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At least 1,099 records · Page 61

Experimentally reproduced textures and mineral chemistries of high-titanium mare basalts

Many of the textures, morphologies, and mineral chemistries of the high-titanium mare basalts have been experimentally duplicated using single-stage cooling histories. Lunar high-titanium mare basalts are modeled in a 1 m thick gravitationally differentiating flow based on cooling rates, thermal models, and modal olivine contents. The low-pressure equilibrium phase relations of a synthetic high-titanium basalt composition were investigated as a function of oxygen fugacity, and petrographic criteria are developed for the recognition of phenocrysts which were present in the liquid at the time of eruption.

Usselman, T. M.↗

Lunar petrogenesis in a well-stirred magma ocean

The principal group of low-KREEP highlands rocks as indicated by quartz-olivine-anorthite pseudoternary phase diagrams shows chemical trends which violate the Bowen reaction principle, in that the greater the concentration of magnesian and mafic minerals, the more sodic the coexisting plagioclase tends to be. It is suggested that this trend was established during the primary differentiation of the lunar crust and is a result of crystallization in a vigorously convecting (well-stirred) system. Under these conditions all plagioclase crystals, all pyroxene crystals, and all of the residual liquid remain fairly uniform in composition until advanced crystallization immobilizes the system. The rock suite then established would vary continuously from anorthositic types at the top to ultramafic types at the bottom.

Wood, J. A.↗

Evolution of the lunar highland crust

The evolution of three distinct element associations in the lunar highland crust is discussed in terms of the Taylor-Jakes model which involves melting of most of the moon during accretion. Sources for (1) high Ca, Al, Sr, Eu, (2) high Mg and Cr, and (3) high K, REE, Zr, Hf, Nb are suggested. Bombardment by large projectiles during the differentiation process causes melting and mixing, which produces a wide range of compositions in the crust. The formation of dunite, troctolite, high-, medium-, and low-K Fra Mauro basalts, and rocks close to the olivine-spinel-plagioclase peritectic point is considered.

Taylor, S. R.↗

Volatiles on the surface of Apollo 15 green glass and trace-element distributions among Apollo 15 soils

Zn, Ge, Cd, In, and Au have been detected in surficial deposits on Apollo 15 green-glass spherules, and it is suggested that these deposits are condensates from the magmatic gas phase which was responsible for the pneumatic expulsion of the green glass from the lunar interior. Thermodynamic data indicate that chlorides and fluorides were the dominant forms of the volatile metals. The Ar-40x content of a nongreen-glass soil fraction is greater than that found in green-glass. Mare and low-K Fra Mauro basalts seem to be the most prominent components of Apollo 15 soil. The correlation of Zn with Ar-40x and with Pb-204 is studied, and the distribution of quartz-normative and olivine-normative basalts is considered.

Chou, C.-L.↗

Microcrater investigations on lunar rock 12002

Relative ages of 26 submillimeter-sized pits from an equilibrium population in rock 12002 were measured by determining the densities of pits 0.7 microns in diameter and larger on the submillimeter-sized pits. Production rates for 0.7 micron diameter pits were determined from solar-flare track exposure age measurements, and the data for rock 12002 are consistent with previously obtained data for sample 15205 if a lower meteoroid flux prevailed in the past. Metal mounds or spherules within a microcrater pit glass were found to have a meteoritic composition, and an impact lining consisting of protruding crystals was observed. The crystals apparently developed during exposure to space immediately after the 200-micron diameter pit was formed by impact into an olivine grain.

Hartung, J. B.↗

Track studies bearing on solar-system regoliths

The paper reports a comparative study of solar-flare tracks and other microscopic features in unmetamorphosed lunar breccias, carbonaceous chondrites, and noncarbonaceous gas-rich meteoritic breccias. The data suggest that these objects originated from material once on and just below the surface of solar-system regoliths. Characteristics of these regoliths are discussed with reference to the track-rich olivines in Orgueil and the impregnated Apollo 16 deep drill core. The use of a variant of the fission-track method to determine the time of compaction of soil grains into a breccia is explained.

Price, P. B.↗

The Galatia, Kansas, chondrite

The paper describes the Galatia meteorite found August 1971 approximately 7 km ENE of Galatia, Barton County, Kansas (98 deg 53 min W, 38 deg 39.5 min N). The single stone weighed 23.9 kg and is partially weathered. Olivine (Fa 24.9) and pyroxene (Fs 20.9) compositions indicate L-group classification, and textural observations indicate that the stone is of petrologic type 6. While Galatia is similar in many respects to the Otis L6 chondrite found 20 miles to the west, Galatia does not have the brecciated structure of Otis and is therefore not part of the same fall.

Van Schmus, W. R.↗

The Chassigny meteorite - A cumulate dunite with hydrous amphibole-bearing melt inclusions

The Chassigny meteorite, an iron-rich dunite (Fo 68), is a moderately shocked olivine achondrite or chassignite with features indicative of a cumulate origin with some subsolidus annealing. The evidence that the meteorite experienced shock pressures of approximately 150-200 kbar is described. Kaersutitic amphibole, found only in melt inclusions, represents the first extraterrestrial occurence of hydrous amphibole and the first meteoritic amphibole type other than fluorichterite. Fractionation data indicate that Chassigny formed under relatively more oxidizing conditions than most other achondrites, which implies that its parental melt could not have been directly derived from a chondritic composition in a simple single-stage process. Similarities and differences with the Brachina meteorite, the only other meteorite of the Chassigny type, are considered.

Floran, R. J.↗

Infrared spectra of lunar soils

Measured data obtained by Michelson interferometer spectrometer were stored in a computer file and smoothed by being passed forward and backward through a digital four-pole low pass filter. Infrared spectra of the 10 lunar samples are presented in the format of brightness temperature versus frequency. The mol % of feldspar, pyroxene, olivine, ilmenite and ferromagnetic silicate in each sample is presented in tables. The reflectance spectra of ilmenite and enstatite are shown in graphs.

Aronson, J. R.↗

Fluorescent accessory phases in the carbonaceous matrix of ureilites

The carbonaceous matrix of ureilite meteorites (C-bearing olivine-pigeonite achondrites) contain abundant minute phases that emit a multicolored fluorescence under electron bombardment. These include NaCl and KCl, found in all seven ureilites studied, high-Si glass with pyroxene and chlorapatite quench crystals in North Haig, an unidentified high-Ca-Al-Cl phase in Novo Urei, and possibly free SiO2 in Novo Urei and Dingo Pup Donga. The origin of these phases is uncertain but some, especially chlorides and glass, may represent residual postcumulus materials precipitated from a late-stage interstitial liquid during the igneous phase of ureilite history.

Berkley, J. L.↗

Thermal metamorphism of primitive meteorites. VII - Mineralogy-petrology of heated Murchison /C2/ and alteration of C30 and other chondrites

Alterations caused by week-long heating of Murchison in a low-pressure environment at 400-1400 C are of two types: thermodynamically favored kinetically controlled or thermodynamically controlled rapid processes. Kinetically controlled changes pertinent to chondritic evolution and which vary progressively with temperature in heated Murchison include: chondrule blurring; matrix coarsening; increasing mean Fa and Fs contents of ferromagnesian silicates; equilibration of olivine; increasing Mg/Si, Ca/Si, Al/Si, and Cr/Si and decreasing Fe/Si, Ni/Si, and S/Si in matrix; Cr loss from kamacite; and homogenization and Ni-zoning in taenite at high temperatures. Low-temperature thermodynamically controlled changes include: transformation of high-Ni troilite to low-Ni and formation of Ni- and Co-rich metal from pentlandite. High-temperature changes include formation of Cr-rich magnetite and formation of a Ni-rich sulfide similar to that found in highly altered chondrites. Trends resulting from processes of both kinds in Murchison are consistent with characteristics of a postulated C30 metamorphic suite, while those changes caused by reactions of the second kind are similar to those in heavily shock-heated ordinary chondrites and the heavily metamorphosed C5-6 chondrite, Mulga West. Either the simulations support the metamorphic origin of the C30 suite and other thermally induced changes or the natural alterations support the utility of laboratory simulations in studying meteoritic evolution.

Matza, S. D.↗

The chaotic solar nebula - Evidence for episodic condensation in several distinct zones

Abundances of rare earth elements in Allende inclusions are considered along with the rim sequence on coarse-grained chondrules. It is found that in at least several zones the nebula went through episodes of condensation and gas/grain separation. Four separate zones are required to make the two types of fine-grained aggregates and the two types of coarse-grained chondrules. Other types of inclusions in Allende, such as the olivine aggregates, may well require additional condensation zones. All of these conclusions are based on data from one meteorite. Although the details of the gas/grain separation mechanism in these zones is not well understood, it is clear that a single monotonic-cooling condensation sequence followed by isolation of grains from gas cannot account for the observations.

Boynton, W. V.↗

The Shaw meteorite - History of a chondrite consisting of impact-melted and metamorphic lithologies

Three intermingled lithologies are identified in the Shaw L-group chondrite: a light-colored lithology with a poikilitic texture, consisting of olivine and augite crystals surrounded by larger orthopyroxene grains; a dark-colored lithology containing remnant chondrules and exhibiting a microgranular texture; and a gray lithology which appears to be intermediate between the other two. Contrary to published opinions, the Shaw meteorite contains normal L-group chondrite abundances of metal and troilite, though these phases are irregularly distributed. The lithological analyses suggest that 4.52 Byr ago an impact took place on the L-group chondrite parent object of Shaw.

Taylor, G. J.↗

From Serenity to Langemak - A regional chemical setting for Mare Crisium

The chemistry of the region surrounding Mare Crisium is described using improved Al/Si and Mg/Si intensity ratios derived from Apollo 15 X-ray fluorescence measurements. Mg/Si ratios are shown to increase from 0.6 in the region east of Mare Smythii to 1.0 in western Mare Serenitatis, while Al/Si ratios show sharp decreases in all mare areas. It is concluded that the terra (nonmare) material has a uniform Al/Si ratio, hence plagioclase content, and increases in the Mg/Si ratio in terra material imply similar increases of Mg in the pyroxenes and olivines of this material. The observed diversity of terra soils can be explained by an originally chemically diverse region not homogenized by heavy bombardment, or by volcanism subsequent to bombardment. Maria Crisium, Serenitatis and Smythii are found to be filled with low albedo materials which have a wide range of Mg/Si values, with small and apparently consistent differences in Al/Si ratio.

Hubbard, N. J.↗

Grain size and the evolution of Luna 24 soils

The grain size distribution of six Luna 24 samples has been determined. These samples are characterized by a bimodal distribution which is indicative of soils formed primarily by mixing rather than by reworking. Although agglutinate content decreases with depth, it is not likely that the Luna 24 soils have undergone appreciable in situ reworking. Particle types and abundances in each of four size fractions have been determined petrographically. Mineral fragments are very abundant in all analyzed size fractions. Pyroxene and plagioclase increase slightly in abundance at finer grain sizes, but olivine decreases significantly. Compared with typical mare soils, the Luna 24 trends are anomalous. They are compatible with the hypothesis than many, if not most, of the mineral grains in the 20-250-micron fractions come from coarse-grain rocks having average mineral grain sizes greater than 250 microns. The mineralogy and chemistry of the coarse-grained rocks has not been well characterized, but there is evidence that at least some of them are higher in MgO than the analyzed finer-grained basalts.

Mckay, D. S.↗

Glasses in the Luna 24 core and petrogenesis of ferrobasalts

Modal abundance and major- and minor-element chemical analysis of homogeneous, non-agglutinitic mare and non-mare glasses from the Luna 24 drill core show that most glasses can be related to known rock types. Mare glasses include: brown glass identical in composition to the fine-grained low-Mg VLT basalt; green glass which might be related to a coarser-grained ferrogabbro; a high-K green glass; and a high-Ti orange glass. Highland glass compositions include Highland basalt, gabbroic anorthosite, and pure anorthosite (i.e. plagioclase); minor Fra Mauro-type glass may also be present. It is apparent that fractional crystallization of some primitive basaltic magma occurred at Mare Crisium producing a chemically evolved ferrobasalt and related glasses. An early, high-Mg basin fill, as represented by the olivine vitrophyres, may be the parent magma. Subsequent near-surface fractionation produced a multiply-saturated liquid that finally erupted as the ferrobasalt flows sampled by Luna 24.

Norman, M.↗

On the origin of Luna 24 basalts and soils

Analyses of fine-grained very low titanium (VLT) basalt from the Luna 24 drill core suggest that a single homogeneous magma is represented by the sample. In particular, the small variation in MgO contents of the fine-grained basalt, together with the tight clustering of the compositions of brown glasses (which may be pyroclastic equivalents of the VLT basalt), provides evidence for the single-magma hypothesis. The high-Mg component in the soil samples, though not obviously explainable in petrographic terms, may be derived from material similar to olivine vitrophyre and its degraded products, or from some other high-Mg VLT basalt.

Ryder, G.↗

VLT mare basalts - Impact mixing, parent magma types, and petrogenesis

Available major-element compositions of very low-Ti (VLT) mare basalt lithic fragments and glasses are examined. Many of the lithic fragments contain relic mineral and sometimes lithic clasts, which suggests that many samples of VLT mare basalt glasses and lithic fragments were formed by impact melting. Therefore, some may have compositions that represent mixtures of VLT mare basalts and other types of rocks, not authentic igneous rock compositions. In spite of this problem, a number of possible parent magma compositions are identified. These hypothetical magmas vary in CaO/Al2O3(0.9-1.1), FeO (17 to 24 wt. %), Fe/(Fe + Mg) (0.34-0.46), and K2O (0-0.2 wt. %). Each may have differentiated to produce a wide variety of derivative magmas. Calculations involving olivine fractionation from the proposed parent magmas indicate the Luna 24 ferrobasalts might have formed from a magma whose composition is similar to that of a group of high-MgO (about 13-14 wt. %) Apollo 17 VLT mare basalt glasses.

Taylor, G. J.↗