the product gas are covered, with special attention to electric power generation via combined cycle technology. Control of SO2, NOx, and particulate emissions in the power generating mode is also covered. The application of this technology in a proposed Texaco-Southern California Edison demonstration project is mentioned. Investment information released for a 1000-megawatt advanced combined cycle gasification facility, is also reviewed.

Schlinger, W. G.↗
NASA NTRS1979

The role of NaCl in flame chemistry, in the deposition process, and in its reactions with protective oxides as related to hot corrosion

Sodium chloride is believed to be the primary source of turbine engine contamination that contributes to hot corrosion. The behavior of NaCl-containing aerosols ingested with turbine intake air is very complex; some of the NaCl may vaporize during combustion while some may remain as particulates. The NaCl can lead to Na2SO4 formation by several possible routes or it can contribute to corrosion directly. Hydrogen or oxygen atom reaction with NaCl(c) was shown to result in the release of Na(g). Gaseous NaCl in flames can be partially converted to gaseous Na2SO4 by homogeneous reactions. The remaining gaseous NaCl and other Na-containing molecules can act as sodium carriers for condensate deposition of Na2SO4 on cool surfaces. A frozen boundary layer theory was developed to predict the rates of deposition. The condensed phase NaCl can be converted directly to condensed Na2SO4 by reaction with sulfur oxides and O2. Reaction of gaseous NaCl with Cr2O3 results in the vapor phase transport of chromium by the formation of complex Cr-containing gaseous molecules. Similar gaseous complexes are formed with molybdenum. The presence of gaseous NaCl was shown to affect the oxidation kinetics of Ni-Cr alloys. It also causes changes in the surface morphology of Al2O3 scales formed on Al-containing alloys.

Kohl, F. J.↗