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At least 1,099 records · Page 61

Force-triggered, Bio-based, Sealants for Prefabricated Building Components: Towards Improved Efficiency, Performance and Sustainability

The prefabricated building construction industry has made extensive progress in expediting the manufacture of prefabricated components at offsite plants. However, this progress has not translated to the assembly of the prefabricated components at the construction site. Case in point, sealing the joints between components to prevent air leaks requires the manual application of tape, caulk, or spray foam at the jobsite, and performance is highly dependent on the skills of the installer. To reduce assembly time and improve the airtightness and waterproofness of prefabricated components, we developed a sealant that can be installed at the plant and have its curing reaction triggered at the jobsite. Additionally, we used this opportunity to explore the use of bio-based feedstocks that are abundant and not used for food. We evaluated a series of force-triggered, bio-based, high strength, and fast curing sealants, consisting of a one-part heterogeneous system. These sealants are derived from formulations with ≥80% of bio-based components, consisting of a cardanol derived diepoxy that is microencapsulated in a polymer shell and embedded in a cardanol derived amine curing agent. The microcapsule shell allows separation of the reactive species in the one-part sealant allowing a fast-curing system to remain unreacted until the right trigger is applied. When the microcapsules are activated and broken by force, the highly reactive species mix and cure, exhibiting peel strengths up to 143 ppi. The open-air shelf stability of the sealant complexes was demonstrated by peel strength values of ~16 ppi when triggering the curing reaction even after being exposed for 8 months to open air and humidity. The successful on-demand triggering of curing reactions and the shelf stability provide efficacy of these force-triggered sealants for installation on prefabricated components, storage for months prior to delivery, and assembly at the jobsite. These force-triggered bio-based sealants for prefabricated buildings could result in lower installation time and cost as well as better performance than tapes and caulks at the jobsite.

Cortes Guzman, Karen [ORNL] (ORCID:000000028793468↗

Late-life restoration of mitochondrial function reverses cardiac dysfunction in old mice

Diastolic dysfunction is a prominent feature of cardiac aging in both mice and humans. We show here that 8-week treatment of old mice with the mitochondrial targeted peptide SS-31 (elamipretide) can substantially reverse this deficit. SS-31 normalized the increase in proton leak and reduced mitochondrial ROS in cardiomyocytes from old mice, accompanied by reduced protein oxidation and a shift towards a more reduced protein thiol redox state in old hearts. Improved diastolic function was concordant with increased phosphorylation of cMyBP-C Ser282 but was independent of titin isoform shift. Late-life viral expression of mitochondrial-targeted catalase (mCAT) produced similar functional benefits in old mice and SS-31 did not improve cardiac function of old mCAT mice, implicating normalizing mitochondrial oxidative stress as an overlapping mechanism. These results demonstrate that pre-existing cardiac aging phenotypes can be reversed by targeting mitochondrial dysfunction and implicate mitochondrial energetics and redox signaling as therapeutic targets for cardiac aging.

59 BASIC BIOLOGICAL SCIENCES↗

NREL 25-cm2 High-Pressure Low-Temperature Electrolysis Cell Hardware (Open Source)

This data resource describes an open-source cell hardware that enables low temperature electrolysis (LTE) testing at elevated pressures. Existing commercial options have several downsides when it comes to R&D testing. They are often not designed for repeated reassembly, may not be able to accommodate porous transport layers with different thicknesses, and do not give state-of-the-art performance. Therefore, this hardware was developed specifically with LTE R&D in mind and its design is being made available to the global LTE community. This work was planned and funded by the U.S. Department of Energy's H2NEW consortium (https://h2new.energy.gov/). The hardware design package (.zip file) details the drawings, auxiliary materials, and procedures required to fabricate, assemble, and operate the National Renewable Energy Laboratory's (NREL's) high-pressure low-temperature electrolysis cells. While the hardware itself—end plates, current collectors, flow fields, bolts and washers, tube fittings—is always the same, the assembly and operating procedures may change depending on the active materials being tested, especially for the membrane. Material-specific assembly and operating procedures will be posted to the H2NEW website as they are developed and validated. Disclaimer: The documents and drawings included in this download package describe a design for a low temperature electrolysis hardware that is intended to comply with leak testing according to ASME B31.1. Safe operation at ambient and elevated pressures is the sole responsibility of the end user, which should be evaluated on a case-by-case basis for each individual cell. Factors affecting the sealing capability may depend on, for example, machining quality, cell assembly components, operating conditions, and operating history. Operation at pressure should only be performed on qualified test stands by qualified operators. NREL/ALLIANCE FOR SUSTAINABLE ENERGY, LLC/DOE DISCLAIM ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING THE WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, AND MAKES NO WARRANTY AS TO THE ACCURACY, COMPLETENESS, OR USEFULNESS OF ANY INFORMATION PROVIDED HEREIN. USE OF THIS PACKAGE IS AT THE USER’S OWN RISK.

08 HYDROGEN↗

ANALYSIS OF CRYOGENIC PROPELLANT FEED SYSTEMS FOR ELECTROTHERMAL ENGINES.

An analytical investigation was made of the problems associated with the long-term storage and control of flow of cryogenic propellants for electrothermal engines. Storage of 35 to 174 pounds of propellant for three years is made difficult by the high ratio of surface area to storage tank volume, and the resulting high rate of heat leak. Vented and non-vented storage, storage as high pressure gas, and the use of refrigeration were considered. Recommended storage methods are: for ethane and ammonia vented storage - by venting propellant stored in excess of mission requirements; for hydrogen and helium - by non-vented storage of cold supercritical vapor; and for methane by storage as a non-vented two-phase mixture. The optimum propellant density in the storage tank and optimum insulation thickness were also determined. Design charts were developed for hydrogen and helium, for estimating the maximum pressure expected in non-vented storage tanks, as function of mission requirements. Separation of the constituent phases of liquid-vapor mixtures is achieved by throttling the two-phase mixture to a lower pressure (and temperature) and vaporizing the liquid in the mixture by heat exchange with the contents of the storage tank. The time limitations for continuous use of this method are discussed. Linde super insulations SI-44 or SI -91 are recommended for insulation. Precooling the insulation to temperatures below the steady state level with cold helium vapor before or during fueling of the storage tank eliminates the flow of heat to the tank contents during countdown and take-off. The masses, sizes, and power requirements of the recommended systems are low. The controls are simple and reliable. From the equations and charts in this report the components of the system for a particular mission can be sized. Recommendations are given for experimental work required for the development and testing of such components.

ELECTROTHERMAL ENGINE↗

Proposal for Determining the Mass of Liquid Propellant Within a Space Vehicle Propellant Tank Subjected to a Zero Gravity Environment

A liquid propellant mass measurement system is proposed for the zero gravity environment. The known thermodynamic relationships for the liquid propellant and helium gas concomitant with state of the art instrumentation are used to provide a system comparable with present day terrestrial mass measuring systems. In particular, the operation of the system is outlined for the propellant transfer method and for the determination of leaks and leakage rates. A second concept which is a simplified version of the proposed mass measurement system is introduced and discussed.

PROPELLANT TANK↗

Feasibility of liquid-metal vacuum seals

A basic component of any ultrahigh-vacuum system is a seal capable of isolating a test chamber from its higher pressure surroundings. Two of the most common vacuum seals now in use are the elastomer O-ring seal and the metallic shear seal. The former has the problem of outgassing and gas permeation; the latter requires a large force per unit seal-length to maintain the sealing action. The search for a seal which would provide minimal virtual and real leak rates in a chamber, without requiring a large force to consummate the seal, led to investigation of a liquid-metal seal.

SEALANT↗

Mount makes liquid nitrogen-cooled gamma ray detector portable

Liquid nitrogen-cooled gamma ray detector system is made portable by attaching the detector to a fixture which provides a good thermal conductive path between the detector and the liquid nitrogen in a dewar flask and a low heat leak path between the detector and the external environment.

Fessler, T. E.↗

Soft-seal valve holds hazardous fluids safely

Valve assembly allows transfer of hazardous or reactive fluids such as liquid fluorine without corrosion of valve face and seat material. The assembly consists of a plug to block bulk flow and a soft-seal outer seat to effect zero-leak stoppage.

Source record↗

Expandable rubber plug seals openings for pressure testing

Plug assembly seals openings in piping systems, vessels, and chambers for low pressure leak testing. The assembly, which consists of a rubber sealing plug and the mechanism for expanding it into a pressure-tight configuration, adequately seals irregular diameters without damage to mating surfaces.

Source record↗

Closed loop operation eliminates need for auxiliary gas in high pressure pumping station

Closed loop system for a liquid nitrogen high pressure pump feeds back gaseous nitrogen generated by heat leak into the reservoir to maintain the pressure in the storage tank. This safer, more efficient system eliminates the need for auxiliary gas to maintain the tank pressure and can be used on relatively high cryogenic pumping systems.

Landy, D. G.↗

Seal-off assembly permits rapid evacuation of air from containers

Seal-off assembly which permits rapid container evacuation using large diameter tubing has a vacuum valve that permits sealing plate transfer from the vacuum valve stem to the container after evacuation. The sealing plate can be reused repeatedly. This device can repump in case of a small leak without exposing the container to the atmosphere.

Demers, R. R.↗

Combination spacer and gasket provides effective static seal

Closely machined steel ring having narrow sealing lands on both faces and a thin coating of a commercially available halocarbon polymer combines the functions of a spacer and static seal ring or gasket having a minimum of potential leak paths. The device is effective over a wide range of temperatures down to minus 423 deg F and at pressure up to 180 psig.

Jones, F. B.↗

Mixer conditions temperature of liquified gas streams

Room temperature gaseous hydrogen mixed with liquified hydrogen in a venturi produces a two- phased liquid hydrogen stream at a stable temperature. This technique is useful in laboratory testing where presently, temperature control is maintained by a calibrated heat leak that results in considerable expenditure of cryogenic refrigerants.

Talmor, E.↗

Nonspace technology resulting from the NASA FLUID connector programs

Leakage at static seals is a problem common to both NASA and industry. The subject of an intensive investigation has been the establishing of design criteria for reliable, low-weight, leak-tight fluid connectors. The problem has been broken into areas of investigation: the structure which supports the actual seal and the seal itself. A Separable Connector Design Handbook has been written to direct designers' efforts toward the optimum connector design for a given purpose. Included in this paper is a brief discussion of the topics covered in the Handbook, notable flanged connector design, threaded connector design, pressure energized seal design, leakage measurement techniques, and a catalog of current satisfactory seal configurations. Also included in this paper is a discussion of the principles of sealing, including the uses and characteristics of elastomers, plastics, and metals. The load-leakage characteristics of seals, the effect of internal pressure, the effect of surface finish on the leakage rate, the mode of material deformation under load, and the advantages of various seal configurations are discussed.

Sealing↗

Special tooling for joining tubing in place

The Saturn S-II stage and the Apollo spacecraft will include in their design and construction various pressurized tubing systems that will encounter service temperatures of 280° F to -423° F. Design engineering and reliability requirements and weight restrict ions have dictated new concepts to assure leak-tight joints for rocket engine fuel lines, pressurization systems, utility systems, and hydraulic systems. An investigation was initiated at North American Aviation, Inc., Space and Information Systems Division, utilizing the in-place automatically controlled miniaturized fusion-welding equipment originally developed by the Los Angeles Division of NAA and modified to meet the needs of Apollo and Saturn welded tubular systems. The objective was to make circumferential flanged weld joints in any position in 304L stainless for Saturn S-II and sleeve-type joints in 304L for Apollo. Inconel X, commercially pure titanium, 5052-0 aluminum, and 6061 T6 aluminum were also tested experimentally. Extensive environmental, static, and dynamic testing programs were conducted to determine the as-welded mechanical properties, design allowables, and reliability for the tube joints. This paper discusses both the experimental and production phases. Subsequently, the new tube welding process was approved and incorporated into manufacturing fabrication methods for tube joining.

Saturn S-II stage↗